BR0110008A - Processo e catalisador para desidrogenação de álcoois primários na produção de sais de ácido carboxìlico - Google Patents

Processo e catalisador para desidrogenação de álcoois primários na produção de sais de ácido carboxìlico

Info

Publication number
BR0110008A
BR0110008A BR0110008-4A BR0110008A BR0110008A BR 0110008 A BR0110008 A BR 0110008A BR 0110008 A BR0110008 A BR 0110008A BR 0110008 A BR0110008 A BR 0110008A
Authority
BR
Brazil
Prior art keywords
catalyst
carboxylic acid
copper
dehydrogenation
support
Prior art date
Application number
BR0110008-4A
Other languages
English (en)
Other versions
BRPI0110008B1 (pt
Inventor
David A Morgenstern
Juan P Arhancet
Howard C Berk
William L Moench Jr
James C Peterson
Original Assignee
Monsanto Technology Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Technology Llc filed Critical Monsanto Technology Llc
Publication of BR0110008A publication Critical patent/BR0110008A/pt
Publication of BRPI0110008B1 publication Critical patent/BRPI0110008B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
    • C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
    • C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/56—Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/34—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation
    • B01J37/348—Electrochemical processes, e.g. electrochemical deposition or anodisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C227/00—Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton
    • C07C227/02—Formation of carboxyl groups in compounds containing amino groups, e.g. by oxidation of amino alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/835—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with germanium, tin or lead

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Electrochemistry (AREA)
  • Physics & Mathematics (AREA)
  • Molecular Biology (AREA)
  • Plasma & Fusion (AREA)
  • Toxicology (AREA)
  • Biochemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

"PROCESSO E CATALISADOR PARA DESIDROGENAçãO DE áLCOOIS PRIMáRIOS NA PRODUçãO DE SAIS DE áCIDO CARBOXìLICO". Esta invenção direciona-se a um processo para produção de um sal do ácido carboxílico. O processo compreende o contato de um catalisador com uma mistura alcalina compreendendo um álcool primário. Em uma modalidade, por exemplo, o catalisador compreende um suporte metálico (de preferência um suporte de esponja metálica) com uma fase ativa contendo cobre e sua superfície. O suporte é resistente a deformação sob condições de reação de desidrogenação. Em uma outra modalidade, o catalisador compreende uma esponja metálica com uma fase ativa contendo cobre em sua superfície e uma estrutura de suporte contendo pelo menos 10% de metal não-cobre. Esta invenção também se dirige a catalisadores contendo cobre que podem ser usados no processo acima, por exemplo. Esta invenção dirige-se ainda a processos para produção de tais catalisadores.
BRPI0110008A 2000-04-11 2001-04-11 processo para preparação de um sal de ácido carboxílico por desidrogenação de um álcool primário BRPI0110008B1 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/547,373 US6376708B1 (en) 2000-04-11 2000-04-11 Process and catalyst for dehydrogenating primary alcohols to make carboxylic acid salts
PCT/US2001/040488 WO2001077054A2 (en) 2000-04-11 2001-04-11 Process and catalyst for dehydrogenating primary alcohols to make carboxylic acid salts

Publications (2)

Publication Number Publication Date
BR0110008A true BR0110008A (pt) 2003-02-11
BRPI0110008B1 BRPI0110008B1 (pt) 2016-04-19

Family

ID=24184399

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0110008A BRPI0110008B1 (pt) 2000-04-11 2001-04-11 processo para preparação de um sal de ácido carboxílico por desidrogenação de um álcool primário

Country Status (10)

Country Link
US (6) US6376708B1 (pt)
EP (1) EP1272451B1 (pt)
CN (2) CN100469749C (pt)
AR (1) AR029059A1 (pt)
AU (2) AU2001257598B2 (pt)
BR (1) BRPI0110008B1 (pt)
CA (1) CA2405853C (pt)
ES (1) ES2390657T3 (pt)
MX (1) MXPA02010161A (pt)
WO (1) WO2001077054A2 (pt)

