BR112014008748B1 - Copolímero heterofásico modificado de polipropileno, artigos grandes, profundos, complexos e/ou espessos, processo para termoformagem de copolímero heterofásico modificado de polipropileno, e, uso do mesmo - Google Patents
Copolímero heterofásico modificado de polipropileno, artigos grandes, profundos, complexos e/ou espessos, processo para termoformagem de copolímero heterofásico modificado de polipropileno, e, uso do mesmo Download PDFInfo
- Publication number
- BR112014008748B1 BR112014008748B1 BR112014008748-2A BR112014008748A BR112014008748B1 BR 112014008748 B1 BR112014008748 B1 BR 112014008748B1 BR 112014008748 A BR112014008748 A BR 112014008748A BR 112014008748 B1 BR112014008748 B1 BR 112014008748B1
- Authority
- BR
- Brazil
- Prior art keywords
- polypropylene
- fact
- articles
- modified
- thermoforming
- Prior art date
Links
- -1 POLYPROPYLENE Polymers 0.000 title claims abstract description 165
- 239000004743 Polypropylene Substances 0.000 title claims abstract description 158
- 229920001155 polypropylene Polymers 0.000 title claims abstract description 158
- 238000003856 thermoforming Methods 0.000 title claims abstract description 56
- 238000000034 method Methods 0.000 title claims abstract description 26
- 229920001577 copolymer Polymers 0.000 title claims abstract description 23
- 230000008569 process Effects 0.000 title abstract description 16
- 229920005606 polypropylene copolymer Polymers 0.000 title description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 8
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000005977 Ethylene Substances 0.000 claims abstract description 4
- 238000012986 modification Methods 0.000 claims description 23
- 230000004048 modification Effects 0.000 claims description 23
- 229920001971 elastomer Polymers 0.000 claims description 15
- 239000005060 rubber Substances 0.000 claims description 15
- 238000001125 extrusion Methods 0.000 claims description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- 230000015572 biosynthetic process Effects 0.000 claims description 7
- 239000012530 fluid Substances 0.000 claims description 6
- 239000000945 filler Substances 0.000 claims description 5
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 4
- 238000000465 moulding Methods 0.000 claims description 4
- 239000002667 nucleating agent Substances 0.000 claims description 4
- 150000004756 silanes Chemical class 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- 239000000155 melt Substances 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- 239000006096 absorbing agent Substances 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 150000007513 acids Chemical class 0.000 claims description 2
- 229940069428 antacid Drugs 0.000 claims description 2
- 239000003159 antacid agent Substances 0.000 claims description 2
- 239000003963 antioxidant agent Substances 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 239000000975 dye Substances 0.000 claims description 2
- 239000000314 lubricant Substances 0.000 claims description 2
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical class [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 claims description 2
- 235000012239 silicon dioxide Nutrition 0.000 claims description 2
- 239000004408 titanium dioxide Substances 0.000 claims description 2
- 238000003786 synthesis reaction Methods 0.000 claims 3
- 230000001012 protector Effects 0.000 claims 2
- 150000001336 alkenes Chemical class 0.000 claims 1
- 239000002216 antistatic agent Substances 0.000 claims 1
- 239000008395 clarifying agent Substances 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- 229920005631 polypropylene heterophasic copolymer Polymers 0.000 claims 1
