BG62928B1 - N-(орто-заместени бензилокси)имини и тяхното използване като фунгициди, акарициди и инсектициди - Google Patents

N-(орто-заместени бензилокси)имини и тяхното използване като фунгициди, акарициди и инсектициди Download PDF

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Publication number
BG62928B1
BG62928B1 BG101403A BG10140397A BG62928B1 BG 62928 B1 BG62928 B1 BG 62928B1 BG 101403 A BG101403 A BG 101403A BG 10140397 A BG10140397 A BG 10140397A BG 62928 B1 BG62928 B1 BG 62928B1
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Bulgaria
Prior art keywords
formula
substituted
unsubstituted
compound
alkyl
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BG101403A
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Bulgarian (bg)
English (en)
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BG101403A (en
Inventor
Hugo Ziegler
Stephan Trah
Rene Zurflueh
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Novartis Ag
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Publication of BG101403A publication Critical patent/BG101403A/xx
Publication of BG62928B1 publication Critical patent/BG62928B1/bg

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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D239/00Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
    • C07D239/02Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
    • C07D239/24Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
    • C07D239/26Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C251/00Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C251/32Oximes
    • C07C251/34Oximes with oxygen atoms of oxyimino groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals
    • C07C251/36Oximes with oxygen atoms of oxyimino groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals with the carbon atoms of the oxyimino groups bound to hydrogen atoms or to acyclic carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C251/00Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C251/32Oximes
    • C07C251/50Oximes having oxygen atoms of oxyimino groups bound to carbon atoms of substituted hydrocarbon radicals
    • C07C251/60Oximes having oxygen atoms of oxyimino groups bound to carbon atoms of substituted hydrocarbon radicals of hydrocarbon radicals substituted by carboxyl groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00Carboxylic acid nitriles
    • C07C255/01Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
    • C07C255/11Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms containing cyano groups and singly-bound oxygen atoms bound to the same saturated acyclic carbon skeleton
    • C07C255/14Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms containing cyano groups and singly-bound oxygen atoms bound to the same saturated acyclic carbon skeleton containing cyano groups and esterified hydroxy groups bound to the carbon skeleton
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00Carboxylic acid nitriles
    • C07C255/01Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
    • C07C255/24Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms containing cyano groups and singly-bound nitrogen atoms, not being further bound to other hetero atoms, bound to the same saturated acyclic carbon skeleton
    • C07C255/29Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms containing cyano groups and singly-bound nitrogen atoms, not being further bound to other hetero atoms, bound to the same saturated acyclic carbon skeleton containing cyano groups and acylated amino groups bound to the carbon skeleton
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00Carboxylic acid nitriles
    • C07C255/63Carboxylic acid nitriles containing cyano groups and nitrogen atoms further bound to other hetero atoms, other than oxygen atoms of nitro or nitroso groups, bound to the same carbon skeleton
    • C07C255/64Carboxylic acid nitriles containing cyano groups and nitrogen atoms further bound to other hetero atoms, other than oxygen atoms of nitro or nitroso groups, bound to the same carbon skeleton with the nitrogen atoms further bound to oxygen atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C381/00Compounds containing carbon and sulfur and having functional groups not covered by groups C07C301/00 - C07C337/00
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D213/00Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/24Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D213/44Radicals substituted by doubly-bound oxygen, sulfur, or nitrogen atoms, or by two such atoms singly-bound to the same carbon atom
    • C07D213/53Nitrogen atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D213/00Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/61Halogen atoms or nitro radicals
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D261/00Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings
    • C07D261/02Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings
    • C07D261/06Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings having two or more double bonds between ring members or between ring members and non-ring members
    • C07D261/08Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings having two or more double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D263/00Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings
    • C07D263/02Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings
    • C07D263/08Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D263/10Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D265/00Heterocyclic compounds containing six-membered rings having one nitrogen atom and one oxygen atom as the only ring hetero atoms
    • C07D265/041,3-Oxazines; Hydrogenated 1,3-oxazines
    • C07D265/061,3-Oxazines; Hydrogenated 1,3-oxazines not condensed with other rings
    • C07D265/081,3-Oxazines; Hydrogenated 1,3-oxazines not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D277/00Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
    • C07D277/02Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings
    • C07D277/08Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D277/10Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D277/00Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
    • C07D277/60Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings condensed with carbocyclic rings or ring systems
    • C07D277/62Benzothiazoles
    • C07D277/64Benzothiazoles with only hydrocarbon or substituted hydrocarbon radicals attached in position 2
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D285/00Heterocyclic compounds containing rings having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by groups C07D275/00 - C07D283/00
    • C07D285/01Five-membered rings
    • C07D285/02Thiadiazoles; Hydrogenated thiadiazoles
    • C07D285/04Thiadiazoles; Hydrogenated thiadiazoles not condensed with other rings
    • C07D285/061,2,3-Thiadiazoles; Hydrogenated 1,2,3-thiadiazoles
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D295/00Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/16Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms
    • C07D295/18Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms by radicals derived from carboxylic acids, or sulfur or nitrogen analogues thereof
    • C07D295/182Radicals derived from carboxylic acids
    • C07D295/185Radicals derived from carboxylic acids from aliphatic carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D307/00Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/52Radicals substituted by nitrogen atoms not forming part of a nitro radical
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00Systems containing only non-condensed rings
    • C07C2601/02Systems containing only non-condensed rings with a three-membered ring

