MX2014008636A - Elastomeros termoplasticos mediante polimerizacion de radicales de transferencia de atomos de aceite vegetal. - Google Patents
Elastomeros termoplasticos mediante polimerizacion de radicales de transferencia de atomos de aceite vegetal.Info
- Publication number
- MX2014008636A MX2014008636A MX2014008636A MX2014008636A MX2014008636A MX 2014008636 A MX2014008636 A MX 2014008636A MX 2014008636 A MX2014008636 A MX 2014008636A MX 2014008636 A MX2014008636 A MX 2014008636A MX 2014008636 A MX2014008636 A MX 2014008636A
- Authority
- MX
- Mexico
- Prior art keywords
- monomer
- block
- plant oil
- radically polymerizable
- radical polymerization
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F267/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated polycarboxylic acids or derivatives thereof as defined in group C08F22/00
- C08F267/06—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated polycarboxylic acids or derivatives thereof as defined in group C08F22/00 on to polymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
- C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2438/00—Living radical polymerisation
- C08F2438/01—Atom Transfer Radical Polymerization [ATRP] or reverse ATRP
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2555/00—Characteristics of bituminous mixtures
- C08L2555/40—Mixtures based upon bitumen or asphalt containing functional additives
- C08L2555/80—Macromolecular constituents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/24—Graft or block copolymers according to groups C08L51/00, C08L53/00 or C08L55/02; Derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Graft Or Block Polymers (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
La presente invención se refiere a un copolímero bloque que comprende al menos un bloque de PA y al menos un bloque PB. El bloque PA representa un bloque de polímero que comprende una o más unidades de monómero A, y el bloque de PB representa un bloque de polímero que comprende una o más unidades de monómero B. El monómero A es un monómero de acrilonitrilo, vinilo, acrílico, diolefina, nitrilo o dinitrilo. El monómero B es un monómero de aceite vegetal polimerizable por radicales que contiene uno o más triglicéridos. La presente invención también se refiere a un método para preparar un copolímero de bloque termoplástico al polimerizar por radicales un monómero polimerizable por radicales con un monómero de aceite vegetal polimerizables por radicales que contiene uno o más triglicéridos, en la presencia de un indicador y un sistema catalizador de metales de transición para formar el copolímero de bloque termoplástico. Los copolímeros de bloque a base de aceite vegetal polimerizables son útiles en una variedad de aplicaciones, tales como modificadores de asfalto, composiciones de caucho, adhesivos, neumáticos, en la industria automotriz, calzado, empaquetado, etc.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201261587816P | 2012-01-18 | 2012-01-18 | |
PCT/US2013/022131 WO2013109878A1 (en) | 2012-01-18 | 2013-01-18 | Thermoplastic elastomers via atom transfer radical polymerization of plant oil |
Publications (2)
Publication Number | Publication Date |
---|---|
MX2014008636A true MX2014008636A (es) | 2014-12-08 |
MX350257B MX350257B (es) | 2017-08-31 |
Family
ID=48780405
