BR112015003762A2 - processo - Google Patents

processo

Info

Publication number
BR112015003762A2
BR112015003762A2 BR112015003762A BR112015003762A BR112015003762A2 BR 112015003762 A2 BR112015003762 A2 BR 112015003762A2 BR 112015003762 A BR112015003762 A BR 112015003762A BR 112015003762 A BR112015003762 A BR 112015003762A BR 112015003762 A2 BR112015003762 A2 BR 112015003762A2
Authority
BR
Brazil
Prior art keywords
bisphosphite
catalytic metal
psig
kpa
chelating
Prior art date
Application number
BR112015003762A
Other languages
English (en)
Other versions
BR112015003762B1 (pt
Inventor
L Watkins Avery
A Brammer Michael
B Watson Rick
Original Assignee
Dow Technology Investments Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Technology Investments Llc filed Critical Dow Technology Investments Llc
Publication of BR112015003762A2 publication Critical patent/BR112015003762A2/pt
Publication of BR112015003762B1 publication Critical patent/BR112015003762B1/pt

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

resumo “processo” a presente invenção refere-se a um processo para formar um catalisador a partir de um precursor de metal catalítico, um bisfosfito quelante e um monofosfito volumoso, com uma quantidade ligeiramente maior que a estequiométrica de quelante de bisfosfito relativamente ao metal catalítico sob uma pressão parcial de pelo menos 172 kpa (25 psig). 1/1
BR112015003762-3A 2012-08-29 2013-08-15 Processo para a formação de um catalisador de hidroformilação BR112015003762B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201261694329P 2012-08-29 2012-08-29
US61/694,329 2012-08-29
PCT/US2013/055048 WO2014035673A1 (en) 2012-08-29 2013-08-15 Catalyst preparation process

Publications (2)

Publication Number Publication Date
BR112015003762A2 true BR112015003762A2 (pt) 2017-07-04
BR112015003762B1 BR112015003762B1 (pt) 2021-04-13

Family

ID=49118766

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112015003762-3A BR112015003762B1 (pt) 2012-08-29 2013-08-15 Processo para a formação de um catalisador de hidroformilação

Country Status (12)

Country Link
US (1) US9539566B2 (pt)
EP (1) EP2890493A1 (pt)
JP (1) JP6339572B2 (pt)
KR (1) KR102131204B1 (pt)
CN (1) CN104602815B (pt)
BR (1) BR112015003762B1 (pt)
MX (1) MX360063B (pt)
MY (1) MY181661A (pt)
RU (1) RU2639874C2 (pt)
TW (1) TWI605872B (pt)
WO (1) WO2014035673A1 (pt)
ZA (1) ZA201501030B (pt)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102014209533A1 (de) * 2014-05-20 2015-12-17 Evonik Degussa Gmbh Gemische von Monophosphitligand und deren Verwendung zur Katalyse einer Hydroformylierungsreaktion
US11130725B2 (en) 2018-05-30 2021-09-28 Dow Technology Investments Llc Methods for slowing deactivation of a catalyst and/or slowing tetraphosphine ligand usage in hydroformylation processes
PL3802476T3 (pl) 2018-05-30 2022-08-08 Dow Technology Investments Llc Sposoby kontrolowania procesów hydroformylowania

Family Cites Families (41)

