AU2010318178B2 - A cable and production process thereof - Google Patents
A cable and production process thereof Download PDFInfo
- Publication number
- AU2010318178B2 AU2010318178B2 AU2010318178A AU2010318178A AU2010318178B2 AU 2010318178 B2 AU2010318178 B2 AU 2010318178B2 AU 2010318178 A AU2010318178 A AU 2010318178A AU 2010318178 A AU2010318178 A AU 2010318178A AU 2010318178 B2 AU2010318178 B2 AU 2010318178B2
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- Prior art keywords
- cable
- semiconductive
- polymer composition
- composition
- insulation layer
- Prior art date
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- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- IEHBBDRFGVUINZ-UHFFFAOYSA-N CCCC=CCCCCC.CCCC=CCCCCC Chemical compound CCCC=CCCCCC.CCCC=CCCCCC IEHBBDRFGVUINZ-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 101710178035 Chorismate synthase 2 Proteins 0.000 description 1
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- 240000004752 Laburnum anagyroides Species 0.000 description 1
- 229920010126 Linear Low Density Polyethylene (LLDPE) Polymers 0.000 description 1
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- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
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- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 230000002902 bimodal effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- BXIQXYOPGBXIEM-UHFFFAOYSA-N butyl 4,4-bis(tert-butylperoxy)pentanoate Chemical compound CCCCOC(=O)CCC(C)(OOC(C)(C)C)OOC(C)(C)C BXIQXYOPGBXIEM-UHFFFAOYSA-N 0.000 description 1
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- 230000003749 cleanliness Effects 0.000 description 1
- 229940125898 compound 5 Drugs 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000012967 coordination catalyst Substances 0.000 description 1
- 239000004703 cross-linked polyethylene Substances 0.000 description 1
- 229920003020 cross-linked polyethylene Polymers 0.000 description 1
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- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- PWWSSIYVTQUJQQ-UHFFFAOYSA-N distearyl thiodipropionate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCCCCCCCC PWWSSIYVTQUJQQ-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
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- 125000005842 heteroatom Chemical group 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000013627 low molecular weight specie Substances 0.000 description 1
- 239000006078 metal deactivator Substances 0.000 description 1
- 239000012968 metallocene catalyst Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
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- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
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- 229910052698 phosphorus Inorganic materials 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- 239000000376 reactant Substances 0.000 description 1
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Classifications
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- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
- B05D5/12—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain a coating with specific electrical properties
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/001—Removal of residual monomers by physical means
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/04—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of carbon-silicon compounds, carbon or silicon
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B17/00—Insulators or insulating bodies characterised by their form
- H01B17/56—Insulating bodies
- H01B17/60—Composite insulating bodies
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/005—Stabilisers against oxidation, heat, light, ozone
