ATE388184T1 - Verfahren zur kontinuierlichen herstellung von hochmolekularem polyester sowie vorrichtung zur durchführung des verfahrens - Google Patents
Verfahren zur kontinuierlichen herstellung von hochmolekularem polyester sowie vorrichtung zur durchführung des verfahrensInfo
- Publication number
- ATE388184T1 ATE388184T1 AT02787634T AT02787634T ATE388184T1 AT E388184 T1 ATE388184 T1 AT E388184T1 AT 02787634 T AT02787634 T AT 02787634T AT 02787634 T AT02787634 T AT 02787634T AT E388184 T1 ATE388184 T1 AT E388184T1
- Authority
- AT
- Austria
- Prior art keywords
- carrying
- terephthalate
- high molecular
- continuous production
- molecular polyester
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/785—Preparation processes characterised by the apparatus used
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/18—Stationary reactors having moving elements inside
- B01J19/1887—Stationary reactors having moving elements inside forming a thin film
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00076—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements inside the reactor
- B01J2219/00085—Plates; Jackets; Cylinders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00105—Controlling the temperature by indirect heating or cooling employing heat exchange fluids part or all of the reactants being heated or cooled outside the reactor while recycling
- B01J2219/0011—Controlling the temperature by indirect heating or cooling employing heat exchange fluids part or all of the reactants being heated or cooled outside the reactor while recycling involving reactant liquids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00164—Controlling or regulating processes controlling the flow
- B01J2219/00166—Controlling or regulating processes controlling the flow controlling the residence time inside the reactor vessel
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Polyesters Or Polycarbonates (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10155419A DE10155419B4 (de) | 2001-11-12 | 2001-11-12 | Verfahren zur kontinuierlichen Herstellung von hochmolekularem Polyester sowie Vorrichtung zur Durchführung des Verfahrens |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE388184T1 true ATE388184T1 (de) | 2008-03-15 |
Family
ID=7705415
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT02787634T ATE388184T1 (de) | 2001-11-12 | 2002-11-11 | Verfahren zur kontinuierlichen herstellung von hochmolekularem polyester sowie vorrichtung zur durchführung des verfahrens |
Country Status (11)
| Country | Link |
|---|---|
| US (2) | US7115701B2 (enExample) |
| EP (1) | EP1448658B1 (enExample) |
| JP (1) | JP2005519141A (enExample) |
| KR (1) | KR100776859B1 (enExample) |
| CN (1) | CN100469813C (enExample) |
| AT (1) | ATE388184T1 (enExample) |
| DE (2) | DE10155419B4 (enExample) |
| ES (1) | ES2300491T3 (enExample) |
