BR112012019413A2 - processo para producao de uma corrente de alimentacao de ester para producao de esteres e coproducao de etanol - Google Patents

processo para producao de uma corrente de alimentacao de ester para producao de esteres e coproducao de etanol

Info

Publication number
BR112012019413A2
BR112012019413A2 BR112012019413A BR112012019413A BR112012019413A2 BR 112012019413 A2 BR112012019413 A2 BR 112012019413A2 BR 112012019413 A BR112012019413 A BR 112012019413A BR 112012019413 A BR112012019413 A BR 112012019413A BR 112012019413 A2 BR112012019413 A2 BR 112012019413A2
Authority
BR
Brazil
Prior art keywords
ester
feed stream
production
ethanol
ester feed
Prior art date
Application number
BR112012019413A
Other languages
English (en)
Inventor
Torres Alfonso
T Chapman Josefina
Sarager Lincoln
Jay Warner R
Jevtic Radmila
Cunningham Robert
Horton Trinity
J Johnston Victor
Original Assignee
Celanese Int Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Celanese Int Corp filed Critical Celanese Int Corp
Publication of BR112012019413A2 publication Critical patent/BR112012019413A2/pt

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/16Clays or other mineral silicates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56Platinum group metals
    • B01J23/62Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B01J23/622Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
    • B01J23/626Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with tin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/09Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis
    • C07C29/095Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of esters of organic acids
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/76Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
    • C07C29/80Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/76Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
    • C07C29/80Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation
    • C07C29/84Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation by extractive distillation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst

Abstract

processo para produção de uma corrente de alimentação de éster para produção de ésters e coprodução de etanol. a presente invenção refere-se á recuperação de uma corrente de alimentação de éster, opcionalmente com a recuperação de etanol, de um produto de etanol cru obtido a partir da hidrogenação de ácido acético. processos de separação e purificação dos produtos de etanol crus são empregados para permitir a recuperação da corrente de alimentação de éster e para integração da corrente de alimentação de éster com um processo de produção de ésteres. a composição da corrente de alimentação de éster pode variar, proém pelo menos compreende acetado de etila e etanol. a corrente de alimentação de éster pode ser alimentada para uma ou mais localizações dentro do processo de produção de ésteres dependendo da composição da corrente de alimentação de éster.
BR112012019413A 2010-02-02 2011-02-01 processo para producao de uma corrente de alimentacao de ester para producao de esteres e coproducao de etanol BR112012019413A2 (pt)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
US30081510P 2010-02-02 2010-02-02
US33272810P 2010-05-07 2010-05-07
US33269910P 2010-05-07 2010-05-07
US33269610P 2010-05-07 2010-05-07
US34634410P 2010-05-19 2010-05-19
US12/833,816 US8394985B2 (en) 2010-02-02 2010-07-09 Process for producing an ester feed stream for esters production and co-production of ethanol
PCT/US2011/023338 WO2011097227A2 (en) 2010-02-02 2011-02-01 Process for producing an ester feed stream for esters production and co-production of ethanol

Publications (1)

Publication Number Publication Date
BR112012019413A2 true BR112012019413A2 (pt) 2018-03-20

Family

ID=44544074

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112012019413A BR112012019413A2 (pt) 2010-02-02 2011-02-01 processo para producao de uma corrente de alimentacao de ester para producao de esteres e coproducao de etanol

Country Status (11)

Country Link
US (1) US8394985B2 (pt)
EP (1) EP2531471A2 (pt)
CN (1) CN102421730B (pt)
AU (1) AU2011213066A1 (pt)
BR (1) BR112012019413A2 (pt)
CA (1) CA2787821A1 (pt)
HK (1) HK1169383A1 (pt)
MX (1) MX2012008939A (pt)
SG (1) SG182693A1 (pt)
TW (1) TW201134805A (pt)
WO (1) WO2011097227A2 (pt)

