BR0017502B1 - terpolÍmero de butila halogenado compreendendo um monâmero de c4-c8 monoolefina, um monâmero de c4 a c14 multiolefina e p-metilestireno. - Google Patents
terpolÍmero de butila halogenado compreendendo um monâmero de c4-c8 monoolefina, um monâmero de c4 a c14 multiolefina e p-metilestireno. Download PDFInfo
- Publication number
- BR0017502B1 BR0017502B1 BRPI0017502-1A BR0017502A BR0017502B1 BR 0017502 B1 BR0017502 B1 BR 0017502B1 BR 0017502 A BR0017502 A BR 0017502A BR 0017502 B1 BR0017502 B1 BR 0017502B1
- Authority
- BR
- Brazil
- Prior art keywords
- monomer
- terpolymer
- weight
- rubber product
- cured rubber
- Prior art date
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- 239000000178 monomer Substances 0.000 title claims description 110
- 229920001897 terpolymer Polymers 0.000 title claims description 77
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 title claims description 41
- 150000005673 monoalkenes Chemical class 0.000 title claims description 29
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 title claims description 12
- 229920000642 polymer Polymers 0.000 claims description 53
- 239000000203 mixture Substances 0.000 claims description 42
- 229920001971 elastomer Polymers 0.000 claims description 37
- 239000005060 rubber Substances 0.000 claims description 37
- 238000000034 method Methods 0.000 claims description 24
- 230000008569 process Effects 0.000 claims description 22
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 21
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 18
- 230000032683 aging Effects 0.000 claims description 15
- 229910052736 halogen Inorganic materials 0.000 claims description 11
- 150000002367 halogens Chemical class 0.000 claims description 11
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims description 10
- 125000003118 aryl group Chemical group 0.000 claims description 10
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 8
- MGNZXYYWBUKAII-UHFFFAOYSA-N cyclohexa-1,3-diene Chemical compound C1CC=CC=C1 MGNZXYYWBUKAII-UHFFFAOYSA-N 0.000 claims description 8
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 claims description 8
- UAJRSHJHFRVGMG-UHFFFAOYSA-N 1-ethenyl-4-methoxybenzene Chemical compound COC1=CC=C(C=C)C=C1 UAJRSHJHFRVGMG-UHFFFAOYSA-N 0.000 claims description 6
- 239000003054 catalyst Substances 0.000 claims description 6
- 230000007423 decrease Effects 0.000 claims description 5
- GQIJYUMTOUBHSH-IJIVKGSJSA-N piperyline Chemical compound C=1C=C2OCOC2=CC=1/C=C/C=C/C(=O)N1CCCC1 GQIJYUMTOUBHSH-IJIVKGSJSA-N 0.000 claims description 5
- JLSUFZZPRVNDIW-UHFFFAOYSA-N 1-ethenylcyclohexa-1,3-diene Chemical compound C=CC1=CC=CCC1 JLSUFZZPRVNDIW-UHFFFAOYSA-N 0.000 claims description 4
- 230000002140 halogenating effect Effects 0.000 claims description 4
- KTZVZZJJVJQZHV-UHFFFAOYSA-N 1-chloro-4-ethenylbenzene Chemical compound ClC1=CC=C(C=C)C=C1 KTZVZZJJVJQZHV-UHFFFAOYSA-N 0.000 claims description 3
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 3
- NFWSQSCIDYBUOU-UHFFFAOYSA-N methylcyclopentadiene Chemical compound CC1=CC=CC1 NFWSQSCIDYBUOU-UHFFFAOYSA-N 0.000 claims 3
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 claims 2
- 230000002794 monomerizing effect Effects 0.000 claims 1
- 230000000379 polymerizing effect Effects 0.000 claims 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 12
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 12
- 229910052794 bromium Inorganic materials 0.000 description 12
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 12
- 229920005549 butyl rubber Polymers 0.000 description 9
- 229920001577 copolymer Polymers 0.000 description 7
- 229920005555 halobutyl Polymers 0.000 description 7
- 238000006116 polymerization reaction Methods 0.000 description 7
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- 230000003247 decreasing effect Effects 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 230000003679 aging effect Effects 0.000 description 5
