BR112014019467A8 - Processo para revestimento de superfícies metálicas de substratos e objetos revestidos segundo esse processo - Google Patents

Processo para revestimento de superfícies metálicas de substratos e objetos revestidos segundo esse processo

Info

Publication number
BR112014019467A8
BR112014019467A8 BR112014019467A BR112014019467A BR112014019467A8 BR 112014019467 A8 BR112014019467 A8 BR 112014019467A8 BR 112014019467 A BR112014019467 A BR 112014019467A BR 112014019467 A BR112014019467 A BR 112014019467A BR 112014019467 A8 BR112014019467 A8 BR 112014019467A8
Authority
BR
Brazil
Prior art keywords
coating
substrates
coated according
objects coated
metallic surfaces
Prior art date
Application number
BR112014019467A
Other languages
English (en)
Other versions
BR112014019467B1 (pt
BR112014019467A2 (pt
Inventor
Wasserfallen Daniel
Schwamb Michael
Frenkel Aliaksandr
Sotke Vera
Bremser Wolfgang
Droll Martin
Seewald Oliver
Eilinghoff Ron
Gerold Stephanie
Niesen Evgenija
Schachtsiek Lars
Traut Manuel
Original Assignee
Chemetall Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chemetall Gmbh filed Critical Chemetall Gmbh
Publication of BR112014019467A2 publication Critical patent/BR112014019467A2/pt
Publication of BR112014019467A8 publication Critical patent/BR112014019467A8/pt
Publication of BR112014019467B1 publication Critical patent/BR112014019467B1/pt

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/14Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
    • B05D7/142Auto-deposited coatings, i.e. autophoretic coatings
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601Process or apparatus
    • C23C18/1633Process of electroless plating
    • C23C18/1635Composition of the substrate
    • C23C18/1637Composition of the substrate metallic substrate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/14Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
    • B05D7/16Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies using synthetic lacquers or varnishes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • C09D133/14Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • C09D5/088Autophoretic paints
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601Process or apparatus
    • C23C18/1633Process of electroless plating
    • C23C18/1689After-treatment
    • C23C18/1692Heat-treatment
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/18Pretreatment of the material to be coated
    • C23C18/1803Pretreatment of the material to be coated of metallic material surfaces or of a non-specific material surfaces
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00Processes for applying liquids or other fluent materials
    • B05D1/18Processes for applying liquids or other fluent materials performed by dipping
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/14Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Paints Or Removers (AREA)
  • Chemical Treatment Of Metals (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)
  • Chemically Coating (AREA)

Abstract

PROCESSO PARA REVESTIMENTO DE SUPERFÍCIES METÁLICAS DE SUBSTRATOS E OBJETOS REVESTIDOS SEGUNDO ESSE PROCESSO. A presente invenção refere-se a um processo para revestimento de superfícies, a um revestimento correspondente assim como ao emprego de objetos revestidos segundo esse processo. De acordo com a invenção a tarefa é solucionada por um processo para revestimento de superfícies metálicas de substratos que compreendem as etapas ou que consistem nas etapas: I. preparação de um substrato com uma superfície metálica, limpa, II. contatação e revestimento de superfícies metálicas com uma composição aquosa na forma de dispersão e/ou suspensão, IX. se apropriado enxague do revestimento orgânico e X. secagem e/ou queima do revestimento orgânico ou XI. se apropriado secagem do revestimento orgânico e revestimento com uma composição de revestimento similar ou diferente, antes de uma secagem e/ou queima, formando um revestimento à base de um gel ionogênico, que liga cátions desprendidos da superfície metálica e esses cátions provém de uma etapa de tratamento prévio e/ou são provenientes da contactação na etapa II.
BR112014019467-0A 2012-02-07 2013-02-07 Processo para revestimento de superfícies metálicas de substratos e objetos revestidos segundo esse processo BR112014019467B1 (pt)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
DE102012201804.2 2012-02-07
DE102012201804 2012-02-07
DE102012221521 2012-11-26
DE102012221521.2 2012-11-26
PCT/EP2013/052363 WO2013117611A1 (de) 2012-02-07 2013-02-07 Verfahren zum beschichten von metallischen oberflächen von substraten und nach diesem verfahren beschichteten gegenstände