Families Citing this family (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012039840A2 (en) * 2010-02-02 2012-03-29 Celanese International Corporation Processes for producing alcohols from a mixed acid feed
US8858659B2 (en) 2010-02-02 2014-10-14 Celanese International Corporation Processes for producing denatured ethanol
US8932372B2 (en) 2010-02-02 2015-01-13 Celanese International Corporation Integrated process for producing alcohols from a mixed acid feed
US8846986B2 (en) 2011-04-26 2014-09-30 Celanese International Corporation Water separation from crude alcohol product
US9150474B2 (en) 2010-07-09 2015-10-06 Celanese International Corporation Reduction of acid within column through esterification during the production of alcohols
US8846988B2 (en) 2010-07-09 2014-09-30 Celanese International Corporation Liquid esterification for the production of alcohols
US8884080B2 (en) 2010-07-09 2014-11-11 Celanese International Corporation Reduced energy alcohol separation process
US8536384B2 (en) 2010-07-09 2013-09-17 Celanese International Corporation Recovering ethanol sidedraw by separating crude product from hydrogenation process
US9126125B2 (en) 2010-07-09 2015-09-08 Celanese International Corporation Reduced energy alcohol separation process having water removal
US8686200B2 (en) 2011-04-26 2014-04-01 Celanese International Corporation Process to recover alcohol from an acidic residue stream
US8907141B2 (en) 2011-04-26 2014-12-09 Celanese International Corporation Process to recover alcohol with secondary reactors for esterification of acid
US8748675B2 (en) 2011-06-16 2014-06-10 Celanese International Corporation Extractive distillation of crude alcohol product
US9073816B2 (en) 2011-04-26 2015-07-07 Celanese International Corporation Reducing ethyl acetate concentration in recycle streams for ethanol production processes
TW201245128A (en) * 2011-04-26 2012-11-16 Celanese Int Corp Reduced energy alcohol separation process having water removal
WO2012149199A2 (en) * 2011-04-26 2012-11-01 Celanese International Corporation Process for producing ethanol and reducing acetic acid concentration
MX2013012537A (es) * 2011-04-26 2013-12-02 Celanese Int Corp Reduccion de acido dentro de la columna a traves de la esterificacion durante la produccion de alcoholes.
US8686199B2 (en) 2011-04-26 2014-04-01 Celanese International Corporation Process for reducing the concentration of acetic acid in a crude alcohol product
US9000232B2 (en) 2011-04-26 2015-04-07 Celanese International Corporation Extractive distillation of crude alcohol product
US9000233B2 (en) 2011-04-26 2015-04-07 Celanese International Corporation Process to recover alcohol with secondary reactors for hydrolysis of acetal
US9024085B2 (en) 2011-04-26 2015-05-05 Celanese International Corporation Process to reduce ethanol recycled to hydrogenation reactor
US9024082B2 (en) 2011-04-26 2015-05-05 Celanese International Corporation Using a dilute acid stream as an extractive agent
US8927787B2 (en) 2011-04-26 2015-01-06 Celanese International Corporation Process for controlling a reboiler during alcohol recovery and reduced ester formation
US8933278B2 (en) 2011-04-26 2015-01-13 Celanese International Corporation Process for producing ethanol and reducing acetic acid concentration
US9024084B2 (en) 2011-04-26 2015-05-05 Celanese International Corporation Reduced energy alcohol separation process having controlled pressure
US8927788B2 (en) 2011-04-26 2015-01-06 Celanese International Corporation Process to recover alcohol with reduced water from overhead of acid column
WO2013078207A1 (en) * 2011-11-22 2013-05-30 Celanese International Corporation Esterifying an ethanol and acetic acid mixture to produce an ester feed for hydrogenolysis
WO2013078212A1 (en) * 2011-11-22 2013-05-30 Celanese International Corporation Hydrogenating acetic acid to produce ethyl acetate and reducing ethyl acetate to ethanol
WO2013089990A1 (en) * 2011-12-14 2013-06-20 Celanese International Corporation Phasing reactor product from hydrogenating acetic acid into ethyl acetate feed to produce ethanol
WO2013101305A1 (en) * 2011-12-30 2013-07-04 Celanese International Corporation Pressure driven distillation for producing and recovering ethanol from hydrogenation process
CN102718627B (zh) * 2012-06-25 2014-06-18 西安隽通电子设备有限公司 一种乙酸乙酯加氢制乙醇的工艺方法
US8853469B2 (en) * 2012-11-20 2014-10-07 Celanese International Corporation Combined column for separating products of different hydrogenation reactors
CN103657155B (zh) * 2013-10-11 2015-07-29 上海华谊工程有限公司 乙酸乙酯的分离设备、制备乙酸乙酯的装置及制备方法
CN106365989B (zh) * 2016-08-29 2019-05-21 西南化工研究设计院有限公司 一种甲酸乙酯和乙酸乙酯联产的方法