- 239000004568 cement Substances 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Chemical compound C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- PCLIMKBDDGJMGD-UHFFFAOYSA-N N-bromosuccinimide Chemical compound BrN1C(=O)CCC1=O PCLIMKBDDGJMGD-UHFFFAOYSA-N 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 230000031709 bromination Effects 0.000 description 4
- 238000005893 bromination reaction Methods 0.000 description 4
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 3
- 239000008116 calcium stearate Substances 0.000 description 3
- 235000013539 calcium stearate Nutrition 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 238000001069 Raman spectroscopy Methods 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 230000026030 halogenation Effects 0.000 description 2
- 238000005658 halogenation reaction Methods 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000000523 sample Substances 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- 230000035882 stress Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- JIGUICYYOYEXFS-UHFFFAOYSA-N 3-tert-butylbenzene-1,2-diol Chemical compound CC(C)(C)C1=CC=CC(O)=C1O JIGUICYYOYEXFS-UHFFFAOYSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 1
- 241001441571 Hiodontidae Species 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001649 bromium compounds Chemical class 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 238000010538 cationic polymerization reaction Methods 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 239000012986 chain transfer agent Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000013068 control sample Substances 0.000 description 1
- 239000006184 cosolvent Substances 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000035876 healing Effects 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000003550 marker Substances 0.000 description 1
- 229940050176 methyl chloride Drugs 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000000425 proton nuclear magnetic resonance spectrum Methods 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 238000010092 rubber production Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000007613 slurry method Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000007655 standard test method Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000010558 suspension polymerization method Methods 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 230000009261 transgenic effect Effects 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
- 239000004636 vulcanized rubber Substances 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/18—Introducing halogen atoms or halogen-containing groups
- C08F8/20—Halogenation
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA2282900A CA2282900C (en) | 1999-09-20 | 1999-09-20 | Halogenated terpolymers of isobutylene, diolefin monomer and styrenic monomer |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR0017502B1 true BR0017502B1 (pt) | 2013-03-05 |
Family
ID=4164170
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0017502-1A BR0017502B1 (pt) | 1999-09-20 | 2000-09-19 | terpolÍmero de butila halogenado compreendendo um monâmero de c4-c8 monoolefina, um monâmero de c4 a c14 multiolefina e p-metilestireno. |
| BR0014125-9A BR0014125A (pt) | 1999-09-20 | 2000-09-19 | Terpolìmeros halogenados de isobutileno, monÈmero de diolefina e monÈmero estirênico |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR0014125-9A BR0014125A (pt) | 1999-09-20 | 2000-09-19 | Terpolìmeros halogenados de isobutileno, monÈmero de diolefina e monÈmero estirênico |
Country Status (10)
| Country | Link |
|---|---|
| US (4) | US6960632B2 (enExample) |
| EP (1) | EP1228106B1 (enExample) |
| JP (2) | JP2003510380A (enExample) |
| CN (1) | CN1159351C (enExample) |
| AU (1) | AU7262900A (enExample) |
| BR (2) | BR0017502B1 (enExample) |
| CA (1) | CA2282900C (enExample) |
| RU (1) | RU2002110664A (enExample) |
| TW (1) | TW591042B (enExample) |
| WO (1) | WO2001021672A1 (enExample) |
