BR112012019367A2 - processo para integração de calor para produção de etanol e processo de purificação. - Google Patents

processo para integração de calor para produção de etanol e processo de purificação.

Info

Publication number
BR112012019367A2
BR112012019367A2 BR112012019367A BR112012019367A BR112012019367A2 BR 112012019367 A2 BR112012019367 A2 BR 112012019367A2 BR 112012019367 A BR112012019367 A BR 112012019367A BR 112012019367 A BR112012019367 A BR 112012019367A BR 112012019367 A2 BR112012019367 A2 BR 112012019367A2
Authority
BR
Brazil
Prior art keywords
heat integration
purification
ethanol production
production
ethanol
Prior art date
Application number
BR112012019367A
Other languages
English (en)
Inventor
Ronald OLSSON Fred
Grusendorf Gerald
Sarager Lincoln
Viard Murray
Kirk Powell Nathan
Jay Warner R
Jevtic Radmila
Roundy Samuel
J Johnston Victor
Original Assignee
Celanese Int Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Celanese Int Corp filed Critical Celanese Int Corp
Publication of BR112012019367A2 publication Critical patent/BR112012019367A2/pt

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D3/00Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/007Energy recuperation; Heat pumps
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D3/00Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/14Fractional distillation or use of a fractionation or rectification column
    • B01D3/143Fractional distillation or use of a fractionation or rectification column by two or more of a fractionation, separation or rectification step
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/04Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • B01J8/0446Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical
    • B01J8/0449Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more cylindrical beds
    • B01J8/0457Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more cylindrical beds the beds being placed in separate reactors
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/76Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
    • C07C29/80Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002Chemical plants
    • B01J2219/00004Scale aspects
    • B01J2219/00006Large-scale industrial plants
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/10Greenhouse gas [GHG] capture, material saving, heat recovery or other energy efficient measures, e.g. motor control, characterised by manufacturing processes, e.g. for rolling metal or metal working

Abstract

processo para integração de calor para produção de etanol e processo de purificação. a presente invenção refere-se à produção de etanol da hidrogenação de ácido acético que exige energia para direcionar a reação de hidrogenação e a purificação do produto de etanol bruto. o processo de integração de calor para recuperar calor de uma parte do processo de produção a ser usado dentro do processo melhora as eficiências e reduz os custos.
BR112012019367A 2010-02-02 2011-02-01 processo para integração de calor para produção de etanol e processo de purificação. BR112012019367A2 (pt)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US30081510P 2010-02-02 2010-02-02
US33269910P 2010-05-07 2010-05-07
US33269610P 2010-05-07 2010-05-07
US12/986,008 US8552226B2 (en) 2010-02-02 2011-01-06 Process for heat integration for ethanol production and purification process
PCT/US2011/023305 WO2011097208A2 (en) 2010-02-02 2011-02-01 Process for heat integration for ethanol production and purification process

Publications (1)

Publication Number Publication Date
BR112012019367A2 true BR112012019367A2 (pt) 2018-05-08

Family

ID=44342219

Family Applications (2)

Application Number Title Priority Date Filing Date
BR112012019367A BR112012019367A2 (pt) 2010-02-02 2011-02-01 processo para integração de calor para produção de etanol e processo de purificação.
BR112012019035A BR112012019035A2 (pt) 2010-02-02 2011-02-01 "processo para vaporização de ácido acético para processos de hidrogenação para produzir etanol".

Family Applications After (1)

Application Number Title Priority Date Filing Date
BR112012019035A BR112012019035A2 (pt) 2010-02-02 2011-02-01 "processo para vaporização de ácido acético para processos de hidrogenação para produzir etanol".

