BR0306556B1 - fibra para tecidos não-tecidos de fios ligados, processo de fiação em fundido para a produção da mesma, bem como composições e processos para preparação das referidas composições. - Google Patents
fibra para tecidos não-tecidos de fios ligados, processo de fiação em fundido para a produção da mesma, bem como composições e processos para preparação das referidas composições. Download PDFInfo
- Publication number
- BR0306556B1 BR0306556B1 BRPI0306556-1A BR0306556A BR0306556B1 BR 0306556 B1 BR0306556 B1 BR 0306556B1 BR 0306556 A BR0306556 A BR 0306556A BR 0306556 B1 BR0306556 B1 BR 0306556B1
- Authority
- BR
- Brazil
- Prior art keywords
- weight
- polymer
- ethylene
- propylene
- xylene
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims description 118
- 239000000835 fiber Substances 0.000 title claims description 38
- 238000000034 method Methods 0.000 title claims description 24
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- 238000009987 spinning Methods 0.000 title description 6
- 229920000642 polymer Polymers 0.000 claims description 73
- 229920001577 copolymer Polymers 0.000 claims description 59
- 239000005977 Ethylene Substances 0.000 claims description 54
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 54
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 52
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 45
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 40
- 239000008096 xylene Substances 0.000 claims description 39
- -1 polypropylene Polymers 0.000 claims description 33
- 239000004711 α-olefin Substances 0.000 claims description 30
- 238000002844 melting Methods 0.000 claims description 20
- 230000008018 melting Effects 0.000 claims description 20
- 229920006301 statistical copolymer Polymers 0.000 claims description 19
- 239000003054 catalyst Substances 0.000 claims description 15
- 239000002243 precursor Substances 0.000 claims description 15
- 238000002144 chemical decomposition reaction Methods 0.000 claims description 12
- 229920001519 homopolymer Polymers 0.000 claims description 12
- 229920001155 polypropylene Polymers 0.000 claims description 12
- 238000006731 degradation reaction Methods 0.000 claims description 9
- 230000015556 catabolic process Effects 0.000 claims description 8
- 239000000178 monomer Substances 0.000 claims description 7
- 229920001384 propylene homopolymer Polymers 0.000 claims description 6
- 239000004743 Polypropylene Substances 0.000 claims description 5
- 230000000306 recurrent effect Effects 0.000 claims description 5
- 238000010828 elution Methods 0.000 claims description 4
- 238000005194 fractionation Methods 0.000 claims description 4
- 150000001336 alkenes Chemical class 0.000 claims description 2
- 230000000379 polymerizing effect Effects 0.000 claims description 2
- 239000000155 melt Substances 0.000 claims 1
- 238000002074 melt spinning Methods 0.000 claims 1
- 239000004745 nonwoven fabric Substances 0.000 description 34
- 238000006116 polymerization reaction Methods 0.000 description 24
- 230000003197 catalytic effect Effects 0.000 description 18
- 230000000052 comparative effect Effects 0.000 description 17
- 150000001875 compounds Chemical class 0.000 description 17
- 239000007789 gas Substances 0.000 description 12
- 239000007787 solid Substances 0.000 description 12
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 10
- 239000004744 fabric Substances 0.000 description 9
- 150000002978 peroxides Chemical class 0.000 description 9
- 125000000753 cycloalkyl group Chemical group 0.000 description 7
- 239000011777 magnesium Substances 0.000 description 7
- 229910052749 magnesium Inorganic materials 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 238000003490 calendering Methods 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 6
- 125000004122 cyclic group Chemical group 0.000 description 6
- 229910052739 hydrogen Inorganic materials 0.000 description 6
- 239000001257 hydrogen Substances 0.000 description 6