Families Citing this family (39)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001046208A2 (en) 1999-12-21 2001-06-28 Monsanto Technology Llc Use of a supplemental promoter in conjunction with a carbon-supported, noble-metal-containing catalyst in liquid phase oxidation reactions
US6376708B1 (en) * 2000-04-11 2002-04-23 Monsanto Technology Llc Process and catalyst for dehydrogenating primary alcohols to make carboxylic acid salts
MXPA04002824A (es) * 2001-09-27 2004-07-05 Hoffmann La Roche Derivados de indol como inhibidores de cox ii.
AU2002362929B2 (en) * 2001-10-18 2007-08-09 Monsanto Technology Llc Process and catalyst for dehydrogenating primary alcohols to make carboxylic acid salts
DE10161674A1 (de) * 2001-12-14 2003-06-26 Basf Ag Katalysatoren zur Herstellung von Carbonsäuresalzen
WO2003068387A1 (en) * 2002-02-14 2003-08-21 Monsanto Technology Llc Oxidation catalyst and process for its preparation and process for oxidation using it
US7390920B2 (en) * 2002-02-14 2008-06-24 Monsanto Technology Llc Oxidation catalyst and process
AU2003233738A1 (en) * 2002-06-05 2003-12-22 University Technologies International Inc. Oxygen reduction catalyst
US6911161B2 (en) * 2002-07-02 2005-06-28 Conocophillips Company Stabilized nickel-containing catalysts and process for production of syngas
KR101052385B1 (ko) * 2002-10-18 2011-07-28 몬산토 테크놀로지 엘엘씨 알코올 개질용 금속 지지 구리 촉매의 용도
US7375053B2 (en) * 2003-04-07 2008-05-20 W. R. Grace & Co.- Conn. Nickel and cobalt plated sponge catalysts
WO2005016519A1 (en) 2003-08-14 2005-02-24 Monsanto Technology Llc Transition metal-carbide and nitride containing catalysts , their preparation and use as oxidation and dehydrogenation catalysts
GB0323386D0 (en) * 2003-10-07 2003-11-05 Johnson Matthey Plc Catalyst for manufacture of esters
US20050100493A1 (en) * 2003-11-06 2005-05-12 George Yaluris Ferrierite compositions for reducing NOx emissions during fluid catalytic cracking
US20050100494A1 (en) * 2003-11-06 2005-05-12 George Yaluris Ferrierite compositions for reducing NOx emissions during fluid catalytic cracking
RU2372991C2 (ru) * 2004-01-20 2009-11-20 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Способ восстановления каталитической активности отработанного катализатора водородообработки, отработанный катализатор водородообработки, имеющий восстановленную каталитическую активность, и способ водородообработки
US7304011B2 (en) * 2004-04-15 2007-12-04 W.R. Grace & Co. -Conn. Compositions and processes for reducing NOx emissions during fluid catalytic cracking
US20050232839A1 (en) * 2004-04-15 2005-10-20 George Yaluris Compositions and processes for reducing NOx emissions during fluid catalytic cracking
