ATE375367T1 - Herstellung von polyethylen mit breiter molekulargewichtsverteilung - Google Patents

Herstellung von polyethylen mit breiter molekulargewichtsverteilung

Info

Publication number
ATE375367T1
ATE375367T1 AT00920640T AT00920640T ATE375367T1 AT E375367 T1 ATE375367 T1 AT E375367T1 AT 00920640 T AT00920640 T AT 00920640T AT 00920640 T AT00920640 T AT 00920640T AT E375367 T1 ATE375367 T1 AT E375367T1
Authority
AT
Austria
Prior art keywords
reactor
polyethylene
ethylene
production
molecular weight
Prior art date
Application number
AT00920640T
Other languages
English (en)
Inventor
Guy Debras
Original Assignee
Total Petrochemicals Res Feluy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Total Petrochemicals Res Feluy filed Critical Total Petrochemicals Res Feluy
Application granted granted Critical
Publication of ATE375367T1 publication Critical patent/ATE375367T1/de

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/905Polymerization in presence of transition metal containing catalyst in presence of hydrogen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
AT00920640T 1999-03-29 2000-03-28 Herstellung von polyethylen mit breiter molekulargewichtsverteilung ATE375367T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP99106378A EP1041090A1 (de) 1999-03-29 1999-03-29 Herstellung von Polyethylen mit breiter Molekulargewichtsverteilung

Publications (1)

Publication Number Publication Date
ATE375367T1 true ATE375367T1 (de) 2007-10-15

Family

ID=8237880

Family Applications (1)

Application Number Title Priority Date Filing Date
AT00920640T ATE375367T1 (de) 1999-03-29 2000-03-28 Herstellung von polyethylen mit breiter molekulargewichtsverteilung

Country Status (7)

Country Link
US (1) US6291601B1 (de)
EP (2) EP1041090A1 (de)
JP (1) JP4686028B2 (de)
AT (1) ATE375367T1 (de)
AU (1) AU4114600A (de)
DE (1) DE60036695T2 (de)
WO (1) WO2000058376A1 (de)

