ATE449778T1 - Grignard-verfahren mit verbesserter ausbeutung an diphenylchlorsilanen - Google Patents
Grignard-verfahren mit verbesserter ausbeutung an diphenylchlorsilanenInfo
- Publication number
- ATE449778T1 ATE449778T1 AT04815121T AT04815121T ATE449778T1 AT E449778 T1 ATE449778 T1 AT E449778T1 AT 04815121 T AT04815121 T AT 04815121T AT 04815121 T AT04815121 T AT 04815121T AT E449778 T1 ATE449778 T1 AT E449778T1
- Authority
- AT
- Austria
- Prior art keywords
- grignard
- reactants
- diphenylchlorosilanes
- phenyl
- solvent
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 6
- 239000002904 solvent Substances 0.000 abstract 6
- 239000000376 reactant Substances 0.000 abstract 4
- 239000007818 Grignard reagent Substances 0.000 abstract 3
- 150000004945 aromatic hydrocarbons Chemical class 0.000 abstract 3
- 230000008878 coupling Effects 0.000 abstract 3
- 238000010168 coupling process Methods 0.000 abstract 3
- 238000005859 coupling reaction Methods 0.000 abstract 3
- -1 phenyl Grignard reagent Chemical class 0.000 abstract 3
- GTPDFCLBTFKHNH-UHFFFAOYSA-N chloro(phenyl)silicon Chemical compound Cl[Si]C1=CC=CC=C1 GTPDFCLBTFKHNH-UHFFFAOYSA-N 0.000 abstract 2
- ZDHXKXAHOVTTAH-UHFFFAOYSA-N trichlorosilane Chemical compound Cl[SiH](Cl)Cl ZDHXKXAHOVTTAH-UHFFFAOYSA-N 0.000 abstract 2
- 239000005052 trichlorosilane Substances 0.000 abstract 2
- 239000005046 Chlorosilane Substances 0.000 abstract 1
- VTMOWGGHUAZESJ-UHFFFAOYSA-N chloro(diphenyl)silane Chemical class C=1C=CC=CC=1[SiH](Cl)C1=CC=CC=C1 VTMOWGGHUAZESJ-UHFFFAOYSA-N 0.000 abstract 1
- KOPOQZFJUQMUML-UHFFFAOYSA-N chlorosilane Chemical compound Cl[SiH3] KOPOQZFJUQMUML-UHFFFAOYSA-N 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/12—Organo silicon halides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/12—Organo silicon halides
- C07F7/121—Preparation or treatment not provided for in C07F7/14, C07F7/16 or C07F7/20
- C07F7/122—Preparation or treatment not provided for in C07F7/14, C07F7/16 or C07F7/20 by reactions involving the formation of Si-C linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B49/00—Grignard reactions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
- C07F3/02—Magnesium compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US53444304P | 2004-01-06 | 2004-01-06 | |
| PCT/US2004/043005 WO2005068475A1 (en) | 2004-01-06 | 2004-12-17 | Grignard processes with improved yields of diphenylchlorosilanes as products |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE449778T1 true ATE449778T1 (de) | 2009-12-15 |
Family
ID=34794279
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT04815121T ATE449778T1 (de) | 2004-01-06 | 2004-12-17 | Grignard-verfahren mit verbesserter ausbeutung an diphenylchlorsilanen |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US7456308B2 (de) |
| EP (1) | EP1701964B1 (de) |
| JP (1) | JP4747104B2 (de) |
| KR (1) | KR20060123433A (de) |
| CN (1) | CN100546989C (de) |
| AT (1) | ATE449778T1 (de) |
| DE (1) | DE602004024336D1 (de) |
| RU (1) | RU2345084C2 (de) |
| WO (1) | WO2005068475A1 (de) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7351847B2 (en) | 2004-01-06 | 2008-04-01 | Dow Corning Corporation | Grignard processes with increased content of diphenylchlorosilanes |
| DE602004024336D1 (de) | 2004-01-06 | 2010-01-07 | Dow Corning | Grignard-verfahren mit verbesserter ausbeutung an diphenylchlorsilanen |