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 5
- 125000003710 aryl alkyl group Chemical group 0.000 description 5
- 125000003118 aryl group Chemical group 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 229910001629 magnesium chloride Inorganic materials 0.000 description 5
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 4
- DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical compound CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 description 4
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 4
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 4
- 125000002877 alkyl aryl group Chemical group 0.000 description 4
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 4
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
- 125000005843 halogen group Chemical group 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 150000003254 radicals Chemical class 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 4
- 238000002083 X-ray spectrum Methods 0.000 description 3
- JWCYDYZLEAQGJJ-UHFFFAOYSA-N dicyclopentyl(dimethoxy)silane Chemical compound C1CCCC1[Si](OC)(OC)C1CCCC1 JWCYDYZLEAQGJJ-UHFFFAOYSA-N 0.000 description 3
- 125000005842 heteroatom Chemical group 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229940078552 o-xylene Drugs 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 229920000098 polyolefin Polymers 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- 125000001424 substituent group Chemical group 0.000 description 3
- 150000003900 succinic acid esters Chemical class 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- 150000003609 titanium compounds Chemical class 0.000 description 3
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 3
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 description 2
- UWNADWZGEHDQAB-UHFFFAOYSA-N 2,5-dimethylhexane Chemical group CC(C)CCC(C)C UWNADWZGEHDQAB-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 229910003074 TiCl4 Inorganic materials 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 150000005840 aryl radicals Chemical class 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 2
- 235000013539 calcium stearate Nutrition 0.000 description 2
- 239000008116 calcium stearate Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 238000005243 fluidization Methods 0.000 description 2
- 238000012685 gas phase polymerization Methods 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 150000003377 silicon compounds Chemical class 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 125000006702 (C1-C18) alkyl group Chemical group 0.000 description 1
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 description 1
- OUPPKRIDJAMCCA-UHFFFAOYSA-N 1-methoxy-2-(methoxymethyl)-2,3-dimethylbutane Chemical compound COCC(C)(C(C)C)COC OUPPKRIDJAMCCA-UHFFFAOYSA-N 0.000 description 1
- BHPDSAAGSUWVMP-UHFFFAOYSA-N 3,3-bis(methoxymethyl)-2,6-dimethylheptane Chemical compound COCC(C(C)C)(COC)CCC(C)C BHPDSAAGSUWVMP-UHFFFAOYSA-N 0.000 description 1
- PVWCLOAAEFMTLH-UHFFFAOYSA-N 4,4-bis(methoxymethyl)-2,6-dimethylheptane Chemical compound COCC(COC)(CC(C)C)CC(C)C PVWCLOAAEFMTLH-UHFFFAOYSA-N 0.000 description 1
- HZXMLBSUEZTYHZ-UHFFFAOYSA-N 4-(cyclohexylmethoxy)-4-oxobutanoic acid Chemical compound OC(=O)CCC(=O)OCC1CCCCC1 HZXMLBSUEZTYHZ-UHFFFAOYSA-N 0.000 description 1
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
- ZWINORFLMHROGF-UHFFFAOYSA-N 9,9-bis(methoxymethyl)fluorene Chemical compound C1=CC=C2C(COC)(COC)C3=CC=CC=C3C2=C1 ZWINORFLMHROGF-UHFFFAOYSA-N 0.000 description 1
- 101100277337 Arabidopsis thaliana DDM1 gene Proteins 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 239000004831 Hot glue Substances 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-N Propionic acid Chemical compound CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- XMYDKOZNENQEHO-UHFFFAOYSA-N [1-methoxy-2-(methoxymethyl)-3-methylbutan-2-yl]cyclopentane Chemical compound COCC(COC)(C(C)C)C1CCCC1 XMYDKOZNENQEHO-UHFFFAOYSA-N 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 159000000032 aromatic acids Chemical class 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 230000006583 body weight regulation Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000010538 cationic polymerization reaction Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 101150113676 chr1 gene Proteins 0.000 description 1