Family Cites Families (114)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1939116A (en) 1929-07-23 1933-12-12 Firm Of Deutsche Gold Und Silb Process for the continuous production of esters of ethyl alcohol
US2882244A (en) 1953-12-24 1959-04-14 Union Carbide Corp Molecular sieve adsorbents
US3130007A (en) 1961-05-12 1964-04-21 Union Carbide Corp Crystalline zeolite y
DE1235879B (de) 1964-03-17 1967-03-09 Basf Ag Verfahren zur Herstellung von Alkoholen durch katalytische Hydrierung von Carbonsaeuren
US3408267A (en) 1966-01-17 1968-10-29 Nat Distillers Chem Corp Extractive distillation of ethanol followed by activated carbon treatment
US3445345A (en) 1968-05-08 1969-05-20 Raphael Katzen Associates Extractive distillation of c1 to c3 alcohols and subsequent distillation of purge streams
US3884981A (en) 1972-12-27 1975-05-20 Union Carbide Corp Vapor phase hydrogenolysis dehydrogenation process
US3990952A (en) 1974-10-10 1976-11-09 Raphael Katzen Associates International, Inc. Alcohol distillation process
FR2426037A1 (fr) 1978-05-17 1979-12-14 Rhone Poulenc Ind Procede de preparation de l'acetate d'ethyle
US4352940A (en) 1980-04-28 1982-10-05 E. I. Du Pont De Nemours And Company Hydrolysis of methyl acetate
US4306942A (en) 1980-06-27 1981-12-22 Raphael Katzen Associates International, Inc. Hydrous alcohol distillation method and apparatus
US4319058A (en) 1980-10-10 1982-03-09 Uop Inc. Process for the separation of ethanol from water
DE3101750A1 (de) 1981-01-21 1982-08-26 Basf Ag, 6700 Ludwigshafen Verfahren zur kontinuierlichen herstellung von ethanol
US4886905A (en) 1981-01-30 1989-12-12 Eastman Kodak Company Preparation of ethyl acetate
US4465854A (en) 1981-03-17 1984-08-14 Eastman Kodak Company Preparation of ethyl acetate
US4471136A (en) 1981-03-17 1984-09-11 Eastman Kodak Company Preparation of ethyl acetate
US4398039A (en) 1981-05-18 1983-08-09 The Standard Oil Company Hydrogenation of carboxylic acids
DE3303571C2 (de) 1982-03-11 1984-07-26 Buckau-Walther AG, 4048 Grevenbroich Verfahren und Anlage zur Herstellung von Äthanol
DE3363702D1 (en) 1982-03-26 1986-07-03 Davy Mckee London Process for the production of ethanol
FR2527200A1 (fr) 1982-05-24 1983-11-25 Inst Francais Du Petrole Procede catalytique de production d'alcools par hydrogenolyse d'esters d'acides carboxyliques
US4480115A (en) 1983-03-17 1984-10-30 Celanese Corporation Direct hydrogenation of carboxylic acids to alcohol and esters
DE3313530A1 (de) 1983-04-14 1984-10-18 Fried. Krupp Gmbh, 4300 Essen Verfahren zur abtrennung von aethanol aus einer athanolhaltigen loesung
US5124004A (en) 1983-08-22 1992-06-23 Trustees Of Dartmouth College Distillation process for ethanol
US4626321A (en) 1983-08-22 1986-12-02 Trustees Of Dartmouth College Distillation systems and methods
BR8404579A (pt) 1983-09-14 1985-08-06 Halcon Sd Group Inc Processo para tratamento de acido acetico aquoso diluido
US5026908A (en) 1984-05-03 1991-06-25 Hoechst Celanese Corporation Methanol carbonylation process
US5144068A (en) 1984-05-03 1992-09-01 Hoechst Celanese Corporation Methanol carbonylation process
US5001259A (en) 1984-05-03 1991-03-19 Hoechst Celanese Corporation Methanol carbonylation process
EP0167300A1 (en) 1984-06-06 1986-01-08 Humphreys & Glasgow Limited Process for the production of alcohols
US4497967A (en) 1984-06-15 1985-02-05 The Halcon Sd Group, Inc. Process for the preparation of ethanol from methanol, carbon monoxide _and hydrogen