| MX (1) | MXPA04004426A (enExample) |
| TW (1) | TW593408B (enExample) |
| WO (1) | WO2003042278A1 (enExample) |
Families Citing this family (59)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100507698B1 (ko) * | 2002-05-31 | 2005-08-11 | 주식회사 효성 | 뱃치식 폴리에스터 중합장치 |
| DE10322106B4 (de) * | 2003-05-09 | 2006-05-11 | Aquafil Engineering Gmbh | Verfahren und Reaktor zur kontinuierlichen Herstellung von Polymeren |
| DE10351085A1 (de) * | 2003-10-31 | 2005-06-16 | Inventa-Fischer Gmbh & Co. Kg | Turmreaktor sowie dessen Verwendung zur kontinuierlichen Herstellung von hochmolekularem Polyester |
| DE102005013764B3 (de) * | 2005-03-22 | 2006-10-12 | Epc Industrial Engineering Gmbh | Modulare Vorrichtung zur kontinuierlichen Entgasung und Herstellung polymerer Vorkondensate, mit reaktionstechnisch hohem Verhältnis Produktoberfläche zu Volumen, bei schonender Behandlung der Reaktionsproduktmasse |
| US7718137B2 (en) * | 2005-10-28 | 2010-05-18 | Eastman Chemical Company | Reactor with optimized internal tray design |
| WO2007098638A1 (en) * | 2006-02-28 | 2007-09-07 | China Textile Industrial Engineering Institute | A power external circulation estering reactor |
| DE102006025942B4 (de) * | 2006-06-02 | 2011-07-07 | Uhde Inventa-Fischer GmbH & Co. KG, 13509 | Verfahren zur kontinuierlichen Herstellung von hochmolekularen Polyestern durch Veresterung von Dicarbonsäuren und/oder Umesterung von Dicarbonsäuren mit Diolen und/oder deren Mischungen sowie Vorrichtung hierzu |
| DE102007040135A1 (de) | 2007-08-24 | 2009-02-26 | Bkg Bruckmann & Kreyenborg Granuliertechnik Gmbh | Verfahren zur Herstellung von Polyester-Granulaten aus hochviskosen Polyester-Schmelzen sowie Vorrichtung zur Herstellung der Polyester-Granulate |
| US7834109B2 (en) * | 2007-12-07 | 2010-11-16 | Eastman Chemical Company | System for producing low impurity polyester |
| CN101220140B (zh) * | 2007-12-24 | 2010-08-25 | 中昊晨光化工研究院 | 一种酯交换和缩聚反应的反应装置 |
| WO2009127555A1 (de) | 2008-04-15 | 2009-10-22 | Basf Se | Verfahren zur kontinuierlichen herstellung von biologisch abbaubaren polyestern |
| EP2268702B1 (de) | 2008-04-15 | 2012-11-14 | Basf Se | Verfahren zur kontinuierlichen herstellung von biologisch abbaubaren polyestern |
| KR100888882B1 (ko) * | 2008-09-23 | 2009-03-17 | 김창현 | 폴리(트리메틸렌 테레프탈레이트)의 제조방법 |
| CN101768254B (zh) * | 2008-12-29 | 2012-12-05 | 合肥杰事杰新材料股份有限公司 | 含1，2-丙二醇链结构的聚酯共聚物及其制备方法 |
| BR112012008514A2 (pt) * | 2009-10-15 | 2016-04-05 | Basf Se | processo para a produção contínua de misturas de poliéster |
| US20120240452A1 (en) * | 2011-03-23 | 2012-09-27 | Endicott Biofuels ll, LLC | Production of biodiesel fuels |
| CN102350294B (zh) * | 2011-07-21 | 2013-07-03 | 董欣 | 基于喷射器的逆流式传质、传热、反应装置 |
| CN102492127B (zh) * | 2011-11-22 | 2013-06-12 | 浙江尤夫高新纤维股份有限公司 | 列管式缩聚反应釜 |
| ES2548528T3 (es) | 2011-12-13 | 2015-10-19 | Uhde Inventa-Fischer Gmbh | Procedimiento de preparación de poliésteres alifáticos |