Families Citing this family (55)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FI111954B (fi) * 2000-02-21 2003-10-15 Borealis Tech Oy Menetelmä polyeteenipäällysteen valmistamiseksi substraatille
DE60028537T2 (de) * 2000-04-13 2007-06-21 Borealis Technology Oy HDPE Polymerzusammensetzung
MXPA03004960A (es) * 2000-12-04 2004-04-02 Exxonmobil Chem Patents Inc Composiciones de copolimero de etileno adecuadas para composiciones mejoradas del indice de viscosidad y lubricantes.
US6787608B2 (en) * 2001-08-17 2004-09-07 Dow Global Technologies, Inc. Bimodal polyethylene composition and articles made therefrom
ATE287924T1 (de) 2001-08-31 2005-02-15 Dow Global Technologies Inc Multimodal polyethylenmaterial
US6924340B2 (en) * 2002-04-04 2005-08-02 Equistar Chemicals L.P. Process for removal of intermediate hydrogen from cascaded polyolefin slurry reactors
GB0227666D0 (en) * 2002-11-27 2003-01-08 Borealis Tech Oy Use
US6921804B2 (en) * 2003-03-25 2005-07-26 Equistar Chemicals L.P. Cascaded polyolefin slurry polymerization employing disengagement vessel between reactors
US8013069B2 (en) * 2005-01-31 2011-09-06 Exxonmobil Chemical Patents Inc. Polymer blends and pellets and methods of producing same
US7786203B2 (en) * 2005-09-16 2010-08-31 Milliken & Company Polymer compositions comprising nucleating or clarifying agents and articles made using such compositions
JP2007177020A (ja) * 2005-12-27 2007-07-12 Mitsui Chemicals Inc エチレン系重合体組成物およびこれから得られる成形体
JP2007177021A (ja) * 2005-12-27 2007-07-12 Mitsui Chemicals Inc 熱可塑性樹脂組成物およびこれから得られる成形体
US20070229833A1 (en) * 2006-02-22 2007-10-04 Allan Rosencwaig High-sensitivity surface detection system and method
US7847042B2 (en) * 2006-03-30 2010-12-07 Total Petrochemicals Research Feluy Slurry polymerisation process of ethylene in the presence of low amount of scavenger
KR101141494B1 (ko) * 2007-09-05 2012-05-03 에스케이이노베이션 주식회사 다봉 분자량 분포를 갖는 에틸렌 공중합체 및 이의제조방법
US9108147B2 (en) 2010-10-15 2015-08-18 Chevron Phillips Chemical Company Lp Component separations in polymerization
US8410329B2 (en) 2010-10-15 2013-04-02 Chevron Phillips Chemical Company Lp Ethylene separation
US9180405B2 (en) 2010-10-15 2015-11-10 Chevron Phillips Chemical Company Lp Ethylene recovery by absorption
EP2583998B1 (de) * 2011-10-21 2018-02-28 Borealis AG Polyethylenzusammensetzung mit sehr schneller Rissausbreitungsbeständigkeit und Druckbeständigkeit
IN2014DN08508A (de) 2012-04-13 2015-05-15 Chevron Phillips Chemical Co
US8987390B2 (en) 2012-12-18 2015-03-24 Chevron Phillips Chemical Company, Lp Chain transfer agent removal between polyolefin polymerization reactors
US9840570B2 (en) 2013-03-11 2017-12-12 Chevron Phillips Chemical Company, Lp Medium density polyethylene compositions
US8822608B1 (en) 2013-03-12 2014-09-02 Chevron Phillips Chemical Co. LP. Polyolefin production with different diluents in multiple polymerization reactors
ES2665432T3 (es) 2013-11-19 2018-04-25 Chevron Phillips Chemical Company Lp Sistemas de catalizadores que contienen compuestos metalocenos de ciclopentadienilo-fluorenilo con puente de boro con un sustituyente alquenilo
WO2015077100A2 (en) 2013-11-19 2015-05-28 Chevron Phillips Chemical Company Lp Boron-bridged bis-indenyl metallocene catalyst systems and polymers produced therefrom
US9540465B2 (en) 2013-11-19 2017-01-10 Chevron Phillips Chemical Company Lp Boron-bridged metallocene catalyst systems and polymers produced therefrom
US9217049B2 (en) 2013-11-19 2015-12-22 Chevron Phillips Chemical Company Lp Dual catalyst systems for producing polymers with a broad molecular weight distribution and a uniform short chain branch distribution
US9376559B2 (en) 2013-11-22 2016-06-28 Exxonmobil Chemical Patents Inc. Reverse staged impact copolymers
JP6426898B2 (ja) * 2014-02-25 2018-11-21 旭化成株式会社 インフレーションフィルム
SG11201608527WA (en) * 2014-04-17 2016-11-29 Chevron Phillips Chemical Co Lp Boron-bridged metallocene catalyst systems and polymers produced therefrom
US9469698B2 (en) * 2014-04-29 2016-10-18 Chevron Phillips Chemical Company Lp Process for forming polyolefins
CA2947141C (en) 2014-04-30 2019-01-15 Tepha, Inc. Three-dimensional resorbable implants for tissue reinforcement and hernia repair
US10934372B2 (en) 2016-08-23 2021-03-02 Exxonmobil Chemical Patents Inc. Olefin polymerization processes
WO2018038796A1 (en) 2016-08-23 2018-03-01 Exxonmobil Chemical Patents Inc. Olefin polymerization processes
RU2759904C2 (ru) 2016-09-12 2021-11-18 Тай Полиэтилен Ко., Лтд. Бимодальная полиэтиленовая композиция и содержащая ее труба
ES2758793T5 (es) 2016-09-12 2022-10-31 Thai Polyethylene Co Ltd Proceso para la preparación de polietileno multimodal
PT3293211T (pt) 2016-09-12 2019-09-12 Scg Chemicals Co Ltd Tampa roscada em polietileno multimodal
ES2728941T3 (es) 2016-09-12 2019-10-29 Thai Polyethylene Co Ltd Película de polietileno multimodal
EP3293214B1 (de) 2016-09-12 2019-12-25 Thai Polyethylene Co., Ltd. Multimodales hochleistungs-polyethylen mit ultrahohem molekulargewicht
HUE047424T2 (hu) 2016-09-12 2020-04-28 Thai Polyethylene Co Ltd Multimodális polietilén vékony film
PT3293213T (pt) 2016-09-12 2019-10-29 Scg Chemicals Co Ltd Contentor de polietileno multimodal
PT3293207T (pt) 2016-09-12 2019-10-25 Scg Chemicals Co Ltd Tubo de polietileno multimodal
ES2767704T3 (es) 2016-09-12 2020-06-18 Thai Polyethylene Co Ltd Tubería de polietileno multimodal
JP6800409B2 (ja) * 2016-12-21 2020-12-16 東ソー株式会社 超高分子量ポリエチレン系重合体の製造方法
SG11202005184XA (en) 2017-12-18 2020-07-29 Dow Global Technologies Llc Zirconocene-titanocene catalyst system
CN112292417B (zh) 2018-06-15 2023-10-13 陶氏环球技术有限责任公司 包括具有高分子量高密度级分的双峰型乙烯类聚合物的吹塑膜
SG11202012176XA (en) * 2018-06-15 2021-01-28 Dow Global Technologies Llc Process for the production of bimodal ethylene-based polymers having high molecular weight high density fractions
EP3807329A1 (de) 2018-06-15 2021-04-21 Dow Global Technologies Llc Bimodale ethylenbasierte polymere mit fraktionen von hohem molekulargewicht und hoher dichte
CA3103015A1 (en) 2018-06-15 2019-12-19 Dow Global Technologies Llc Cast films comprising bimodal ethylene-based polymers having high molecular weight high density fractions
PT3774930T (pt) * 2018-06-21 2021-11-04 Basell Polyolefine Gmbh Processo de suspensão para preparar copolímeros de etileno numa cascata de reatores
TWI839414B (zh) 2018-11-30 2024-04-21 美商陶氏全球科技有限責任公司 具有平衡特性之基於聚合物之膜
KR20220044202A (ko) 2019-07-31 2022-04-06 다우 글로벌 테크놀로지스 엘엘씨 고분자량 폴리에틸렌 제조용 중합 촉매
KR20220042395A (ko) 2019-07-31 2022-04-05 다우 글로벌 테크놀로지스 엘엘씨 지글러-나타 촉매 및 수소화 촉매를 사용한 용액 공정에서의 에틸렌의 중합
KR20220042394A (ko) 2019-07-31 2022-04-05 다우 글로벌 테크놀로지스 엘엘씨 지글러-나타 촉매 및 수소화 전구촉매를 사용한 용액 공정에서의 에틸렌의 중합
CN110590981A (zh) * 2019-09-05 2019-12-20 北方华锦化学工业股份有限公司 一种用于低熔垂大口径管材料的聚乙烯树脂生产方法