Country Status (10)

Country Link
US (2) US8552226B2 (pt)
EP (1) EP2531478A2 (pt)
CN (1) CN102421731B (pt)
AU (1) AU2011213047A1 (pt)
BR (2) BR112012019367A2 (pt)
CA (1) CA2787417A1 (pt)
MX (1) MX2012008932A (pt)
SG (1) SG182609A1 (pt)
TW (1) TW201136876A (pt)
WO (1) WO2011097208A2 (pt)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8575403B2 (en) 2010-05-07 2013-11-05 Celanese International Corporation Hydrolysis of ethyl acetate in ethanol separation process
US8710279B2 (en) 2010-07-09 2014-04-29 Celanese International Corporation Hydrogenolysis of ethyl acetate in alcohol separation processes
US9272970B2 (en) 2010-07-09 2016-03-01 Celanese International Corporation Hydrogenolysis of ethyl acetate in alcohol separation processes
US8664454B2 (en) 2010-07-09 2014-03-04 Celanese International Corporation Process for production of ethanol using a mixed feed using copper containing catalyst
US8754268B2 (en) 2011-04-26 2014-06-17 Celanese International Corporation Process for removing water from alcohol mixtures
US8592635B2 (en) 2011-04-26 2013-11-26 Celanese International Corporation Integrated ethanol production by extracting halides from acetic acid
TW201302684A (zh) 2011-04-26 2013-01-16 Celanese Int Corp 由醋酸進料及再循環醋酸乙酯進料生產乙醇之製程
CN103080053B (zh) 2011-04-26 2015-08-12 国际人造丝公司 使用叠置床反应器生产乙醇的方法
US9073816B2 (en) 2011-04-26 2015-07-07 Celanese International Corporation Reducing ethyl acetate concentration in recycle streams for ethanol production processes
US8895786B2 (en) 2011-08-03 2014-11-25 Celanese International Corporation Processes for increasing alcohol production
US20140073813A1 (en) * 2012-09-13 2014-03-13 Celanese International Corporation Heat Integration of Carbonylation and Aldol Condensation Reaction Processes
US9000237B2 (en) * 2012-12-20 2015-04-07 Celanese International Corporation Ethanol refining process using intermediate reboiler
US8975450B2 (en) * 2013-03-15 2015-03-10 Celanese International Corporation Ethanol and ethyl acetate production using an acetic acid and acetic anhydride mixed feed
GB202208864D0 (en) * 2022-06-16 2022-08-10 Johnson Matthey Davy Technologies Ltd Process for the recovery of ethanol from crude ethyl acetate

