BR0201173B1 - composições de polietileno tendo resistência a vulcanização aperfeiçoada, processo de preparação e uso das mesmas. - Google Patents
composições de polietileno tendo resistência a vulcanização aperfeiçoada, processo de preparação e uso das mesmas. Download PDFInfo
- Publication number
- BR0201173B1 BR0201173B1 BRPI0201173-5A BR0201173A BR0201173B1 BR 0201173 B1 BR0201173 B1 BR 0201173B1 BR 0201173 A BR0201173 A BR 0201173A BR 0201173 B1 BR0201173 B1 BR 0201173B1
- Authority
- BR
- Brazil
- Prior art keywords
- tert
- alkyl
- bis
- octyldiphenylamine
- phenyl
- Prior art date
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- -1 polyethylene Polymers 0.000 title claims description 133
- 239000000203 mixture Substances 0.000 title claims description 49
- 238000004073 vulcanization Methods 0.000 title claims description 37
- 239000004698 Polyethylene Substances 0.000 title claims description 26
- 229920000573 polyethylene Polymers 0.000 title claims description 26
- 238000002360 preparation method Methods 0.000 title claims description 5
- 230000002028 premature Effects 0.000 claims description 29
- 239000003112 inhibitor Substances 0.000 claims description 26
- 238000004132 cross linking Methods 0.000 claims description 25
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 25
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 claims description 22
- 150000001875 compounds Chemical class 0.000 claims description 20
- 150000002978 peroxides Chemical class 0.000 claims description 18
- GQBHYWDCHSZDQU-UHFFFAOYSA-N 4-(2,4,4-trimethylpentan-2-yl)-n-[4-(2,4,4-trimethylpentan-2-yl)phenyl]aniline Chemical compound C1=CC(C(C)(C)CC(C)(C)C)=CC=C1NC1=CC=C(C(C)(C)CC(C)(C)C)C=C1 GQBHYWDCHSZDQU-UHFFFAOYSA-N 0.000 claims description 14
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 claims description 13
- 150000001412 amines Chemical class 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 12
- 150000001451 organic peroxides Chemical class 0.000 claims description 11
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 10
- 125000006705 (C5-C7) cycloalkyl group Chemical group 0.000 claims description 9
- 229910052739 hydrogen Inorganic materials 0.000 claims description 9
- 239000001257 hydrogen Substances 0.000 claims description 9
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 9
- 238000002844 melting Methods 0.000 claims description 8
- 230000008018 melting Effects 0.000 claims description 8
- 125000000217 alkyl group Chemical group 0.000 claims description 7
- 125000000304 alkynyl group Chemical group 0.000 claims description 7
- 238000009413 insulation Methods 0.000 claims description 7
- 125000003944 tolyl group Chemical group 0.000 claims description 7
- 125000003358 C2-C20 alkenyl group Chemical group 0.000 claims description 6
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 6
- 238000000354 decomposition reaction Methods 0.000 claims description 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 6
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims description 5
- OSFOTMWFXQGWKZ-UHFFFAOYSA-N n-phenyl-4-(2,4,4-trimethylpentan-2-yl)aniline Chemical compound C1=CC(C(C)(C)CC(C)(C)C)=CC=C1NC1=CC=CC=C1 OSFOTMWFXQGWKZ-UHFFFAOYSA-N 0.000 claims description 5
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 229910052717 sulfur Inorganic materials 0.000 claims description 4