WO2006031938A2 (en) * 2004-09-15 2006-03-23 Monsanto Technology Llc Oxidation catalyst and its use for catalyzing liquid phase oxidation reactions
US8198479B2 (en) * 2005-02-17 2012-06-12 Monsanto Technology Llc Transition metal-containing catalysts and catalyst combinations including transition metal-containing catalysts and processes for their preparation and use as oxidation catalysts
KR101382014B1 (ko) 2005-04-27 2014-04-04 더블유.알. 그레이스 앤드 캄파니-콘. 유동상 접촉 분해 중의 ＮＯｘ 방출 감소를 위한 조성물 및공정
CA2642226A1 (en) * 2006-02-17 2007-08-30 Monsanto Technology Llc Transition metal-containing catalysts and processes for their preparation and use as fuel cell catalysts
DE102006016227A1 (de) * 2006-04-06 2007-10-11 Degussa Gmbh Verfahren zur Herstellung von Kreatin, Kreatin-Monohydrat oder Guanidinoessigsäure
EP2035682A2 (en) * 2006-06-13 2009-03-18 Monsanto Technology LLP Reformed alcohol power systems
US8252953B2 (en) 2008-05-01 2012-08-28 Monsanto Technology Llc Metal utilization in supported, metal-containing catalysts
JP5605984B2 (ja) * 2008-09-22 2014-10-15 独立行政法人物質・材料研究機構 メタノール改質反応用触媒またはメタノール分解反応用触媒
US8669396B2 (en) 2009-05-18 2014-03-11 Monsanto Technology Llc Recovery of phosphorus values and salt impurities from aqueous waste streams
US20110011772A1 (en) * 2009-07-15 2011-01-20 Stephen Raymond Schmidt Nickel and Cobalt Plated Sponge Catalysts
EP2547648B1 (de) 2010-03-18 2013-07-10 Basf Se Verfahren zur herstellung nebenproduktarmer aminocarboxylate
US9315736B2 (en) 2010-12-16 2016-04-19 Energia Technologies, Inc. Methods of fuel production
AU2011343489A1 (en) 2010-12-16 2013-08-01 Energia Technologies, Inc. Catalysts, methods of preparation of catalyst, methods of deoxygenation, and systems for fuel production
RU2452565C1 (ru) * 2011-02-16 2012-06-10 Учреждение Российской академии наук Институт катализа им. Г.К. Борескова Сибирского отделения РАН Катализатор, способ его приготовления и способ получения динатриевой соли иминодиуксусной кислоты
CN103497117B (zh) * 2013-09-25 2016-03-23 河北诚信有限责任公司 乙二胺四乙酸的生产工艺
AU2015332529B2 (en) * 2014-10-16 2021-05-20 Energizer Brands Uk Limited A buckling resistant current collector
EP3370518B1 (en) 2015-10-14 2023-08-23 X-Therma, Inc. Compositions and methods for reducing ice crystal formation
CN108212162B (zh) * 2016-12-22 2021-03-16 成功大学 纳米镍触媒及碳氧化物的氢化方法
CN108503530B (zh) * 2017-02-28 2021-04-13 中国石油化工股份有限公司 一种制备异辛酸的工艺方法
CN112079707B (zh) * 2020-09-23 2021-06-01 中国科学院大连化学物理研究所 一种钴盐催化氧化伯醇制备羧酸及联产α-烯烃的方法
CA3212507A1 (en) * 2021-03-04 2022-09-09 Monsanto Technology Llc Two-compartment bipolar membrane electrodialysis of salts of amino acids

