BR0003855A - Processo para a oxidação catalìtica de fase gasosa - Google Patents
Processo para a oxidação catalìtica de fase gasosaInfo
- Publication number
- BR0003855A BR0003855A BR0003855-5A BR0003855A BR0003855A BR 0003855 A BR0003855 A BR 0003855A BR 0003855 A BR0003855 A BR 0003855A BR 0003855 A BR0003855 A BR 0003855A
- Authority
- BR
- Brazil
- Prior art keywords
- gas phase
- heating medium
- catalytic oxidation
- reactor
- heating
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/008—Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
- B01J8/067—Heating or cooling the reactor
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
- C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
- C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
- C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
- C07C51/265—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
- B01J2208/00212—Plates; Jackets; Cylinders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
- B01J2208/00212—Plates; Jackets; Cylinders
- B01J2208/00221—Plates; Jackets; Cylinders comprising baffles for guiding the flow of the heat exchange medium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
- B01J2208/00256—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles in a heat exchanger for the heat exchange medium separate from the reactor
Abstract
<B>PROCESSO PARA A OXIDAçãO CATALìTICA DE FASE GASOSA<D> Na reação de oxidação catalítica de fase gasosa por meio de um reator do tipo carcaça e tubos, adaptado para circular um meio de aquecimento para a carcaça do reator, por meio de um dispositivo de circulação, conectando um conduto anular ao mesmo, um processo para oxidação catalítica de fase gasosa caracterizado pelo fato de que submete uma parte do meio e aquecimento extraído da carcaça do reator à troca do calor, introduz o meio de aquecimento resultante da troca de calor nas proximidades de uma entrada de circulação de meio de aquecimento, no lado de entrada do dispositivo de circulação ou o conduto anular no lado de saída do reator. Prefere-se que a razão de fluxo do meio de aquecimento após a troca de calor esteja na faixa de 2 - 40% em volume, com base na razão de fluxo do meio de aquecimento dentro da carcaça do reator e a diferença de temperatura do meio de aquecimento na entrada e na saída estando na faixa de 15 - 150°C. De acordo com esta invenção é possível reduzir-se uniformemente os pontos quentes nos tubos de reação, aperfeiçoar o rendimento do produto desejado e implementar uma reação de oxidação catalítica de fase gasosa de propileno ou isobutileno.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP24605699 | 1999-08-31 |
Publications (1)
Publication Number | Publication Date |
---|---|
BR0003855A true BR0003855A (pt) | 2001-04-03 |
Family
ID=17142819
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR0003855-5A BR0003855A (pt) | 1999-08-31 | 2000-08-29 | Processo para a oxidação catalìtica de fase gasosa |
Country Status (8)
Country | Link |
---|---|
US (1) | US6613940B1 (pt) |
EP (1) | EP1080781B1 (pt) |
KR (1) | KR100457894B1 (pt) |
CN (1) | CN1096878C (pt) |
BR (1) | BR0003855A (pt) |
DE (1) | DE60026794T2 (pt) |
MY (1) | MY122598A (pt) |
ZA (1) | ZA200004211B (pt) |
Families Citing this family (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4092090B2 (ja) * | 2001-06-26 | 2008-05-28 | 株式会社日本触媒 | 固体粒子充填反応器およびその反応器を用いた接触気相酸化方法 |
BRPI0306797B1 (pt) | 2002-01-11 | 2016-07-12 | Mitsubishi Chem Corp | reator multitubular, e, métodos de oxidação catalítica em fase vapor e para iniciar um reator tipo casco-tubo |
AU2003211899B2 (en) * | 2002-03-11 | 2008-09-25 | Mitsubishi Chemical Corporation | Process for catalytic vapor phase oxidation |
JP4145607B2 (ja) | 2002-08-23 | 2008-09-03 | 三菱化学株式会社 | 多管式反応器を用いた気相接触酸化方法 |
TWI302147B (en) | 2003-09-01 | 2008-10-21 | Lg Chemical Ltd | Method of producing unsaturated aldehyde and unsaturated acid in fixed-bed catalytic partial oxidation reactor with enhanced heat control system |
JP2005330205A (ja) * | 2004-05-19 | 2005-12-02 | Mitsubishi Chemicals Corp | (メタ)アクロレイン又は(メタ)アクリル酸の製造方法 |
JP4341591B2 (ja) * | 2005-06-22 | 2009-10-07 | 住友化学株式会社 | 塩素製造用反応器および塩素の製造方法 |