- UOMXLEWVJZEVGP-UHFFFAOYSA-N 4-tert-butyl-n-phenylaniline Chemical compound C1=CC(C(C)(C)C)=CC=C1NC1=CC=CC=C1 UOMXLEWVJZEVGP-UHFFFAOYSA-N 0.000 claims description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- 125000003854 p-chlorophenyl group Chemical group [H]C1=C([H])C(*)=C([H])C([H])=C1Cl 0.000 claims description 3
- 125000001037 p-tolyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])([H])[H] 0.000 claims description 3
- OPEKHRGERHDLRK-UHFFFAOYSA-N 4-tert-butyl-n-(4-tert-butylphenyl)aniline Chemical compound C1=CC(C(C)(C)C)=CC=C1NC1=CC=C(C(C)(C)C)C=C1 OPEKHRGERHDLRK-UHFFFAOYSA-N 0.000 claims description 2
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 claims 2
- 229920003020 cross-linked polyethylene Polymers 0.000 claims 2
- 239000004703 cross-linked polyethylene Substances 0.000 claims 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 17
- AKFWYZBRXBSZJX-UHFFFAOYSA-N 2-[[3-tert-butyl-5-(carboxymethylsulfanylmethyl)-4-hydroxyphenyl]methylsulfanyl]acetic acid Chemical compound CC(C)(C)C1=CC(CSCC(O)=O)=CC(CSCC(O)=O)=C1O AKFWYZBRXBSZJX-UHFFFAOYSA-N 0.000 description 12
- 229920000642 polymer Polymers 0.000 description 12
- 150000002148 esters Chemical class 0.000 description 10
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 8
- 238000001125 extrusion Methods 0.000 description 8
- 239000003381 stabilizer Substances 0.000 description 7
- GAODDBNJCKQQDY-UHFFFAOYSA-N 2-methyl-4,6-bis(octylsulfanylmethyl)phenol Chemical compound CCCCCCCCSCC1=CC(C)=C(O)C(CSCCCCCCCC)=C1 GAODDBNJCKQQDY-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000007788 liquid Substances 0.000 description 5
- GJYCVCVHRSWLNY-UHFFFAOYSA-N 2-butylphenol Chemical compound CCCCC1=CC=CC=C1O GJYCVCVHRSWLNY-UHFFFAOYSA-N 0.000 description 4
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000004020 conductor Substances 0.000 description 4
- 239000003431 cross linking reagent Substances 0.000 description 4
- 229920001519 homopolymer Polymers 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- OJURWUUOVGOHJZ-UHFFFAOYSA-N methyl 2-[(2-acetyloxyphenyl)methyl-[2-[(2-acetyloxyphenyl)methyl-(2-methoxy-2-oxoethyl)amino]ethyl]amino]acetate Chemical compound C=1C=CC=C(OC(C)=O)C=1CN(CC(=O)OC)CCN(CC(=O)OC)CC1=CC=CC=C1OC(C)=O OJURWUUOVGOHJZ-UHFFFAOYSA-N 0.000 description 4
- 150000002989 phenols Chemical class 0.000 description 4
- 239000001294 propane Substances 0.000 description 4
- ZBHJTSZJYILOET-UHFFFAOYSA-N 3-[[3-tert-butyl-5-(2-carboxyethylsulfanylmethyl)-4-hydroxyphenyl]methylsulfanyl]propanoic acid Chemical compound CC(C)(C)C1=CC(CSCCC(O)=O)=CC(CSCCC(O)=O)=C1O ZBHJTSZJYILOET-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 3
- 229920001684 low density polyethylene Polymers 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 2
- CVKLQWPMXWTXJK-UHFFFAOYSA-N 2-[[3-tert-butyl-5-(1-carboxyethylsulfanylmethyl)-4-hydroxyphenyl]methylsulfanyl]propanoic acid Chemical compound OC(=O)C(C)SCC1=CC(CSC(C)C(O)=O)=C(O)C(C(C)(C)C)=C1 CVKLQWPMXWTXJK-UHFFFAOYSA-N 0.000 description 2
- 125000001494 2-propynyl group Chemical group [H]C#CC([H])([H])* 0.000 description 2
- HGYCIUGAHIOJSW-UHFFFAOYSA-N 2-tert-butyl-4,6-bis(prop-2-enylsulfanylmethyl)phenol Chemical compound CC(C)(C)C1=CC(CSCC=C)=CC(CSCC=C)=C1O HGYCIUGAHIOJSW-UHFFFAOYSA-N 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- LMYHHCDPOACYBO-UHFFFAOYSA-N C(C#C)SCC1=C(C(=CC(=C1)CSCC#C)C(C)(C)C)O Chemical compound C(C#C)SCC1=C(C(=CC(=C1)CSCC#C)C(C)(C)C)O LMYHHCDPOACYBO-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 150000004982 aromatic amines Chemical class 0.000 description 2
