AR119447A1 - N-fenil-n-amino-uracilos sustituidos, además de sus sales y su uso como sustancias activas herbicidas - Google Patents

N-fenil-n-amino-uracilos sustituidos, además de sus sales y su uso como sustancias activas herbicidas

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AR119447A1
AR119447A1 ARP200102042A ARP200102042A AR119447A1 AR 119447 A1 AR119447 A1 AR 119447A1 AR P200102042 A ARP200102042 A AR P200102042A AR P200102042 A ARP200102042 A AR P200102042A AR 119447 A1 AR119447 A1 AR 119447A1
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alkyl
aryl
alkoxy
amino
haloalkyl
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ARP200102042A
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Frackenpohl Jens Dr
Heinemann Ines Dr
Willms Lothar Dr
Jakobi Harald Dr
Helmke Hendrik Dr
Rosinger Christopher Hugh Dr
Asmus Elisabeth Dr
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Bayer Ag
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    • C—CHEMISTRY; METALLURGY
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    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/60—1,4-Diazines; Hydrogenated 1,4-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/76—1,3-Oxazoles; Hydrogenated 1,3-oxazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N55/00—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
    • A01N55/08—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur containing boron
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
    • A01P13/00—Herbicides; Algicides
    • A01P13/02—Herbicides; Algicides selective
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/14—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing three or more hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
    • C07D405/14—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing three or more hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
    • C07D409/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing three or more hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D413/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
    • C07D413/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing three or more hetero rings
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    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D417/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00
    • C07D417/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing three or more hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D453/00—Heterocyclic compounds containing quinuclidine or iso-quinuclidine ring systems, e.g. quinine alkaloids
    • C07D453/02—Heterocyclic compounds containing quinuclidine or iso-quinuclidine ring systems, e.g. quinine alkaloids containing not further condensed quinuclidine ring systems
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    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D493/00—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
    • C07D493/02—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
    • C07D493/04—Ortho-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D493/00—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
    • C07D493/02—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
    • C07D493/08—Bridged systems

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental Sciences (AREA)
  • Zoology (AREA)
  • Engineering & Computer Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Wood Science & Technology (AREA)
  • Agronomy & Crop Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • Health & Medical Sciences (AREA)
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  • General Chemical & Material Sciences (AREA)
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  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catching Or Destruction (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)