Family Cites Families (103)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1975853A (en) * 1931-04-11 1934-10-09 Du Pont Catalytic dehydrogenation of primary alcohols
US2028267A (en) 1933-04-05 1936-01-21 Standard Alcohol Co Manufacturing ketones
US2384816A (en) 1941-12-20 1945-09-18 Carbide & Carbon Chem Corp Preparation of amino carboxylic acids and their salts
US2384817A (en) 1942-09-05 1945-09-18 Carbide & Carbon Chem Corp Catalytic alkaline oxidation of alcohols
US2892801A (en) 1955-12-13 1959-06-30 Gen Electric Catalysts
US3184417A (en) * 1960-12-29 1965-05-18 Gen Aniline & Film Corp Method of preparing a copper modified nickel catalyst composition
US3254128A (en) * 1961-11-09 1966-05-31 Eastman Kodak Co Catalytic dehydrogenation of primary alcohols to aldehydes
US3206414A (en) * 1962-07-10 1965-09-14 Gunther Arnold Method of preparing a catalyst composition comprising nickel, iron and copper and the product thereof
DE1567785A1 (de) 1965-03-13 1970-05-27 Siemens Ag Verfahren zur Herstellung eines Katalysators fuer die Gewinnung von Wasserstoff durch katalytische Umsetzung von Kohlenwasserstoffen und deren sauerstoffhaltigen Derivaten mit Wasserdampf
US3522019A (en) 1965-08-03 1970-07-28 United Aircraft Corp Apparatus for generating hydrogen from liquid hydrogen - containing feedstocks
US3668012A (en) * 1968-11-13 1972-06-06 Varta Ag Electrode for electrochemical devices and method of its manufacture
DE2139774C3 (de) 1971-08-09 1975-01-02 Varta Batterie Ag, 3000 Hannover Vorrichtung zur Entgiftung der Abgase von Kraftfahrzeug-Verbrennungsmotoren
GB1436843A (en) 1972-07-21 1976-05-26 Ici Ltd Preparation of n-phosphonomethyl-glycine
US3998758A (en) 1973-02-21 1976-12-21 Clyde Robert A Supported catalyst
US3876456A (en) * 1973-03-16 1975-04-08 Olin Corp Catalyst for the reduction of automobile exhaust gases
US3892600A (en) * 1973-06-22 1975-07-01 Gen Electric Annealed coated air-stable cobalt-rare earth alloy particles
US3928441A (en) * 1974-08-08 1975-12-23 Nalco Chemical Co Raney copper catalyst production and use
US4021373A (en) 1973-11-12 1977-05-03 The International Nickel Company, Inc. Method of preparing a catalytic structure
US3960898A (en) * 1974-02-05 1976-06-01 Commercial Solvents Corporation Zearalanone-zearalanol product
US3969398A (en) 1974-05-01 1976-07-13 Monsanto Company Process for producing N-phosphonomethyl glycine
US3927080A (en) 1974-09-03 1975-12-16 Monsanto Co Process for producing N-phosphonomethyl glycine
HU170253B (pt) * 1974-10-07 1977-05-28
DE2501250A1 (de) 1975-01-14 1976-07-15 Siemens Ag Verfahren zum betrieb einer brennkraftmaschine
US4083905A (en) 1975-04-25 1978-04-11 Champion Spark Plug Company Open mesh, random fiber, ceramic structure, monolithic catalyst support
US4024044A (en) 1975-09-15 1977-05-17 Diamond Shamrock Corporation Electrolysis cathodes bearing a melt-sprayed and leached nickel or cobalt coating
US4070375A (en) * 1976-08-05 1978-01-24 Chevron Research Company Process for preparing 1,4-dioxan-2-ones
US4086887A (en) * 1977-02-09 1978-05-02 Schoonover Alan G Rocker arm shaft support
DE2713374B2 (de) 1977-03-25 1980-02-14 Bayer Ag, 5090 Leverkusen Raney-Nickel-Eisen-Katalysator
US4378336A (en) * 1979-12-18 1983-03-29 Conoco Inc. Monolith reactor
NL8001878A (nl) * 1980-03-29 1981-11-02 Stamicarbon Werkwijze voor de bereiding van aldehyden.