- 239000003426 co-catalyst Substances 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000004210 cyclohexylmethyl group Chemical group [H]C([H])(*)C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C1([H])[H] 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- WGFNXLQURMLAGC-UHFFFAOYSA-N diethyl 2,3-di(propan-2-yl)butanedioate Chemical compound CCOC(=O)C(C(C)C)C(C(C)C)C(=O)OCC WGFNXLQURMLAGC-UHFFFAOYSA-N 0.000 description 1
- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000003028 elevating effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- GATNOFPXSDHULC-UHFFFAOYSA-N ethylphosphonic acid Chemical compound CCP(O)(O)=O GATNOFPXSDHULC-UHFFFAOYSA-N 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000003701 inert diluent Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 150000002680 magnesium Chemical class 0.000 description 1
- 150000002681 magnesium compounds Chemical class 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 150000002899 organoaluminium compounds Chemical class 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
- 125000003538 pentan-3-yl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])C([H])([H])[H] 0.000 description 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 125000004437 phosphorous atom Chemical group 0.000 description 1
- 239000003504 photosensitizing agent Substances 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 125000003367 polycyclic group Chemical group 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 230000000707 stereoselective effect Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical group O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 239000003017 thermal stabilizer Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/08—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
- D04H3/16—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic filaments produced in association with filament formation, e.g. immediately following extrusion
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/14—Copolymers of propene
- C08L23/142—Copolymers of propene at least partially crystalline copolymers of propene with other olefins
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
- D01F6/46—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/12—Applications used for fibers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Nonwoven Fabrics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Artificial Filaments (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP02021421 | 2002-09-25 | ||
| EP02021421.9 | 2002-09-25 | ||
| US41699202P | 2002-10-08 | 2002-10-08 | |
| US60/416,992 | 2002-10-08 | ||
| PCT/EP2003/010707 WO2004029342A1 (en) | 2002-09-25 | 2003-09-23 | Polypropylene fibres suitable for spunbonded non-woven fabrics |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR0306556A BR0306556A (pt) | 2004-11-30 |
| BR0306556B1 true BR0306556B1 (pt) | 2012-11-27 |
Family
ID=42777637
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0306556-1A BR0306556B1 (pt) | 2002-09-25 | 2003-09-23 | fibra para tecidos não-tecidos de fios ligados, processo de fiação em fundido para a produção da mesma, bem como composições e processos para preparação das referidas composições. |
Country Status (12)
| Country | Link |
|---|---|
| EP (1) | EP1543185B1 (https=) |
| JP (1) | JP2006500487A (https=) |
| CN (1) | CN100338275C (https=) |
| AR (1) | AR041391A1 (https=) |
| AT (1) | ATE441745T1 (https=) |
| AU (1) | AU2003271644A1 (https=) |
| BR (1) | BR0306556B1 (https=) |
| CA (1) | CA2499702A1 (https=) |
| PL (1) | PL374316A1 (https=) |
