BR0014354A - Processo para produção de fenilsulfoniluréias substituìdas de sulfohalogenetos - Google Patents
Processo para produção de fenilsulfoniluréias substituìdas de sulfohalogenetosInfo
- Publication number
- BR0014354A BR0014354A BR0014354-5A BR0014354A BR0014354A BR 0014354 A BR0014354 A BR 0014354A BR 0014354 A BR0014354 A BR 0014354A BR 0014354 A BR0014354 A BR 0014354A
- Authority
- BR
- Brazil
- Prior art keywords
- compound
- carried out
- solvents
- reaction
- mixture
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 5
- 239000000203 mixture Substances 0.000 abstract 3
- 150000003839 salts Chemical class 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 239000000010 aprotic solvent Substances 0.000 abstract 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- -1 heterocycle amine Chemical class 0.000 abstract 1
- 125000000623 heterocyclic group Chemical group 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 239000012948 isocyanate Substances 0.000 abstract 1
- UJYAZVSPFMJCLW-UHFFFAOYSA-N n-(oxomethylidene)benzenesulfonamide Chemical compound O=C=NS(=O)(=O)C1=CC=CC=C1 UJYAZVSPFMJCLW-UHFFFAOYSA-N 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
- C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
- C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
- C07D251/26—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hetero atoms directly attached to ring carbon atoms
- C07D251/40—Nitrogen atoms
- C07D251/42—One nitrogen atom
- C07D251/44—One nitrogen atom with halogen atoms attached to the two other ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
- C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
- C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
- C07D251/26—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hetero atoms directly attached to ring carbon atoms
- C07D251/40—Nitrogen atoms
- C07D251/42—One nitrogen atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
- C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
- C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
- C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
- C07D239/30—Halogen atoms or nitro radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
- C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
- C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
- C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
- C07D239/32—One oxygen, sulfur or nitrogen atom
- C07D239/42—One nitrogen atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
- C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
- C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
- C07D251/14—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hydrogen or carbon atoms directly attached to at least one ring carbon atom
- C07D251/16—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hydrogen or carbon atoms directly attached to at least one ring carbon atom to only one ring carbon atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
- C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
- C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
- C07D251/14—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hydrogen or carbon atoms directly attached to at least one ring carbon atom
- C07D251/22—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hydrogen or carbon atoms directly attached to at least one ring carbon atom to two ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
- C07D307/10—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D307/12—Radicals substituted by oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
- C07D307/10—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D307/14—Radicals substituted by nitrogen atoms not forming part of a nitro radical
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D309/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings
- C07D309/02—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
- C07D309/04—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
- C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
- C07D405/12—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a chain containing hetero atoms as chain links
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
- C07D409/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings
- C07D409/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
Abstract
"PROCESSO PARA PRODUçãO DE FENILSULFONILURéIAS SUBSTITUìDAS DE SULFOHALOGENETOS". A invenção refere-se a um processo de produção para compostos ( I ) ou sais dos mesmos, onde Q, X*, Y, Z, R, R^ 1^, R^ 2^ e R^ 3^ estão definidos tal como na reivindicação 1, caracterizado pelo fato de que a) um composto ( II ), onde Hal = átomo de halogênio, é amonolizado para ( III ), preferivelmente, ( a1 ) a reação é realizada na mistura de solventes orgânicos ( mistura de S ), que contém ( 1 ) HC ( hidrocarbonetos ) aromáticos [ solventes ( 1 ) 1 ], e ( 2 ) solventes polares, apróticos [ solventes ( 2 ) ], na relação de peso de S ( 1 ): S ( 2 ) de 20:1 a 1:1, ( b ) o composto ( III ) é fosgenizado com isocianato de fenilsulfonila da fórmula ( IV ), preferivelmente, no caso de X* = halogênio, realiza-se a reação com fosgênio em um S orgânico, na presença de isocianatos de R'-NCO como catalisador, sendo que R' é igual a HC ( subst. ), com ou sem uma base de amina, ( c ) o composto ( IV ) obtido é reagido em S org., com heterociclo de amina H~ 2~H-Het ( Het = heterociclo tal como em ( I ), para o composto ( I ) ou sais do mesmo, preferivelmente, a reação é realizada na mistura de S, de hidrocarbonetos aromáticos, opcionalmente halogenados, com um ponto de ebulição de mais de 110<198>C, e S aprótico, polar. Pelo menos uma das etapas parciais ( a1 ) a ( c1 ) é realizada no processo.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19946341A DE19946341B4 (de) | 1999-09-28 | 1999-09-28 | Verfahren zur Herstellung substituierter Phenylsulfonylharnstoffe aus Sulfohalogeniden |
| PCT/EP2000/009466 WO2001023368A2 (de) | 1999-09-28 | 2000-09-28 | Verfahren zur herstellung substituierter phenylsulfonylharnstoffe aus sulfohalogeniden |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR0014354A true BR0014354A (pt) | 2002-06-11 |
Family
ID=7923509
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR0014354-5A BR0014354A (pt) | 1999-09-28 | 2000-09-28 | Processo para produção de fenilsulfoniluréias substituìdas de sulfohalogenetos |
Country Status (20)
| Country | Link |
|---|---|
| US (1) | US7026477B1 (pt) |
| EP (2) | EP1911748B1 (pt) |
| JP (1) | JP4991065B2 (pt) |
| KR (1) | KR100800926B1 (pt) |
| CN (2) | CN101200452A (pt) |
| AT (2) | ATE463487T1 (pt) |
| AU (1) | AU1019901A (pt) |
| BR (1) | BR0014354A (pt) |
| CA (1) | CA2386655A1 (pt) |
| CZ (1) | CZ20021125A3 (pt) |
| DE (3) | DE19946341B4 (pt) |
| HU (1) | HUP0203072A3 (pt) |
| IL (1) | IL148742A0 (pt) |
| MX (1) | MXPA02003315A (pt) |
| PL (1) | PL356121A1 (pt) |
| RU (1) | RU2002111347A (pt) |
| TR (1) | TR200200847T2 (pt) |
| TW (1) | TW473544B (pt) |
| WO (1) | WO2001023368A2 (pt) |
| ZA (1) | ZA200202408B (pt) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10218704B4 (de) * | 2002-04-26 | 2006-11-30 | Bayer Cropscience Gmbh | Halosulfonylbenzoesäurehalogenide, Verfahren zu deren Herstellung und deren Verwendung zur Herstellung von substituierten Phenylsulfonylharnstoffen |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2852557A (en) * | 1954-04-09 | 1958-09-16 | Schenley Ind Inc | 4-sulfonyl derivatives of salicylic acid |
| US4238621A (en) * | 1979-04-13 | 1980-12-09 | E. I. Du Pont De Nemours And Company | Intermediates for herbicidal sulfonamides |
| DK163123C (da) * | 1978-05-30 | 1992-06-09 | Du Pont | Benzensulfonylurinstoffer til anvendelse som herbicider eller plantevaekstregulatorer, praeparat indeholdende dem samt deres anvendelse |
| JP2552261B2 (ja) * | 1978-05-30 | 1996-11-06 | イー・アイ・デユポン・ドウ・ヌムール・アンド・カンパニー | 農業用スルホンアミド類およびその製造法 |
| US4647303A (en) | 1978-05-30 | 1987-03-03 | E. I. Du Pont De Nemours And Company | Agriculture sulfonamides |
| ZA806970B (en) | 1979-11-30 | 1982-06-30 | Du Pont | Agricultural sulfonamides |
| SU1233456A1 (ru) | 1984-02-01 | 1996-03-10 | В.Е. Антипанова | Способ получения замещенных n-[(1,3,5-триазин-2-ил)аминокарбонил]бензолсульфонамидов |
| US4602942A (en) | 1984-03-19 | 1986-07-29 | E. I. Du Pont De Nemours And Company | Herbicidal sulfonamides |
| US4849010A (en) * | 1985-04-10 | 1989-07-18 | E. I. Dupont De Nemours And Company | Herbicidal sulfonamides |