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
  • Pyridine Compounds (AREA)
  • Storage Of Fruits Or Vegetables (AREA)
  • Bakery Products And Manufacturing Methods Therefor (AREA)
  • Jellies, Jams, And Syrups (AREA)
BG101403A 1994-10-07 1997-04-10 N-(орто-заместени бензилокси)имини и тяхното използване като фунгициди, акарициди и инсектициди BG62928B1 (bg)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH03033/94A CH689228A5 (de) 1994-10-07 1994-10-07 Oximether, sowie diese enthaltende Pflanzenschutzmittel.
PCT/EP1995/003802 WO1996011183A1 (en) 1994-10-07 1995-09-26 N-(ortho-substituted benzyloxy)imine derivatives and their use as fungicides, acaricides or insecticides

Publications (2)

Publication Number Publication Date
BG101403A BG101403A (en) 1997-12-30
BG62928B1 true BG62928B1 (bg) 2000-11-30

Family

ID=4247124

Family Applications (1)

Application Number Title Priority Date Filing Date
BG101403A BG62928B1 (bg) 1994-10-07 1997-04-10 N-(орто-заместени бензилокси)имини и тяхното използване като фунгициди, акарициди и инсектициди

Country Status (30)

Country Link
US (1) US5863951A (hu)
EP (1) EP0784611B1 (hu)
JP (1) JPH10507168A (hu)
KR (1) KR100406819B1 (hu)
CN (1) CN1096446C (hu)
AT (1) ATE186294T1 (hu)
AU (1) AU692613B2 (hu)
BG (1) BG62928B1 (hu)
BR (1) BR9509284A (hu)
CA (1) CA2200590A1 (hu)
CH (1) CH689228A5 (hu)
CZ (1) CZ288918B6 (hu)
DE (1) DE69513189T2 (hu)
DK (1) DK0784611T3 (hu)
EE (1) EE9700063A (hu)
ES (1) ES2139246T3 (hu)
FI (1) FI971353A (hu)
GR (1) GR3032214T3 (hu)
HU (1) HU220446B1 (hu)
IL (1) IL115545A (hu)
MD (1) MD970125A (hu)
MX (1) MX9702512A (hu)
NO (1) NO308734B1 (hu)
NZ (1) NZ294237A (hu)
PL (1) PL181426B1 (hu)
RU (1) RU2180899C2 (hu)
SK (1) SK282027B6 (hu)
TW (1) TW300882B (hu)
WO (1) WO1996011183A1 (hu)
ZA (1) ZA958438B (hu)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SK282153B6 (sk) * 1994-02-04 2001-11-06 Basf Aktiengesellschaft Deriváty kyseliny fenyloctovej, spôsob a medziprodukty ich výroby, ich použitie a prostriedok proti živočíšnym škodcom alebo škodlivým hubám s ich obsahom
DE19540989A1 (de) * 1995-11-03 1997-05-07 Basf Ag Pyridylessigsäurederivate, Verfahren und Zwischenprodukte zu ihrer Herstellung und sie enthaltende Mittel
BR9611813A (pt) * 1995-12-07 1999-02-23 Novartis Ag Processo para o preparo de pesticidas
DE69623806T2 (de) * 1995-12-07 2003-02-20 Bayer Cropscience Ag Pestizide
WO1998016499A1 (fr) * 1996-10-15 1998-04-23 Shionogi & Co., Ltd. Derives d'oxime, derives d'hydrazone, et leur utilisation
WO1999058510A1 (en) 1998-05-11 1999-11-18 Takeda Chemical Industries, Ltd. Oxyiminoalkanoic acid derivatives with hypoglycemic and hypolipidemic activity
US6313344B1 (en) 1998-05-27 2001-11-06 Bayer Aktiengesellschaft Organic compounds
GB9827163D0 (en) 1998-12-10 1999-02-03 Novartis Ag Organic compounds
JP2002531540A (ja) * 1998-12-10 2002-09-24 バイエル アクチェンゲゼルシャフト ストロビルリン中間体の製造方法
AU1007400A (en) * 1999-01-27 2000-08-03 Dow Agrosciences Llc Aryl and heteroarylcyclopropyl oxime ethers and their use as fungicides and insecticides
CN101677571B (zh) * 2007-05-23 2013-04-24 巴塞尔聚烯烃股份有限公司 杀虫组合物及由其获得的制品
CN101959415B (zh) * 2007-05-23 2014-07-09 巴塞尔聚烯烃股份有限公司 杀虫组合物以及由其获得的物品
CN103180291B (zh) * 2010-06-24 2015-08-19 组合化学工业株式会社 烷氧基亚氨基衍生物和有害生物防除剂
CN103202289B (zh) * 2012-11-20 2015-03-11 北京农学院 1,2-二羟基-二十六烷-4-酮水悬浮剂及其制备方法
CN103181384B (zh) * 2012-11-20 2014-07-16 北京农学院 一种1,2-二羟基-二十六烷-4-酮乳油及其制备方法
CN103598176B (zh) * 2013-05-13 2015-03-11 北京农学院 1,2-二羟基-二十六烷-4-酮水乳剂及其制备方法

