AR119449A1 - N-feniluracilos sustituidos y sus sales y su uso como principios activos herbicidas - Google Patents

N-feniluracilos sustituidos y sus sales y su uso como principios activos herbicidas

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Publication number
AR119449A1
AR119449A1 ARP200102044A ARP200102044A AR119449A1 AR 119449 A1 AR119449 A1 AR 119449A1 AR P200102044 A ARP200102044 A AR P200102044A AR P200102044 A ARP200102044 A AR P200102044A AR 119449 A1 AR119449 A1 AR 119449A1
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AR
Argentina
Prior art keywords
alkyl
alkoxy
aryl
bis
haloalkyl
Prior art date
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ARP200102044A
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English (en)
Inventor
Heinemann Ines Dr
Frackenpohl Jens Dr
Willms Lothar Dr
Jakobi Harald Dr
Helmke Hendrik Dr
Rosinger Christopher Hugh Dr
Gatzweiler Elmar Dr
Asmus Elisabeth Dr
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Bayer Ag
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Publication of AR119449A1 publication Critical patent/AR119449A1/es

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    • C07D401/12Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
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    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
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    • A01N47/12Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Agronomy & Crop Science (AREA)
  • Toxicology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

N-feniluracilos sustituidos y sus sales y su uso como principios activos herbicidas. La presente se refiere a N-feniluracilos sustituidos de la fórmula general (1) o sus sales, en donde los radicales de la fórmula general (1) se corresponden con las definiciones indicadas en la descripción, además de su uso como herbicida, especialmente para controlar las malezas y/o las gramíneas en cultivos de plantas útiles y/o como reguladores del crecimiento vegetal para ejercer influencia en el crecimiento de cultivos de plantas útiles. Reivindicación 1: N-feniluracilos sustituidos de la fórmula general (1) o sus sales, caracterizados por que R¹ significa hidrógeno, C₁₋₈-haloalquilo, R² significa hidrógeno, flúor, cloro, bromo, trifluorometilo, C₁₋₈-alcoxi, R³ significa hidrógeno, halógeno, C₁₋₈-alcoxi, R⁴ significa halógeno, ciano, NO₂, C(O)NH₂, C(S)NH₂, C₁₋₈-haloalquilo, C₂₋₈-alquinilo, R⁵, R⁶ y R⁷ significan independientemente uno de otro hidrógeno, halógeno, ciano, C₁₋₈-alquilo, C₁₋₈-haloalquilo, C₁₋₈-alcoxi, C₁₋₈-haloalcoxi, G significa C₁₋₈-alquileno lineal o ramificado, Q representa un resto de la fórmula (2), R⁸ significa hidrógeno, C₁₋₈-alquilo, C₁₋₈-haloalquilo, arilo, aril-C₁₋₈-alquilo, heteroarilo, C₂₋₈-alquinilo, C₂₋₈-alquenilo, C(O)R¹³, C(O)OR¹³, C₁₋₈-alcoxi-C₁₋₈-alquilo, R⁹ significa hidrógeno o C₁₋₈-alquilo, R¹⁰ significa ciano, NO₂, heteroarilo, heteroaril-C₁₋₈-alquilo, heterociclilo, heterociclil-C₁₋₈-alquilo, R¹¹R¹²N-C₁₋₈-alquilo, R¹³O-C₁₋₈-alquilo, ciano-C₁₋₈-alquilo, C₁₋₈-alquilcarboniloxi-C₁₋₈-alquilo, C₃₋₈-cicloalquilcarboniloxi-C₁₋₈-alquilo, arilcarboniloxi-C₁₋₈-alquilo, heteroarilcarboniloxi-C₁₋₈-alquilo, heterociclilcarboniloxi-C₁₋₈-alquilo, OR¹³, NR¹¹R¹², SR¹⁴, S(O)R¹⁴, SO₂R¹⁴, R¹⁴S-C₁₋₈-alquilo, R¹⁴(O)S-C₁₋₈-alquilo, R¹⁴O₂S-C₁₋₈-alquilo, tris-[C₁₋₈-alquil]silil-C₁₋₈-alquilo, bis-[C₁₋₈-alquil](aril)sililC₁₋₈-alquilo, [C₁₋₈-alquil]-bis-(aril)silil-C₁₋₈-alquilo, tris-[C₁₋₈-alquil]sililo, bis-hidroxiboril-C₁₋₈-alquilo, bis-[C₁₋₈-alcoxi]boril-C₁₋₈-alquilo, tetrametil-1,3,2-dioxaborolan-2-ilo, tetrametil-1,3,2-dioxaborolan-2-il-C₁₋₈-alquilo, nitro-C₁₋₈-alquilo, C(O)R¹⁴, bis-C₁₋₈-alcoximetilo, bis-C₁₋₈-alcoximetil-C₁₋₈-alquilo, o R⁸ y R¹⁰, con el átomo de carbono al que están enlazados, forman un heterociclilo monocíclico o bicíclico completamente saturado o parcialmente saturado y eventualmente más sustituido de 3 a 10 miembros, R¹¹ y R¹² son idénticos o diferentes y significan independientemente uno del otro hidrógeno, C₁₋₈-alquilo, C₂₋₈-alquenilo, C₂₋₈-alquinilo, C₁₋₈-cianoalquilo, C₁₋₁₀-haloalquilo, C₂₋₈-haloalquenilo, C₃₋₈-haloalquinilo, C₃₋₁₀-cicloalquilo, C₃₋₁₀-halocicloalquilo, C₄₋₁₀-cicloalquenilo, C₄₋₁₀-halocicloalquenilo, C₁₋₈-alcoxi-C₁₋₈-alquilo, C₁₋₈-haloalcoxi-C₁₋₈-alquilo, C₁₋₈-alquiltio-C₁₋₈-alquilo, C₁₋₈-haloalquiltio-C₁₋₈-alquilo, C₁₋₈-alcoxi-C₁₋₈-haloalquilo, arilo, aril-C₁₋₈-alquilo, heteroarilo, heteroaril-C₁₋₈-alquilo, C₃₋₈-cicloalquil-C₁₋₈-alquilo, C₄₋₁₀-cicloalquenil-C₁₋₈-alquilo, COR¹³, SO₂R¹⁴, heterociclilo, C₁₋₈-alcoxicarbonilo, bis-[C₁₋₈-alquil]aminocarbonil-C₁₋₈-alquilo, C₁₋₈-alquilaminocarbonil-C₁₋₈-alquilo, aril-C₁₋₈-alquil-aminocarbonil-C₁₋₈-alquilo, aril-C₁₋₈-alcoxicarbonilo, heteroaril-C₁₋₈-alcoxicarbonilo, C₂₋₈-alqueniloxicarbonilo, C₂₋₈-alquiniloxicarbonilo, heterociclil-C₁₋₈-alquilo, o R¹¹ y R¹² con