| DE102012003417A1 (de) | 2012-02-17 | 2013-08-22 | Uhde Inventa-Fischer Gmbh | Verfahren zur Herstellung eines hochmolekularen, heteroaromatischen Polyesters oder Copolyesters |
| EP2660270B1 (de) | 2012-04-30 | 2023-10-25 | HDC POLYALL Co., Ltd. | Verfahren zur Abtrennung von volatilen Substanzen aus Stoffgemischen sowie Vorrichtung zur Herstellung von Polyarylensulfiden |
| CN103041763B (zh) * | 2013-01-17 | 2015-12-09 | 扬州惠通化工技术有限公司 | 立式无搅拌缩聚反应器 |
| CN103319705B (zh) | 2013-06-17 | 2014-06-04 | 浙江理工大学 | 一种熔融缩聚反应方法及其反应器和降膜管 |
| CN103665356B (zh) * | 2013-11-25 | 2015-08-26 | 张家港市宝田新型材料科技有限公司 | 一种连续法制备粉末涂料用聚酯树脂的方法 |
| CN103819621B (zh) * | 2014-01-24 | 2016-03-23 | 青岛科技大学 | 一种大分子网状结构的衣康酸类共聚酯的制备方法 |
| WO2015199798A2 (en) | 2014-04-22 | 2015-12-30 | Plastipak Packaging, Inc. | Pellet and precursor with recycled content |
| EP3180386B1 (en) | 2014-08-15 | 2019-11-06 | SABIC Global Technologies B.V. | Batch process for making polybutylene terephthalate |
| US10344119B2 (en) * | 2015-01-30 | 2019-07-09 | Sabic Global Technologies B.V. | Continuous process for making polybutylene terephthalate using purified terephthalic acid and 1,4-butane diol |
| CN105175696A (zh) * | 2015-07-16 | 2015-12-23 | 重庆海庆新材料有限公司 | 使用固载型复合催化剂制备不饱和聚酯树脂的方法 |
| EP3205684A1 (en) | 2016-02-15 | 2017-08-16 | SABIC Global Technologies B.V. | Process for the production of poly(butylene terephthalates) |
| CN105664796B (zh) * | 2016-02-23 | 2017-12-22 | 扬州惠通化工科技股份有限公司 | 立式酯化预缩聚反应器和酯化预缩聚反应的方法 |
| EP3214108A1 (en) | 2016-03-01 | 2017-09-06 | Novamont S.p.A. | Process for removal of tetrahydrofuran |
| CN105771816B (zh) * | 2016-04-22 | 2018-01-23 | 扬州惠通化工科技股份有限公司 | 酯化聚合一体式反应塔 |
| CN105771868B (zh) * | 2016-04-22 | 2017-09-19 | 扬州惠通化工科技股份有限公司 | 一种酯化聚合两釜装置 |
| CN105944651B (zh) * | 2016-05-16 | 2018-01-12 | 浙江大学 | 一种多层落管式降膜缩聚反应器 |
| WO2018093823A1 (en) | 2016-11-15 | 2018-05-24 | Sabic Global Technologies B.V. | Methods of forming dynamic cross-linked polymer compositions using functional chain extenders under continuous process |
| ES2876266T5 (en) | 2017-05-31 | 2025-03-05 | Basf Se | Aliphatic-aromatic polyesters having an increased white level index |
| CN107337244B (zh) * | 2017-08-15 | 2023-03-21 | 华南理工大学 | 一种鼓泡液幕一体式太阳能海水淡化装置 |
| KR102306544B1 (ko) | 2017-09-07 | 2021-09-30 | 주식회사 엘지화학 | 에스터화 반응에서의 1가 알코올의 제거 방법 및 이를 포함하는 에스터 조성물의 제조 방법 |
| WO2019096920A1 (de) | 2017-11-20 | 2019-05-23 | Basf Se | Verfahren zur reinigung eines aliphatischen polyesters |
| WO2019096918A1 (de) | 2017-11-20 | 2019-05-23 | Basf Se | Kontinuierliches verfahren zur herstellung eines aliphatischen polyesters |
| DE102018202547A1 (de) | 2018-02-20 | 2019-10-02 | Thyssenkrupp Ag | Vorrichtung und Verfahren zum Einmischen von Recyclingmaterial in eine Polyesterschmelze |
