BR112012013579A2 - processo para preparação de um sistema de catalisador de metaloceno sólido, não suportado e seu uso na polimerização de poliolefina - Google Patents

processo para preparação de um sistema de catalisador de metaloceno sólido, não suportado e seu uso na polimerização de poliolefina

Info

Publication number
BR112012013579A2
BR112012013579A2 BR112012013579A BR112012013579A BR112012013579A2 BR 112012013579 A2 BR112012013579 A2 BR 112012013579A2 BR 112012013579 A BR112012013579 A BR 112012013579A BR 112012013579 A BR112012013579 A BR 112012013579A BR 112012013579 A2 BR112012013579 A2 BR 112012013579A2
Authority
BR
Brazil
Prior art keywords
preparing
catalyst system
metallocene catalyst
polyolefin polymerization
solid metallocene
Prior art date
Application number
BR112012013579A
Other languages
English (en)
Inventor
Nicolas Ronan
Peter Denifl
Original Assignee
Borealis Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Borealis Ag filed Critical Borealis Ag
Publication of BR112012013579A2 publication Critical patent/BR112012013579A2/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/06—Hydrocarbons
    • C08F12/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/14—Monomers containing only one unsaturated aliphatic radical containing one ring substituted by hetero atoms or groups containing heteroatoms
    • C08F12/16—Halogens
    • C08F12/20—Fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/14—Monomers containing only one unsaturated aliphatic radical containing one ring substituted by hetero atoms or groups containing heteroatoms
    • C08F12/22—Oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/01—Additive used together with the catalyst, excluding compounds containing Al or B
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/01—Atom Transfer Radical Polymerization [ATRP] or reverse ATRP
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
BR112012013579A 2009-12-07 2010-12-03 processo para preparação de um sistema de catalisador de metaloceno sólido, não suportado e seu uso na polimerização de poliolefina BR112012013579A2 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP09178177.3A EP2330136B1 (en) 2009-12-07 2009-12-07 Process for the preparation of an unsupported, solid metallocene catalyst system and its use in polymerization of olefins
PCT/EP2010/068783 WO2011069888A1 (en) 2009-12-07 2010-12-03 Process for the preparation of an unsupported, solid metallocene catalyst system and its use in polymerization of olefins

Publications (1)

Publication Number Publication Date
BR112012013579A2 true BR112012013579A2 (pt) 2016-09-13

Family

ID=42091480

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112012013579A BR112012013579A2 (pt) 2009-12-07 2010-12-03 processo para preparação de um sistema de catalisador de metaloceno sólido, não suportado e seu uso na polimerização de poliolefina

Country Status (8)

Country Link
US (1) US8791042B2 (pt)
EP (1) EP2330136B1 (pt)
JP (1) JP5547298B2 (pt)
KR (1) KR101475576B1 (pt)
CN (1) CN102656196B (pt)
BR (1) BR112012013579A2 (pt)
EA (1) EA021590B1 (pt)
WO (1) WO2011069888A1 (pt)

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JP6432846B2 (ja) 2013-12-06 2018-12-05 エルジー・ケム・リミテッド ブロック共重合体
CN105899557B (zh) 2013-12-06 2018-10-26 株式会社Lg化学 嵌段共聚物
WO2015084131A1 (ko) 2013-12-06 2015-06-11 주식회사 엘지화학 블록 공중합체
EP3078694B1 (en) * 2013-12-06 2021-01-27 LG Chem, Ltd. Block copolymer
EP3101043B1 (en) 2013-12-06 2021-01-27 LG Chem, Ltd. Block copolymer
JP6334706B2 (ja) 2013-12-06 2018-05-30 エルジー・ケム・リミテッド ブロック共重合体
JP6419820B2 (ja) 2013-12-06 2018-11-07 エルジー・ケム・リミテッド ブロック共重合体
EP3078654B1 (en) * 2013-12-06 2021-07-07 LG Chem, Ltd. Monomer and block copolymer
US10227437B2 (en) 2013-12-06 2019-03-12 Lg Chem, Ltd. Block copolymer
CN105873968B (zh) 2013-12-06 2018-09-28 株式会社Lg化学 嵌段共聚物
WO2015084123A1 (ko) 2013-12-06 2015-06-11 주식회사 엘지화학 블록 공중합체
CN105960422B (zh) 2013-12-06 2019-01-18 株式会社Lg化学 嵌段共聚物
EP3078688B1 (en) * 2013-12-06 2020-03-04 LG Chem, Ltd. Block copolymer
EP3078687B1 (en) 2013-12-06 2020-06-03 LG Chem, Ltd. Block copolymer
CN107075055B (zh) * 2014-09-30 2019-08-27 株式会社Lg化学 嵌段共聚物
WO2016053011A1 (ko) 2014-09-30 2016-04-07 주식회사 엘지화학 블록 공중합체
US10310378B2 (en) 2014-09-30 2019-06-04 Lg Chem, Ltd. Block copolymer
CN107077066B9 (zh) 2014-09-30 2021-05-14 株式会社Lg化学 制造图案化基底的方法
JP6394798B2 (ja) 2014-09-30 2018-09-26 エルジー・ケム・リミテッド ブロック共重合体
CN107075054B (zh) 2014-09-30 2020-05-05 株式会社Lg化学 嵌段共聚物
CN107075051B (zh) 2014-09-30 2019-09-03 株式会社Lg化学 嵌段共聚物
CN107078026B (zh) 2014-09-30 2020-03-27 株式会社Lg化学 图案化基底的制备方法
JP6538159B2 (ja) * 2014-09-30 2019-07-03 エルジー・ケム・リミテッド ブロック共重合体
US10287429B2 (en) 2014-09-30 2019-05-14 Lg Chem, Ltd. Block copolymer
US10240035B2 (en) 2014-09-30 2019-03-26 Lg Chem, Ltd. Block copolymer
CN105582975B (zh) * 2014-10-22 2018-03-27 中国科学院大连化学物理研究所 一种改性沸石催化剂及其在异丙基甲苯裂解制甲苯中的应用
KR101699157B1 (ko) * 2015-04-10 2017-01-24 대한유화 주식회사 메탈로센 촉매 제조방법 및 이를 이용한 초 고분자량 폴리에틸렌의 제조방법
JP7004656B2 (ja) * 2015-12-31 2022-02-04 ハンファ ケミカル コーポレーション 混成メタロセン担持触媒、およびそれを用いたオレフィン重合体の製造方法

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Also Published As

Publication number Publication date
EP2330136B1 (en) 2013-08-28
WO2011069888A1 (en) 2011-06-16
EA021590B1 (ru) 2015-07-30
CN102656196B (zh) 2014-07-09
KR101475576B1 (ko) 2014-12-22
CN102656196A (zh) 2012-09-05
EA201200700A1 (ru) 2013-01-30
JP5547298B2 (ja) 2014-07-09
EP2330136A1 (en) 2011-06-08
KR20120086334A (ko) 2012-08-02
JP2013512323A (ja) 2013-04-11
US8791042B2 (en) 2014-07-29
US20120309913A1 (en) 2012-12-06

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