- 235000010290 biphenyl Nutrition 0.000 description 2
- 239000004305 biphenyl Substances 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 230000003749 cleanliness Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 125000004093 cyano group Chemical group *C#N 0.000 description 2
- 230000008030 elimination Effects 0.000 description 2
- 238000003379 elimination reaction Methods 0.000 description 2
- 229920001038 ethylene copolymer Polymers 0.000 description 2
- 125000006351 ethylthiomethyl group Chemical group [H]C([H])([H])C([H])([H])SC([H])([H])* 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 239000012774 insulation material Substances 0.000 description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 239000004702 low-density polyethylene Substances 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000003878 thermal aging Methods 0.000 description 2
- 239000004711 α-olefin Substances 0.000 description 2
- QEQBMZQFDDDTPN-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy benzenecarboperoxoate Chemical compound CC(C)(C)OOOC(=O)C1=CC=CC=C1 QEQBMZQFDDDTPN-UHFFFAOYSA-N 0.000 description 1
- KDGNCLDCOVTOCS-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy propan-2-yl carbonate Chemical compound CC(C)OC(=O)OOC(C)(C)C KDGNCLDCOVTOCS-UHFFFAOYSA-N 0.000 description 1
- OXYKVVLTXXXVRT-UHFFFAOYSA-N (4-chlorobenzoyl) 4-chlorobenzenecarboperoxoate Chemical compound C1=CC(Cl)=CC=C1C(=O)OOC(=O)C1=CC=C(Cl)C=C1 OXYKVVLTXXXVRT-UHFFFAOYSA-N 0.000 description 1
- RIPYNJLMMFGZSX-UHFFFAOYSA-N (5-benzoylperoxy-2,5-dimethylhexan-2-yl) benzenecarboperoxoate Chemical group C=1C=CC=CC=1C(=O)OOC(C)(C)CCC(C)(C)OOC(=O)C1=CC=CC=C1 RIPYNJLMMFGZSX-UHFFFAOYSA-N 0.000 description 1
- BLKRGXCGFRXRNQ-SNAWJCMRSA-N (z)-3-carbonoperoxoyl-4,4-dimethylpent-2-enoic acid Chemical group OC(=O)/C=C(C(C)(C)C)\C(=O)OO BLKRGXCGFRXRNQ-SNAWJCMRSA-N 0.000 description 1
- WKKRYWQLVOISAU-UHFFFAOYSA-N 1,3,5-tris(2-tert-butylperoxypropan-2-yl)benzene Chemical compound CC(C)(C)OOC(C)(C)C1=CC(C(C)(C)OOC(C)(C)C)=CC(C(C)(C)OOC(C)(C)C)=C1 WKKRYWQLVOISAU-UHFFFAOYSA-N 0.000 description 1
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N 1,4-Benzenediol Natural products OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 1
- RZLFNZFPQFDUFW-UHFFFAOYSA-N 2,4-bis(1,3-benzothiazol-2-ylsulfanylmethyl)-6-tert-butylphenol Chemical compound C1=CC=C2SC(SCC=3C=C(CSC=4SC5=CC=CC=C5N=4)C=C(C=3O)C(C)(C)C)=NC2=C1 RZLFNZFPQFDUFW-UHFFFAOYSA-N 0.000 description 1
- CPALSSDUQKWXFM-UHFFFAOYSA-N 2,4-bis(benzylsulfanylmethyl)-6-methylphenol Chemical compound C=1C(CSCC=2C=CC=CC=2)=C(O)C(C)=CC=1CSCC1=CC=CC=C1 CPALSSDUQKWXFM-UHFFFAOYSA-N 0.000 description 1
- CWTXAAIRSCFWLN-UHFFFAOYSA-N 2,4-bis(benzylsulfanylmethyl)-6-tert-butylphenol Chemical compound C=1C(CSCC=2C=CC=CC=2)=C(O)C(C(C)(C)C)=CC=1CSCC1=CC=CC=C1 CWTXAAIRSCFWLN-UHFFFAOYSA-N 0.000 description 1
- SHOFCMBBNVNGRM-UHFFFAOYSA-N 2,4-bis(dodecylsulfanylmethyl)-6-(2-methylbutan-2-yl)phenol Chemical compound CCCCCCCCCCCCSCC1=CC(CSCCCCCCCCCCCC)=C(O)C(C(C)(C)CC)=C1 SHOFCMBBNVNGRM-UHFFFAOYSA-N 0.000 description 1
- VEYURQYVHJAECH-UHFFFAOYSA-N 2,4-bis(dodecylsulfanylmethyl)-6-(2-methylpentan-2-yl)phenol Chemical compound CCCCCCCCCCCCSCC1=CC(CSCCCCCCCCCCCC)=C(O)C(C(C)(C)CCC)=C1 VEYURQYVHJAECH-UHFFFAOYSA-N 0.000 description 1
- MWHVHEXZUKRHDN-UHFFFAOYSA-N 2,4-bis(dodecylsulfanylmethyl)-6-(2-phenylpropan-2-yl)phenol Chemical compound CCCCCCCCCCCCSCC1=CC(CSCCCCCCCCCCCC)=C(O)C(C(C)(C)C=2C=CC=CC=2)=C1 MWHVHEXZUKRHDN-UHFFFAOYSA-N 0.000 description 1