| CN109400856B (zh) * | 2018-09-26 | 2021-01-01 | 浙江恒澜科技有限公司 | 一种采用金属复合催化剂催化合成高特性粘度且良好色相的聚对苯二甲酸丙二醇酯的方法 |
| CN109621867A (zh) * | 2018-12-13 | 2019-04-16 | 中国石油天然气集团有限公司 | 新型气相空间结构的缩聚反应器 |
| WO2020234293A1 (en) * | 2019-05-22 | 2020-11-26 | Basf Se | Process for purifying an aliphatic-aromatic polyester |
| WO2020234294A1 (en) * | 2019-05-22 | 2020-11-26 | Basf Se | Continuous process for producing an aliphatic-aromatic polyester |
| US20220250292A1 (en) | 2019-07-29 | 2022-08-11 | Lanxess Deutschland Gmbh | Polybutylene Terephthalate With Low THF Content |
| CN114174428B (zh) | 2019-07-29 | 2023-07-18 | 朗盛德国有限责任公司 | 具有低thf含量的聚对苯二甲酸丁二酯 |
| CN110433513B (zh) * | 2019-09-12 | 2023-05-23 | 张健 | 降膜管 |
| CN110964181B (zh) * | 2019-11-27 | 2022-03-15 | 仪征威英化纤有限公司 | 一种再生聚酯熔体的增黏装置及再生纤维的生产方法 |
| JP2023506396A (ja) * | 2019-12-19 | 2023-02-16 | ディーエスエム アイピー アセッツ ビー．ブイ． | 連続固相重合方法及びそこで使用するための反応器カラム |
| CN114790279B (zh) * | 2021-01-26 | 2024-09-27 | 惠生工程（中国）有限公司 | 一种聚乙醇酸低聚物的工业化生产工艺方法 |
| CN113145022B (zh) * | 2021-05-26 | 2024-06-25 | 大连鼎燕医药化工有限公司 | 芳胺氟化氢重氮盐的连续化热解氟代工艺与设备 |
| CN113583227B (zh) * | 2021-07-15 | 2023-07-28 | 江苏志成新材料科技有限公司 | 一种全连续可降解聚酯的生产系统 |
| CN114437331B (zh) * | 2022-02-07 | 2024-06-25 | 万华化学集团股份有限公司 | 一种低齐聚物残留的脂肪族聚酯及其制备方法 |
| CN117659362A (zh) * | 2022-08-31 | 2024-03-08 | 科泽新材料股份有限公司 | 一种制备pent共聚酯的方法 |
| CN116856069B (zh) * | 2023-06-29 | 2024-11-19 | 江苏阿代尔新材料科技有限公司 | 一种再生聚酯熔体的增黏装置及再生纤维的生产方法 |
| WO2025109040A1 (en) | 2023-11-22 | 2025-05-30 | Sabic Global Technologies B.V. | Process for producing polycarbonate |
| CN117816083B (zh) * | 2024-03-05 | 2024-05-14 | 珞氢新材料科技(广东)有限公司 | 一种催化剂原位制备装置及其应用方法 |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2727882A (en) | 1952-10-14 | 1955-12-20 | Du Pont | Process and apparatus for the continuous polymerization of bis-2-hydroxyethyl terephthalate |
| BE553307A (enExample) | 1956-01-25 | |||
| US3329401A (en) | 1961-06-19 | 1967-07-04 | Becker Drilling Alberta Ltd | Apparatus for recovering drill pipe |
| AT309080B (de) * | 1965-12-20 | 1973-08-10 | Karl Fischer App Und Rohrleitu | Dünnschichtverdampfer zur Polykondensation von Bis-(2-hydroxyäthyl)-terephthalat |
| FR1545487A (fr) | 1966-11-30 | 1968-11-08 | Bemberg Spa | Procédé continu pour la production de téréphtalate de polyméthylène à haut degré de polymérisation, produit ainsi obtenu et fibres fabriquées avec ce produit |
| US3676485A (en) * | 1968-08-12 | 1972-07-11 | Eastman Kodak Co | Method for use in a continuous flow reaction for producing a monomer and or a protopolymer |
| US3644096A (en) | 1970-03-30 | 1972-02-22 | Eastman Kodak Co | Apparatus for use in a continuous flow reaction for producing a monomer and/or a protopolymer |
| US4100142A (en) * | 1972-09-13 | 1978-07-11 | Fiber Industries, Inc. | Polyester process and product |
| DE2504258A1 (de) * | 1975-02-01 | 1976-08-05 | Dynamit Nobel Ag | Verfahren und apparatur zur herstellung von oligomeren alkylenterephthalaten |