- 229920001519 homopolymer Polymers 0.000 abstract description 9
- 229920005604 random copolymer Polymers 0.000 abstract description 4
- 239000000047 product Substances 0.000 description 42
- 239000013256 coordination polymer Substances 0.000 description 27
- 239000000203 mixture Substances 0.000 description 16
- 230000006399 behavior Effects 0.000 description 15
- 239000011159 matrix material Substances 0.000 description 14
- 229920005669 high impact polystyrene Polymers 0.000 description 10
- 239000004797 high-impact polystyrene Substances 0.000 description 10
- 239000010410 layer Substances 0.000 description 10
- 230000008859 change Effects 0.000 description 9
- 230000000694 effects Effects 0.000 description 8
- 229920001903 high density polyethylene Polymers 0.000 description 7
- 239000004700 high-density polyethylene Substances 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 6
- 229920000573 polyethylene Polymers 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 5
- 238000002844 melting Methods 0.000 description 5
- 230000008018 melting Effects 0.000 description 5
- 150000002978 peroxides Chemical class 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 230000009467 reduction Effects 0.000 description 5
- 239000004698 Polyethylene Substances 0.000 description 4
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 4
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 4
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 4
- 238000003780 insertion Methods 0.000 description 4
- 230000037431 insertion Effects 0.000 description 4
- 239000012764 mineral filler Substances 0.000 description 4
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 4
- 239000004793 Polystyrene Substances 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 230000002860 competitive effect Effects 0.000 description 3
- 238000009264 composting Methods 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 229920001684 low density polyethylene Polymers 0.000 description 3
- 239000004702 low-density polyethylene Substances 0.000 description 3
- 229920005629 polypropylene homopolymer Polymers 0.000 description 3
- 229920002223 polystyrene Polymers 0.000 description 3
- 239000004814 polyurethane Substances 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000004711 α-olefin Substances 0.000 description 3
- 230000002902 bimodal effect Effects 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 239000003431 cross linking reagent Substances 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 150000001993 dienes Chemical class 0.000 description 2
- 238000000265 homogenisation Methods 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 229920000092 linear low density polyethylene Polymers 0.000 description 2
- 239000004707 linear low-density polyethylene Substances 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000002356 single layer Substances 0.000 description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- BFCGQKHVWYGVLK-UHFFFAOYSA-N carboxy hydrogen carbonate;1-hexadecylperoxyhexadecane Chemical compound OC(=O)OC(O)=O.CCCCCCCCCCCCCCCCOOCCCCCCCCCCCCCCCC BFCGQKHVWYGVLK-UHFFFAOYSA-N 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 230000000877 morphologic effect Effects 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- HSVFKFNNMLUVEY-UHFFFAOYSA-N sulfuryl diazide Chemical class [N-]=[N+]=NS(=O)(=O)N=[N+]=[N-] HSVFKFNNMLUVEY-UHFFFAOYSA-N 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C51/00—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
- B29C51/10—Forming by pressure difference, e.g. vacuum
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/14—Copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2791/00—Shaping characteristics in general