Family Cites Families (94)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2702783A (en) * 1952-03-14 1955-02-22 Gulf Research Development Co Process of separating mixtures of organic compounds
US2649407A (en) * 1952-03-14 1953-08-18 Gulf Research Development Co Separation of ethyl acetate and ethanol by azeotropic distillation with methanol
US2882244A (en) * 1953-12-24 1959-04-14 Union Carbide Corp Molecular sieve adsorbents
US2744939A (en) * 1954-11-26 1956-05-08 Standard Oil Co Production of alcohols of high purity by improved oxo process
US3130007A (en) * 1961-05-12 1964-04-21 Union Carbide Corp Crystalline zeolite y
DE1235879B (de) * 1964-03-17 1967-03-09 Basf Ag Verfahren zur Herstellung von Alkoholen durch katalytische Hydrierung von Carbonsaeuren
US3408267A (en) * 1966-01-17 1968-10-29 Nat Distillers Chem Corp Extractive distillation of ethanol followed by activated carbon treatment
US3445345A (en) * 1968-05-08 1969-05-20 Raphael Katzen Associates Extractive distillation of c1 to c3 alcohols and subsequent distillation of purge streams
FR2426037A1 (fr) * 1978-05-17 1979-12-14 Rhone Poulenc Ind Procede de preparation de l'acetate d'ethyle
US4317918A (en) * 1979-11-05 1982-03-02 Sumitomo Chemical Co., Ltd. Process for preparing alcohols
NL8003405A (nl) * 1980-06-12 1982-01-04 Shell Int Research Werkwijze voor het bereiden van ethanol.
US4306942A (en) * 1980-06-27 1981-12-22 Raphael Katzen Associates International, Inc. Hydrous alcohol distillation method and apparatus
US4319058A (en) * 1980-10-10 1982-03-09 Uop Inc. Process for the separation of ethanol from water
DE3101750A1 (de) * 1981-01-21 1982-08-26 Basf Ag, 6700 Ludwigshafen Verfahren zur kontinuierlichen herstellung von ethanol
US4471136A (en) * 1981-03-17 1984-09-11 Eastman Kodak Company Preparation of ethyl acetate
US4465854A (en) * 1981-03-17 1984-08-14 Eastman Kodak Company Preparation of ethyl acetate
US4398039A (en) * 1981-05-18 1983-08-09 The Standard Oil Company Hydrogenation of carboxylic acids
DE3142518A1 (de) * 1981-10-27 1983-05-05 Chemische Werke Hüls AG, 4370 Marl Destillationsverfahren zur herstellung von entwaessertem ethanol
DE3303571C2 (de) * 1982-03-11 1984-07-26 Buckau-Walther AG, 4048 Grevenbroich Verfahren und Anlage zur Herstellung von Äthanol
JPS59500516A (ja) 1982-03-26 1984-03-29 デイビ− マツキ− (ロンドン) リミテツド エタノ−ルの生成方法
DE3221077A1 (de) * 1982-06-04 1983-12-08 Basf Ag, 6700 Ludwigshafen Verfahren zur kontinuierlichen herstellung von ethanol
US4421939A (en) * 1982-10-15 1983-12-20 Union Carbide Corporation Production of ethanol from acetic acid
US4480115A (en) * 1983-03-17 1984-10-30 Celanese Corporation Direct hydrogenation of carboxylic acids to alcohol and esters
DE3313530A1 (de) * 1983-04-14 1984-10-18 Fried. Krupp Gmbh, 4300 Essen Verfahren zur abtrennung von aethanol aus einer athanolhaltigen loesung
US4626321A (en) * 1983-08-22 1986-12-02 Trustees Of Dartmouth College Distillation systems and methods
US5124004A (en) * 1983-08-22 1992-06-23 Trustees Of Dartmouth College Distillation process for ethanol
US5026908A (en) * 1984-05-03 1991-06-25 Hoechst Celanese Corporation Methanol carbonylation process
US5144068A (en) * 1984-05-03 1992-09-01 Hoechst Celanese Corporation Methanol carbonylation process
US5001259A (en) * 1984-05-03 1991-03-19 Hoechst Celanese Corporation Methanol carbonylation process
US4497967A (en) * 1984-06-15 1985-02-05 The Halcon Sd Group, Inc. Process for the preparation of ethanol from methanol, carbon monoxide _and hydrogen
GB8509530D0 (en) * 1985-04-13 1985-05-15 Bp Chem Int Ltd Hydrogenation of carboxylic acids
US5215902A (en) * 1985-08-12 1993-06-01 Georgia Tech Research Corporation Process for recovering alcohol with energy integration
GB8601081D0 (en) * 1986-01-17 1986-02-19 Distillers Co Carbon Dioxide Removing water from ethanol
US4961826A (en) * 1986-02-13 1990-10-09 Trustees Of Dartmouth College Distillation process for ethanol