DE3163066D1 (en) 1980-06-26 1984-05-24 Inst Francais Du Petrole Process for the preparation of a ketone by dehydrogenation of a secondary alcohol
EP0055695A1 (de) 1980-12-30 1982-07-07 Ciba-Geigy Ag Verfahren zur Herstellung von N-phosphonomethylglycin
US4539403A (en) 1982-02-16 1985-09-03 Ube Industries, Ltd. Process for the preparation of a 2-alkyl-4-amino-5-aminomethylpyrimidine
EP0087298B1 (en) 1982-02-23 1986-05-28 Sumitomo Chemical Company, Limited Process for producing benzaldehydes
DE3471092D1 (en) 1983-03-09 1988-06-16 Firmenich & Cie Composition essentially consisting of trans-1-(2,6,6-trimethylcyclohexyl)-hexan-3-ol, utilization of same and process for its preparation; cycloaliphatic ketone and alcohol intermediates
GB2148287B (en) 1983-10-05 1987-04-15 Nippon Catalytic Chem Ind Preparation of aminocarboxylic acid salts from amino alcohols
US4624937A (en) 1984-05-10 1986-11-25 Monsanto Company Process for removing surface oxides from activated carbon catalyst
DE3423605A1 (de) 1984-06-27 1986-01-09 W.C. Heraeus Gmbh, 6450 Hanau Verbundelektrode, verfahren zu ihrer herstellung und ihre anwendung
US4775498A (en) 1984-12-05 1988-10-04 Monsanto Company Process for preparing N,N-diacetic acid aminomethylenephosphonic acid
US4582650A (en) 1985-02-11 1986-04-15 Monsanto Company Oxidation with encapsulated co-catalyst
US4696772A (en) 1985-02-28 1987-09-29 Monsanto Company Amine oxidation using carbon catalyst having oxides removed from surface
JP2511866B2 (ja) 1986-02-07 1996-07-03 株式会社日立製作所 燃料電池発電システム及びその起動方法
JPS63256136A (ja) * 1987-04-14 1988-10-24 Idemitsu Kosan Co Ltd メタノ−ル改質用触媒
US4857233A (en) * 1988-05-26 1989-08-15 Potters Industries, Inc. Nickel particle plating system
US5017729A (en) 1988-09-30 1991-05-21 Mitsui Petrochemical Industries, Ltd. Phenol preparation process and propylene recovery therefrom
US4994427A (en) * 1988-11-28 1991-02-19 Virginia Tech Intellectual Properties, Inc. Supported aqueous phase organometallic catalyst useful for hydroformylation and other reactions, and a method for its preparation
US6155212A (en) * 1989-06-12 2000-12-05 Mcalister; Roy E. Method and apparatus for operation of combustion engines
ES2021229A6 (es) 1990-03-12 1991-10-16 Ercros Sa Perfeccionamientos introducidos en un procedimiento de obtencion de n-fosfonometilglicina por oxidacion de n-fosfonometiliminodiacetico.
WO1992006949A1 (fr) * 1990-10-23 1992-04-30 Nippon Shokubai Co., Ltd. Procede de production de sels d'acide aminocarboxylique
JPH06506744A (ja) 1990-11-23 1994-07-28 クラシンゲ　アルマドゥラ　ナンダセナ　シルバ 液体燃料の燃焼
DK0513396T3 (da) * 1990-11-27 1996-07-29 Nippon Catalytic Chem Ind Fremgangsmåde til fremstilling af aminosyresalte
US5099073A (en) 1991-02-11 1992-03-24 Texaco Chemical Company Catalytic process for the production of diketone derivatives of polyoxypropylene glycols
EP0793772A1 (en) 1991-09-05 1997-09-10 McAlister, Roy E. Method and apparatus for operation of engines
EP0694030B2 (en) 1993-04-12 2003-01-02 Monsanto Company Process to prepare amino carboxylic acid salts
US5292936A (en) 1993-04-12 1994-03-08 Monsanto Company Process to prepare amino carboxylic acid salts
US5603844A (en) 1993-09-22 1997-02-18 The United States Of America As Represented By The Secretary Of The Interior Instant, chemical-free dechlorination of water supplies