- B29C2791/004—Shaping under special conditions
- B29C2791/006—Using vacuum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C51/00—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
- B29C51/002—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor characterised by the choice of material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
- B29K2023/10—Polymers of propylene
- B29K2023/12—PP, i.e. polypropylene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/30—Applications used for thermoforming
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/02—Heterophasic composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/07—Long chain branching
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/BR2011/000360 WO2013053025A1 (pt) | 2011-10-11 | 2011-10-11 | Polipropileno para confecção de artigos termoformados, artigos grandes, profundos, complexos e/ou espessos, processo para termoformação de polipropileno modificado em artigos grandes, profundos, complexos e/ou espessos, e, uso do polipropileno |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR112014008748A2 BR112014008748A2 (pt) | 2017-04-18 |
| BR112014008748B1 true BR112014008748B1 (pt) | 2020-06-16 |
Family
ID=48081282
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR112014008748-2A BR112014008748B1 (pt) | 2011-10-11 | 2011-10-11 | Copolímero heterofásico modificado de polipropileno, artigos grandes, profundos, complexos e/ou espessos, processo para termoformagem de copolímero heterofásico modificado de polipropileno, e, uso do mesmo |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US9663648B2 (enExample) |
| EP (1) | EP2767559B1 (enExample) |
| JP (1) | JP2014534297A (enExample) |
| KR (1) | KR101829624B1 (enExample) |
| CN (1) | CN103987778A (enExample) |
| BR (1) | BR112014008748B1 (enExample) |
| CA (1) | CA2851847C (enExample) |
| ES (1) | ES2712557T3 (enExample) |
| IN (1) | IN2014DN03187A (enExample) |
| MX (1) | MX355926B (enExample) |
| WO (1) | WO2013053025A1 (enExample) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL2810961T3 (pl) * | 2013-06-05 | 2016-12-30 | Jednoetapowe wytwarzanie kompozycji polipropylenowej | |
| WO2015200586A1 (en) | 2014-06-25 | 2015-12-30 | Exxonmobil Chemcal Patents Inc. | High melt strength polypropylene and extrusion process for preserving melt strength |
| EP3334602A4 (en) | 2015-08-13 | 2019-01-09 | ExxonMobil Chemical Patents Inc. | MULTILAYER FILMS WITH POLYPROPYLENE WITH HIGH MELTING STRENGTH |
| JP6720804B2 (ja) * | 2015-10-09 | 2020-07-08 | 日本ポリプロ株式会社 | 熱成形用シートおよび成形体 |
| US20190184625A1 (en) * | 2016-08-09 | 2019-06-20 | Japan Polypropylene Corporation | Decorative film and method for producing decorative molded body using same |
| TR201709820A2 (tr) * | 2017-07-04 | 2019-01-21 | Arcelik As | Plasti̇k i̇ç duvar i̇çeren buzdolabi |
| KR102420733B1 (ko) * | 2017-07-13 | 2022-07-15 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 변형률 경화된 폴리프로필렌의 제조 방법 |
| CN114539678B (zh) * | 2022-03-22 | 2023-08-15 | 天津金发新材料有限公司 | 一种节能型再生聚丙烯复合材料及其制备方法 |
Family Cites Families (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4567089A (en) | 1984-07-23 | 1986-01-28 | Mitsubishi Petrochemical Co., Ltd. | Thermoforming propylene polymer laminated sheet |
| IN166935B (enExample) * | 1985-01-31 | 1990-08-11 | Himont Inc | |
| US5286428A (en) | 1987-10-16 | 1994-02-15 | Sekisui Kaseihin Kogyo Kabushiki Kaisha | Polypropylene resin foamed sheet for thermoforming and process for producing the same |
| US5047485A (en) * | 1989-02-21 | 1991-09-10 | Himont Incorporated | Process for making a propylene polymer with free-end long chain branching and use thereof |
