BR112014017476A2 - elastômeros termoplásticos via polimerização de radical por transferência de átomo de óleo de planta - Google Patents

elastômeros termoplásticos via polimerização de radical por transferência de átomo de óleo de planta

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Publication number
BR112014017476A2
BR112014017476A2 BR112014017476A BR112014017476A BR112014017476A2 BR 112014017476 A2 BR112014017476 A2 BR 112014017476A2 BR 112014017476 A BR112014017476 A BR 112014017476A BR 112014017476 A BR112014017476 A BR 112014017476A BR 112014017476 A2 BR112014017476 A2 BR 112014017476A2
Authority
BR
Brazil
Prior art keywords
block
monomer
plant oil
radically polymerizable
radical polymerization
Prior art date
Application number
BR112014017476A
Other languages
English (en)
Other versions
BR112014017476A8 (pt
BR112014017476B1 (pt
Inventor
A Cascione Andrew
William Cochran Eric
Hernandez Nacu
Christopher Williams Ronald
Original Assignee
Univ Iowa State Res Found Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univ Iowa State Res Found Inc filed Critical Univ Iowa State Res Found Inc
Publication of BR112014017476A2 publication Critical patent/BR112014017476A2/pt
Publication of BR112014017476A8 publication Critical patent/BR112014017476A8/pt
Publication of BR112014017476B1 publication Critical patent/BR112014017476B1/pt

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F267/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated polycarboxylic acids or derivatives thereof as defined in group C08F22/00
    • C08F267/06—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated polycarboxylic acids or derivatives thereof as defined in group C08F22/00 on to polymers of esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/01—Atom Transfer Radical Polymerization [ATRP] or reverse ATRP
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2555/00—Characteristics of bituminous mixtures
    • C08L2555/40—Mixtures based upon bitumen or asphalt containing functional additives
    • C08L2555/80—Macromolecular constituents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/24—Graft or block copolymers according to groups C08L51/00, C08L53/00 or C08L55/02; Derivatives thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Graft Or Block Polymers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

abstract of the disclosure thermoplastic elastomers via atom transfer radical polymerization of plant oil the present invention relates to a block copolymer comprising at least one pa block and at least one pb block. the pa block represents a polymer block comprising one or more units of monomer a, and the pb block represents a polymer block comprising one or more units of monomer b. monomer a is a vinyl, acrylic, diolefin, nitrile, dinitrile, or acrylonitrile monomer. monomer b is a radically polymerizable plant oil monomer containing one or more triglycerides. the present invention also relates to a method of preparing a thermoplastic block copolymer by radical polymerizing a radically polymerizable monomer with a radically polymerizable plant oil monomer containing one or more triglycerides, in the presence of an initiator and a transition-metal catalyst system to form the thermoplastic block copolymer. the polymerized plant oil- based block copolymers are useful in a variety of applications, such as asphalt modifiers, rubber compositions, adhesives, tires, in the automobile industry, footwear, packaging, etc. _____________________________________________________________________ tradução do resumo resumo patente de invenção: "elastômeros termoplásticos via polimerização de radical por transferência de átomo de óleo de planta". a presente invenção se refere a um copolímero em bloco compreendendo pelo menos um bloco de pa e pelo menos um bloco de pb. o bloco de pa representa um bloco de polímero compreendendo uma ou mais unidades de monômero a e o bloco de pb representa um bloco de polímero compreendendo uma ou mais unidades de monômero b. o monômero a é monômero de vinil, acrílico, diolefina, nitrila, dinitrila ou acrilonitrila. o monômero b é um óleo de planta radicalmente polimerizável contendo um ou mais triglicerídeos. a presente invenção também se refere a um método para preparar um copolímero em bloco termoplástico por polimerização em radical de um monômero radicalmente polimerizável com um monômero de óleo de planta radicalmente polimerizável contendo um ou mais triglicerídeos na presença de um iniciador e um sistema de catalisador de metal de transição para formar o copolímero em bloco termoplástico. os copolímeros em bloco à base de óleo de planta polimerizados são úteis em uma variedade de aplicações, tal como modificadores de asfalto, composições de borracha, adesivos, pneus, na indústria automobilística, calçados, embalagens, etc.
BR112014017476-8A 2012-01-18 2013-01-18 Copolímero em bloco, composições elastomérica, asfáltica e adesiva, pneu de veículo, métodos para preparar um polímero ou copolímero em bloco termoplástico, e polímero termoplástico BR112014017476B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201261587816P 2012-01-18 2012-01-18
US61/587,816 2012-01-18
PCT/US2013/022131 WO2013109878A1 (en) 2012-01-18 2013-01-18 Thermoplastic elastomers via atom transfer radical polymerization of plant oil

Publications (3)

Publication Number Publication Date
BR112014017476A2 true BR112014017476A2 (pt) 2017-06-13
BR112014017476A8 BR112014017476A8 (pt) 2017-07-04
BR112014017476B1 BR112014017476B1 (pt) 2021-03-30

Family

ID=48780405

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112014017476-8A BR112014017476B1 (pt) 2012-01-18 2013-01-18 Copolímero em bloco, composições elastomérica, asfáltica e adesiva, pneu de veículo, métodos para preparar um polímero ou copolímero em bloco termoplástico, e polímero termoplástico

Country Status (15)

Country Link
US (2) US9932435B2 (pt)
EP (1) EP2804882B1 (pt)
JP (1) JP2015505339A (pt)
KR (1) KR20140119116A (pt)
CN (3) CN104204014B (pt)
BR (1) BR112014017476B1 (pt)
CA (1) CA2860861A1 (pt)
CL (2) CL2014001890A1 (pt)
EA (2) EA201491384A1 (pt)
IL (1) IL233491A0 (pt)
MX (1) MX350257B (pt)
MY (1) MY185219A (pt)
SG (1) SG11201404228UA (pt)
WO (1) WO2013109878A1 (pt)
ZA (1) ZA201405084B (pt)

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Also Published As

Publication number Publication date
KR20140119116A (ko) 2014-10-08
EP2804882B1 (en) 2021-12-22
CN104204014A (zh) 2014-12-10
CN108623762B (zh) 2021-11-23
BR112014017476A8 (pt) 2017-07-04
US20130184383A1 (en) 2013-07-18
SG11201404228UA (en) 2014-10-30
ZA201405084B (en) 2018-12-19
CN108774300A (zh) 2018-11-09
EA201792241A1 (ru) 2018-02-28
WO2013109878A1 (en) 2013-07-25
EP2804882A4 (en) 2015-07-29
US20180237571A1 (en) 2018-08-23
EP2804882A1 (en) 2014-11-26
CN108774300B (zh) 2022-04-05
US10570238B2 (en) 2020-02-25
MY185219A (en) 2021-04-30
CN108623762A (zh) 2018-10-09
CL2017003074A1 (es) 2018-04-06
CL2014001890A1 (es) 2015-01-30
BR112014017476B1 (pt) 2021-03-30
JP2015505339A (ja) 2015-02-19
MX350257B (es) 2017-08-31
CA2860861A1 (en) 2013-07-25
MX2014008636A (es) 2014-12-08
US9932435B2 (en) 2018-04-03
IL233491A0 (en) 2014-08-31
CN104204014B (zh) 2018-06-15
EA201491384A1 (ru) 2015-03-31

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