Families Citing this family (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2282900C (en) * | 1999-09-20 | 2011-02-01 | Bayer Inc. | Halogenated terpolymers of isobutylene, diolefin monomer and styrenic monomer |
| RU2303044C2 (ru) * | 2001-12-10 | 2007-07-20 | Эксонмобил Кемикэл Пейтентс Инк. | Галогенированные тройные сополимеры на изоолефиновой основе и их использование в композициях для применения в пневматической диафрагме, такой как внутренняя оболочка шины или камера для пневматической шины |
| US7329697B2 (en) | 2001-12-10 | 2008-02-12 | Exxonmobil Chemical Patents Inc. | Elastomeric compositions |
| ATE428734T1 (de) * | 2001-12-10 | 2009-05-15 | Exxonmobil Chem Patents Inc | Elastomere zusammensetzungen |
| CA2383474A1 (en) * | 2002-04-26 | 2003-10-26 | Bayer Inc. | Rubber composition for tire treads |
| CA2438024C (en) * | 2003-08-14 | 2013-05-28 | Bayer Inc. | Peroxide curable butyl formulations |
| CA2465407C (en) * | 2004-04-28 | 2012-11-13 | Rui Resendes | Peroxide curable butyl formulations |
| CA2551997C (en) * | 2005-08-26 | 2014-05-27 | Lanxess Inc. | Novel methods for the preparation of butyl graft copolymers |
| US7294768B1 (en) | 2005-09-27 | 2007-11-13 | Monsanto Technology Llc | Soybean variety 0384279 |
| EP2502742B1 (en) | 2005-10-27 | 2017-06-21 | ExxonMobil Chemical Patents Inc. | Construction comprising tie layer for pneumatic tire |
| US7585914B2 (en) * | 2005-11-09 | 2009-09-08 | Exxonmobil Chemical Patents Inc. | Thermoplastic elastomer compositions and methods for making the same |
| CA2575652A1 (en) * | 2006-02-15 | 2007-08-15 | Lanxess Inc. | Method of halogenating butyl rubber without acid neutralization agents |
| US7767743B2 (en) * | 2006-03-10 | 2010-08-03 | Exxonmobil Chemical Patents Inc. | Processable branched isoolefin-alkylstyrene elastomers |
| BRPI0818579A2 (pt) * | 2007-10-19 | 2011-09-13 | Lanxess Inc | compostos de borracha de butila compreendendo um sistema modificador de três componentes mistos |
| JP5632858B2 (ja) | 2009-02-13 | 2014-11-26 | ランクセス・インク． | 再生ブチルアイオノマー及び再生方法 |
| BRPI1008436A2 (pt) | 2009-02-13 | 2020-02-27 | Lanxess Inc. | Ionomeros de butila para uso na reducao de uma populacao de e/ou prevencao do acumulo de organismos e revestimentos feitos a partir deles |
| GB2474356A (en) * | 2009-10-07 | 2011-04-13 | Bromine Compounds Ltd | Preparation of bromine-containing copolymers |
| MY160881A (en) | 2010-03-24 | 2017-03-31 | Arlanxeo Deutschland Gmbh | Process for the production of water and solvent-free polymers |
| WO2011117297A1 (en) | 2010-03-24 | 2011-09-29 | Lanxess International Sa | Process for the production of water and solvent-free halobutyl rubbers |
| KR101467650B1 (ko) | 2010-03-24 | 2014-12-01 | 란세스 인터내쇼날 에스에이 | 고무 이오노머 및 중합체 나노복합체의 제조 방법 |
| CA2807732A1 (en) | 2010-08-13 | 2012-02-16 | Lanxess Inc. | Butyl ionomer latex |
| TW201235359A (en) | 2010-11-24 | 2012-09-01 | Lanxess Inc | Ionomers comprising pendant vinyl groups and processes for preparing same |
| JP2015502439A (ja) | 2011-12-22 | 2015-01-22 | ランクセス・インターナショナル・エス・アー | アジド化共重合体及びその製造方法 |
| JP2015500915A (ja) | 2011-12-22 | 2015-01-08 | ランクセス・インターナショナル・エス・アー | 硬化重合体の製造方法 |
| TW201518370A (zh) * | 2013-06-27 | 2015-05-16 | Lanxess Butyl Pte Ltd | 固化的彈性體及其製備方法 |
| CN104592466B (zh) * | 2013-10-30 | 2018-02-02 | 中国石油化工股份有限公司 | 一种卤化聚合物及其制备方法 |
| CN104592465B (zh) * | 2013-10-30 | 2017-03-08 | 中国石油化工股份有限公司 | 一种多嵌段卤化聚合物及其制备方法 |
| US12415915B2 (en) | 2018-02-20 | 2025-09-16 | Exxonmobil Chemical Patents Inc. | Isobutylene-containing compositions and articles made thereof |
| WO2019221919A1 (en) * | 2018-05-17 | 2019-11-21 | Exxonmobil Chemical Patents Inc. | Isobutylene-containing compositions and articles made thereof |
| WO2021126625A1 (en) | 2019-12-17 | 2021-06-24 | Exxonmobil Chemical Patents Inc. | Functionalized polymers tread additive for improved winter tire performance |
| EP4077528B1 (en) | 2019-12-17 | 2024-09-18 | ExxonMobil Chemical Patents Inc. | Functionalized polymers tread additive to improve all-season tire performance |