| JP2008528687A (ja) * | 2005-02-01 | 2008-07-31 | ダウ・コーニング・コーポレイション | 脂肪族又はシクロパラフィン系の炭化水素溶剤を用いたフェニル含有クロロシランの製造方法 |
| CN107207730B (zh) | 2014-12-18 | 2020-12-11 | 美国陶氏有机硅公司 | 用于制备芳基官能硅烷的方法 |
| EP4065630A1 (de) | 2019-11-26 | 2022-10-05 | Dow Silicones Corporation | Verfahren zur herstellung von polysiloxazanen und ihre verwendung zur herstellung aminofunktioneller polyorganosiloxane |
| WO2021108067A1 (en) | 2019-11-26 | 2021-06-03 | Dow Silicones Corporation | Hydrocarbyloxy-functional arylsilanes and their use as promoters for platinum catalyzed hydrosilylation reactions |
| CN117279981A (zh) | 2021-05-18 | 2023-12-22 | 美国陶氏有机硅公司 | 用于制备聚环氧硅氮烷和使用其产生氨基官能化聚有机硅氧烷的方法 |
Family Cites Families (40)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE243028C (de) | ||||
| DE243031C (de) | ||||
| US2426122A (en) | 1944-10-17 | 1947-08-19 | Montclair Res Corp | Production of organo-silicon compounds |
| GB622970A (en) | 1946-02-04 | 1949-05-10 | Dow Chemical Co | Improvements in organo-silicon halides |
| GB657704A (en) | 1947-09-20 | 1951-09-26 | Monsanto Chemicals | Improvements in or relating to the production of organo-silicon compounds |
| US2795628A (en) | 1954-05-12 | 1957-06-11 | Metal & Thermit Corp | Preparation of phenyl magnesium chloride |
| US2795627A (en) | 1954-05-12 | 1957-06-11 | Metal & Thermit Corp | Preparation of phenyl magnesium chloride |
| US2894012A (en) | 1955-02-01 | 1959-07-07 | Metal & Thermit Corp | Grignard reactions in presence of cyclic ethers |
| US2816937A (en) | 1957-02-18 | 1957-12-17 | Metal & Thermit Corp | Preparation of phenyl magnesium chloride |
| US3140321A (en) | 1960-02-16 | 1964-07-07 | Cincinnati Milling Machine Co | Preparation of grignard reagents in predominantly hydrocarbon media |
| US3095460A (en) | 1961-10-25 | 1963-06-25 | Dow Chemical Co | Preparation of stabilized magnesium alkyls |
| US3264360A (en) | 1963-01-31 | 1966-08-02 | Texas Us Chem Co | Preparation of organomagnesium compounds |
| DE1244182B (de) | 1966-01-11 | 1967-07-13 | Bayer Ag | Verfahren zur partiellen Phenylierung von Chlorsilanen |
| US4127507A (en) | 1977-06-29 | 1978-11-28 | Texas Alkyls, Inc. | Hydrocarbon soluble straight-chain di-(lower alkyl) magnesium compositions |
| US4687874A (en) | 1980-02-12 | 1987-08-18 | Exxon Research And Engineering Company | Selective hydroformylation process using alkyl diaryl phosphine rhodium carbonyl hydride catalysts |
| SU477626A1 (ru) | 1982-07-07 | 1985-08-15 | Предприятие П/Я Г-4236 | Способ получени реактива Гринь ра |
| JPS60222492A (ja) | 1984-04-17 | 1985-11-07 | Shin Etsu Chem Co Ltd | 第３級炭化水素シリル化合物の製造方法 |
| JPS6222790A (ja) | 1985-07-24 | 1987-01-30 | Shin Etsu Chem Co Ltd | 第３級炭化水素シリル化合物の製造方法 |
| JPH0798827B2 (ja) | 1988-06-02 | 1995-10-25 | 信越化学工業株式会社 | ω−シリルアルキニルシラン化合物およびその製造方法 |
| JPH03109389A (ja) | 1989-09-22 | 1991-05-09 | Hitachi Chem Co Ltd | ビス（３，４―ジメチルフエニル）ジメチルシランの製造法 |
| DE4027608A1 (de) | 1990-08-31 | 1992-03-05 | Bayer Ag | Verfahren zur herstellung von 1-chlor-2-(1-chlor-cyclopropyl)-3-(2-chlor-phenyl)-propan-2-ol und/oder 2-(1-chlor-cyclopropyl)-2-(2-chlor-benzyl)-oxiran |
| GB9126339D0 (en) | 1991-12-11 | 1992-02-12 | Ici Plc | Chemical process |
| EP0729931B1 (de) | 1995-03-03 | 1998-08-19 | Dow Corning Corporation | Verfahren zur Herstellung von 1,5-Hexadien |
| JPH08245641A (ja) | 1995-03-13 | 1996-09-24 | Nitto Kasei Co Ltd | グリニャール試薬 |
| JP3656168B2 (ja) | 1995-06-12 | 2005-06-08 | 日東化成株式会社 | ハロゲン原子の結合したケイ素化合物の製造方法 |