DE4335360A1 (de) 1993-10-16 1995-04-20 Degussa Aktivierter Metall-Festbettkatalysator nach Raney und Verfahren zu seiner Herstellung
FR2716450B1 (fr) * 1994-02-21 1996-05-24 Rhone Poulenc Chimie Procédé de préparation d'acide acétique par oxydation ménagée de l'éthanol.
EP1662113B1 (en) 1994-04-10 2012-11-21 McAlister, Roy E. Apparatus for operation of engines
US5689000A (en) 1994-07-01 1997-11-18 Monsanto Company Process for preparing carboxylic acid salts and catalysts useful in such process
US5916840A (en) 1994-07-01 1999-06-29 Monsanto Company Process for preparing carboxylic acid salts and catalysts useful in such process
JPH10502369A (ja) 1994-07-01 1998-03-03 モンサント・カンパニー Ｎ−ホスホノメチルアミノカルボン酸を製造する方法
TW340806B (en) 1995-03-28 1998-09-21 Mitsui Toatsu Chemicals Modified Raney catalyst and process for preparation thereof
RU2162991C2 (ru) * 1995-06-07 2001-02-10 Джеймс Шнелл Геотермальная система для выработки электроэнергии
DE19534433C1 (de) 1995-09-16 1996-10-10 Daimler Benz Ag Katalysatorschichtstruktur für einen Methanolreformierungsreaktor und Verfahren zu ihrer Herstellung
US5837402A (en) * 1995-12-21 1998-11-17 Dowa Mining Co., Ltd. Zinc powders for use in batteries and a secondary alkaline zinc battery using said zinc powders
EP0812802B1 (de) 1996-06-15 1999-08-18 dbb fuel cell engines GmbH Reformierungsreaktor, insbesondere zur Wasserdampfreformierung von Methanol
DE19624435C1 (de) 1996-06-19 1997-08-28 Daimler Benz Ag Reformierungsreaktor, insbesondere zur Wasserdampfreformierung von Methanol
HUP9904636A3 (en) 1996-09-26 2000-08-28 Akzo Nobel Nv Catalyst for dehydrogenation of amino alcohols or of ethylene glycol(derivatives), method for their production and their use
CN1239473A (zh) * 1997-02-13 1999-12-22 孟山都公司 制备氨基羧酸的方法
US6209494B1 (en) 1997-03-14 2001-04-03 Procyon Power Systems, Inc. Hybrid fuel-cell electric-combustion power system using complete pyrolysis
US5898085A (en) * 1997-03-28 1999-04-27 E. I. Du Pont De Nemours And Company Production of 1,3-diaminopentane by hydrogenation of 3-aminopentanenitrile
US5922921A (en) 1997-10-27 1999-07-13 Celanese International Corporation Process for the production of n-butanol
US6077620A (en) 1997-11-26 2000-06-20 General Motors Corporation Fuel cell system with combustor-heated reformer
US5866725A (en) 1997-12-11 1999-02-02 Celanese International Corporation Process for the production of n-propanol
US6232494B1 (en) * 1998-02-12 2001-05-15 Monsanto Company Process for the preparation of N-(phosphonomethyl)glycine by oxidizing N-substituted N-(phosphonomethyl)glycine
EP1062221B1 (en) 1998-02-12 2006-05-10 Monsanto Technology LLC Process for making glyphosate by oxidizing n-substituted glyphosates
US6417133B1 (en) 1998-02-25 2002-07-09 Monsanto Technology Llc Deeply reduced oxidation catalyst and its use for catalyzing liquid phase oxidation reactions
US5986127A (en) 1999-03-15 1999-11-16 E. I. Du Pont De Nemours And Company Aminonitrile production
ITTO980249A1 (it) * 1998-03-23 1999-09-23 Finchimica Srl Procedimento per la preparazione di sali di acidi carbossilici
AR043078A1 (es) * 1998-09-14 2005-07-20 Dow Agrosciences Llc Procesos para preparar acidos carboxilicos
DE19847987C2 (de) 1998-10-17 2001-06-13 Xcellsis Gmbh Verfahren zur Herstellung einer Vorrichtung zur Wasserstofferzeugung und Vorrichtung zur Wasserstofferzeugung