Publications (3)

Publication Number Publication Date
BR112014019467A2 BR112014019467A2 (pt) 2017-06-20
BR112014019467A8 true BR112014019467A8 (pt) 2017-07-11
BR112014019467B1 BR112014019467B1 (pt) 2021-09-08

Family

ID=47757565

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112014019467-0A BR112014019467B1 (pt) 2012-02-07 2013-02-07 Processo para revestimento de superfícies metálicas de substratos e objetos revestidos segundo esse processo

Country Status (18)

Country Link
US (1) US9556523B2 (pt)
EP (1) EP2812130B1 (pt)
JP (1) JP6351512B2 (pt)
KR (1) KR102116280B1 (pt)
CN (1) CN104395004B (pt)
AU (1) AU2013218068B2 (pt)
BR (1) BR112014019467B1 (pt)
CA (1) CA2863927A1 (pt)
DE (1) DE102013201966A1 (pt)
DK (1) DK2812130T3 (pt)
ES (1) ES2675159T3 (pt)
HU (1) HUE037904T2 (pt)
MX (1) MX361029B (pt)
PL (1) PL2812130T3 (pt)
PT (1) PT2812130T (pt)
SG (1) SG11201404732TA (pt)
TR (1) TR201808379T4 (pt)
WO (1) WO2013117611A1 (pt)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9816189B2 (en) 2013-03-15 2017-11-14 Honda Motor Co., Ltd. Corrosion inhibiting compositions and coatings including the same
US9605162B2 (en) 2013-03-15 2017-03-28 Honda Motor Co., Ltd. Corrosion inhibiting compositions and methods of making and using
AU2014289198B2 (en) 2013-07-10 2018-06-21 Chemetall Gmbh Method for coating metal surfaces of substrates and objects coated in accordance with said method
JP6461136B2 (ja) * 2013-07-18 2019-01-30 ヒェメタル ゲゼルシャフト ミット ベシュレンクテル ハフツングChemetall GmbH 基材の金属表面を被覆する方法およびこの方法により被覆された物品
AU2015215023B2 (en) 2014-02-04 2018-11-01 Chemetall Gmbh Method for removing organic coatings from substrates coated with organic coatings
CN106413920B (zh) * 2014-02-27 2020-03-27 凯密特尔有限责任公司 用于涂覆基材的金属表面的方法和根据该方法涂覆的物件
US20170081542A1 (en) * 2014-05-14 2017-03-23 Chemetall Gmbh Method for Coating Metal Surfaces of Substrates and Objects Coated in Accordance With Said Method
DE102014116403A1 (de) * 2014-11-11 2016-05-12 Temming Holding Gmbh Verfahren zur Herstellung einer verkratzungs- und verschmutzungstoleranten Oberfläche eines Metallbauteils und damit versehenes Metallbauteil
JP2016217914A (ja) * 2015-05-21 2016-12-22 セイコーエプソン株式会社 センサー用ゲルおよびセンサー
CN104946026A (zh) * 2015-07-17 2015-09-30 江苏金基特钢有限公司 一种防腐蚀性合金钢涂料的制备方法
CN104946025A (zh) * 2015-07-17 2015-09-30 江苏金基特钢有限公司 一种防腐蚀性合金钢涂料组合物
WO2017197448A1 (en) * 2016-05-16 2017-11-23 Bluescope Steel Limited Coating process
ES2846185T3 (es) 2016-06-10 2021-07-28 Chemetall Gmbh Ligantes estabilizados en fase acuosa
CN108467649B (zh) * 2018-05-28 2020-06-16 宁波沪荣汽车部件有限公司 耐磨抗蚀高强度镀锌板制备工艺
CN110078883B (zh) * 2019-05-22 2021-08-03 西华大学 一种基于魔芋粉的水性涂料树脂、其制备方法与组合物
US20210214578A1 (en) * 2020-01-10 2021-07-15 Smart Wipes, LLC d/b/a Hyge Products, LLC Method for strengthening a biodegradable or compostable substrate using annealing wax process
US20210371678A1 (en) * 2020-05-28 2021-12-02 Axalta Coating Systems Ip Co., Llc Electrocoating composition
EP4217432A1 (en) 2020-09-22 2023-08-02 Swimc Llc Chitosan-containing coating compositions
CN113234387A (zh) * 2021-05-10 2021-08-10 东阳市荣跃新材料有限公司 一种疏水高强度防腐涂层的制备方法

