KR870002041A - C₁내지 c10지방족 탄화수소 또는 혼합알콜의 제조방법 - Google Patents

C₁내지 c10지방족 탄화수소 또는 혼합알콜의 제조방법 Download PDF

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KR870002041A
KR870002041A KR1019860006455A KR860006455A KR870002041A KR 870002041 A KR870002041 A KR 870002041A KR 1019860006455 A KR1019860006455 A KR 1019860006455A KR 860006455 A KR860006455 A KR 860006455A KR 870002041 A KR870002041 A KR 870002041A
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catalytic
sulfide
process according
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mixed
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알. 스티븐스 렉스
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리챠드 지. 워터맨
더 다우 케미칼 컴퍼니
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Publication of KR870002041A publication Critical patent/KR870002041A/ko

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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G39/00—Compounds of molybdenum
    • C01G39/06—Sulfides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/02—Monohydroxylic acyclic alcohols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/04—Sulfides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/04—Sulfides
    • B01J27/047—Sulfides with chromium, molybdenum, tungsten or polonium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/0445—Preparation; Activation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/10—Magnesium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C07C2523/04—Alkali metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of zinc, cadmium or mercury
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of rare earths
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/12—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of actinides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/745—Iron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/75—Cobalt
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/755—Nickel
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/02—Sulfur, selenium or tellurium; Compounds thereof
    • C07C2527/04—Sulfides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/02—Sulfur, selenium or tellurium; Compounds thereof
    • C07C2527/04—Sulfides
    • C07C2527/047—Sulfides with chromium, molybdenum, tungsten or polonium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Abstract

내용 없음.

Description

C1내지 C10지방족 탄화수소 또는 혼합알콜의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 중심성 전구체인 (NH4)2MoS2O2를 일반적으로 나타낸 것이다.
제2도는 선행기술의 침상 전구체인 (NH4)2MoS2O2를 일반적으로 나타낸 것이다.

Claims (13)

  1. 수소 및 일산화탄소를 함유하는 기체상 혼합물을 촉매량의 비지지된 내마모성 촉매성 황화물(이는 Nb,Ta,Mo,W,Tc 또는 Re를 함유하며; 중심성 입자상 전구체를 침전시킨 다음, 전구체를 열분해 하여 제조한다)과 반응시킴을 특징으로 하여 C1내지 C10지방족 탄화수소 또는 C1내지 C10혼합알콜을 제조하는 방법.
  2. 제1항에 있어서, 촉매성 황화물이 Fe,Ni,Co,La,Ce,Sm,Th,Na,K,Zn,Mg 및 Ca 중에서 선택되는 유리형태 또는 혼합형태의 금속 촉진제를 추가로 함유하는 방법.
  3. 제1항 또는 제2항에 있어서, 유동층 반응기를 사용하여 C1내지 C10혼합 알콜 또는 C1내지 C10지방족 탄화수소를 제조하는 방법.
  4. 제1항, 제2항 또는 제3항에 있어서, 촉매성 황화물의 손실로 측정되는 촉매성 황화물의 내마모성이 약 33중량%이하인 방법.
  5. 제1항에 있어서, 촉매성 황화물이 Mo 또는 W를 함유하는 방법.
  6. 제5항에 있어서, 제조된 지방족 탄화수소가 C2내지 C5알칸인 방법.
  7. 제6항에 있어서, 촉매성 황화물의 활성이 1x108단위 이상이며, 제조된 C2내지 C5알칸이 메탄인 방법.
  8. 제6항 또는 제7항에 있어서, 12 내지 18℃의 온도하에 수용액으로 부터 (NH4)2MoS2O2를 침전시킨 다음, 400 내지 700℃의 온도하에 질소중에서 0.5 내지 2시간 동안 열분해시키는 방법.
  9. 제2항에 있어서, 제조된 혼합알콜이 C1내지 C5혼합 알콜이며, 이 혼합 알콜이 적어도 70%의 CO2가 없는 탄소 선택성으로 제조되는 방법.
  10. 제9항에 있어서, 촉매성 황화물이 Co 및 알칼리금속을 함유하는 금속 촉진제, 및 Mo를 함유하는 방법.
  11. 중심성(NH4)2MoS2O2의 전구체 촉매조성물.
  12. 제11항에 있어서, 열분해되어 중심성 MoS2를 생성시키는 조성물.
  13. 제12항에 있어서, 제2항에서 정의한 금속 촉진제를 함유하는 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019860006455A 1985-08-05 1986-08-05 C₁내지 c10지방족 탄화수소 또는 혼합알콜의 제조방법 KR870002041A (ko)

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US76223985A 1985-08-05 1985-08-05
US762239 1985-08-05

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EP (1) EP0216472A1 (ko)
JP (1) JPS6234986A (ko)
KR (1) KR870002041A (ko)
CN (1) CN1015357B (ko)
AU (1) AU6074986A (ko)
NO (1) NO863134L (ko)
PL (1) PL260931A1 (ko)
ZA (1) ZA865875B (ko)

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FR2780303B1 (fr) 1998-06-25 2000-07-28 Inst Francais Du Petrole Procede de sulfuration de catalyseurs en milieu reducteur et utilisation du catalyseur sulfure dans des reactions de raffinage ou d'hydroconversion
US6562752B2 (en) 1998-06-25 2003-05-13 Institut Francais Du Petrole Metallic sulphide catalysts, processes for synthesising said catalysts and use thereof
CA2648630A1 (en) 2006-04-13 2008-04-24 Max M. Tirtowidjojo Mixed alcohol synthesis with enhanced carbon value use
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JP5691119B2 (ja) * 2007-08-03 2015-04-01 アタカ大機株式会社 水素化触媒の製造方法およびそれを使用したメタンガスの製造方法
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CN113072099B (zh) * 2020-01-03 2022-07-08 中国科学院上海微系统与信息技术研究所 TMDs二维材料薄膜、器件及制备方法

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Publication number Priority date Publication date Assignee Title
CN102987462A (zh) * 2012-12-28 2013-03-27 黑龙江新曙光牧业集团有限公司 一种速溶大豆低聚糖肽花生产品的制备方法

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CN86105974A (zh) 1987-07-08
CN1015357B (zh) 1992-02-05
ZA865875B (en) 1988-04-27
PL260931A1 (en) 1988-07-07
NO863134L (no) 1987-02-06
JPS6234986A (ja) 1987-02-14
EP0216472A1 (en) 1987-04-01
AU6074986A (en) 1987-02-12

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