- ILIVLFQJLLUVKN-UHFFFAOYSA-N 2,4-bis(dodecylsulfanylmethyl)-6-(4-methylphenyl)phenol Chemical compound CCCCCCCCCCCCSCC1=CC(CSCCCCCCCCCCCC)=C(O)C(C=2C=CC(C)=CC=2)=C1 ILIVLFQJLLUVKN-UHFFFAOYSA-N 0.000 description 1
- VTFXHGBOGGGYDO-UHFFFAOYSA-N 2,4-bis(dodecylsulfanylmethyl)-6-methylphenol Chemical compound CCCCCCCCCCCCSCC1=CC(C)=C(O)C(CSCCCCCCCCCCCC)=C1 VTFXHGBOGGGYDO-UHFFFAOYSA-N 0.000 description 1
- KGAUIOQJPCLOAQ-UHFFFAOYSA-N 2,4-bis(dodecylsulfanylmethyl)-6-phenylphenol Chemical compound CCCCCCCCCCCCSCC1=CC(CSCCCCCCCCCCCC)=C(O)C(C=2C=CC=CC=2)=C1 KGAUIOQJPCLOAQ-UHFFFAOYSA-N 0.000 description 1
- DEHMQOBXMQCZOO-UHFFFAOYSA-N 2,4-bis(dodecylsulfanylmethyl)-6-prop-2-enylphenol Chemical compound CCCCCCCCCCCCSCC1=CC(CSCCCCCCCCCCCC)=C(O)C(CC=C)=C1 DEHMQOBXMQCZOO-UHFFFAOYSA-N 0.000 description 1
- WJKUELLRFKSAID-UHFFFAOYSA-N 2,4-bis(dodecylsulfanylmethyl)-6-propan-2-ylphenol Chemical compound CCCCCCCCCCCCSCC1=CC(CSCCCCCCCCCCCC)=C(O)C(C(C)C)=C1 WJKUELLRFKSAID-UHFFFAOYSA-N 0.000 description 1
- DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical compound CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 description 1
- TUAPLLGBMYGPST-UHFFFAOYSA-N 2,5-dimethyl-2,5-bis(2-methylbutan-2-ylperoxy)hexane Chemical compound CCC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)CC TUAPLLGBMYGPST-UHFFFAOYSA-N 0.000 description 1
- ZRIFTGCCLFJBFK-UHFFFAOYSA-N 2,6-bis(benzylsulfanylmethyl)-6-methylcyclohexa-2,4-dien-1-ol Chemical compound C1=CC=C(CSCC=2C=CC=CC=2)C(O)C1(C)CSCC1=CC=CC=C1 ZRIFTGCCLFJBFK-UHFFFAOYSA-N 0.000 description 1
- GLBUCGXMLJPYEY-UHFFFAOYSA-N 2,6-bis(octylsulfanylmethyl)-4-(2,4,4-trimethylpentan-2-yl)phenol Chemical compound CCCCCCCCSCC1=CC(C(C)(C)CC(C)(C)C)=CC(CSCCCCCCCC)=C1O GLBUCGXMLJPYEY-UHFFFAOYSA-N 0.000 description 1
- SLQFXVVIVBSBFH-UHFFFAOYSA-N 2,6-ditert-butyl-4-[2-[[3-tert-butyl-5-[2-(3,5-ditert-butyl-4-hydroxyphenyl)ethylsulfanylmethyl]-4-hydroxyphenyl]methylsulfanyl]ethyl]phenol Chemical compound C=1C(CSCCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C(O)C(C(C)(C)C)=CC=1CSCCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SLQFXVVIVBSBFH-UHFFFAOYSA-N 0.000 description 1
- ZEKHKSIENLGKRM-UHFFFAOYSA-N 2-[[3-(2-acetyloxyethylsulfanylmethyl)-5-tert-butyl-4-hydroxyphenyl]methylsulfanyl]ethyl acetate Chemical compound CC(=O)OCCSCC1=CC(CSCCOC(C)=O)=C(O)C(C(C)(C)C)=C1 ZEKHKSIENLGKRM-UHFFFAOYSA-N 0.000 description 1
- NGWNICNKXKEEMM-UHFFFAOYSA-N 2-[[3-tert-butyl-4-hydroxy-5-(1-oxopropan-2-ylsulfanylmethyl)phenyl]methylsulfanyl]propanal Chemical compound O=CC(C)SCC1=CC(CSC(C)C=O)=C(O)C(C(C)(C)C)=C1 NGWNICNKXKEEMM-UHFFFAOYSA-N 0.000 description 1
- IKSPANFZXPSGLH-UHFFFAOYSA-N 2-benzyl-4,6-bis(dodecylsulfanylmethyl)phenol Chemical compound CCCCCCCCCCCCSCC1=CC(CSCCCCCCCCCCCC)=C(O)C(CC=2C=CC=CC=2)=C1 IKSPANFZXPSGLH-UHFFFAOYSA-N 0.000 description 1
- 125000001731 2-cyanoethyl group Chemical group [H]C([H])(*)C([H])([H])C#N 0.000 description 1
- QOOIECWFYOYLNV-UHFFFAOYSA-N 2-cyclohexyl-4,6-bis(dodecylsulfanylmethyl)phenol Chemical compound CCCCCCCCCCCCSCC1=CC(CSCCCCCCCCCCCC)=C(O)C(C2CCCCC2)=C1 QOOIECWFYOYLNV-UHFFFAOYSA-N 0.000 description 1
- KRDXTHSSNCTAGY-UHFFFAOYSA-N 2-cyclohexylpyrrolidine Chemical compound C1CCNC1C1CCCCC1 KRDXTHSSNCTAGY-UHFFFAOYSA-N 0.000 description 1
- JJRDRFZYKKFYMO-UHFFFAOYSA-N 2-methyl-2-(2-methylbutan-2-ylperoxy)butane Chemical compound CCC(C)(C)OOC(C)(C)CC JJRDRFZYKKFYMO-UHFFFAOYSA-N 0.000 description 1