KR20010080643A (ko) 1998-12-01 2001-08-22 릴리 엠 씨즐러 스피허, 아네뜨 워너 아미노카복실산의 제조 방법
CA2370621A1 (en) 1999-05-03 2000-11-09 Monsanto Technology Llc Process for the preparation of carboxylic acid salts from primary alcohols
US6309758B1 (en) 1999-05-06 2001-10-30 W. R. Grace & Co.-Conn. Promoted porous catalyst
FR2795339B1 (fr) 1999-06-24 2001-09-21 Peugeot Citroen Automobiles Sa Catalyseur et procede de reformage de l'ethanol ainsi que systeme de pile a combustible les utilisant
DE19936135A1 (de) 1999-07-31 2001-02-15 Degussa Festbettkatalysatoren
US20020012624A1 (en) * 2000-01-07 2002-01-31 Figueroa Juan C. Bulk nickel alloy catalysts and process for production of syngas
US20020038051A1 (en) 2000-02-18 2002-03-28 Degussa-Huls Ag Raney copper
EP1127613A1 (de) 2000-02-18 2001-08-29 Degussa AG Geformter Festbettraney-Kupferkatalysator zur Verwendung bei der Dehydrierung von Alkoholen
EP1382388A1 (de) 2000-02-18 2004-01-21 Degussa AG Festbettraney-Kupferkatalysator zur Dehydrierung von Alkoholen
US6376708B1 (en) 2000-04-11 2002-04-23 Monsanto Technology Llc Process and catalyst for dehydrogenating primary alcohols to make carboxylic acid salts
DE10025033A1 (de) 2000-05-20 2001-11-29 Dmc2 Degussa Metals Catalysts Verfahren zur elektrischen Energiegewinnung mit Hilfe einer Brennstoffzelle
US6541142B1 (en) 2000-10-04 2003-04-01 General Motors Corporation Fuel cell system having a methanol decomposition reactor
US6828055B2 (en) * 2001-07-27 2004-12-07 Hewlett-Packard Development Company, L.P. Bipolar plates and end plates for fuel cells and methods for making the same
AU2002362929B2 (en) * 2001-10-18 2007-08-09 Monsanto Technology Llc Process and catalyst for dehydrogenating primary alcohols to make carboxylic acid salts
US6818720B2 (en) 2001-11-08 2004-11-16 Degussa Ag Supported hydrogenating catalyst in powder form
US6668763B2 (en) * 2002-03-11 2003-12-30 The University Of Chicago Process for in-situ production of hydrogen (H2) by alcohol decomposition for emission reduction from internal combustion engines
JP2004082007A (ja) 2002-08-27 2004-03-18 Honda Motor Co Ltd 触媒粒子及びアルコールの脱水素触媒粒子
KR101052385B1 (ko) 2002-10-18 2011-07-28 몬산토 테크놀로지 엘엘씨 알코올 개질용 금속 지지 구리 촉매의 용도
US7375053B2 (en) 2003-04-07 2008-05-20 W. R. Grace & Co.- Conn. Nickel and cobalt plated sponge catalysts
US20050049434A1 (en) 2003-08-28 2005-03-03 Tustin Gerald Charles Fluidizable carbon catalysts
JP4039383B2 (ja) 2003-10-21 2008-01-30 トヨタ自動車株式会社 水素利用内燃機関

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AR029059A1 (es) 2003-06-04
BRPI0110008B1 (pt) 2016-04-19
EP1272451B1 (en) 2012-08-01
WO2001077054A3 (en) 2002-04-25
CN100469749C (zh) 2009-03-18
ES2390657T3 (es) 2012-11-15
US20120190889A1 (en) 2012-07-26
US6706662B2 (en) 2004-03-16
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CA2405853C (en) 2011-01-25
EP1272451A2 (en) 2003-01-08
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US20020161259A1 (en) 2002-10-31
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US6376708B1 (en) 2002-04-23
US20110071018A1 (en) 2011-03-24
US20050159305A1 (en) 2005-07-21
CN1427812A (zh) 2003-07-02
WO2001077054A2 (en) 2001-10-18
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US8298985B2 (en) 2012-10-30
US7329778B2 (en) 2008-02-12

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