BR112013000521A2 - espuma rígida de poliuretano, composição de resina, e, método para formar espuma rígida de poliuretano - Google Patents
espuma rígida de poliuretano, composição de resina, e, método para formar espuma rígida de poliuretanoInfo
- Publication number
- BR112013000521A2 BR112013000521A2 BR112013000521A BR112013000521A BR112013000521A2 BR 112013000521 A2 BR112013000521 A2 BR 112013000521A2 BR 112013000521 A BR112013000521 A BR 112013000521A BR 112013000521 A BR112013000521 A BR 112013000521A BR 112013000521 A2 BR112013000521 A2 BR 112013000521A2
- Authority
- BR
- Brazil
- Prior art keywords
- polyurethane foam
- rigid polyurethane
- resin composition
- novolac polyol
- forming
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/54—Polycondensates of aldehydes
- C08G18/542—Polycondensates of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/302—Water
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3203—Polyhydroxy compounds
- C08G18/3215—Polyhydroxy compounds containing aromatic groups or benzoquinone groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
- C08G18/4027—Mixtures of compounds of group C08G18/54 with other macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
- C08G18/4208—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
- C08G18/4208—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups
- C08G18/4211—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
- C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/141—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/147—Halogen containing compounds containing carbon and halogen atoms only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0025—Foam properties rigid
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
- C08J2203/142—Halogenated saturated hydrocarbons, e.g. H3C-CF3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2205/00—Foams characterised by their properties
- C08J2205/10—Rigid foams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
- C08J2375/12—Polyurethanes from compounds containing nitrogen and active hydrogen, the nitrogen atom not being part of an isocyanate group
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
espuma rígida de poliuretano, composição de resina, e, método para formar espuma rígida de poliuretano. uma espuma rígida de poliuretano inclui o produto de reação de uma composição de resina e uma composição de isocianato. a composição de resina inclui um poliol novolac tendo uma estrutura química geral (i). nesta estrutura, r é um grupo alquila ou alquileno e o poliol novolac tem uma funcionalidade de hidroxila média de 2 a 30 calculado pela divisão do peso molecular médio ponderado do poliol novolac pelo peso equivalente do poliol novolac. o poliol novolac está presente em uma quantidade de 3 a 65 partes em peso por 100 partes em peso da composição de resina.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US36254910P | 2010-07-08 | 2010-07-08 | |
PCT/EP2011/061245 WO2012004229A1 (en) | 2010-07-08 | 2011-07-04 | Rigid polyurethane foam |
Publications (1)
Publication Number | Publication Date |
---|---|
BR112013000521A2 true BR112013000521A2 (pt) | 2016-05-17 |
Family
ID=44558244
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112013000521A BR112013000521A2 (pt) | 2010-07-08 | 2011-07-04 | espuma rígida de poliuretano, composição de resina, e, método para formar espuma rígida de poliuretano |