el átomo de nitrógeno al que están enlazados conforman un anillo monocíclico o bicíclico de 3 a 10 miembros completamente saturado o parcialmente saturado, dado el caso interrumpido por heteroátomos y dado el caso también sustituido, R¹³ significa hidrógeno, C₁₋₈-alquilo, C₂₋₈-alquenilo, C₂₋₈-alquinilo, C₁₋₈-cianoalquilo, C₁₋₁₀-haloalquilo, C₂₋₈-haloalquenilo, C₃₋₈-haloalquinilo, C₃₋₁₀-cicloalquilo, C₃₋₁₀-halocicloalquilo, C₄₋₁₀-cicloalquenilo, C₄₋₁₀-halocicloalquenilo, C₁₋₈-alcoxi-C₁₋₈-alquilo, C₁₋₈-haloalcoxi-C₁₋₈-alquilo, C₁₋₈-alcoxi-C₁₋₈-haloalquilo, C₁₋₈-alcoxi-C₁₋₈-alcoxi-C₁₋₈-alquilo, C₁₋₈-alcoxi-C₁₋₈-alcoxi-C₁₋₈-alcoxi-C₁₋₈-alquilo, C₁₋₈-alcoxi-C₁₋₈-alcoxi-C₁₋₈-alcoxi-C₁₋₈-alcoxi-C₁₋₈-alquilo, arilo, aril-C₁₋₈-alquilo, arilo-C₁₋₈-alcoxi-C₁₋₈-alquilo, heteroarilo, heteroaril-C₁₋₈-alquilo, C₃₋₈-cicloalquil-C₁₋₈-alquilo, C₄₋₁₀-cicloalquenil-C₁₋₈-alquilo, bis-[C₁₋₈-alquil]aminocarbonil-C₁₋₈-alquilo, C₁₋₈-alquil-aminocarbonil-C₁₋₈-alquilo, aril-C₁₋₈-alquilaminocarbonil-C₁₋₈-alquilo, bis-[C₁₋₈-alquil]amino-C₂₋₆-alquilo, C₁₋₈-alquil-amino-C₂₋₆-alquilo, aril-C₁₋₈-alquil-amino-C₂₋₆-alquilo, R¹⁴S-C₁₋₈-alquilo, R¹⁴(O)S-C₁₋₈-alquilo, R¹⁴O₂S-C₁₋₈-alquilo, hidroxicarbonil-C₁₋₈-alquilo, heterociclilo, heterociclil-C₁₋₈-alquilo, tris-[C₁₋₈-alquil]silil-C₁₋₈-alquilo, bis-[C₁₋₈-alquil](aril)sililC₁₋₈-alquilo, [C₁₋₈-alquil]-bis-(aril)silil-C₁₋₈-alquilo, C₁₋₈-alquilcarboniloxi-C₁₋₈-alquilo, C₃₋₈-cicloalquilcarboniloxi-C₁₋₈-alquilo, arilcarboniloxi-C₁₋₈-alquilo, heteroarilcarboniloxi-C₁₋₈-alquilo, heterociclilcarboniloxi-C₁₋₈-alquilo, ariloxi-C₁₋₈-alquilo, heteroariloxi-C₁₋₈-alquilo, C₁₋₈-alcoxicarbonilo, R¹⁴ significa hidrógeno, C₁₋₈-alquilo, C₂₋₈-alquenilo, C₂₋₈-alquinilo, C₁₋₈-cianoalquilo, C₁₋₁₀-haloalquilo, C₂₋₈-haloalquenilo, C₃₋₈-haloalquinilo, C₃₋₁₀-cicloalquilo, C₃₋₁₀-halocicloalquilo, C₄₋₁₀-cicloalquenilo, C₄₋₁₀-halocicloalquenilo, C₁₋₈-alcoxi-C₁₋₈-alquilo, C₁₋₈-alcoxi-C₁₋₈-haloalquilo, arilo, aril-C₁₋₈-alquilo, heteroarilo, heteroaril-C₁₋₈-alquilo, heterociclil-C₁₋₈-alquilo, C₃₋₈-cicloalquil-C₁₋₈-alquilo, C₄₋₁₀-cicloalquenil-C₁₋₈-alquilo, bis-[C₁₋₈-alquil]amino, C₁₋₈-alquil-amino, aril-C₁₋₈-amino, aril-C₁₋₆-alquil-amino, aril-[C₁₋₈-alquil]amino; C₃₋₈-cicloalquil-amino, C₃₋₈-cicloalquil-[C₁₋₈-alquil]amino; N-acetidinilo, N-pirrolidinilo, N-piperidinilo, N-morfolinilo, y X e Y independientemente uno de otro significan O (oxígeno) o S (azufre).
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