| RU (1) | RU2322535C2 (https=) |
| TW (1) | TW200420767A (https=) |
| WO (1) | WO2004029342A1 (https=) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8466235B2 (en) | 2002-08-27 | 2013-06-18 | Braskem America, Inc. | Polypropylene blends for non-woven production |
| US7655582B2 (en) * | 2004-05-12 | 2010-02-02 | Sunoco Chemicals, Inc. | Polypropylene blends for non-woven fabrics |
| DK1826304T3 (da) * | 2004-11-26 | 2013-06-24 | Mitsui Chemicals Inc | Polypropylen-ikke-vævet stof og anvendelse deraf |
| US20090029621A1 (en) * | 2005-12-20 | 2009-01-29 | Basell Poliolefine Italia S.R.L. | Soft Non-Woven Fabrics |
| CN101341177B (zh) * | 2005-12-20 | 2012-08-08 | 巴塞尔聚烯烃意大利有限责任公司 | 柔软的无纺布 |
| DK1983082T3 (da) * | 2006-02-06 | 2013-11-04 | Mitsui Chemicals Inc | Spindeklæbet fiberdug |
| US8728960B2 (en) * | 2007-01-19 | 2014-05-20 | Exxonmobil Chemical Patents Inc. | Spunbond fibers and fabrics from polyolefin blends |
| EP1964948A1 (en) * | 2007-02-28 | 2008-09-03 | Total Petrochemicals Research Feluy | Polypropylene fibers and spunbond nonwoven with improved properties. |
| JP5276671B2 (ja) | 2007-11-27 | 2013-08-28 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | ポリオレフィンナノ複合材料 |
| EP2264099A1 (en) * | 2009-05-21 | 2010-12-22 | Basell Poliolefine Italia S.R.L. | Propylene polymer compositions |
| CN102639774B (zh) * | 2009-12-09 | 2015-12-09 | 东丽株式会社 | 长纤维非织造布的制造方法 |
| CN104583302B (zh) * | 2012-06-27 | 2017-06-06 | 道达尔研究技术弗吕公司 | 用于高韧度纤维和无纺物的丙烯均聚物 |
| EP2682505A1 (en) * | 2012-07-06 | 2014-01-08 | Basell Poliolefine Italia S.r.l. | Polypropylene fiber |
| WO2014046070A1 (ja) * | 2012-09-19 | 2014-03-27 | 三井化学株式会社 | 農業用被覆材及びその製造方法 |
| TWI627321B (zh) * | 2012-09-20 | 2018-06-21 | Asahi Kasei Fibers Corp | Polypropylene non-woven fabric, manufacturing method thereof and sanitary material |
| US9322114B2 (en) * | 2012-12-03 | 2016-04-26 | Exxonmobil Chemical Patents Inc. | Polypropylene fibers and fabrics |
| RU2648675C2 (ru) * | 2013-05-22 | 2018-03-28 | Бореалис Аг | Полипропилен для применения в пленках |
| EP3303675A4 (en) * | 2015-06-05 | 2019-01-09 | ExxonMobil Chemical Patents Inc. | SPINNING MATERIALS WITH PROPYLENE BASE ELASTOMER COMPOSITIONS AND METHOD THEREFOR |
| CN108474160B (zh) * | 2016-01-04 | 2022-03-08 | 北欧化工公司 | 由不含邻苯二甲酸酯的pp均聚物制成的纺粘无纺织物 |
| US10844529B2 (en) | 2016-05-02 | 2020-11-24 | Exxonmobil Chemicals Patents Inc. | Spunbond fabrics comprising propylene-based elastomer compositions and methods for making the same |
| CN112639182A (zh) | 2018-09-21 | 2021-04-09 | 北欧化工公司 | 用于熔纺纤维应用的聚丙烯组合物 |
| KR102609593B1 (ko) * | 2019-05-28 | 2023-12-04 | 도레이첨단소재 주식회사 | 부직포, 이의 제조방법, 상기 부직포를 포함하는 물품, 및 상기 부직포를 사용한 위생용품 |
| CN113811645A (zh) * | 2019-06-07 | 2021-12-17 | 巴塞尔聚烯烃意大利有限公司 | 丙烯聚合物纤维 |
| JP2023553887A (ja) * | 2020-12-08 | 2023-12-26 | ダブリュー・アール・グレース・アンド・カンパニー－コーン | 高速紡糸用高結晶性オレフィンポリマー |
| CN113337903A (zh) * | 2021-06-01 | 2021-09-03 | 鹤山市东海塑料色母有限公司 | 一种抗病毒聚丙烯无纺布及其制备方法 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW275076B (https=) * | 1992-12-02 | 1996-05-01 | Hoechst Ag | |
| US5460884A (en) * | 1994-08-25 | 1995-10-24 | Kimberly-Clark Corporation | Soft and strong thermoplastic polymer fibers and nonwoven fabric made therefrom |
| EP1025162B1 (en) * | 1998-08-20 | 2003-09-03 | Basell Poliolefine Italia S.p.A. | Crystalline propylene copolymer compositions having improved sealability and optical properties and reduced solubility |
| ES2235855T3 (es) * | 1999-04-15 | 2005-07-16 | Basell Poliolefine Italia S.P.A. | Fibras de poliolefina termicamente unibles, las cuales contienen un copolimero aleatorio de propileno. |
| MY132768A (en) * | 2001-10-09 | 2007-10-31 | Basell Poliolefine Italia Spa | Crystalline propylene copolymer compositions having improved sealability and optical properties and reduced solubility. |
-
2003
- 2003-09-23 PL PL03374316A patent/PL374316A1/xx unknown
- 2003-09-23 TW TW092126183A patent/TW200420767A/zh unknown
- 2003-09-23 WO PCT/EP2003/010707 patent/WO2004029342A1/en not_active Ceased