FR2568873B1 (fr) 1984-08-08 1987-01-09 Inst Francais Du Petrole Procede de production d'alcools par hydrogenolyse d'esters d'acides carboxyliques en presence d'un catalyseur contenant du nickel et de l'etain, du germanium ou du plomb
GB8509530D0 (en) 1985-04-13 1985-05-15 Bp Chem Int Ltd Hydrogenation of carboxylic acids
GB8601081D0 (en) 1986-01-17 1986-02-19 Distillers Co Carbon Dioxide Removing water from ethanol
US4961826A (en) 1986-02-13 1990-10-09 Trustees Of Dartmouth College Distillation process for ethanol
CA1299195C (en) 1986-06-16 1992-04-21 G. Paull Torrence Addition of hydrogen to carbon monoxide feed gas in producing acetic acid by carbonylation of methanol
GB8707595D0 (en) 1987-03-31 1987-05-07 British Petroleum Co Plc Chemical process
US5149680A (en) 1987-03-31 1992-09-22 The British Petroleum Company P.L.C. Platinum group metal alloy catalysts for hydrogenation of carboxylic acids and their anhydrides to alcohols and/or esters
US5250271A (en) 1987-07-24 1993-10-05 Minister Of International Trade & Industry Apparatus to concentrate and purify alcohol
US5198592A (en) 1987-12-11 1993-03-30 Engelhard De Meern B.V. Hydrogenolysis reaction and catalyst suitable therefor
GB8828616D0 (en) * 1988-12-07 1989-01-11 Bp Chem Int Ltd Chemical process
FI80218C (fi) 1988-12-30 1990-05-10 Alko Ab Oy Foerfarande och anlaeggning foer rening av en tvaokomponentvaetskeblandning medelst destillering.
GB8917157D0 (en) 1989-07-27 1989-09-13 Bp Chem Int Ltd Chemical process
US4994606A (en) * 1989-11-20 1991-02-19 Occidental Chemical Corporation Process for the preparation of 4,5-difluoroanthranilic acid from 4,5-difluorophthalic anhydride or 4,5-difluorophthalic acid
US5035776A (en) 1990-03-29 1991-07-30 University Of Massachusetts Low energy extractive distillation process for producing anhydrous ethanol
JPH0635403B2 (ja) 1990-04-16 1994-05-11 通商産業省基礎産業局長 粗製エタノール水溶液中の不純物の分離方法
US5241106A (en) 1991-10-22 1993-08-31 Mitsui Toatsu Chemicals, Inc. Process for producing ethyl acetate
US5414161A (en) 1992-06-30 1995-05-09 Korea Institute Of Science And Technology Process for the preparation of ethanol from methanol
US5821111A (en) 1994-03-31 1998-10-13 Bioengineering Resources, Inc. Bioconversion of waste biomass to useful products
IT1256062B (it) 1992-11-20 1995-11-23 Snam Progetti Procedimento per l'ottenimento di correnti di metanolo, etanolo, n-propanolo,isobutanolo,utilizzabili soprattutto nella preparazione diprodotti alto ottanici, da miscele contenenti detti alcoli con acqua ed altri composti bassobollenti e altobollenti
USRE35377E (en) 1993-05-27 1996-11-12 Steinberg; Meyer Process and apparatus for the production of methanol from condensed carbonaceous material
JP3381804B2 (ja) 1993-07-27 2003-03-04 荒川化学工業株式会社 カルボン酸直接還元用触媒および該触媒の製造方法ならびにアルコール化合物の製造方法
KR960022419A (ko) 1994-12-29 1996-07-18 김준웅 반응증류를 이용하여 메틸아세테이트로부터 초산과 메탄올을 제조하는 방법 및 장치
US5502248A (en) 1995-02-27 1996-03-26 Uop Process for concurrent hydrolysis of esters and separation of products using a simulated moving bed
US5599976A (en) 1995-04-07 1997-02-04 Hoechst Celanese Corporation Recovery of acetic acid from dilute aqueous streams formed during a carbonylation process
DE69607536T2 (de) 1995-08-02 2001-02-08 Bp Chem Int Ltd Estersynthese
DE19631859A1 (de) * 1996-08-07 1998-02-12 Bayer Ag Verfahren zur Polymerisation von Isocyanaten