KR100868454B1 (ko) * | 2005-07-08 | 2008-11-11 | 주식회사 엘지화학 | 고정층 촉매 부분산화 반응기에서 고효율의 불포화산의제조방법 |
WO2007040146A1 (ja) * | 2005-09-30 | 2007-04-12 | Matsushita Electric Industrial Co., Ltd. | 水素生成装置及び燃料電池システム |
TWI322882B (en) | 2006-02-24 | 2010-04-01 | Lg Chemical Ltd | Annular distributor having guide vane to improve flow rate distribution, reactor/heat exchanger including the annular distributor and method of producing unsaturated aldehyde or unsaturated acid from olefin by catalytic gas phase oxidation in the reactor |
KR100866757B1 (ko) * | 2006-02-24 | 2008-11-03 | 주식회사 엘지화학 | 반응기 및 열교환기 환상도관을 위한 열매체 분산기구 |
US20080008747A1 (en) * | 2006-07-07 | 2008-01-10 | Royds Robert B | Transdermal patch |
DE102007003076A1 (de) * | 2007-01-16 | 2008-07-17 | Basf Se | Verfahren zur Herstellung einer das Element Eisen in oxidischer Form enthaltenden Multielementoxidmasse |
CN102361687B (zh) | 2009-01-21 | 2015-05-13 | 巴斯夫欧洲公司 | 用于非催化或均相催化反应的管束反应器 |
EP2468394A1 (en) * | 2010-12-23 | 2012-06-27 | Shell Internationale Research Maatschappij B.V. | Multi-tubular fixed bed reactor and its use |
DE102011084476A1 (de) * | 2011-10-13 | 2013-04-18 | Man Diesel & Turbo Se | Rohrbündelreaktor |
JP6156860B2 (ja) | 2012-04-04 | 2017-07-05 | 住友化学株式会社 | 多管式反応器および多管式反応器の設計方法 |
CN103706303A (zh) * | 2013-12-12 | 2014-04-09 | 桂林华德机械设备有限公司 | 一种新型甲醛氧化器 |
DE102014103691A1 (de) * | 2014-03-18 | 2015-09-24 | Basf Se | Wärmetauscher, Reaktoranordnung umfassend diesen Wärmetauscher und Verfahren zum Temperieren eines Reaktors |
CN107597056A (zh) * | 2017-11-09 | 2018-01-19 | 曹恩康 | 一种放热反应用反应热可再利用的反应釜 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE838598C (de) * | 1948-10-02 | 1952-06-03 | Metallgesellschaft Ag | Verfahren und Vorrichtung zur Durchfuehrung exothermer katalytischer Reaktionen in Kontaktoefen |
BE793928A (fr) * | 1972-01-13 | 1973-05-02 | Deggendorfer Werft Eisenbau | Appareil pour la mise en oeuvre de processus chimiques exothermiques et endothermiques |
US4203906A (en) * | 1977-07-13 | 1980-05-20 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Process for catalytic vapor phase oxidation |
DE2750824C2 (de) | 1977-11-14 | 1979-08-09 | Deggendorfer Werft Und Eisenbau Gmbh, 8360 Deggendorf | Röhren-Reaktor zur Durchführung katalytischer Reaktionen |
DE3409159A1 (de) | 1984-03-13 | 1985-09-26 | Deggendorfer Werft Und Eisenbau Gmbh, 8360 Deggendorf | Rohrbuendel-reaktionsapparat |
US5379391A (en) * | 1991-03-01 | 1995-01-03 | Storage Technology Corporation | Method and apparatus to access data records in a cache memory by multiple virtual addresses |
JP2778878B2 (ja) * | 1991-09-12 | 1998-07-23 | 株式会社日本触媒 | エチレンオキシドの製造方法 |
DE4431949A1 (de) * | 1994-09-08 | 1995-03-16 | Basf Ag | Verfahren zur katalytischen Gasphasenoxidation von Acrolein zu Acrylsäure |
DE4431957A1 (de) | 1994-09-08 | 1995-03-16 | Basf Ag | Verfahren zur katalytischen Gasphasenoxidation von Propen zu Acrolein |
JP3559456B2 (ja) * | 1998-09-18 | 2004-09-02 | 株式会社日本触媒 | 接触気相酸化方法及び多管式反応器 |
-
2000
- 2000-08-17 ZA ZA200004211A patent/ZA200004211B/xx unknown
- 2000-08-24 DE DE60026794T patent/DE60026794T2/de not_active Expired - Lifetime
- 2000-08-24 EP EP00307312A patent/EP1080781B1/en not_active Expired - Lifetime
- 2000-08-25 MY MYPI20003936A patent/MY122598A/en unknown
- 2000-08-25 US US09/648,950 patent/US6613940B1/en not_active Expired - Fee Related
- 2000-08-29 BR BR0003855-5A patent/BR0003855A/pt not_active Application Discontinuation
- 2000-08-30 KR KR10-2000-0050726A patent/KR100457894B1/ko not_active IP Right Cessation
- 2000-08-31 CN CN00131724A patent/CN1096878C/zh not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
CN1289635A (zh) | 2001-04-04 |
MY122598A (en) | 2006-04-29 |
US6613940B1 (en) | 2003-09-02 |
CN1096878C (zh) | 2002-12-25 |
DE60026794D1 (de) | 2006-05-11 |
EP1080781B1 (en) | 2006-03-22 |
DE60026794T2 (de) | 2007-01-18 |
KR20010050268A (ko) | 2001-06-15 |
ZA200004211B (en) | 2001-02-14 |
KR100457894B1 (ko) | 2004-11-18 |
EP1080781A1 (en) | 2001-03-07 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
B06A | Patent application procedure suspended [chapter 6.1 patent gazette] | ||
B11B | Dismissal acc. art. 36, par 1 of ipl - no reply within 90 days to fullfil the necessary requirements |