- 2003-09-23 EP EP03753461A patent/EP1543185B1/en not_active Expired - Lifetime
- 2003-09-23 AT AT03753461T patent/ATE441745T1/de not_active IP Right Cessation
- 2003-09-23 RU RU2005112215/04A patent/RU2322535C2/ru not_active IP Right Cessation
- 2003-09-23 BR BRPI0306556-1A patent/BR0306556B1/pt not_active IP Right Cessation
- 2003-09-23 JP JP2005509668A patent/JP2006500487A/ja not_active Withdrawn
- 2003-09-23 CA CA002499702A patent/CA2499702A1/en not_active Abandoned
- 2003-09-23 AU AU2003271644A patent/AU2003271644A1/en not_active Abandoned
- 2003-09-23 CN CNB038229293A patent/CN100338275C/zh not_active Expired - Fee Related
- 2003-09-25 AR ARP030103491A patent/AR041391A1/es not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| BR0306556A (pt) | 2004-11-30 |
| PL374316A1 (en) | 2005-10-03 |
| EP1543185A1 (en) | 2005-06-22 |
| ATE441745T1 (de) | 2009-09-15 |
| TW200420767A (en) | 2004-10-16 |
| CN1685093A (zh) | 2005-10-19 |
| WO2004029342A1 (en) | 2004-04-08 |
| EP1543185B1 (en) | 2009-09-02 |
| CN100338275C (zh) | 2007-09-19 |
| JP2006500487A (ja) | 2006-01-05 |
| RU2322535C2 (ru) | 2008-04-20 |
| AU2003271644A1 (en) | 2004-04-19 |
| CA2499702A1 (en) | 2004-04-08 |
| AR041391A1 (es) | 2005-05-18 |
| RU2005112215A (ru) | 2005-09-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| BR0306556B1 (pt) | fibra para tecidos não-tecidos de fios ligados, processo de fiação em fundido para a produção da mesma, bem como composições e processos para preparação das referidas composições. | |
| DK2631269T3 (en) | Fiber quality with improved spinning performance and mechanical properties | |
| JP4782800B2 (ja) | 均一ポリマー・ブレンドおよび該ブレンドからの製品 | |
| JP5520227B2 (ja) | プロピレン系エラストマーを用いて調製される繊維及び不織布 | |
| BR0108586B1 (pt) | filmes de polipropileno biorientado (bopp) e composição polimérica de propileno. | |
| US20050130544A1 (en) | Elastic nonwoven fabrics made from blends of polyolefins and processes for making the same | |
| JP2003535944A (ja) | 低粘度プロピレンホモポリマーを含むポリオレフィン組成物、それらから調製された繊維及び伸縮性不織布。 | |
| MXPA01011548A (es) | Fibras elasticas y articulos hechos de las mismas, incluyendo polimeros de propileno crsitalinos y cristalizables. | |
| JP2003119614A (ja) | メタロセン触媒を使用として得られるプロピレン−α−オレフィン・ランダム共重合体の熔融紡糸繊維 | |
| US20060057374A1 (en) | Polypropylene fibres suitable for spunbonded non-woven fabrics | |
| CN101087905B (zh) | 具有弹性的纤维 | |
| BR112014000025B1 (pt) | Copolímero de propileno e 1-hexeno, fibra e tecido não-tecido | |
| BR112012028757B1 (pt) | Tecido não tecido, tecido ligado por fiação, e, tecido soprado em fusão | |
| EP1543186B1 (en) | Polypropylene fibres suitable for thermally bonded non-woven fabrics | |
| US20060154064A1 (en) | Polypropylene fibres suitable for thermally bonded non-woven fabrics | |
| BR112021003939A2 (pt) | composição de polipropileno para aplicações de fibra fiada por fusão | |
| TW201902948A (zh) | 低ｍｆｉ茂金屬聚丙烯的拉伸製品及製造該拉伸製品的方法 | |
| JP2019099983A (ja) | ポリプロピレン延伸繊維 | |
| US20080061468A1 (en) | Fiber processing of high ethylene level propylene-ethylene random copolymers by use of nucleators |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B25D | Requested change of name of applicant approved |
Owner name: BASELL POLIOLEFINE ITALIA S.R.L. (IT) Free format text: ALTERADO DE: BASELL POLIOLEFINE ITALIA S.P.A. |
|
| B06A | Patent application procedure suspended [chapter 6.1 patent gazette] | ||
| B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
| B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 23/09/2003, MEDIANTE O RECOLHIMENTO DA TAXA QUINQUENAL DE MANUTENCAO (ARTIGOS 119 E 120 DA LPI) E OBSERVADAS AS DEMAIS CONDICOES LEGAIS. |
|
| B21F | Lapse acc. art. 78, item iv - on non-payment of the annual fees in time |
Free format text: REFERENTE A 13A ANUIDADE. |
|
| B24J | Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12) |
Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2385 DE 20-09-2016 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013. |