GB9616573D0 (en) 1996-08-07 1996-09-25 Bp Chem Int Ltd Process
IN192600B (pt) 1996-10-18 2004-05-08 Hoechst Celanese Corp
US5770761A (en) 1996-11-08 1998-06-23 Chinese Petroleum Corporation Process for ethyl acetate production
CA2256626C (en) 1997-03-26 2006-08-22 Bp Chemicals Limited Ester co-production
US5998658A (en) 1998-06-26 1999-12-07 Industrial Technology Research Institute Catalytic processes for the preparation of acetic esters
US5973193A (en) 1998-07-16 1999-10-26 Mobil Oil Corporation Ethyl acetate synthesis from ethylene and acetic acid using solid acid catalysts
EP0992484A1 (en) 1998-10-01 2000-04-12 Kvaerner Process Technology Limited Process
EP0992482A1 (en) 1998-10-01 2000-04-12 Kvaerner Process Technology Limited Process
EP0990638A1 (en) 1998-10-01 2000-04-05 Kvaerner Process Technology Limited Process
DE69910962T2 (de) 1998-12-24 2004-07-22 Council Of Scientific & Industrial Research Verfahren zur Herstellung von Estern
ATE405665T1 (de) 1999-03-11 2008-09-15 Zeachem Inc Verfahren zur herstellung von äthanol
US7074603B2 (en) 1999-03-11 2006-07-11 Zeachem, Inc. Process for producing ethanol from corn dry milling
CZ292620B6 (cs) 1999-10-14 2003-11-12 Sulzer Chemtech Ltd. Způsob výroby etylacetátu a zařízení k provádění tohoto způsobu
US6232352B1 (en) 1999-11-01 2001-05-15 Acetex Limited Methanol plant retrofit for acetic acid manufacture
DE19953058A1 (de) * 1999-11-03 2001-05-10 Basf Ag Phosphite
US6723886B2 (en) 1999-11-17 2004-04-20 Conocophillips Company Use of catalytic distillation reactor for methanol synthesis
US6768021B2 (en) 1999-12-22 2004-07-27 Celanese International Corporation Process improvement for continuous ethyl acetate production
DE10009817A1 (de) 2000-03-01 2001-09-06 Basf Ag Verfahren zur Herstellung von Alkoholen an rheniumhaltigen Aktivkohle-Trägerkatalysatoren
US6399812B1 (en) * 2000-04-27 2002-06-04 Tsoung Y. Yan Production of aliphatic esters
WO2001087458A1 (en) 2000-05-12 2001-11-22 University Of Cincinnati Magnetic bead-based arrays
US6627770B1 (en) 2000-08-24 2003-09-30 Celanese International Corporation Method and apparatus for sequesting entrained and volatile catalyst species in a carbonylation process
US6765110B2 (en) 2000-12-19 2004-07-20 Celanese International Corporation Process for the simultaneous coproduction and purification of ethyl acetate and isopropyl acetate
US6657078B2 (en) 2001-02-07 2003-12-02 Celanese International Corporation Low energy carbonylation process
US6685754B2 (en) 2001-03-06 2004-02-03 Alchemix Corporation Method for the production of hydrogen-containing gaseous mixtures
US7297236B1 (en) 2001-06-30 2007-11-20 Icm, Inc. Ethanol distillation process
US7115772B2 (en) 2002-01-11 2006-10-03 Celanese International Corporation Integrated process for producing carbonylation acetic acid, acetic anhydride, or coproduction of each from a methyl acetate by-product stream
US7005541B2 (en) 2002-12-23 2006-02-28 Celanese International Corporation Low water methanol carbonylation process for high acetic acid production and for water balance control
WO2005073161A1 (en) 2004-01-29 2005-08-11 Zeachem Inc. Recovery of organic acids
US7208624B2 (en) 2004-03-02 2007-04-24 Celanese International Corporation Process for producing acetic acid
US7700801B2 (en) 2004-11-15 2010-04-20 Celanese International Corporation Co-production of vinyl acetate and ethyl acetate
DE112006001685A5 (de) 2005-04-20 2008-04-03 White Fox Technologies Ltd. Trennverfahren