- 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- OBCGHTWADUANHH-UHFFFAOYSA-N 2-tert-butyl-4,6-bis(2-ethylhexylsulfanylmethyl)phenol Chemical compound CCCCC(CC)CSCC1=CC(CSCC(CC)CCCC)=C(O)C(C(C)(C)C)=C1 OBCGHTWADUANHH-UHFFFAOYSA-N 0.000 description 1
- VUNXZIAWEWTTRR-UHFFFAOYSA-N 2-tert-butyl-4,6-bis(2-hydroxyethylsulfanylmethyl)phenol Chemical compound CC(C)(C)C1=CC(CSCCO)=CC(CSCCO)=C1O VUNXZIAWEWTTRR-UHFFFAOYSA-N 0.000 description 1
- OEMRNJYOAJHCMP-UHFFFAOYSA-N 2-tert-butyl-4,6-bis(butylsulfanylmethyl)phenol Chemical compound CCCCSCC1=CC(CSCCCC)=C(O)C(C(C)(C)C)=C1 OEMRNJYOAJHCMP-UHFFFAOYSA-N 0.000 description 1
- UJVLWJVGJQJTKV-UHFFFAOYSA-N 2-tert-butyl-4,6-bis(cyclohexylsulfanylmethyl)phenol Chemical compound C=1C(CSC2CCCCC2)=C(O)C(C(C)(C)C)=CC=1CSC1CCCCC1 UJVLWJVGJQJTKV-UHFFFAOYSA-N 0.000 description 1
- NRUHXQWZAZOAPO-UHFFFAOYSA-N 2-tert-butyl-4,6-bis(ethylsulfanylmethyl)phenol Chemical compound CCSCC1=CC(CSCC)=C(O)C(C(C)(C)C)=C1 NRUHXQWZAZOAPO-UHFFFAOYSA-N 0.000 description 1
- KHASFNSBLQNSHW-UHFFFAOYSA-N 2-tert-butyl-4,6-bis(hexylsulfanylmethyl)phenol Chemical compound CCCCCCSCC1=CC(CSCCCCCC)=C(O)C(C(C)(C)C)=C1 KHASFNSBLQNSHW-UHFFFAOYSA-N 0.000 description 1
- IBDZMVMIJIDGGR-UHFFFAOYSA-N 2-tert-butyl-4,6-bis(icosylsulfanylmethyl)phenol Chemical compound CCCCCCCCCCCCCCCCCCCCSCC1=CC(CSCCCCCCCCCCCCCCCCCCCC)=C(O)C(C(C)(C)C)=C1 IBDZMVMIJIDGGR-UHFFFAOYSA-N 0.000 description 1
- ZYJXQDCMXTWHIV-UHFFFAOYSA-N 2-tert-butyl-4,6-bis(octylsulfanylmethyl)phenol Chemical compound CCCCCCCCSCC1=CC(CSCCCCCCCC)=C(O)C(C(C)(C)C)=C1 ZYJXQDCMXTWHIV-UHFFFAOYSA-N 0.000 description 1
- FDNIHGGWNUXZMN-UHFFFAOYSA-N 2-tert-butyl-4,6-bis(phenylsulfanylmethyl)phenol Chemical compound C=1C(CSC=2C=CC=CC=2)=C(O)C(C(C)(C)C)=CC=1CSC1=CC=CC=C1 FDNIHGGWNUXZMN-UHFFFAOYSA-N 0.000 description 1
- OLSHZEQMMKHCDJ-UHFFFAOYSA-N 2-tert-butyl-4,6-bis(propan-2-ylsulfanylmethyl)phenol Chemical compound CC(C)SCC1=CC(CSC(C)C)=C(O)C(C(C)(C)C)=C1 OLSHZEQMMKHCDJ-UHFFFAOYSA-N 0.000 description 1
- GFIJUMNEFNCAQP-UHFFFAOYSA-N 2-tert-butyl-4,6-bis(propylsulfanylmethyl)phenol Chemical compound CCCSCC1=CC(CSCCC)=C(O)C(C(C)(C)C)=C1 GFIJUMNEFNCAQP-UHFFFAOYSA-N 0.000 description 1
- PHVKQQZJMOESQM-UHFFFAOYSA-N 2-tert-butyl-4,6-bis(tert-butylsulfanylmethyl)phenol Chemical compound CC(C)(C)SCC1=CC(CSC(C)(C)C)=C(O)C(C(C)(C)C)=C1 PHVKQQZJMOESQM-UHFFFAOYSA-N 0.000 description 1
- OKKTWRDEUFRMIA-UHFFFAOYSA-N 2-tert-butyl-4,6-bis[(2-hydroxycyclohexyl)sulfanylmethyl]phenol Chemical compound C=1C(CSC2C(CCCC2)O)=C(O)C(C(C)(C)C)=CC=1CSC1CCCCC1O OKKTWRDEUFRMIA-UHFFFAOYSA-N 0.000 description 1
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- SYIAVRMBFSBTIF-UHFFFAOYSA-N 2-tert-butyl-4,6-bis[(4-methoxyphenyl)sulfanylmethyl]phenol Chemical compound C1=CC(OC)=CC=C1SCC1=CC(CSC=2C=CC(OC)=CC=2)=C(O)C(C(C)(C)C)=C1 SYIAVRMBFSBTIF-UHFFFAOYSA-N 0.000 description 1
- PHCJJMOSGYJCTH-UHFFFAOYSA-N 2-tert-butyl-4,6-bis[(4-methylphenyl)sulfanylmethyl]phenol Chemical compound C1=CC(C)=CC=C1SCC1=CC(CSC=2C=CC(C)=CC=2)=C(O)C(C(C)(C)C)=C1 PHCJJMOSGYJCTH-UHFFFAOYSA-N 0.000 description 1
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- QDVRXJQKEIGTIM-UHFFFAOYSA-N 3-[[3-tert-butyl-5-(2-cyanoethylsulfanylmethyl)-4-hydroxyphenyl]methylsulfanyl]propanenitrile Chemical compound CC(C)(C)C1=CC(CSCCC#N)=CC(CSCCC#N)=C1O QDVRXJQKEIGTIM-UHFFFAOYSA-N 0.000 description 1