CA1299195C (en) * 1986-06-16 1992-04-21 G. Paull Torrence Addition of hydrogen to carbon monoxide feed gas in producing acetic acid by carbonylation of methanol
GB8707595D0 (en) * 1987-03-31 1987-05-07 British Petroleum Co Plc Chemical process
US5149680A (en) * 1987-03-31 1992-09-22 The British Petroleum Company P.L.C. Platinum group metal alloy catalysts for hydrogenation of carboxylic acids and their anhydrides to alcohols and/or esters
US5250271A (en) * 1987-07-24 1993-10-05 Minister Of International Trade & Industry Apparatus to concentrate and purify alcohol
GB8917862D0 (en) * 1989-08-04 1989-09-20 Davy Mckee London Process
US5237108A (en) * 1990-03-06 1993-08-17 Ausimont S.R.L. Perfluoropolyethers and processes for their preparation
US5035776A (en) * 1990-03-29 1991-07-30 University Of Massachusetts Low energy extractive distillation process for producing anhydrous ethanol
JPH0699337B2 (ja) * 1990-12-27 1994-12-07 花王株式会社 アルコールの製造方法
US5070016A (en) * 1991-03-28 1991-12-03 Revolution Fuels Of America, Inc. Integrated process for producing ethanol, methanol and butyl ethers
US5185308A (en) * 1991-05-06 1993-02-09 Bp Chemicals Limited Catalysts and processes for the manufacture of vinyl acetate
US5821111A (en) * 1994-03-31 1998-10-13 Bioengineering Resources, Inc. Bioconversion of waste biomass to useful products
IT1256062B (it) * 1992-11-20 1995-11-23 Snam Progetti Procedimento per l'ottenimento di correnti di metanolo, etanolo, n-propanolo,isobutanolo,utilizzabili soprattutto nella preparazione diprodotti alto ottanici, da miscele contenenti detti alcoli con acqua ed altri composti bassobollenti e altobollenti
USRE35377E (en) * 1993-05-27 1996-11-12 Steinberg; Meyer Process and apparatus for the production of methanol from condensed carbonaceous material
JPH07258136A (ja) * 1994-02-28 1995-10-09 Texaco Dev Corp 複数段蒸留におけるエネルギー保存方法
KR960022419A (ko) * 1994-12-29 1996-07-18 김준웅 반응증류를 이용하여 메틸아세테이트로부터 초산과 메탄올을 제조하는 방법 및 장치
US5599976A (en) * 1995-04-07 1997-02-04 Hoechst Celanese Corporation Recovery of acetic acid from dilute aqueous streams formed during a carbonylation process
IN192600B (pt) * 1996-10-18 2004-05-08 Hoechst Celanese Corp
US6121498A (en) * 1998-04-30 2000-09-19 Eastman Chemical Company Method for producing acetaldehyde from acetic acid
US6294703B1 (en) * 1998-06-22 2001-09-25 Mitsubishi Chemical Company Process for the manufacture of cycloalkyldimethanol
EP0992482A1 (en) * 1998-10-01 2000-04-12 Kvaerner Process Technology Limited Process
US6375807B1 (en) * 1999-01-28 2002-04-23 Izak Nieuwoudt Separation of ethanol mixtures by extractive distillation
US6509180B1 (en) * 1999-03-11 2003-01-21 Zeachem Inc. Process for producing ethanol
US7074603B2 (en) * 1999-03-11 2006-07-11 Zeachem, Inc. Process for producing ethanol from corn dry milling
CZ292620B6 (cs) * 1999-10-14 2003-11-12 Sulzer Chemtech Ltd. Způsob výroby etylacetátu a zařízení k provádění tohoto způsobu
US6232352B1 (en) 1999-11-01 2001-05-15 Acetex Limited Methanol plant retrofit for acetic acid manufacture
US6723886B2 (en) * 1999-11-17 2004-04-20 Conocophillips Company Use of catalytic distillation reactor for methanol synthesis
DE10009817A1 (de) * 2000-03-01 2001-09-06 Basf Ag Verfahren zur Herstellung von Alkoholen an rheniumhaltigen Aktivkohle-Trägerkatalysatoren
US6399812B1 (en) * 2000-04-27 2002-06-04 Tsoung Y. Yan Production of aliphatic esters
US6627770B1 (en) * 2000-08-24 2003-09-30 Celanese International Corporation Method and apparatus for sequesting entrained and volatile catalyst species in a carbonylation process
US6657078B2 (en) * 2001-02-07 2003-12-02 Celanese International Corporation Low energy carbonylation process
US6685754B2 (en) * 2001-03-06 2004-02-03 Alchemix Corporation Method for the production of hydrogen-containing gaseous mixtures
US7297236B1 (en) * 2001-06-30 2007-11-20 Icm, Inc. Ethanol distillation process
US7115772B2 (en) * 2002-01-11 2006-10-03 Celanese International Corporation Integrated process for producing carbonylation acetic acid, acetic anhydride, or coproduction of each from a methyl acetate by-product stream