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/01—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2308/00—Chemical blending or stepwise polymerisation process with the same catalyst
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Organic Insulating Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Specially Adapted For Manufacturing Cables (AREA)
- Conductive Materials (AREA)
- Polymerisation Methods In General (AREA)
- Manufacturing Of Electric Cables (AREA)
- Communication Cables (AREA)
- Insulated Conductors (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP09175692.4 | 2009-11-11 | ||
| EP09175692 | 2009-11-11 | ||
| PCT/EP2010/066709 WO2011057925A1 (en) | 2009-11-11 | 2010-11-03 | A cable and production process thereof |
Publications (2)
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| AU2010318178A1 AU2010318178A1 (en) | 2012-05-17 |
| AU2010318178B2 true AU2010318178B2 (en) | 2013-10-24 |
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| AU2010318178A Active AU2010318178B2 (en) | 2009-11-11 | 2010-11-03 | A cable and production process thereof |
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| MX356041B (es) | 2009-11-11 | 2018-05-10 | Borealis Ag | Composicion polimerica y un cable de energia que comprende la composicion polimerica. |
| KR102080451B1 (ko) | 2009-11-11 | 2020-02-21 | 보레알리스 아게 | 가교결합성 중합체 조성물 및 유리한 전기적 특성을 갖는 케이블 |
| WO2011057926A1 (en) * | 2009-11-11 | 2011-05-19 | Borealis Ag | A polymer composition comprising a polyolefin produced in a high pressure process, a high pressure process and an article |
| EP3591670A1 (en) | 2010-11-03 | 2020-01-08 | Borealis AG | A polymer composition and a power cable comprising the polymer composition |
| BR112013032432B1 (pt) * | 2011-06-23 | 2020-10-20 | Dow Global Technologies Llc. | processo para produzir uma composição de polietileno |
| EP2636691A1 (en) * | 2012-03-07 | 2013-09-11 | Borealis AG | Process and plant for manufacturing polyethylene-diene-copolymers |
| EP2636690A1 (en) | 2012-03-07 | 2013-09-11 | Borealis AG | Process and plant for manufacturing polyethylene-silane-copolymers |
| JP2014072133A (ja) * | 2012-10-01 | 2014-04-21 | Viscas Corp | 直流電力ケーブル |
| US9115274B2 (en) | 2012-12-13 | 2015-08-25 | General Cable Technologies Corporation | Fire and water resistant cable cover |
| WO2014125992A1 (ja) * | 2013-02-15 | 2014-08-21 | 三菱瓦斯化学株式会社 | 高誘電率材料用樹脂組成物、それを含む成形品、および着色用マスターバッチ |
| KR102231397B1 (ko) * | 2013-03-12 | 2021-03-25 | 다우 글로벌 테크놀로지스 엘엘씨 | 두꺼운 절연 층을 갖는 전력 케이블 및 그의 제조 방법 |
| KR102266116B1 (ko) * | 2013-09-20 | 2021-06-17 | 다우 글로벌 테크놀로지스 엘엘씨 | 가교결합된 전원 케이블의 탈기 방법 |
| CA2932825A1 (en) | 2013-12-10 | 2015-06-18 | General Cable Technologies Corporation | Thermally conductive compositions and cables thereof |
| FR3019368B1 (fr) * | 2014-03-31 | 2017-10-06 | Nexans | Dispositif electrique a moyenne ou haute tension |
| AU2015306161B2 (en) | 2014-08-19 | 2018-07-05 | Borealis Ag | A new crosslinked polymer composition, structured layer and cable |
| EP3212709B1 (en) * | 2014-10-27 | 2022-04-13 | Borealis AG | Polymer composition and cable with advantageous electrical properties |
| US10934420B2 (en) * | 2014-10-27 | 2021-03-02 | Borealis Ag | Polymer composition for cable applications with advantageous electrical properties |
| EP3035344A1 (en) | 2014-12-15 | 2016-06-22 | Borealis AG | High pressure radical polymerisation process for a copolymer of ethylene with silane groups containing comonomer |
| KR102249186B1 (ko) * | 2014-12-17 | 2021-05-07 | 엘에스전선 주식회사 | Dc 케이블의 체적저항측정 시스템 |
| US10943710B2 (en) * | 2014-12-19 | 2021-03-09 | Borealis Ag | Power cable polymer composition comprising thermoplastic and having advantageous properties |
| EP3234954B1 (en) * | 2014-12-19 | 2025-09-10 | Borealis GmbH | Polymer composition for w&c application with advantageous electrical properties |
| KR101717646B1 (ko) | 2015-02-12 | 2017-03-17 | (주)인테크놀로지 | 초고압 전선의 압출피복용 친환경 무독성 난연 컴파운드 및 제조방법 |