* Cited by examiner, † Cited by third party
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US3527809A (en) 1967-08-03 1970-09-08 Union Carbide Corp Hydroformylation process
US4148830A (en) 1975-03-07 1979-04-10 Union Carbide Corporation Hydroformylation of olefins
DE2646792C2 (de) 1975-10-23 1985-05-09 Mitsubishi Petrochemical Co., Ltd., Tokio/Tokyo Verfahren zur Herstellung einer α-(arylsubstituierten)-Propionsäure und/oder eines Esters derselben
US4247486A (en) 1977-03-11 1981-01-27 Union Carbide Corporation Cyclic hydroformylation process
US4518809A (en) 1981-06-11 1985-05-21 Monsanto Company Preparation of pentyl nonanols
US4528403A (en) 1982-10-21 1985-07-09 Mitsubishi Chemical Industries Ltd. Hydroformylation process for preparation of aldehydes and alcohols
GB8334359D0 (en) 1983-12-23 1984-02-01 Davy Mckee Ltd Process
US4599206A (en) 1984-02-17 1986-07-08 Union Carbide Corporation Transition metal complex catalyzed reactions
US4567302A (en) 1984-07-20 1986-01-28 Angus Chemical Polymeric quaternary ammonium salts possessing antimicrobial activity and methods for preparation and use thereof
US4737588A (en) 1984-12-28 1988-04-12 Union Carbide Corporation Transition metal complex catalyzed reactions
US4748261A (en) 1985-09-05 1988-05-31 Union Carbide Corporation Bis-phosphite compounds
US4668651A (en) 1985-09-05 1987-05-26 Union Carbide Corporation Transition metal complex catalyzed processes
US4885401A (en) 1985-09-05 1989-12-05 Union Carbide Corporation Bis-phosphite compounds
US4774361A (en) * 1986-05-20 1988-09-27 Union Carbide Corporation Transition metal complex catalyzed reactions
US4835299A (en) 1987-03-31 1989-05-30 Union Carbide Corporation Process for purifying tertiary organophosphites
US5113022A (en) 1988-08-05 1992-05-12 Union Carbide Chemicals & Plastics Technology Corporation Ionic phosphites used in homogeneous transition metal catalyzed processes
US5277532A (en) 1989-07-31 1994-01-11 Cefin S.P.A. Mechanical acceleration device in can welding machines
DE4026406A1 (de) 1990-08-21 1992-02-27 Basf Ag Rhodiumhydroformylierungskatalysatoren mit bis-phosphit-liganden
US5179055A (en) 1990-09-24 1993-01-12 New York University Cationic rhodium bis(dioxaphosphorus heterocycle) complexes and their use in the branched product regioselective hydroformylation of olefins
TW213465B (pt) 1991-06-11 1993-09-21 Mitsubishi Chemicals Co Ltd
US5360938A (en) 1991-08-21 1994-11-01 Union Carbide Chemicals & Plastics Technology Corporation Asymmetric syntheses
DE4204808A1 (de) 1992-02-18 1993-08-19 Basf Ag Verfahren zur herstellung von (omega)-formylalkancarbonsaeureestern
US5312996A (en) 1992-06-29 1994-05-17 Union Carbide Chemicals & Plastics Technology Corporation Hydroformylation process for producing 1,6-hexanedials
US5364950A (en) 1992-09-29 1994-11-15 Union Carbide Chimicals & Plastics Technology Corporation Process for stabilizing phosphite ligands in hydroformylation reaction mixtures
US5288918A (en) 1992-09-29 1994-02-22 Union Carbide Chemicals & Plastics Technology Corporation Hydroformylation process
BE1008017A3 (nl) 1994-01-06 1995-12-12 Dsm Nv Werkwijze voor de bereiding van 5-formylvaleriaanzure ester.
US5756855A (en) 1994-08-19 1998-05-26 Union Carbide Chemicals & Plastics Technology Corporation Stabilization of phosphite ligands in hydroformylation process
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US5741944A (en) 1995-12-06 1998-04-21 Union Carbide Chemicals & Plastics Technology Corporation Hydroformaylation processes
EP0839787A1 (en) * 1996-11-04 1998-05-06 Dsm N.V. Process for the preparation of an aldehyde
KR100732894B1 (ko) 2001-03-08 2007-06-27 미쓰비시 가가꾸 가부시키가이샤 알데히드의 제조 방법
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RU2458906C2 (ru) * 2007-03-20 2012-08-20 Дау Текнолоджи Инвестментс Ллс Способ гидроформилирования с усовершенствованным контролем над изомерами продуктов
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RU2354642C2 (ru) * 2007-06-26 2009-05-10 Общество с ограниченной ответственностью "Объединенный центр исследований и разработок" Способ получения альдегидов c3-c21
ES2446722T5 (es) 2009-12-22 2020-03-20 Dow Technology Investments Llc Control de la relación aldehído normal:isoaldehído en un proceso de hidroformilación de ligando mixto mediante el control de la presión parcial del gas de síntesis
EP2581362B1 (en) 2009-12-22 2018-01-31 Dow Technology Investments LLC Controlling the normal:iso aldehyde ratio in a mixed ligand hydroformylation process
EP2516373B2 (en) 2009-12-22 2020-08-12 Dow Technology Investments LLC Controlling the normal : iso aldehyde ratio in a mixed ligand hydroformylation process

Also Published As

Publication number Publication date
KR20150048753A (ko) 2015-05-07
WO2014035673A1 (en) 2014-03-06
JP2015532616A (ja) 2015-11-12
US9539566B2 (en) 2017-01-10
EP2890493A1 (en) 2015-07-08
JP6339572B2 (ja) 2018-06-06
CN104602815B (zh) 2017-03-01
BR112015003762B1 (pt) 2021-04-13
RU2015111174A (ru) 2016-10-20
US20150209773A1 (en) 2015-07-30
KR102131204B1 (ko) 2020-07-07
CN104602815A (zh) 2015-05-06
RU2639874C2 (ru) 2017-12-25
TW201422307A (zh) 2014-06-16
MX2015002641A (es) 2015-05-20
MX360063B (es) 2018-10-22
ZA201501030B (en) 2016-07-27
MY181661A (en) 2020-12-31
TWI605872B (zh) 2017-11-21

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Legal Events

Date Code Title Description
B06F Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]
B06U Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 15/08/2013, OBSERVADAS AS CONDICOES LEGAIS.