| US4744814A (en) | 1984-12-06 | 1988-05-17 | Ishihara Sangyo Kaisha | N-[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-3-trifluoromethylpyridine-2-sulfonamide or salts thereof, herbicidal composition containing the same |
| US4709092A (en) * | 1986-03-05 | 1987-11-24 | Ciba-Geigy Corporation | Process for the preparation of 2-alkoxybenzosulfonamides |
| ZA92970B (en) * | 1991-02-12 | 1992-10-28 | Hoechst Ag | Arylsulfonylureas,processes for their preparation,and their use as herbicides and growth regulators |
| MY110183A (en) | 1992-08-18 | 1998-02-28 | Novartis Ag | Process for the preparation of n, n''-substituted ureas |
| US5480993A (en) | 1993-03-05 | 1996-01-02 | Lucky Ltd. | Process for preparation of sulfonylurea derivatives and intermediates for the process and process for preparing the same |
| AU691951B2 (en) * | 1994-08-29 | 1998-05-28 | E.I. Du Pont De Nemours And Company | Improved process for making sulfonyl isocyanates |
-
1999
- 1999-09-28 DE DE19946341A patent/DE19946341B4/de not_active Expired - Fee Related
-
2000
- 2000-09-28 KR KR1020027003961A patent/KR100800926B1/ko not_active IP Right Cessation
- 2000-09-28 CN CNA2008100021017A patent/CN101200452A/zh active Pending
- 2000-09-28 JP JP2001526521A patent/JP4991065B2/ja not_active Expired - Lifetime
- 2000-09-28 EP EP07025075A patent/EP1911748B1/de not_active Expired - Lifetime
- 2000-09-28 RU RU2002111347/04A patent/RU2002111347A/ru not_active Application Discontinuation
- 2000-09-28 DE DE50015260T patent/DE50015260D1/de not_active Expired - Lifetime
- 2000-09-28 AT AT07025075T patent/ATE463487T1/de not_active IP Right Cessation
- 2000-09-28 EP EP00971292A patent/EP1220846B1/de not_active Expired - Lifetime
- 2000-09-28 AU AU10199/01A patent/AU1019901A/en not_active Abandoned
- 2000-09-28 BR BR0014354-5A patent/BR0014354A/pt not_active IP Right Cessation
- 2000-09-28 CZ CZ20021125A patent/CZ20021125A3/cs unknown
- 2000-09-28 US US10/089,288 patent/US7026477B1/en not_active Expired - Lifetime
- 2000-09-28 DE DE50015900T patent/DE50015900D1/de not_active Expired - Lifetime
- 2000-09-28 CA CA002386655A patent/CA2386655A1/en not_active Abandoned
- 2000-09-28 HU HU0203072A patent/HUP0203072A3/hu unknown
- 2000-09-28 MX MXPA02003315A patent/MXPA02003315A/es active IP Right Grant
- 2000-09-28 CN CNB008134480A patent/CN100368405C/zh not_active Expired - Lifetime
- 2000-09-28 IL IL14874200A patent/IL148742A0/xx not_active IP Right Cessation
- 2000-09-28 AT AT00971292T patent/ATE400561T1/de not_active IP Right Cessation
- 2000-09-28 PL PL00356121A patent/PL356121A1/xx not_active Application Discontinuation
- 2000-09-28 TR TR2002/00847T patent/TR200200847T2/xx unknown
- 2000-09-28 WO PCT/EP2000/009466 patent/WO2001023368A2/de active IP Right Grant
- 2000-11-01 TW TW089123008A patent/TW473544B/zh not_active IP Right Cessation
-
2002
- 2002-03-26 ZA ZA200202408A patent/ZA200202408B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| KR100800926B1 (ko) | 2008-02-04 |
| RU2002111347A (ru) | 2003-11-27 |
| PL356121A1 (en) | 2004-06-14 |
| DE50015260D1 (de) | 2008-08-21 |
| JP2003510312A (ja) | 2003-03-18 |
| TW473544B (en) | 2002-01-21 |
| WO2001023368A3 (de) | 2002-03-14 |
| EP1220846A1 (de) | 2002-07-10 |
| KR20020031601A (ko) | 2002-05-02 |
| ATE463487T1 (de) | 2010-04-15 |
| DE19946341B4 (de) | 2008-06-05 |
| EP1220846B1 (de) | 2008-07-09 |
| WO2001023368A2 (de) | 2001-04-05 |
| AU1019901A (en) | 2001-04-30 |
| EP1911748B1 (de) | 2010-04-07 |
| DE50015900D1 (de) | 2010-05-20 |
| HUP0203072A3 (en) | 2008-03-28 |
| DE19946341A1 (de) | 2001-04-05 |
| JP4991065B2 (ja) | 2012-08-01 |
| ZA200202408B (en) | 2003-07-30 |
| CN1630647A (zh) | 2005-06-22 |
| CN100368405C (zh) | 2008-02-13 |
| IL148742A0 (en) | 2002-09-12 |
| CN101200452A (zh) | 2008-06-18 |
| CA2386655A1 (en) | 2001-04-05 |
| CZ20021125A3 (cs) | 2002-07-17 |
| EP1911748A1 (de) | 2008-04-16 |
| TR200200847T2 (tr) | 2002-08-21 |
| HUP0203072A2 (hu) | 2003-01-28 |
| US7026477B1 (en) | 2006-04-11 |
| ATE400561T1 (de) | 2008-07-15 |
| MXPA02003315A (es) | 2002-10-04 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B25D | Requested change of name of applicant approved |
Owner name: BAYER CROPSCIENCE GMBH (DE) Free format text: ALTERADO DE: AVENTIS CROPSCIENCE GMBH |
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| B25A | Requested transfer of rights approved |
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