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4851488A (en) * 1987-04-23 1989-07-25 Shell Oil Company Process for altering hydrogenated polymer compositions from high melt flow to low melt flow
US5276115A (en) * 1992-12-14 1994-01-04 Phillips Petroleum Company Mono-1-olefin polymerization in the presence of hydrogen and a cyclopentadienyl compound
BE1007653A3 (fr) * 1993-10-26 1995-09-05 Fina Research Procede de production de polyethylene ayant une distribution large de poids moleculaire.
JPH09216913A (ja) * 1995-12-04 1997-08-19 Mitsubishi Chem Corp オレフィン重合体の製造法
US5739220A (en) * 1997-02-06 1998-04-14 Fina Technology, Inc. Method of olefin polymerization utilizing hydrogen pulsing, products made therefrom, and method of hydrogenation
EP0881237A1 (de) * 1997-05-26 1998-12-02 Fina Research S.A. Verfahren zur Herstellung von bimodalen Polyolefinen mit Metallocenkatalysatoren in zwei Reaktionszonen
GB9712663D0 (en) * 1997-06-16 1997-08-20 Borealis As Process
EP0905151A1 (de) * 1997-09-27 1999-03-31 Fina Research S.A. Herstellung von Polyäthylen mit einer breiten Molekulargewichtsverteilung