| US5596120A (en) | 1995-10-23 | 1997-01-21 | Dow Corning Corporation | Process for preparation of organosilanes |
| RU2159246C2 (ru) | 1996-02-28 | 2000-11-20 | Ниппон Сокубаи Ко., Лтд. | Способ получения фторарилмагниевого производного и способ получения (фторарил) боранового соединения (варианты) |
| US5629439A (en) | 1996-03-28 | 1997-05-13 | Dow Corning Corporation | Method for preparation of allylsilanes |
| US5606088A (en) | 1996-03-28 | 1997-02-25 | Dow Corning Corporation | Process for preparation of organodisilanes |
| RU2174124C2 (ru) | 1999-12-03 | 2001-09-27 | Государственный научный центр Российской Федерации Государственный научно-исследовательский институт химии и технологии элементоорганических соединений | Способ получения трифенилсиланола |
| US6541651B1 (en) | 2002-04-04 | 2003-04-01 | Dow Corning Corporation | Process for chlorosilane intermediates manufacture |
| US7084206B2 (en) | 2002-04-04 | 2006-08-01 | Dow Corning Corporation | Process for preparing phenylorganosilicon intermediates |
| US6552237B1 (en) | 2002-04-04 | 2003-04-22 | Dow Corning Corporation | Grignard preparation of unsaturated organic compounds |
| US6686492B2 (en) | 2002-06-13 | 2004-02-03 | Dow Corning Corporation | Preparation of organosilicon intermediate and their derivatives in a novel grignard process |
| US20050068476A1 (en) | 2003-05-26 | 2005-03-31 | Masato Okabe | Polarizing plate, liquid crystal display using the same and method for manufacturing polarizing plate |
| JP4202221B2 (ja) | 2003-09-26 | 2008-12-24 | シャープ株式会社 | 光屈折素子アレイ基板、画像表示素子および画像表示装置 |
| US20050067476A1 (en) * | 2003-09-29 | 2005-03-31 | Hengami David Todjar | Convenient solid product dispensing package |
| DE602004024336D1 (de) | 2004-01-06 | 2010-01-07 | Dow Corning | Grignard-verfahren mit verbesserter ausbeutung an diphenylchlorsilanen |
| US7351847B2 (en) | 2004-01-06 | 2008-04-01 | Dow Corning Corporation | Grignard processes with increased content of diphenylchlorosilanes |
| JP2008528687A (ja) | 2005-02-01 | 2008-07-31 | ダウ・コーニング・コーポレイション | 脂肪族又はシクロパラフィン系の炭化水素溶剤を用いたフェニル含有クロロシランの製造方法 |
-
2004
- 2004-12-17 DE DE602004024336T patent/DE602004024336D1/de active Active
- 2004-12-17 WO PCT/US2004/043005 patent/WO2005068475A1/en active Application Filing
- 2004-12-17 CN CNB2004800399571A patent/CN100546989C/zh not_active Expired - Fee Related
- 2004-12-17 EP EP04815121A patent/EP1701964B1/de not_active Not-in-force
- 2004-12-17 KR KR1020067013486A patent/KR20060123433A/ko not_active Application Discontinuation
- 2004-12-17 US US10/585,154 patent/US7456308B2/en not_active Expired - Fee Related
- 2004-12-17 JP JP2006549307A patent/JP4747104B2/ja not_active Expired - Fee Related
- 2004-12-17 AT AT04815121T patent/ATE449778T1/de not_active IP Right Cessation
- 2004-12-17 RU RU2006128594/04A patent/RU2345084C2/ru not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| KR20060123433A (ko) | 2006-12-01 |
| WO2005068475A1 (en) | 2005-07-28 |
| EP1701964B1 (de) | 2009-11-25 |
| CN100546989C (zh) | 2009-10-07 |
| JP4747104B2 (ja) | 2011-08-17 |
| EP1701964A1 (de) | 2006-09-20 |
| RU2345084C2 (ru) | 2009-01-27 |
| JP2007517880A (ja) | 2007-07-05 |
| US20070066826A1 (en) | 2007-03-22 |
| DE602004024336D1 (de) | 2010-01-07 |
| CN1902208A (zh) | 2007-01-24 |
| RU2006128594A (ru) | 2008-02-20 |
| US7456308B2 (en) | 2008-11-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| RER | Ceased as to paragraph 5 lit. 3 law introducing patent treaties |