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3274800D1 (en) * 1981-02-05 1987-02-05 Asahi Chemical Ind Apparatus for separating blood components
DE3150984A1 (de) * 1981-12-23 1983-06-30 Bayer Ag, 5090 Leverkusen Oximcarbamate, verfahren zu ihrer herstellung und ihre verwendung als schaedlingsbekaempfungsmittel
HU216144B (hu) * 1988-12-29 1999-04-28 Novartis Ag. Hatóanyagként akrilsavszármazékot tartalmazó fungicid készítmény, és eljárás a hatóanyag előállítására
US5104872A (en) * 1989-08-22 1992-04-14 Nihon Hohyaku Co., Ltd. N-(substituted benzyloxy) imine derivatives and method of use thereof
GB9018408D0 (en) * 1990-08-22 1990-10-03 Ici Plc Fungicides
JP3217191B2 (ja) * 1992-07-16 2001-10-09 ビーエーエスエフ アクチェンゲゼルシャフト ヘテロ芳香族化合物およびこれを含有する植物保護剤
MD1315C2 (ro) * 1994-01-05 2000-06-30 Novartis Ag Eteri oximici şi compuşi intermediari, procedeu de obţinere a lor, compoziţii, procedeu de control şi combatere a dăunătorilor
SK282153B6 (sk) * 1994-02-04 2001-11-06 Basf Aktiengesellschaft Deriváty kyseliny fenyloctovej, spôsob a medziprodukty ich výroby, ich použitie a prostriedok proti živočíšnym škodcom alebo škodlivým hubám s ich obsahom

Also Published As

Publication number Publication date
KR100406819B1 (ko) 2004-05-24
MD970125A (ro) 1999-03-31
DK0784611T3 (da) 2000-04-17
EP0784611A1 (en) 1997-07-23
AU692613B2 (en) 1998-06-11
CZ104897A3 (en) 1997-07-16
SK282027B6 (sk) 2001-10-08
DE69513189T2 (de) 2000-09-21
CA2200590A1 (en) 1996-04-18
NO971555D0 (no) 1997-04-04
CH689228A5 (de) 1998-12-31
AU3699095A (en) 1996-05-02
PL181426B1 (pl) 2001-07-31
CN1160393A (zh) 1997-09-24
US5863951A (en) 1999-01-26
EP0784611B1 (en) 1999-11-03
FI971353A0 (fi) 1997-04-02
SK43597A3 (en) 1997-11-05
EE9700063A (et) 1997-08-15
NO308734B1 (no) 2000-10-23
TW300882B (hu) 1997-03-21
NO971555L (no) 1997-06-02
BG101403A (en) 1997-12-30
JPH10507168A (ja) 1998-07-14
DE69513189D1 (de) 1999-12-09
IL115545A (en) 2000-10-31
WO1996011183A1 (en) 1996-04-18
BR9509284A (pt) 1997-11-18
HUT77295A (hu) 1998-03-30
HU220446B1 (hu) 2002-02-28
IL115545A0 (en) 1996-01-19
CN1096446C (zh) 2002-12-18
MX9702512A (es) 1997-06-28
NZ294237A (en) 1999-04-29
ATE186294T1 (de) 1999-11-15
CZ288918B6 (cs) 2001-09-12
ZA958438B (en) 1996-05-06
GR3032214T3 (en) 2000-04-27
RU2180899C2 (ru) 2002-03-27
ES2139246T3 (es) 2000-02-01
FI971353A (fi) 1997-04-04
PL319689A1 (en) 1997-08-18

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