| US5310584B1 (en) | 1992-04-14 | 1999-02-16 | Amoco Corp | Thermoformable polypropylene-based sheet |
| JP2918135B2 (ja) * | 1992-06-11 | 1999-07-12 | 株式会社ジェイエスピー | プロピレン系樹脂発泡シート |
| US5639818A (en) | 1994-03-11 | 1997-06-17 | Quantum Chemical Corporation | Peroxide modified PP/PE blends with superior melt strength |
| FI973816A0 (fi) | 1997-09-26 | 1997-09-26 | Borealis As | Polypropen med hoeg smaeltstyrka |
| UA60351C2 (uk) * | 1997-11-21 | 2003-10-15 | Акцо Нобель Н.В. | Спосіб модифікації поліпропілену |
| JP3990805B2 (ja) | 1997-12-25 | 2007-10-17 | 日本ポリプロ株式会社 | オレフィン系複合樹脂積層シート |
| CN1167718C (zh) * | 1998-08-26 | 2004-09-22 | 埃克森美孚化学专利公司 | 支化聚丙烯组合物 |
| EP1038893A1 (en) * | 1999-03-19 | 2000-09-27 | Fina Research S.A. | Production of polypropylene having improved properties |
| EP1167404A1 (en) | 2000-06-23 | 2002-01-02 | Borealis GmbH | Polyolefin products with improved toughness, strength and heat resistance |
| US6548600B2 (en) * | 2000-09-22 | 2003-04-15 | Dupont Dow Elastomers L.L.C. | Thermoplastic elastomer compositions rheology-modified using peroxides and free radical coagents |
| JP4031622B2 (ja) * | 2001-05-30 | 2008-01-09 | バセル ポリオレフィン イタリア エス．アール．エル． | ポリプロピレン系樹脂組成物 |
| US6610792B2 (en) * | 2001-07-26 | 2003-08-26 | Fina Technology, Inc. | Polypropylene copolymers and method of preparing polyproylene copolymers |
| US20050070673A1 (en) | 2001-10-01 | 2005-03-31 | Novak Leo R. | Thermoformable propylene polymer compositions |
| US6602956B2 (en) * | 2001-11-13 | 2003-08-05 | Solvay Engineered Polymers | Melt strength thermoplastic elastomers and methods for making same |
| US7338994B2 (en) | 2002-10-01 | 2008-03-04 | Dow Global Technologies Inc. | Rheology-modified thermoplastic elastomer compositions for extruded profiles |
| JP4314154B2 (ja) | 2004-05-27 | 2009-08-12 | 三井化学株式会社 | 自動車内装表皮部材 |
| EP1674809A1 (en) | 2004-12-23 | 2006-06-28 | Borealis Technology OY | Mineral filled polyethylene for inner liners |
| JP2006257332A (ja) | 2005-03-18 | 2006-09-28 | Sumitomo Chemical Co Ltd | 真空成型用熱可塑性エラストマ−組成物および積層体 |
| WO2006124369A1 (en) | 2005-05-12 | 2006-11-23 | Dow Global Technologies Inc. | Thermoformed, extruded sheeting with reduced gloss |
| RU2408623C2 (ru) * | 2005-05-27 | 2011-01-10 | Базелль Полиолефин Италия С.Р.Л. | Полиолефиновые композиции, обладающие хорошей устойчивостью к белению |
| US9074811B2 (en) | 2006-05-31 | 2015-07-07 | Arcelik Anonim Sirketi | Refrigerator |
| ATE465859T1 (de) * | 2007-01-31 | 2010-05-15 | Borealis Tech Oy | Einsatz eines langkettenverzweigten polypropylens zur verbreiterung des verarbeitungsfensters beim spritzstreckblasformen |
| US20110118400A1 (en) | 2008-07-23 | 2011-05-19 | Saudi Basic Industries Corporation | Process for Preparing Modified Polypropylene Compositions |
| PL2452138T3 (pl) | 2009-07-07 | 2014-01-31 | Arcelik As | Lodówka zawierająca wewnętrzną powłokę z tworzywa sztucznego |
| RU2012105023A (ru) * | 2009-07-14 | 2013-08-20 | ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи | Полипропиленовые ударопрочные сополимеры, имеющие высокие текучесть расплава и пластичность в испытании по изоду |
| EP2319885B1 (en) * | 2009-10-29 | 2011-12-21 | Borealis AG | Heterophasic polypropylene resin with long chain branching |
| US8921466B2 (en) * | 2010-01-15 | 2014-12-30 | Reliance Industries Limited | Concurrent solid and melt state grafting of coagents for making long chain branched polypropylene via direct reactive extrusion process |
-
2011
- 2011-10-11 BR BR112014008748-2A patent/BR112014008748B1/pt active IP Right Grant
- 2011-10-11 CA CA2851847A patent/CA2851847C/en active Active
- 2011-10-11 WO PCT/BR2011/000360 patent/WO2013053025A1/pt not_active Ceased