| WO2021126623A1 (en) | 2019-12-17 | 2021-06-24 | Exxonmobil Chemical Patents Inc. | Functionalized polymers as tread additive for improved wet braking and rolling resistance in high silica summer tire |
| US12459295B2 (en) | 2019-12-17 | 2025-11-04 | Exxonmobil Chemical Patents Inc. | Functionalized polymers tread additive to improve tire performance for immiscible all-season tread |
| CN114867783B (zh) | 2019-12-17 | 2024-10-22 | 埃克森美孚化学专利公司 | 用于改进含有高聚丁二烯水平的四季胎面的轮胎性能的官能化聚合物胎面添加剂 |
| CN114846069B (zh) | 2019-12-17 | 2024-08-27 | 埃克森美孚化学专利公司 | 用于改进低二氧化硅夏季轮胎的湿滑制动和滚动阻力的官能化聚合物胎面添加剂 |
| US20230039642A1 (en) | 2019-12-17 | 2023-02-09 | Exxonmobil Chemical Patents Inc. | Functionalized Polymers Tread Additive To Improve Truck And Bus Radial Tire Performance |
| US20250135684A1 (en) | 2021-10-29 | 2025-05-01 | ExxonMobil Technology and Engineering Company | Extrusion Processes |
| CN113968926B (zh) * | 2021-10-29 | 2023-01-13 | 大连理工大学 | 一类乙烯/α-烯烃/功能化苯乙烯衍生物三元共聚物及其制备方法 |
| EP4422839A1 (en) | 2021-10-29 | 2024-09-04 | ExxonMobil Chemical Patents Inc. | Method of forming a composition comprising a functionalized polymer |
Family Cites Families (48)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2513183A (en) | 1945-02-09 | 1950-06-27 | Sun Oil Co | Copolymer products |
| US2497458A (en) | 1945-05-26 | 1950-02-14 | Sun Oil Co | Butadiene-styrene copolymer tackified with isoolefin-diolefin-styrene copolymer |
| US2539523A (en) | 1947-02-14 | 1951-01-30 | Atlantic Refining Co | Polymerization of olefin mixtures |
| US2631953A (en) | 1949-03-12 | 1953-03-17 | Standard Oil Dev Co | Bonding isoolefin-diolefin rubber to metal by an isoolefin-styrenediolefin resin and a modified natural rubber tie ply |
| FR65758E (enExample) * | 1950-04-18 | 1956-03-12 | ||
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-
1999
- 1999-09-20 CA CA2282900A patent/CA2282900C/en not_active Expired - Lifetime
-
2000
- 2000-09-19 BR BRPI0017502-1A patent/BR0017502B1/pt not_active IP Right Cessation
- 2000-09-19 JP JP2001525244A patent/JP2003510380A/ja not_active Revoked
- 2000-09-19 BR BR0014125-9A patent/BR0014125A/pt not_active Application Discontinuation
- 2000-09-19 RU RU2002110664/04A patent/RU2002110664A/ru not_active Application Discontinuation
- 2000-09-19 WO PCT/CA2000/001044 patent/WO2001021672A1/en not_active Ceased
- 2000-09-19 EP EP00960245.9A patent/EP1228106B1/en not_active Expired - Lifetime
- 2000-09-19 CN CNB00813135XA patent/CN1159351C/zh not_active Expired - Lifetime
- 2000-09-19 AU AU72629/00A patent/AU7262900A/en not_active Abandoned
- 2000-09-20 TW TW089119287A patent/TW591042B/zh not_active IP Right Cessation
-
2003
- 2003-03-17 US US10/390,113 patent/US6960632B2/en not_active Expired - Lifetime
-
2005
- 2005-08-19 US US11/208,320 patent/US7402633B2/en not_active Expired - Lifetime
-
2008
- 2008-06-03 US US12/156,501 patent/US20090018297A1/en not_active Abandoned
- 2008-06-25 US US12/146,078 patent/US7868100B2/en not_active Expired - Fee Related
-
2012
- 2012-01-04 JP JP2012000222A patent/JP5450671B2/ja not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JP5450671B2 (ja) | 2014-03-26 |
| CA2282900C (en) | 2011-02-01 |
| CN1374972A (zh) | 2002-10-16 |
| WO2001021672A1 (en) | 2001-03-29 |
| TW591042B (en) | 2004-06-11 |
| RU2002110664A (ru) | 2003-11-20 |
| CN1159351C (zh) | 2004-07-28 |
| EP1228106A1 (en) | 2002-08-07 |
| JP2003510380A (ja) | 2003-03-18 |
| US6960632B2 (en) | 2005-11-01 |
| JP2012062492A (ja) | 2012-03-29 |
| US20090018297A1 (en) | 2009-01-15 |
| US7402633B2 (en) | 2008-07-22 |
| US20080275190A1 (en) | 2008-11-06 |
| EP1228106B1 (en) | 2016-03-16 |
| HK1050539A1 (en) | 2003-06-27 |
| US20030220454A1 (en) | 2003-11-27 |
| US20060116484A1 (en) | 2006-06-01 |
| BR0014125A (pt) | 2002-05-14 |
| US7868100B2 (en) | 2011-01-11 |
| AU7262900A (en) | 2001-04-24 |
| CA2282900A1 (en) | 2001-03-20 |
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