Also Published As

Publication number Publication date
JP4686028B2 (ja) 2011-05-18
AU4114600A (en) 2000-10-16
WO2000058376A1 (en) 2000-10-05
EP1169362A1 (de) 2002-01-09
DE60036695T2 (de) 2008-07-17
DE60036695D1 (de) 2007-11-22
EP1041090A1 (de) 2000-10-04
US6291601B1 (en) 2001-09-18
EP1169362B1 (de) 2007-10-10
JP2003507493A (ja) 2003-02-25

Similar Documents

Publication Publication Date Title
ATE375367T1 (de) Herstellung von polyethylen mit breiter molekulargewichtsverteilung
ATE263196T1 (de) Herstellung von polyäthylen mit einer breiten molekulargewichtsverteilung
DE69428409D1 (de) Verfahren zur Herstellung von Polyethylen mit breiter Molekulargewichtsverteilung
EP0746574B1 (de) Polymerisationskatalysatorsysteme, ihre herstellung und ihre verwendung
AU5403699A (en) Dual reactor ethylene polymerization process
MY112607A (en) Process for preparing polyethylene
DE3675642D1 (de) Einsatz von antistatika zur vermeidung von belagbildung bei der herstellung von ethylenpolymerisaten in gasphasenreakatoren.
ATE361938T1 (de) Bimetallkatalysator zur ethylenpolymerisation mit bimodaler molekulargewichtsverteilung, dessen herstellung und verwendung
NO179286C (no) Flertrinnsprosess for fremstilling av polyetylen
MX9602864A (es) Proceso para producir una mezcla de polietileno in situ.
GR3029597T3 (en) Process for preparing an in situ polyethylene blend
ATE194994T1 (de) Polymerisationsverfahren in einer reaktorenreihe
ATE483736T1 (de) Olefinpolymere, herstellungsverfahren und benutzung davon
MY108973A (en) Polyethylene copolymer and polymerization process
MX9605121A (es) Un proceso para preparar la mezcla de polietileno in situ.
ATE58545T1 (de) Einsatz von antistatika zur vermeidung von belagbildung bei der herstellung von ultrahochmolekularem polyethylen in gasphasenreaktoren.
US7588735B2 (en) Production of polyethylene
GB0217520D0 (en) Product
ATE225810T1 (de) Herstellung von polyäthylen mit einer verbesserten widerstandsfähigkeit gegen risse und/oder schlagzähigkeit
JPS5632508A (en) Polymerization of ethylene
DE69704501D1 (de) Herstellung von polyethylen mit bimodaler molekulargewichtsverteilung
McDaniel et al. Linear, Very Low Density Polyethylene Polymerization Process and Products Thereof
Davidovici Process for the Dimerization of Ethylene and Copolymerization to Polyethylene
TH12533A (th) กรรมวิธีสำหรับการปรับการไหลขณะหลอมของผลิตภัณฑ์ของพอลิเมอร์ของโอลิฟีน
BG105084A (en) Method for copolymerization of ethene with carbon monoxide in the presence of binuclear nickelilide complexes

Legal Events

Date Code Title Description
RER Ceased as to paragraph 5 lit. 3 law introducing patent treaties