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2014008636A MX350257B (es) | 2012-01-18 | 2013-01-18 | Elastomeros termoplasticos mediante polimerizacion de radicales de transferencia de atomos de aceite vegetal. |
Country Status (15)
Country | Link |
---|---|
US (2) | US9932435B2 (es) |
EP (1) | EP2804882B1 (es) |
JP (1) | JP2015505339A (es) |
KR (1) | KR20140119116A (es) |
CN (3) | CN108774300B (es) |
BR (1) | BR112014017476B1 (es) |
CA (1) | CA2860861A1 (es) |
CL (2) | CL2014001890A1 (es) |
EA (2) | EA201491384A1 (es) |
IL (1) | IL233491A0 (es) |
MX (1) | MX350257B (es) |
MY (1) | MY185219A (es) |
SG (1) | SG11201404228UA (es) |
WO (1) | WO2013109878A1 (es) |
ZA (1) | ZA201405084B (es) |
Families Citing this family (24)
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US9932435B2 (en) | 2012-01-18 | 2018-04-03 | Iowa State University Research Foundation, Inc. | Thermoplastic elastomers via atom transfer radical polymerization of plant oil |
WO2014189939A2 (en) | 2013-05-20 | 2014-11-27 | Iowa State University Research Foundation, Inc. | Thermoplastic elastomers via reversible addition-fragmentation chain transfer polymerization of triglycerides |
SG11201609358QA (en) | 2014-05-21 | 2016-12-29 | Univ Iowa State Res Found | Poly(acrylated polyol) and method for making and using thereof as asphalt rubber modifiers, adhesives, fracking additives, or fracking fluids |
US10435542B2 (en) | 2014-12-23 | 2019-10-08 | Bridestone Americas Tire Operations, LLC | Hemp oil-containing rubber compositions and related methods |
CN107429196B (zh) * | 2015-02-09 | 2021-07-16 | 阿彻丹尼尔斯米德兰德公司 | 可再生来源衍生的聚合物油大分子引发剂和由其衍生的热塑性嵌段共聚物 |
CA2976950A1 (en) * | 2015-02-27 | 2016-09-01 | Cargill, Incorporated | Rejuvenating compositions for asphalt applications & methods of manufacturing the same |
BR112017025342A2 (pt) * | 2015-05-29 | 2018-07-31 | Cargill Inc | polímeros termoplásticos compósitos com base em reação com óleos biorrenováveis |
WO2017087655A1 (en) * | 2015-11-17 | 2017-05-26 | University Of Houston System | Biorenewable blends of polylactide and acrylated epoxidized soybean oil compatibilized by a polylactide star polymer |
WO2017123877A1 (en) * | 2016-01-15 | 2017-07-20 | Ndsu Research Foundation | Modified plant oils and rubber containing compositions containing the same |
WO2018031373A1 (en) | 2016-08-12 | 2018-02-15 | Iowa State University Research Foundation, Inc. | Acrylated and acylated or acetalized polyol as a biobased substitute for hard, rigid thermoplastic and thermoplastic and thermoset materials |
US11124644B2 (en) * | 2016-09-01 | 2021-09-21 | University Of Florida Research Foundation, Inc. | Organic microgel system for 3D printing of silicone structures |
US10316192B2 (en) | 2017-08-25 | 2019-06-11 | Cargill, Incorporated | Emulsions with polymerized oils and methods of manufacturing the same |
KR102058068B1 (ko) | 2018-04-03 | 2019-12-20 | 한국타이어앤테크놀로지 주식회사 | 타이어 트레드용 고무 조성물, 이의 제조방법 및 이를 이용하여 제조한 타이어 |
WO2020061030A1 (en) * | 2018-09-17 | 2020-03-26 | Iowa State University Research Foundation, Inc. | Enhancing asphalt's properties with a bio-based polymer modified liquid asphalt cement |
US11732108B1 (en) | 2019-07-03 | 2023-08-22 | Associated Asphalt Partners, Llc | Modified asphalt compositions containing dialkyl polysulfides |
CN111303964B (zh) * | 2020-03-10 | 2023-03-28 | 西安石油大学 | 一种润滑油黏度指数改进剂及其制备方法与应用 |
