BR0013338A - Catalizador de leito fluidificado para a amoxidacão de propileno para acrilonitrila - Google Patents

Catalizador de leito fluidificado para a amoxidacão de propileno para acrilonitrila

Info

Publication number
BR0013338A
BR0013338A BR0013338-8A BR0013338A BR0013338A BR 0013338 A BR0013338 A BR 0013338A BR 0013338 A BR0013338 A BR 0013338A BR 0013338 A BR0013338 A BR 0013338A
Authority
BR
Brazil
Prior art keywords
acrylonitrile
amoxidation
propylene
catalyst
fluidized bed
Prior art date
Application number
BR0013338-8A
Other languages
English (en)
Other versions
BR0013338B1 (pt
Inventor
Lianghua Wu
Guojun Wang
Xin Chen
Original Assignee
China Petrochemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from CN99113988A external-priority patent/CN1101264C/zh
Priority claimed from CN99113989A external-priority patent/CN1094073C/zh
Priority claimed from CN99113987A external-priority patent/CN1100612C/zh
Priority claimed from CN99119953A external-priority patent/CN1130261C/zh
Application filed by China Petrochemical Corp filed Critical China Petrochemical Corp
Publication of BR0013338A publication Critical patent/BR0013338A/pt
Publication of BR0013338B1 publication Critical patent/BR0013338B1/pt

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/835—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with germanium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/881—Molybdenum and iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8878—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
    • B01J23/8885—Tungsten containing also molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B01J27/19—Molybdenum
    • B01J27/192—Molybdenum with bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • B01J27/199—Vanadium with chromium, molybdenum, tungsten or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04—Mixing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B61/00—Other general methods
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
    • C07C253/26—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

"CATALIZADOR DE LEITO FLUIDIFICADO PARA A AMOXIDAçãO DE PROPILENO PARA ACRILONITRILA". A presente invenção está relacionada a um novo catalisador de leito fluidificado usado em um processo para a amoxidação de propileno para acrilonitrila. O catalisador compreende uma sílica como veículo e uma composição representada pelas fórmulas gerais a seguir: A~ a~B~ b~C~ c~Ge~ d~Na~ e~Fe~ f~Bi~ g~Mo~ h~O~ x~ Onde A representa pelo menos um elemento selecionado de um grupo composto por Li, K, Rb, Cs, Sm, em ou Tl; B representa pelo menos um elemento selecionado de um grupo composto por P, Sb, Cr, W. Pr, Ce, As, B, Te, Ga, Al, Nb, Tb, La ou V; C representa um elemento selecionado de um grupo composto por Ni, Co, Sr, Mn, Mg, Ca, Zn, Cd ou Cu e misturas destes; a é um número de 0,01 até 1,5; b é um número de 0,01 até 3,0; c é um número de 0,1 até 12,0; preferencialmente de 2 até 10; d é um número de 0,01 até 2,0; preferencialmente de 0,01 até 1,0; e é um número de 0,01 até 0,7; preferencialmente de 0,05 até 0,5; f é um número de 0,1 até 8; preferencialmente de 1,0 até 3,0; g é um número de 0,01 até 6; preferencialmente de 0,1 até 2,0; h é um número de 12 até 14, 5; X denota o número dé átomos de oxigênio que satisfaz às necessidades de valência dos demais elementos no catalisador; O conteúdo de sílica usado como veículo é de 30-70% em massa. o catalisador da presente invenção pode ser usado na reação para a amoxidação de propileno para acrilonitrila executada sob uma pressão de reação mais elevada e condição de carregamento mais elevada, e ainda pode sustentar um alto rendimento pós-reação de acrilonitrila.
BRPI0013338-8A 1999-08-19 2000-06-21 catalizador de leito fluidificado para a amoxidacão de propileno para acrilonitrila. BR0013338B1 (pt)

Applications Claiming Priority (9)

Application Number Priority Date Filing Date Title
CN99113989.5 1999-08-19
CN99113988A CN1101264C (zh) 1999-08-19 1999-08-19 丙烯氨氧化制造丙烯腈流化床催化剂
CN99113988.7 1999-08-19
CN99113987.9 1999-08-19
CN99113989A CN1094073C (zh) 1999-08-19 1999-08-19 生产丙烯腈的流化床催化剂
CN99113987A CN1100612C (zh) 1999-08-19 1999-08-19 丙烯氨氧化流化床催化剂
CN99119953A CN1130261C (zh) 1999-11-03 1999-11-03 丙烯氨氧化流化床催化剂
CN99119953.7 1999-11-03
PCT/CN2000/000167 WO2001014057A1 (fr) 1999-08-19 2000-06-21 Catalyseur a lit fluidise pour l'ammoxydation de propylene en acrylonitrile