| CN105115428B (zh) * | 2015-04-24 | 2018-02-02 | 上海工程技术大学 | 面向辐对称电缆切面绝缘层厚度的并行图像测量方法 |
| KR102643300B1 (ko) * | 2015-12-09 | 2024-03-07 | 다우 글로벌 테크놀로지스 엘엘씨 | 안정화된 수분-경화성 폴리머 조성물 |
| JP6610411B2 (ja) * | 2016-04-25 | 2019-11-27 | 住友電装株式会社 | 導電部材 |
| US11613633B2 (en) | 2016-06-21 | 2023-03-28 | Borealis Ag | Polymer composition for wire and cable applications with advantageous thermomechanical behaviour and electrical properties |
| EP3261093B1 (en) * | 2016-06-21 | 2023-08-02 | Borealis AG | Cable with advantageous electrical properties |
| EP3261096A1 (en) * | 2016-06-21 | 2017-12-27 | Borealis AG | Cable and composition |
| KR102178359B1 (ko) | 2016-11-10 | 2020-11-12 | 주식회사 엘지화학 | 가교 폴리에틸렌 조성물 |
| CN111511824B (zh) | 2017-12-18 | 2022-03-01 | 博里利斯股份公司 | 具有减少的交联且不含抗氧化剂、不利于甲烷形成的可交联组合物 |
| EP3729472B1 (en) | 2017-12-18 | 2024-02-14 | Borealis AG | Cable made from crosslinkable composition without antioxidant and with beneficial methane formation |
| KR102731870B1 (ko) * | 2017-12-18 | 2024-11-18 | 보레알리스 아게 | 폴리에틸렌을 포함하는 중합체 조성물 |
| CN108003651B (zh) * | 2017-12-28 | 2021-01-22 | 深圳市沃尔核材股份有限公司 | 预制式电缆附件及其制备方法 |
| TWI857950B (zh) * | 2018-03-28 | 2024-10-11 | 美商陶氏全球科技有限責任公司 | 非極性有機聚合物、極性有機聚合物及超低可濕性碳黑之複合物 |
| US11031153B2 (en) * | 2018-11-05 | 2021-06-08 | General Cable Technologies Corporation | Water tree resistant cables |
| US20210134474A1 (en) * | 2019-11-01 | 2021-05-06 | Southwire Company, Llc | Low Sag Tree Wire |
| WO2021202349A1 (en) * | 2020-03-31 | 2021-10-07 | Dow Global Technologies Llc | Substituted silanes as chain transfer agents for polyolefin production |
| EP4161996A1 (en) * | 2020-06-03 | 2023-04-12 | Elkem Silicones USA Corp. | Method and compositions to achieve long-term stable electrical conductivity in silicone material with carbon black as conductive fillers |
| EP4329076A4 (en) * | 2021-05-07 | 2025-07-09 | Lg Chemical Ltd | POROUS OLEFIN POLYMER SUPPORT CONTAINING A CROSSLINKED STRUCTURE, SEPARATOR CONTAINING A CROSSLINKED STRUCTURE COMPRISING THIS SUPPORT FOR A LITHIUM SECONDARY BATTERY, METHOD FOR PRODUCING THE SAME, AND LITHIUM SECONDARY BATTERY COMPRISING THIS SEPARATOR |
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- 2010-11-03 WO PCT/EP2010/066709 patent/WO2011057925A1/en active Application Filing
- 2010-11-03 KR KR1020127014851A patent/KR101805215B1/ko active Active
- 2010-11-03 EP EP10771773.8A patent/EP2499197B2/en active Active
- 2010-11-03 IN IN3436DEN2012 patent/IN2012DN03436A/en unknown
- 2010-11-03 MX MX2012005197A patent/MX346513B/es active IP Right Grant
- 2010-11-03 BR BR112012011265-1A patent/BR112012011265B1/pt active IP Right Grant
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- 2010-11-03 AU AU2010318178A patent/AU2010318178B2/en active Active
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Also Published As
| Publication number | Publication date |
|---|---|
| EP2499197B1 (en) | 2017-03-01 |
| EP2499197A1 (en) | 2012-09-19 |
| CN102597093A (zh) | 2012-07-18 |
| KR20120104229A (ko) | 2012-09-20 |
| CN102597093B (zh) | 2015-01-07 |
| EA021355B1 (ru) | 2015-05-29 |
| ES2758129T3 (es) | 2020-05-04 |
| IN2012DN03436A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 2015-10-23 |
| EP2499197B2 (en) | 2024-01-10 |
| BR112012011265A2 (pt) | 2016-04-12 |
| JP5739442B2 (ja) | 2015-06-24 |
| KR101805215B1 (ko) | 2017-12-05 |
| BR112012011265B1 (pt) | 2020-12-01 |
| EG27174A (en) | 2015-08-31 |
| EA201290299A1 (ru) | 2012-12-28 |
| MX2012005197A (es) | 2012-06-19 |
| JP2013511119A (ja) | 2013-03-28 |
| EP3190152B1 (en) | 2019-10-09 |
| US9365708B2 (en) | 2016-06-14 |
| WO2011057925A1 (en) | 2011-05-19 |
| US20120273253A1 (en) | 2012-11-01 |
| MX346513B (es) | 2017-03-23 |
| AU2010318178A1 (en) | 2012-05-17 |
| FI2499197T4 (fi) | 2024-02-02 |
| EP3190152A1 (en) | 2017-07-12 |
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