ES2539761T3 (es) 2006-04-05 2015-07-03 Woodland Biofuels Inc. Sistema y método para convertir biomasa en etanol a través del gas de síntesis
MX2009008496A (es) 2007-02-09 2009-08-20 Zeachem Inc Metodos de energia eficiente para producir productos.
US8080684B2 (en) 2007-06-27 2011-12-20 H R D Corporation Method of producing ethyl acetate
WO2009009320A1 (en) 2007-07-06 2009-01-15 Best Energies Inc. Improved indirect process for producing ethanol
US7923405B2 (en) 2007-09-07 2011-04-12 Range Fuels, Inc. Cobalt-molybdenum sulfide catalyst materials and methods for ethanol production from syngas
CA2705723A1 (en) 2007-11-14 2009-05-22 Bp P.L.C. Process for the production of alcohol from a carbonaceous feedstock
WO2009063174A1 (en) 2007-11-14 2009-05-22 Bp P.L.C. An improved process for the production of alcohol from a carbonaceous feedstock
EP2060553A1 (en) 2007-11-14 2009-05-20 BP p.l.c. Process for the conversion of hydrocarbons into alcohol
EP2072492A1 (en) 2007-12-17 2009-06-24 BP p.l.c. Process for the conversion of hydrocarbons to ethanol
EP2072489A1 (en) 2007-12-17 2009-06-24 BP p.l.c. Process for the conversion of hydrocarbons into ethanol
EP2072488A1 (en) 2007-12-17 2009-06-24 BP p.l.c. Process for the conversion of hydrocarbon to ethanol
EP2072487A1 (en) 2007-12-17 2009-06-24 BP p.l.c. Process for the conversion of hydrocarbons to ethanol
BRPI0908303A2 (pt) 2008-05-07 2015-08-18 Zeachem Inc Recuperação de ácidos orgânicos
US20100030001A1 (en) 2008-07-31 2010-02-04 Laiyuan Chen Process for catalytically producing ethylene directly from acetic acid in a single reaction zone
US20100030002A1 (en) 2008-07-31 2010-02-04 Johnston Victor J Ethylene production from acetic acid utilizing dual reaction zone process
US8309772B2 (en) 2008-07-31 2012-11-13 Celanese International Corporation Tunable catalyst gas phase hydrogenation of carboxylic acids
US8680317B2 (en) 2008-07-31 2014-03-25 Celanese International Corporation Processes for making ethyl acetate from acetic acid
US20100197486A1 (en) 2008-07-31 2010-08-05 Celanese International Corporation Catalysts for making ethyl acetate from acetic acid
US7863489B2 (en) 2008-07-31 2011-01-04 Celanese International Corporation Direct and selective production of ethanol from acetic acid utilizing a platinum/tin catalyst
US7608744B1 (en) 2008-07-31 2009-10-27 Celanese International Corporation Ethanol production from acetic acid utilizing a cobalt catalyst
US8501652B2 (en) 2008-07-31 2013-08-06 Celanese International Corporation Catalysts for making ethanol from acetic acid
US7820852B2 (en) 2008-07-31 2010-10-26 Celanese International Corporation Direct and selective production of ethyl acetate from acetic acid utilizing a bimetal supported catalyst
US8546622B2 (en) 2008-07-31 2013-10-01 Celanese International Corporation Process for making ethanol from acetic acid using acidic catalysts
EP2186787A1 (en) 2008-11-13 2010-05-19 BP p.l.c. Hydrogenation of ethanoic acid to produce ethanol
US7884253B2 (en) 2008-12-11 2011-02-08 Range Fuels, Inc. Methods and apparatus for selectively producing ethanol from synthesis gas
US8680321B2 (en) 2009-10-26 2014-03-25 Celanese International Corporation Processes for making ethanol from acetic acid using bimetallic catalysts
US8575403B2 (en) 2010-05-07 2013-11-05 Celanese International Corporation Hydrolysis of ethyl acetate in ethanol separation process