| US4110316A (en) | 1977-04-14 | 1978-08-29 | E. I. Du Pont De Nemours And Company | Improved process for preparing poly(ethylene terephthalate) |
| DE3047474C2 (de) | 1980-12-17 | 1983-05-11 | Didier Engineering Gmbh, 4300 Essen | Verfahren und Vorrichtung zur kontinuierlichen Herstellung von Polyestern |
| DE3544551C2 (de) | 1985-12-17 | 2002-02-28 | Zimmer Ag | Verfahren zur kontinuierlichen Herstellung von hochmolekularem Polybutylenterephthalat |
| US4670580A (en) | 1986-03-31 | 1987-06-02 | Celanese Corporation | Process for preparing oligomeric glycol esters of dicarboxylic acids |
| US5372790A (en) | 1991-01-18 | 1994-12-13 | The Dow Chemical Company | Vertical continuous reactor |
| US5434239A (en) * | 1993-10-18 | 1995-07-18 | E. I. Du Pont De Nemours And Company | Continuous polyester process |
| DE59505196D1 (de) | 1994-12-30 | 1999-04-08 | Fischer Karl Ind Gmbh | Reaktorvorrichtung für fliessfähige und höherviskose Medien |
| JP3712739B2 (ja) * | 1995-12-14 | 2005-11-02 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | ポリエステルプレポリマーの合成方法 |
-
2001
- 2001-11-12 DE DE10155419A patent/DE10155419B4/de not_active Withdrawn - After Issue
-
2002
- 2002-10-24 TW TW091124615A patent/TW593408B/zh not_active IP Right Cessation
- 2002-11-11 DE DE50211853T patent/DE50211853D1/de not_active Expired - Lifetime
- 2002-11-11 WO PCT/EP2002/012564 patent/WO2003042278A1/de not_active Ceased
- 2002-11-11 AT AT02787634T patent/ATE388184T1/de not_active IP Right Cessation
- 2002-11-11 JP JP2003544110A patent/JP2005519141A/ja active Pending
- 2002-11-11 KR KR1020047006914A patent/KR100776859B1/ko not_active Expired - Fee Related
- 2002-11-11 US US10/495,197 patent/US7115701B2/en not_active Expired - Lifetime
- 2002-11-11 EP EP02787634A patent/EP1448658B1/de not_active Expired - Lifetime
- 2002-11-11 ES ES02787634T patent/ES2300491T3/es not_active Expired - Lifetime
- 2002-11-11 CN CNB028270207A patent/CN100469813C/zh not_active Expired - Fee Related
- 2002-11-11 MX MXPA04004426A patent/MXPA04004426A/es active IP Right Grant
-
2006
- 2006-03-13 US US11/373,937 patent/US7259227B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| TW593408B (en) | 2004-06-21 |
| EP1448658A1 (de) | 2004-08-25 |
| US20050163679A1 (en) | 2005-07-28 |
| JP2005519141A (ja) | 2005-06-30 |
| WO2003042278A1 (de) | 2003-05-22 |
| KR20050002807A (ko) | 2005-01-10 |
| ES2300491T3 (es) | 2008-06-16 |
| CN1612907A (zh) | 2005-05-04 |
| DE10155419B4 (de) | 2005-06-16 |
| MXPA04004426A (es) | 2005-05-16 |
| US7259227B2 (en) | 2007-08-21 |
| KR100776859B1 (ko) | 2007-12-12 |
| DE10155419A1 (de) | 2003-05-28 |
| US20070066790A1 (en) | 2007-03-22 |
| CN100469813C (zh) | 2009-03-18 |
| US7115701B2 (en) | 2006-10-03 |
| DE50211853D1 (de) | 2008-04-17 |
| EP1448658B1 (de) | 2008-03-05 |
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