KR102381429B1 (ko) * | 2020-08-13 | 2022-04-01 | 주식회사 삼양사 | 블로우 몰딩용 열가소성 폴리에스테르계 엘라스토머 수지의 내구성 평가 방법 |
KR20220059236A (ko) * | 2020-11-02 | 2022-05-10 | 코오롱인더스트리 주식회사 | 점착부여 수지, 이의 제조방법 및 이를 포함한 조성물 |
CN112716283B (zh) * | 2020-12-30 | 2022-07-05 | 成都探寻家科技有限公司 | 一种溏心蛋烹饪方法及煮蛋器 |
CN114106349B (zh) * | 2021-11-12 | 2023-01-17 | 华南农业大学 | 一种全生物基超支化光固化预聚物及其制备方法和应用 |
CN114605653B (zh) * | 2022-04-19 | 2023-07-04 | 东南大学 | 一种代替sbs的生物热塑性弹性体的制备方法及其应用 |
WO2023230252A1 (en) * | 2022-05-25 | 2023-11-30 | University Of Virgina Patent Foundation | Intrinsically reprocessable double-network elastomers |
CN115028784A (zh) * | 2022-05-25 | 2022-09-09 | 东南大学 | 一种生物基弹性体的制备方法及生物基弹性体改性沥青混合料的制备方法 |
CN116179042B (zh) * | 2023-02-28 | 2024-02-02 | 英创新材料(绍兴)有限公司 | 一种高弹性耐低温的防水涂料及其制备方法和应用 |
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2013
- 2013-01-18 US US13/744,733 patent/US9932435B2/en active Active
- 2013-01-18 MX MX2014008636A patent/MX350257B/es active IP Right Grant
- 2013-01-18 CN CN201810474450.2A patent/CN108774300B/zh active Active
- 2013-01-18 MY MYPI2014002118A patent/MY185219A/en unknown
- 2013-01-18 SG SG11201404228UA patent/SG11201404228UA/en unknown
- 2013-01-18 EA EA201491384A patent/EA201491384A1/ru unknown
- 2013-01-18 CN CN201380009567.9A patent/CN104204014B/zh active Active
- 2013-01-18 KR KR1020147022520A patent/KR20140119116A/ko not_active Application Discontinuation
- 2013-01-18 CN CN201810473383.2A patent/CN108623762B/zh active Active
- 2013-01-18 WO PCT/US2013/022131 patent/WO2013109878A1/en active Application Filing
- 2013-01-18 EP EP13738906.0A patent/EP2804882B1/en active Active
- 2013-01-18 EA EA201792241A patent/EA201792241A1/ru unknown
- 2013-01-18 CA CA2860861A patent/CA2860861A1/en not_active Abandoned
- 2013-01-18 BR BR112014017476-8A patent/BR112014017476B1/pt active IP Right Grant
- 2013-01-18 JP JP2014553449A patent/JP2015505339A/ja not_active Ceased
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2014
- 2014-07-02 IL IL233491A patent/IL233491A0/en unknown
- 2014-07-11 ZA ZA2014/05084A patent/ZA201405084B/en unknown
- 2014-07-17 CL CL2014001890A patent/CL2014001890A1/es unknown
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2017
- 2017-12-01 CL CL2017003074A patent/CL2017003074A1/es unknown
-
2018
- 2018-02-14 US US15/896,151 patent/US10570238B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
CN108623762A (zh) | 2018-10-09 |
MY185219A (en) | 2021-04-30 |
CN104204014A (zh) | 2014-12-10 |
KR20140119116A (ko) | 2014-10-08 |
CA2860861A1 (en) | 2013-07-25 |
CN108774300B (zh) | 2022-04-05 |
WO2013109878A1 (en) | 2013-07-25 |
ZA201405084B (en) | 2018-12-19 |
US20180237571A1 (en) | 2018-08-23 |
CN104204014B (zh) | 2018-06-15 |
EA201792241A1 (ru) | 2018-02-28 |
BR112014017476A2 (pt) | 2017-06-13 |
US20130184383A1 (en) | 2013-07-18 |
US10570238B2 (en) | 2020-02-25 |
MX350257B (es) | 2017-08-31 |
BR112014017476B1 (pt) | 2021-03-30 |
CN108774300A (zh) | 2018-11-09 |
EP2804882A1 (en) | 2014-11-26 |
EA201491384A1 (ru) | 2015-03-31 |
EP2804882B1 (en) | 2021-12-22 |
CL2014001890A1 (es) | 2015-01-30 |
CL2017003074A1 (es) | 2018-04-06 |
BR112014017476A8 (pt) | 2017-07-04 |
US9932435B2 (en) | 2018-04-03 |
JP2015505339A (ja) | 2015-02-19 |
IL233491A0 (en) | 2014-08-31 |
CN108623762B (zh) | 2021-11-23 |
EP2804882A4 (en) | 2015-07-29 |
SG11201404228UA (en) | 2014-10-30 |
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