Also Published As

Publication number Publication date
CA2787821A1 (en) 2011-08-11
EP2531471A2 (en) 2012-12-12
CN102421730A (zh) 2012-04-18
MX2012008939A (es) 2012-08-15
WO2011097227A3 (en) 2011-10-27
WO2011097227A2 (en) 2011-08-11
CN102421730B (zh) 2014-07-30
SG182693A1 (en) 2012-08-30
TW201134805A (en) 2011-10-16
AU2011213066A1 (en) 2012-08-02
HK1169383A1 (en) 2013-01-25
US20110190532A1 (en) 2011-08-04
US8394985B2 (en) 2013-03-12

Similar Documents

Publication Publication Date Title
BR112012019413A2 (pt) processo para producao de uma corrente de alimentacao de ester para producao de esteres e coproducao de etanol
BR112012019156A2 (pt) processo para recuperação de etanol
BR112012019406A2 (pt) processo para purificacao de um produto de etanol bruto
BR112012032360A2 (pt) hidrogenólise de acetato de etila em processos de separação de álcool
WO2008130974A3 (en) System and process for producing biodiesel
CL2011001612A1 (es) Proceso de produccion de acetato de vinilo que comprende: contactar una corriente de alimentacion de acido acetico e hidrogeno a temperatura elevada con catalizador de hidrogenacion, enriquecer la corriente con acetato de etilo,contactar la corriente con un catalizador de cracking, y separar el acetato de vinilo
AR082942A1 (es) Composiciones de etanol y metodo de preparacion
BR112012019032A2 (pt) "processo para purificação de etanol"
BR112014019944A8 (pt) Método para a produção contínua de um anidrido de ácido
MX2009012351A (es) Metodo y aparato para elaborar acido acetico con productividad mejorada de columna de fracciones volatiles.
AR086137A1 (es) Proceso para producir etanol desde una alimentacion de acido acetico y una alimentacion de acetato de etilo reciclado
BR112012032411A2 (pt) sistema de recuperação de ácido fraco para processos de separação de etanol
BR112012028453A2 (pt) processo para produzir etanol
WO2011097193A3 (en) Process for purifying a crude ethanol product
BR112012028566A2 (pt) processo para produção de álcool integrando corrente de alimentação de ácido acético que compreende água do processo de carbonilação
BR112012019367A2 (pt) processo para integração de calor para produção de etanol e processo de purificação.
MX2015008022A (es) Sistema y procedimiento para la obtencion de productos de biomasa.
BR112014026199A2 (pt) processo de fermentação
MX2013012534A (es) Procedimiento de separacion que tiene una corriente lateral de alcohol.
BR112012019307A2 (pt) processo para produzir composições de etanol anidras
CO6602151A2 (es) Procesos para producir etanol desnaturalizado
BR112014000848A2 (pt) processo de separação
BR112012019371A2 (pt) processos para maximizar a formação de etanol na hidrogenação de ácido acético.
AR086131A1 (es) Proceso para reducir etanol reciclado hasta reactor de hidrogenacion
BR112012019310A2 (pt) processos para purificação de etanol

Legal Events

Date Code Title Description
B08F Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette]
B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]

Free format text: EM VIRTUDE DO ARQUIVAMENTO PUBLICADO NA RPI 2465 DE 03-04-2018 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDO O ARQUIVAMENTO DO PEDIDO DE PATENTE, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.