- 2011-10-11 CN CN201180075433.8A patent/CN103987778A/zh active Pending
- 2011-10-11 ES ES11874031T patent/ES2712557T3/es active Active
- 2011-10-11 EP EP11874031.5A patent/EP2767559B1/en not_active Revoked
- 2011-10-11 MX MX2014004401A patent/MX355926B/es active IP Right Grant
- 2011-10-11 JP JP2014534892A patent/JP2014534297A/ja active Pending
- 2011-10-11 KR KR1020147011921A patent/KR101829624B1/ko active Active
- 2011-10-11 IN IN3187DEN2014 patent/IN2014DN03187A/en unknown
- 2011-10-11 US US14/351,027 patent/US9663648B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| KR20140074374A (ko) | 2014-06-17 |
| CA2851847C (en) | 2018-11-13 |
| BR112014008748A2 (pt) | 2017-04-18 |
| MX2014004401A (es) | 2014-09-08 |
| EP2767559A4 (en) | 2015-08-19 |
| IN2014DN03187A (enExample) | 2015-05-22 |
| KR101829624B1 (ko) | 2018-03-29 |
| WO2013053025A1 (pt) | 2013-04-18 |
| US9663648B2 (en) | 2017-05-30 |
| EP2767559A1 (en) | 2014-08-20 |
| ES2712557T3 (es) | 2019-05-13 |
| JP2014534297A (ja) | 2014-12-18 |
| CN103987778A (zh) | 2014-08-13 |
| MX355926B (es) | 2018-05-04 |
| EP2767559B1 (en) | 2018-11-21 |
| US20140308502A1 (en) | 2014-10-16 |
| CA2851847A1 (en) | 2013-04-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| BR112014008748B1 (pt) | Copolímero heterofásico modificado de polipropileno, artigos grandes, profundos, complexos e/ou espessos, processo para termoformagem de copolímero heterofásico modificado de polipropileno, e, uso do mesmo | |
| EP2673306B1 (en) | Compatibilized polypropylene heterophasic copolymer and polylactic acid blends for injection molding applications | |
| CN108137834B (zh) | 热成形用片材和成形体 | |
| ATE542855T1 (de) | Propylenpolymerzusammensetzungen und herstellungsverfahren dafür | |
| US20050070673A1 (en) | Thermoformable propylene polymer compositions | |
| CN109983071A (zh) | 用于发泡应用的聚丙烯组合物 | |
| US20220315743A1 (en) | Recycled polyolefin compositions comprising random alpha-olefinic copolymers and additional polymers | |
| JP7061003B2 (ja) | プロピレン樹脂組成物及び射出成形体 | |
| JP6386874B2 (ja) | ポリオレフィン系組成物およびポリオレフィン延伸フィルム並びに延伸フィルムの製造方法 | |
| TR201811902T4 (tr) | Geliştirilmiş toz akışkanlığı, azaltılmış emisyonları ve düşük küçülme özellikli heterofazik polipropilen. | |
| CN107849323B (zh) | 聚丙烯组合物和其热成型片材 | |
| JP7023164B2 (ja) | プロピレン樹脂組成物及び成形体 | |
| US20230406973A1 (en) | High density polyethylene compositions with long-chain branching | |
| JP6948977B2 (ja) | プロピレン樹脂組成物及び射出成形体 | |
| WO2018006149A1 (en) | Nucleated polyolefin compositions and methods and uses thereof | |
| AU2017416025B2 (en) | Refrigerator appliance having at least one inner plastic liner and method for manufacturing the liner | |
| JP7770348B2 (ja) | 熱成形のための透明なポリプロピレン組成物 | |
| CN113348206A (zh) | 具有优异力学性能的可发泡的聚丙烯组合物 | |
| WO2022102706A1 (ja) | ポリプロピレン多層シート | |
| TW201615719A (zh) | 聚烯烴系樹脂組成物、成形物及聚烯烴系樹脂薄膜 | |
| EP3209705A1 (en) | Opaque pp/pla bopp films with broad processing window | |
| BR112020024660A2 (pt) | filme revestido, filme parcialmente revestido, artigo, e, laminado | |
| US20240174777A1 (en) | Polypropylenes for additive manufacturing | |
| US20160046737A1 (en) | Propylene polymer resins | |
| JP3722291B2 (ja) | ポリプロピレン系樹脂発泡シート |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B06F | Objections, documents and/or translations needed after an examination request according art. 34 industrial property law | ||
| B06U | Preliminary requirement: requests with searches performed by other patent offices: suspension of the patent application procedure | ||
| B09A | Decision: intention to grant | ||
| B16A | Patent or certificate of addition of invention granted |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 11/10/2011, OBSERVADAS AS CONDICOES LEGAIS. |