Country Status (11)
Country | Link |
---|---|
US (1) | US20120009407A1 (pt) |
EP (1) | EP2591034A1 (pt) |
JP (1) | JP2013532221A (pt) |
KR (1) | KR20130041182A (pt) |
CN (1) | CN103119076A (pt) |
BR (1) | BR112013000521A2 (pt) |
CA (1) | CA2804547A1 (pt) |
MX (1) | MX2013000273A (pt) |
RU (1) | RU2013105194A (pt) |
WO (1) | WO2012004229A1 (pt) |
ZA (1) | ZA201300945B (pt) |
Families Citing this family (31)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9592516B2 (en) * | 2009-09-08 | 2017-03-14 | Basf Se | Polyurethane spraying system used to minimize emissions of a polyisocyanate |
MX2010009775A (es) | 2009-09-08 | 2011-06-15 | Basf Se | Metodo para minimizar las emisiones durante la formacion de una espuma de poliuretano. |
MX2014007841A (es) | 2011-12-29 | 2015-03-05 | Firestone Building Prod Co Llc | Membranas para techos con grafito expandible como retardantes de llama. |
US9441140B2 (en) | 2012-07-12 | 2016-09-13 | Firestone Building Products Co., LLC | Asphaltic sheet materials including expandable graphite |
US10508193B2 (en) | 2012-11-07 | 2019-12-17 | Firestone Building Products Co., LLC | Pressure-sensitive adhesives including expandable graphite |
US8968853B2 (en) | 2012-11-07 | 2015-03-03 | Firestone Building Products Company, Llc | Pressure-sensitive adhesives including expandable graphite |
US9045904B2 (en) | 2012-11-16 | 2015-06-02 | Firestone Building Products Co., LLC | Thermoplastic membranes containing expandable graphite |
WO2014113379A1 (en) | 2013-01-15 | 2014-07-24 | Basf Se | Rigid foam |
US20140205789A1 (en) | 2013-01-23 | 2014-07-24 | Firestone Building Products Co., LLC | Coated fabrics including expandable graphite |
US9523203B2 (en) | 2013-01-23 | 2016-12-20 | Firestone Building Products Co., LLC | Fire-resistant roof system and membrane composite |
US10017943B1 (en) | 2013-02-14 | 2018-07-10 | Firestone Building Products Co., LLC | Liquid coatings including expandable graphite |
US9594163B2 (en) | 2013-04-15 | 2017-03-14 | Electronics And Telecommunications Research Institute | Security and surveillance system and method |
US10907021B2 (en) * | 2013-07-26 | 2021-02-02 | Basf Se | Isocyanate-epoxy-foam system |
CN103756292A (zh) * | 2014-01-08 | 2014-04-30 | 合肥杰事杰新材料股份有限公司 | 一种线性酚醛树脂改性的聚氨酯复合阻燃泡沫及其制备方法 |
RU2017101191A (ru) * | 2014-06-18 | 2018-07-18 | Асахи Касеи Констракшн Матириалс Корпорейшн | Пена из фенольной смолы и способ ее получения |
US10415249B2 (en) | 2014-07-03 | 2019-09-17 | Firestone Building Products Co., LLC | EPDM roofing membranes with expandable graphite as flame retardant |
US10494473B2 (en) | 2016-03-14 | 2019-12-03 | Raven Lining Systems, Inc. | Hybrid novolac polyurea/polyurethane |
US20180022884A1 (en) * | 2016-07-25 | 2018-01-25 | Honeywell International Inc. | Polyester polyol compositions containing hfo-1336mzzm (z) |
CN106366289A (zh) * | 2016-08-29 | 2017-02-01 | 德州市鑫华润科技股份有限公司 | 阻燃性聚氨酯及其制备方法 |
DE102016123621A1 (de) * | 2016-12-06 | 2018-06-07 | Ask Chemicals Gmbh | Polyurethan Bindemittel mit verbesserter Fließfähigkeit |
CN110582522B (zh) * | 2017-03-24 | 2022-02-01 | 亨茨曼国际有限公司 | 制造硬质的聚氨酯改性的聚异氰脲酸酯泡沫的方法 |
AU2018290799B2 (en) * | 2017-06-27 | 2020-10-01 | Albemarle Corporation | Flame retarded polyurethane foam |
US10118905B1 (en) | 2017-09-22 | 2018-11-06 | Hexion Inc. | Compositions and methods to produce Alkoxylated triazine-arylhydroxy-aldehyde condensates |