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3089783A (en) * 1960-01-06 1963-05-14 Pfaudler Permutit Inc Corrosion resistant coating and method of applying the same
DE19829757A1 (de) * 1998-07-03 2000-01-05 Stockhausen Chem Fab Gmbh Wässrige Klebemitteldispersionen und deren Verwendung zur Herstellung von mehrlagigen Papieren
CA2410362C (en) * 2000-06-14 2008-08-12 The Procter & Gamble Company Long lasting coatings for modifying hard surfaces and processes for applying the same
JPWO2006090719A1 (ja) * 2005-02-22 2008-07-24 国立大学法人 北海道大学 海洋生物付着防止剤及びその方法
US7550520B2 (en) * 2005-05-31 2009-06-23 The University Of Alabama Method of preparing high orientation nanoparticle-containing sheets or films using ionic liquids, and the sheets or films produced thereby
DE102007011553A1 (de) * 2007-03-09 2008-09-11 Chemetall Gmbh Verfahren zur Beschichtung von metallischen Oberflächen mit einer wässerigen, Polymere enthaltenden Zusammensetzung, die wässerige Zusammensetzung und Verwendung der beschichteten Substrate
JP5110505B2 (ja) * 2007-04-04 2012-12-26 奥野製薬工業株式会社 亜鉛又は亜鉛合金上に形成された化成皮膜に対するオーバーコート用組成物
DE102008043682B4 (de) * 2008-11-12 2014-01-23 Chemetall Gmbh Verfahren zum Beschichten von metallischen Oberflächen mit Partikeln, nach diesem Verfahren hergestellte Beschichtung und Verwendungder nach diesem Verfahren beschichteten Substrate
EP2570196B1 (de) * 2009-08-24 2020-04-15 Basf Se Verwendung von Polyelektrolytkomplexen zur Herstellung von Polymerfolien mit Sauerstoffbarriereeigenschaften
JP5585906B2 (ja) * 2009-09-10 2014-09-10 ヒメノイノベック株式会社 可撓性被膜を形成する水性組成物
ES2710856T3 (es) * 2010-09-13 2019-04-29 Chemetall Gmbh Procedimiento para recubrimiento de superficies y uso de los objetos recubiertos según este procedimiento
US10400135B2 (en) * 2012-11-26 2019-09-03 Chemetall Gmbh Method for coating metal surfaces of substrates, and objects coated according to said method

Also Published As

Publication number Publication date
HUE037904T2 (hu) 2018-09-28
ES2675159T3 (es) 2018-07-09
MX361029B (es) 2018-11-26
DK2812130T3 (en) 2018-07-16
AU2013218068B2 (en) 2017-06-01
EP2812130A1 (de) 2014-12-17
EP2812130B1 (de) 2018-03-28
CN104395004A (zh) 2015-03-04
JP6351512B2 (ja) 2018-07-04
JP2015511994A (ja) 2015-04-23
BR112014019467B1 (pt) 2021-09-08
PT2812130T (pt) 2018-06-05
KR102116280B1 (ko) 2020-05-29
DE102013201966A1 (de) 2013-08-08
MX2014009509A (es) 2014-10-24
CN104395004B (zh) 2019-06-11
BR112014019467A2 (pt) 2017-06-20
SG11201404732TA (en) 2014-10-30
PL2812130T3 (pl) 2018-10-31
US9556523B2 (en) 2017-01-31
TR201808379T4 (tr) 2018-07-23
KR20140135726A (ko) 2014-11-26
WO2013117611A1 (de) 2013-08-15
AU2013218068A1 (en) 2014-09-18
US20150079277A1 (en) 2015-03-19
CA2863927A1 (en) 2013-08-15

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Legal Events

Date Code Title Description
B06F Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]
B06U Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 07/02/2013, OBSERVADAS AS CONDICOES LEGAIS.