US7005541B2 (en) * 2002-12-23 2006-02-28 Celanese International Corporation Low water methanol carbonylation process for high acetic acid production and for water balance control
US7208624B2 (en) * 2004-03-02 2007-04-24 Celanese International Corporation Process for producing acetic acid
WO2007095875A1 (de) * 2005-04-20 2007-08-30 White Fox Technologies Limited Trennverfahren
EP1741692A1 (en) 2005-07-06 2007-01-10 BP Chemicals Limited Process for the conversion of hydrocarbons to C2-oxygenates
US7732173B2 (en) * 2005-08-03 2010-06-08 Membrane Technology And Research, Inc. Ethanol recovery process
DE102006003492A1 (de) * 2006-01-25 2007-07-26 Oxeno Olefinchemie Gmbh Verfahren zur Entwässerung von Ethanol
WO2007117590A2 (en) * 2006-04-05 2007-10-18 Woodland Biofuels Inc. System and method for converting biomass to ethanol via syngas
DE102007020786A1 (de) 2007-05-03 2008-11-06 Gea Wiegand Gmbh Alkohol-Rektifikationsanlage
WO2009009322A1 (en) 2007-07-06 2009-01-15 Best Energies, Inc. Integrated facility for producing alcohol using homoacidogenic fermentation
WO2009009323A1 (en) 2007-07-06 2009-01-15 Best Energies, Inc. Improved homoacidogenic fermentation and indirect process for producing alcohols
US8002953B2 (en) * 2007-07-13 2011-08-23 Amt International Inc. Low-energy extractive distillation process for dehydration of aqueous ethanol
NO328571B1 (no) 2007-10-12 2010-03-22 Epcon Energy & Process Control Fremgangsmate ved avvanning av en blanding av overveiende etanol og vann
WO2009063176A1 (en) 2007-11-14 2009-05-22 Bp P.L.C. Process for the production of alcohol from a carbonaceous feedstock
EP2060553A1 (en) * 2007-11-14 2009-05-20 BP p.l.c. Process for the conversion of hydrocarbons into alcohol
US20090166172A1 (en) * 2007-12-28 2009-07-02 Leonard Ray Casey Ethanol plant process
US20090221725A1 (en) 2008-02-28 2009-09-03 Enerkem, Inc. Production of ethanol from methanol
US8309772B2 (en) * 2008-07-31 2012-11-13 Celanese International Corporation Tunable catalyst gas phase hydrogenation of carboxylic acids
US8546622B2 (en) * 2008-07-31 2013-10-01 Celanese International Corporation Process for making ethanol from acetic acid using acidic catalysts
US7863489B2 (en) * 2008-07-31 2011-01-04 Celanese International Corporation Direct and selective production of ethanol from acetic acid utilizing a platinum/tin catalyst
US20100030001A1 (en) * 2008-07-31 2010-02-04 Laiyuan Chen Process for catalytically producing ethylene directly from acetic acid in a single reaction zone
US7820852B2 (en) * 2008-07-31 2010-10-26 Celanese International Corporation Direct and selective production of ethyl acetate from acetic acid utilizing a bimetal supported catalyst
US8501652B2 (en) * 2008-07-31 2013-08-06 Celanese International Corporation Catalysts for making ethanol from acetic acid
US20100030002A1 (en) * 2008-07-31 2010-02-04 Johnston Victor J Ethylene production from acetic acid utilizing dual reaction zone process
US7608744B1 (en) * 2008-07-31 2009-10-27 Celanese International Corporation Ethanol production from acetic acid utilizing a cobalt catalyst
EP2186787A1 (en) 2008-11-13 2010-05-19 BP p.l.c. Hydrogenation of ethanoic acid to produce ethanol
US7884253B2 (en) * 2008-12-11 2011-02-08 Range Fuels, Inc. Methods and apparatus for selectively producing ethanol from synthesis gas
CN102091429B (zh) 2010-12-20 2012-10-03 广东中科天元新能源科技有限公司 低压三效精馏乙醇回收装置及方法

Also Published As

Publication number Publication date
US9073814B2 (en) 2015-07-07
CN102421731B (zh) 2014-10-08
US20140058139A1 (en) 2014-02-27
AU2011213047A1 (en) 2012-08-02
WO2011097208A2 (en) 2011-08-11
CN102421731A (zh) 2012-04-18
WO2011097208A3 (en) 2011-11-17
SG182609A1 (en) 2012-08-30
EP2531478A2 (en) 2012-12-12
TW201136876A (en) 2011-11-01
CA2787417A1 (en) 2011-08-11
US20110190552A1 (en) 2011-08-04
US8552226B2 (en) 2013-10-08
MX2012008932A (es) 2012-08-15
BR112012019035A2 (pt) 2016-09-13

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