US10604614B2 (en) | 2017-09-22 | 2020-03-31 | Hexion Inc. | Compositions and methods to produce alkoxylated triazine-arylhydroxy-aldehyde condensates |
US10435503B2 (en) | 2017-09-22 | 2019-10-08 | Hexion Inc. | Compositions for polyurethane applications |
US10640475B2 (en) | 2017-09-22 | 2020-05-05 | Hexion Inc. | Compositions and methods to produce alkoxylated triazine-arlhydroxy-aldehyde condensates |
DE102018130184A1 (de) | 2018-11-28 | 2020-05-28 | Adler Pelzer Holding Gmbh | Polyurethan-Schaumstoff-Formulierung und Schallisolierungen mit darauf basierenden Schäumen (Motorkapsel) |
WO2020142887A1 (en) * | 2019-01-08 | 2020-07-16 | Dow Global Technologies Llc | Rigid polyisocyanurate and polyurethane foams and methods for preparing the same |
EP3924426A1 (en) * | 2019-02-11 | 2021-12-22 | Dow Global Technologies LLC | Fire resistant polyurethane coating composition and a fire-resistant product comprising the same |
CN110885418A (zh) * | 2019-12-16 | 2020-03-17 | 山东一诺威新材料有限公司 | 联机管集热器用聚氨酯硬质泡沫及其制备方法 |
CN111333807B (zh) * | 2020-02-27 | 2021-09-07 | 西安交通大学 | 一种酚醛基可再生高分子材料及其制备方法和再生应用 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3598771A (en) * | 1968-12-04 | 1971-08-10 | Dow Chemical Co | Polyurethane compositions prepared from polyisocyanates and phenol-aldehyde resins |
GB1351555A (en) * | 1972-09-05 | 1974-05-01 | Dow Chemical Co | Polyurethane foams |
US3872034A (en) * | 1973-02-02 | 1975-03-18 | Cook Paint & Varnish Co | Phenolic foam |
DE60110190T2 (de) * | 2000-11-28 | 2005-09-22 | Hodogaya Chemical Co. Ltd., Kawasaki | Urethan-modifizierter Polyiscoyanuratschaum |
ATE376031T1 (de) * | 2004-05-28 | 2007-11-15 | Albemarle Corp | Flammwidrige polyurethane und additive dafür |
WO2010077602A1 (en) * | 2008-12-08 | 2010-07-08 | Dow Global Technologies Inc. | Open cell rigid polyurethane spray foam having improved fire retardancy |
KR20120027027A (ko) * | 2009-06-16 | 2012-03-20 | 아사히 가라스 가부시키가이샤 | 폴리에테르폴리올의 제조 방법, 및 이것을 사용한 경질 발포 합성 수지의 제조 방법 |
-
2011
- 2011-07-04 KR KR1020137003204A patent/KR20130041182A/ko not_active Application Discontinuation
- 2011-07-04 WO PCT/EP2011/061245 patent/WO2012004229A1/en active Application Filing
- 2011-07-04 EP EP11732407.9A patent/EP2591034A1/en not_active Withdrawn
- 2011-07-04 BR BR112013000521A patent/BR112013000521A2/pt not_active IP Right Cessation
- 2011-07-04 MX MX2013000273A patent/MX2013000273A/es not_active Application Discontinuation
- 2011-07-04 CN CN201180040030XA patent/CN103119076A/zh active Pending
- 2011-07-04 CA CA2804547A patent/CA2804547A1/en not_active Abandoned
- 2011-07-04 JP JP2013517343A patent/JP2013532221A/ja not_active Withdrawn
- 2011-07-04 RU RU2013105194/04A patent/RU2013105194A/ru not_active Application Discontinuation
- 2011-07-08 US US13/178,926 patent/US20120009407A1/en not_active Abandoned
-
2013
- 2013-02-05 ZA ZA2013/00945A patent/ZA201300945B/en unknown
Also Published As
Publication number | Publication date |
---|---|
EP2591034A1 (en) | 2013-05-15 |
KR20130041182A (ko) | 2013-04-24 |
CN103119076A (zh) | 2013-05-22 |
ZA201300945B (en) | 2014-04-30 |
RU2013105194A (ru) | 2014-08-20 |
MX2013000273A (es) | 2013-04-29 |
JP2013532221A (ja) | 2013-08-15 |
CA2804547A1 (en) | 2012-01-12 |
WO2012004229A1 (en) | 2012-01-12 |
US20120009407A1 (en) | 2012-01-12 |
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