- SPJPATBUSZJVAW-UHFFFAOYSA-N 3-[[3-tert-butyl-5-(3-carboxybutan-2-ylsulfanylmethyl)-4-hydroxyphenyl]methylsulfanyl]-2-methylbutanoic acid Chemical compound OC(=O)C(C)C(C)SCC1=CC(CSC(C)C(C)C(O)=O)=C(O)C(C(C)(C)C)=C1 SPJPATBUSZJVAW-UHFFFAOYSA-N 0.000 description 1
- 125000004975 3-butenyl group Chemical group C(CC=C)* 0.000 description 1
- 125000000474 3-butynyl group Chemical group [H]C#CC([H])([H])C([H])([H])* 0.000 description 1
- CAMBAGZYTIDFBK-UHFFFAOYSA-N 3-tert-butylperoxy-2-methylpropan-1-ol Chemical compound CC(CO)COOC(C)(C)C CAMBAGZYTIDFBK-UHFFFAOYSA-N 0.000 description 1
- MKTOIPPVFPJEQO-UHFFFAOYSA-N 4-(3-carboxypropanoylperoxy)-4-oxobutanoic acid Chemical compound OC(=O)CCC(=O)OOC(=O)CCC(O)=O MKTOIPPVFPJEQO-UHFFFAOYSA-N 0.000 description 1
- YGMMTETXBYREEI-UHFFFAOYSA-N 4-methyl-2,6-bis(octylsulfanylmethyl)phenol Chemical compound CCCCCCCCSCC1=CC(C)=CC(CSCCCCCCCC)=C1O YGMMTETXBYREEI-UHFFFAOYSA-N 0.000 description 1
- CCOJJJCQUHWYAT-UHFFFAOYSA-N 4-methyl-4-(2-methylbutan-2-ylperoxy)pentan-2-ol Chemical compound CCC(C)(C)OOC(C)(C)CC(C)O CCOJJJCQUHWYAT-UHFFFAOYSA-N 0.000 description 1
- QFYBZSWKSGOGKS-UHFFFAOYSA-N 4-tert-butyl-2,6-bis(dodecylsulfanylmethyl)phenol Chemical compound CCCCCCCCCCCCSCC1=CC(C(C)(C)C)=CC(CSCCCCCCCCCCCC)=C1O QFYBZSWKSGOGKS-UHFFFAOYSA-N 0.000 description 1
- JNSWFNBIZLIBPH-UHFFFAOYSA-N 4-tert-butylperoxy-4-methylpentan-2-ol Chemical compound CC(O)CC(C)(C)OOC(C)(C)C JNSWFNBIZLIBPH-UHFFFAOYSA-N 0.000 description 1
- DWUSYXYBLHQJBV-UHFFFAOYSA-N 6-tert-butyl-3-methyl-2,4-bis(phenylsulfanylmethyl)phenol Chemical compound C1=C(C(C)(C)C)C(O)=C(CSC=2C=CC=CC=2)C(C)=C1CSC1=CC=CC=C1 DWUSYXYBLHQJBV-UHFFFAOYSA-N 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- GURFSDXJFMXYJZ-UHFFFAOYSA-N C(CCCCCCCCCCC)SCC1=C(C(=CC(=C1)CSCCCCCCCCCCCC)CC#C)O Chemical compound C(CCCCCCCCCCC)SCC1=C(C(=CC(=C1)CSCCCCCCCCCCCC)CC#C)O GURFSDXJFMXYJZ-UHFFFAOYSA-N 0.000 description 1
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- PXXNTAGJWPJAGM-VCOUNFBDSA-N Decaline Chemical compound C=1([C@@H]2C3)C=C(OC)C(OC)=CC=1OC(C=C1)=CC=C1CCC(=O)O[C@H]3C[C@H]1N2CCCC1 PXXNTAGJWPJAGM-VCOUNFBDSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 125000006267 biphenyl group Chemical group 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 125000006547 cyclononyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C([H])([H])C1([H])[H] 0.000 description 1
- 125000000640 cyclooctyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C([H])([H])C1([H])[H] 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- QZYRMODBFHTNHF-UHFFFAOYSA-N ditert-butyl benzene-1,2-dicarboperoxoate Chemical group CC(C)(C)OOC(=O)C1=CC=CC=C1C(=O)OOC(C)(C)C QZYRMODBFHTNHF-UHFFFAOYSA-N 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- NLFBCYMMUAKCPC-KQQUZDAGSA-N ethyl (e)-3-[3-amino-2-cyano-1-[(e)-3-ethoxy-3-oxoprop-1-enyl]sulfanyl-3-oxoprop-1-enyl]sulfanylprop-2-enoate Chemical compound CCOC(=O)\C=C\SC(=C(C#N)C(N)=O)S\C=C\C(=O)OCC NLFBCYMMUAKCPC-KQQUZDAGSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 210000000416 exudates and transudate Anatomy 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000002431 foraging effect Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 125000000687 hydroquinonyl group Chemical class C1(O)=C(C=C(O)C=C1)* 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 229940070765 laurate Drugs 0.000 description 1