Publications (2)

Publication Number Publication Date
BR0013338A true BR0013338A (pt) 2002-04-02
BR0013338B1 BR0013338B1 (pt) 2012-01-24

Family

ID=27430059

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0013338-8A BR0013338B1 (pt) 1999-08-19 2000-06-21 catalizador de leito fluidificado para a amoxidacão de propileno para acrilonitrila.

Country Status (8)

Country Link
US (1) US6420307B1 (pt)
JP (1) JP4095302B2 (pt)
AU (1) AU5387100A (pt)
BR (1) BR0013338B1 (pt)
DE (1) DE10084931B3 (pt)
MX (1) MXPA02001574A (pt)
RO (1) RO120244B1 (pt)
WO (1) WO2001014057A1 (pt)

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AU2003295643A1 (en) * 2002-12-02 2004-06-23 The Standard Oil Company Mixed oxide catalyst of k, cs, ce, cr, co, ni, fe, bi and mo for the manufacture of acrylonitrile
CN100438981C (zh) * 2002-12-02 2008-12-03 伊内奥斯美国公司 用于制造丙烯腈的K、Cs、Ce、Cr、Co、Ni、Fe、Bi和Mo的混合氧化物催化剂
US7071140B2 (en) 2002-12-02 2006-07-04 The Standard Oil Company Catalyst for the manufacture of acrylonitrile
US7232788B2 (en) * 2003-03-31 2007-06-19 Saudi Basic Industries Corporation Mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
US7361791B2 (en) * 2003-03-31 2008-04-22 Saudi Basic Industries Corporation Mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
CN100384531C (zh) * 2005-01-26 2008-04-30 中国石油化工股份有限公司 氨氧化制备丙烯腈的流化床催化剂
CN100352545C (zh) * 2005-01-26 2007-12-05 中国石油化工股份有限公司 丙烯氨氧化的流化床催化剂
US7273829B2 (en) * 2005-12-22 2007-09-25 Saudi Basic Industries Corporation Catalyst for oxidation of saturated and unsaturated aldehydes to unsaturated carboxylic acid, method of making and method of using thereof
CN101534945B (zh) * 2006-10-26 2012-08-29 大野绿水株式会社 丙烯腈制造用流动床催化剂和丙烯腈的制造方法
JP5011167B2 (ja) 2008-03-03 2012-08-29 ダイヤニトリックス株式会社 アクリロニトリル製造用触媒およびアクリロニトリルの製造方法
US8153546B2 (en) 2010-03-23 2012-04-10 Ineos Usa Llc Mixed metal oxide ammoxidation catalysts
US8455388B2 (en) 2010-03-23 2013-06-04 Ineos Usa Llc Attrition resistant mixed metal oxide ammoxidation catalysts
US8420566B2 (en) 2010-03-23 2013-04-16 Ineos Usa Llc High efficiency ammoxidation process and mixed metal oxide catalysts
US8258073B2 (en) 2010-03-23 2012-09-04 Ineos Usa Llc Process for preparing improved mixed metal oxide ammoxidation catalysts
EP3636631A4 (en) 2017-06-09 2020-06-03 Asahi Kasei Kabushiki Kaisha PROCESS FOR PRODUCING UNSATURATED NITRILE

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US4190556A (en) * 1973-07-19 1980-02-26 Standard Oil Company Production of unsaturated nitriles using catalysts promoted with various metals
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Also Published As

Publication number Publication date
AU5387100A (en) 2001-03-19
JP2003507180A (ja) 2003-02-25
DE10084931B3 (de) 2017-03-09
BR0013338B1 (pt) 2012-01-24
MXPA02001574A (es) 2003-07-21
DE10084931T1 (de) 2003-07-17
WO2001014057A1 (fr) 2001-03-01
US6420307B1 (en) 2002-07-16
RO120244B1 (ro) 2005-11-30
JP4095302B2 (ja) 2008-06-04

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