- 238000004811 liquid chromatography Methods 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- TZLNFHKARNTCRP-UHFFFAOYSA-N methyl 2-[[3-tert-butyl-4-hydroxy-5-[(2-methoxycarbonylphenyl)sulfanylmethyl]phenyl]methylsulfanyl]benzoate Chemical compound COC(=O)C1=CC=CC=C1SCC1=CC(CSC=2C(=CC=CC=2)C(=O)OC)=C(O)C(C(C)(C)C)=C1 TZLNFHKARNTCRP-UHFFFAOYSA-N 0.000 description 1
- 125000004092 methylthiomethyl group Chemical group [H]C([H])([H])SC([H])([H])* 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000003136 n-heptyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- ZDSCZDGPYYOCAP-UHFFFAOYSA-N octadecyl 2-[[2-hydroxy-3-[(2-octadecoxy-2-oxoethyl)sulfanylmethyl]-5-prop-2-ynylphenyl]methylsulfanyl]acetate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CSCC1=CC(CC#C)=CC(CSCC(=O)OCCCCCCCCCCCCCCCCCC)=C1O ZDSCZDGPYYOCAP-UHFFFAOYSA-N 0.000 description 1
- XCZNNZGOSKIBGW-UHFFFAOYSA-N octadecyl 2-[[4-hydroxy-2,5-dimethyl-3-[(2-octadecoxy-2-oxoethyl)sulfanylmethyl]phenyl]methylsulfanyl]acetate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CSCC1=CC(C)=C(O)C(CSCC(=O)OCCCCCCCCCCCCCCCCCC)=C1C XCZNNZGOSKIBGW-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 239000012086 standard solution Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- LMBFAGIMSUYTBN-MPZNNTNKSA-N teixobactin Chemical group C([C@H](C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H](CCC(N)=O)C(=O)N[C@H]([C@@H](C)CC)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H]1C(N[C@@H](C)C(=O)N[C@@H](C[C@@H]2NC(=N)NC2)C(=O)N[C@H](C(=O)O[C@H]1C)[C@@H](C)CC)=O)NC)C1=CC=CC=C1 LMBFAGIMSUYTBN-MPZNNTNKSA-N 0.000 description 1
- WYKYCHHWIJXDAO-UHFFFAOYSA-N tert-butyl 2-ethylhexaneperoxoate Chemical compound CCCCC(CC)C(=O)OOC(C)(C)C WYKYCHHWIJXDAO-UHFFFAOYSA-N 0.000 description 1
- 125000001973 tert-pentyl group Chemical group [H]C([H])([H])C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 230000017260 vegetative to reproductive phase transition of meristem Effects 0.000 description 1
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
Landscapes
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Insulating Materials (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP01810356 | 2001-04-10 | ||
| EP01810511 | 2001-05-23 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR0201173A BR0201173A (pt) | 2003-06-10 |
| BR0201173B1 true BR0201173B1 (pt) | 2012-01-10 |
Family
ID=26077366
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0201173-5A BR0201173B1 (pt) | 2001-04-10 | 2002-04-10 | composições de polietileno tendo resistência a vulcanização aperfeiçoada, processo de preparação e uso das mesmas. |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US7056967B2 (https=) |
| JP (1) | JP4051667B2 (https=) |
| KR (1) | KR100923284B1 (https=) |
| CN (1) | CN1250636C (https=) |
| AR (1) | AR033211A1 (https=) |
| AU (1) | AU784703B2 (https=) |
| BR (1) | BR0201173B1 (https=) |
| CA (1) | CA2380987C (https=) |
| CZ (1) | CZ305019B6 (https=) |
| MX (1) | MXPA02003611A (https=) |
| MY (1) | MY133253A (https=) |
| NO (1) | NO333375B1 (https=) |
| SG (1) | SG103854A1 (https=) |
| SK (1) | SK287686B6 (https=) |
| TW (1) | TWI239019B (https=) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB0508350D0 (en) * | 2005-04-26 | 2005-06-01 | Great Lakes Chemical Europ | Stabilized crosslinked polyolefin compositions |
| KR100727207B1 (ko) * | 2006-02-24 | 2007-06-13 | 주식회사 엘지화학 | 스웨트-아웃 억제 및 전기 절연특성이 우수한 가교 폴리에틸렌 조성물 |
| CA2596750C (en) * | 2006-02-24 | 2011-02-01 | Lg Chem, Ltd. | Cross-linked polyethylene having excellent inhibition of sweat-out and insulation properties |
| US8329797B2 (en) * | 2007-07-13 | 2012-12-11 | Dow Global Technologies Llc | Low dielectric loss power cable sheaths comprising high pressure polyolefins free of silane functionality |
| KR101362560B1 (ko) | 2011-08-08 | 2014-02-14 | 주식회사 엘지화학 | 가교 폴리에틸렌 조성물 |
| CN104334630B (zh) | 2012-06-04 | 2018-03-20 | 神华集团有限责任公司 | 一种加工性能改善的交联聚乙烯组合物 |
| US9617356B2 (en) | 2012-06-13 | 2017-04-11 | National Institute Of Clean-And-Low-Carbon Energy | Crosslinked polyethylene composition |
| EP2938669B1 (en) * | 2012-12-29 | 2019-08-28 | Dow Global Technologies LLC | Methods for making cross-linkable polymeric compositions and for producing a coated conductor |
| GB201320919D0 (en) | 2013-11-27 | 2014-01-08 | Addivant Switzerland Gmbh | Composition |
| JP6421217B2 (ja) * | 2017-06-07 | 2018-11-07 | ダウ グローバル テクノロジーズ エルエルシー | 架橋性高分子組成物、それを作製する方法、およびそれから作製される物品 |
| KR101953630B1 (ko) | 2018-04-26 | 2019-03-04 | 정대기 | 다결정 실리콘 조성물 |
| KR102061478B1 (ko) | 2018-04-26 | 2020-01-02 | 정대기 | 다결정 실리콘 성형체 및 그의 제조방법 |
| KR102060324B1 (ko) | 2018-04-26 | 2019-12-30 | 정대기 | 다결정 실리콘 절연체와 그의제조방법 및 그를 포함하는 애자,전력기기 및 부싱 |
| KR102055569B1 (ko) | 2018-04-26 | 2019-12-13 | (주) 이우티이씨 | 다결정 실리콘 절연체를 포함하는 애자 및 피뢰기 |
| KR102133574B1 (ko) | 2018-05-29 | 2020-07-13 | 정대기 | 다결정 실리콘 절연체를 포함하는 케이블용 피복재 |
| CN115219634A (zh) * | 2022-08-26 | 2022-10-21 | 南方电网科学研究院有限责任公司 | 电缆用可交联聚乙烯绝缘料抗烧焦性的评估方法 |
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-
2002
- 2002-04-05 SK SK470-2002A patent/SK287686B6/sk not_active IP Right Cessation
- 2002-04-05 US US10/117,650 patent/US7056967B2/en not_active Expired - Lifetime
- 2002-04-08 NO NO20021657A patent/NO333375B1/no not_active IP Right Cessation
- 2002-04-08 AR ARP020101284A patent/AR033211A1/es active IP Right Grant
- 2002-04-08 CZ CZ2002-1236A patent/CZ305019B6/cs not_active IP Right Cessation
- 2002-04-08 TW TW091106946A patent/TWI239019B/zh not_active IP Right Cessation
- 2002-04-09 SG SG200202081A patent/SG103854A1/en unknown
- 2002-04-09 KR KR1020020019147A patent/KR100923284B1/ko not_active Expired - Lifetime
- 2002-04-09 MY MYPI20021283A patent/MY133253A/en unknown
- 2002-04-09 AU AU32998/02A patent/AU784703B2/en not_active Expired
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- 2002-04-09 CN CNB021060223A patent/CN1250636C/zh not_active Expired - Lifetime
- 2002-04-09 JP JP2002106732A patent/JP4051667B2/ja not_active Expired - Lifetime
- 2002-04-10 MX MXPA02003611A patent/MXPA02003611A/es active IP Right Grant
- 2002-04-10 BR BRPI0201173-5A patent/BR0201173B1/pt not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| AU784703B2 (en) | 2006-06-01 |
| US7056967B2 (en) | 2006-06-06 |
| CZ305019B6 (cs) | 2015-04-01 |
| AU3299802A (en) | 2002-10-17 |
| AR033211A1 (es) | 2003-12-10 |
| CZ20021236A3 (cs) | 2002-11-13 |
| CA2380987A1 (en) | 2002-10-10 |
| KR100923284B1 (ko) | 2009-10-23 |
| KR20020079525A (ko) | 2002-10-19 |
| JP4051667B2 (ja) | 2008-02-27 |
| SK4702002A3 (en) | 2002-11-06 |
| SK287686B6 (sk) | 2011-06-06 |
| TWI239019B (en) | 2005-09-01 |
| MY133253A (en) | 2007-10-31 |
| CA2380987C (en) | 2011-03-15 |
| NO20021657L (no) | 2002-10-11 |
| JP2002363351A (ja) | 2002-12-18 |
| US20020198344A1 (en) | 2002-12-26 |
| BR0201173A (pt) | 2003-06-10 |
| MXPA02003611A (es) | 2002-11-07 |
| NO333375B1 (no) | 2013-05-13 |
| NO20021657D0 (no) | 2002-04-08 |
| CN1250636C (zh) | 2006-04-12 |
| CN1381522A (zh) | 2002-11-27 |
| SG103854A1 (en) | 2004-05-26 |
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