Abstract

N-fenil-N-amino-uracilos sustituidos, además de sus sales y su uso como sustancias activas herbicidas. La presente se refiere a los N-fenil-N-amino-uracilos sustituidos de la fórmula general (1) o sus sales, en donde los radicales de la fórmula general (1) se corresponden con las definiciones indicadas en la descripción, además de su uso como herbicidas, especialmente para controlar las malezas y/o las gramíneas en cultivos de plantas útiles y/o como reguladores del crecimiento vegetal para ejercer influencia en el crecimiento de cultivos de plantas útiles. Reivindicación 1: N-fenil-N-amino-uracilos sustituidos de la fórmula general (1) o sus sales, caracterizados por que R¹ significa hidrógeno, C₁₋₈-haloalquilo, R² significa hidrógeno, flúor, cloro, bromo, trifluorometilo, C₁₋₈-alcoxi, R³ significa hidrógeno, halógeno, C₁₋₈-alcoxi, R⁴ significa halógeno, ciano, NO₂, C(O)NH₂, C(S)NH₂, C₁₋₈-haloalquilo, C₂₋₈-alquinilo, R⁵, R⁶ y R⁷ significan independientemente uno de otro hidrógeno, halógeno, ciano, C₁₋₈-alquilo, C₁₋₈-haloalquilo, C₁₋₈-alcoxi, C₁₋₈-haloalcoxi, G significa C₁₋₈-alquileno lineal o ramificado, Q significa hidroxi o un radical de la fórmula (2), R⁸ significa hidrógeno, C₁₋₈-alquilo, C₁₋₈-haloalquilo, arilo, aril-C₁₋₈-alquilo, heteroarilo, C₂₋₈-alquinilo, C₂₋₈-alquenilo, C(O)R¹³, C(O)OR¹³, C₁₋₈-alcoxi-C₁₋₈-alquilo, R⁹ significa hidrógeno o C₁₋₈-alquilo, R¹⁰ significa hidrógeno, halógeno, ciano, NO₂, C₁₋₈-alquilo, C₁₋₈-haloalquilo, C₃₋₈-cicloalquilo, C₃₋₈-cicloalquil-C₁₋₈-alquilo, C₃₋₈-halocicloalquilo, C₃₋₈-halocicloalquil-C₁₋₈-alquilo, C₂₋₈-alquenilo, C₂₋₈-alquinilo, arilo, aril-C₁₋₈-alquilo, heteroarilo, heteroaril-C₁₋₈-alquilo, heterociclilo, heterociclil-C₁₋₈-alquilo, R¹¹R¹²N-C₁₋₈-alquilo, R¹³O-C₁₋₈-alquilo, ciano-C₁₋₈-alquilo, C₁₋₈-alquilcarboniloxi-C₁₋₈-alquilo, C₃₋₈-cicloalquilcarboniloxi-C₁₋₈-alquilo, arilcarboniloxi-C₁₋₈-alquilo, heteroarilcarboniloxi-C₁₋₈-alquilo, heterociclilcarboniloxi-C₁₋₈-alquilo, OR¹³, NR¹¹R¹², SR¹⁴, S(O)R¹⁴, SO₂R¹⁴, R¹⁴S-C₁₋₈-alquilo, R¹⁴(O)S-C₁₋₈-alquilo, R¹⁴O₂S-C₁₋₈-alquilo, tris-[C₁₋₈-alquil]silil-C₁₋₈-alquilo, bis-[C₁₋₈-alquil](aril)sililC₁₋₈-alquilo, [C₁₋₈-alquil]-bis-(aril)silil-C₁₋₈-alquilo, tris-[C₁₋₈-alquil]sililo, bis-hidroxiboril-C₁₋₈-alquilo, bis-[C₁₋₈-alcoxi]boril-C₁₋₈-alquilo, tetrametil-1,3,2-dioxaborolan-2-ilo, tetrametil-1,3,2-dioxaborolan-2-il-C₁₋₈-alquilo, nitro-C₁₋₈-alquilo, C(O)OR¹³, C(O)R¹³, C(O)NR¹¹R¹², R¹³O(O)C-C₁₋₈-alquilo, R¹¹R¹²N(O)C-C₁₋₈-alquilo, bis-C₁₋₈-alcoxi-C₁₋₈-alquilo, o R⁸ y R¹⁰ con el átomo de carbono al que están enlazados conforman un anillo monocíclico o bicíclico de 3 a 10 miembros completamente saturado o parcialmente saturado, dado el caso interrumpido por heteroátomos y dado el caso también sustituido, R¹¹ y R¹² son idénticos o diferentes y significan independientemente uno del otro hidrógeno, C₁₋₈-alquilo, C₂₋₈-alquenilo, C₂₋₈-alquinilo, C₁₋₈-cianoalquilo, C₁₋₁₀-haloalquilo, C₂₋₈-haloalquenilo, C₃₋₈-haloalquinilo, C₃₋₁₀-cicloalquilo, C₃₋₁₀-halocicloalquilo, C₄₋₁₀-cicloalquenilo, C₄₋₁₀-halocicloalquenilo, C₁₋₈-alcoxi-C₁₋₈-alquilo, C₁₋₈-haloalcoxi-C₁₋₈-alquilo, C₁₋₈-alquiltio-C₁₋₈-alquilo, C₁₋₈-haloalquiltio-C₁₋₈-alquilo, C₁₋₈-alcoxi-C₁₋₈-haloalquilo, arilo, aril-C₁₋₈-alquilo, heteroarilo, heteroaril-C₁₋₈-alquilo, C₃₋₈-cicloalquil-C₁₋₈-alquilo, C₄₋₁₀-cicloalquenil-C₁₋₈-alquilo, COR¹³, SO₂R¹⁴, heterociclilo, C₁₋₈-alcoxicarbonilo, bis-[C₁₋₈-alquil]aminocarbonil-C₁₋₈-alquilo, C₁₋₈-alquilaminocarbonil-C₁₋₈-alquilo, aril-C₁₋₈-alquil-aminocarbonil-C₁₋₈-alquilo, aril-C₁₋₈-alcoxicarbonilo, heteroaril-C₁₋₈-alcoxicarbonilo, C₂₋₈-alqueniloxicarbonilo, C₂₋₈-alquiniloxicarbonilo, heterociclil-C₁₋₈-alquilo, o R¹¹ y R¹² con el átomo de nitrógeno al que están enlazados conforman un anillo de 3 a 10 miembros monocíclico o bicíclico completamente saturado o parcialmente saturado, dado el caso interrumpido por heteroátomos y dado el caso también sustituido, R¹³ significa hidrógeno, C₁₋₈-alquilo, C₂₋₈-alquenilo, C₂₋₈-alquinilo, C₁₋₈-cianoalquilo, C₁₋₁₀-haloalquilo, C₂₋₈-haloalquenilo, C₃₋₈-haloalquinilo, C₃₋₁₀-cicloalquilo, C₃₋₁₀-halocicloalquilo, C₄₋₁₀-cicloalquenilo, C₄₋₁₀-halocicloalquenilo, C₁₋₈-alcoxi-C₁₋₈-alquilo, C₁₋₈-haloalcoxi-C₁₋₈-alquilo, C₁₋₈-alcoxi-C₁₋₈-haloalquilo, C₁₋₈-alcoxi-C₁₋₈-alcoxi-C₁₋₈-alquilo, C₁₋₈-alcoxi-C₁₋₈-alcoxi-C₁₋₈-alcoxi-C₁₋₈-alquilo, C₁₋₈-alcoxi-C₁₋₈-alcoxi-C₁₋₈-alcoxi-C₁₋₈-alcoxi-C₁₋₈-alquilo, arilo, aril-C₁₋₈-alquilo, aril-C₁₋₈-alcoxi-C₁₋₈-alquilo, heteroarilo, heteroaril-C₁₋₈-alquilo, C₃₋₈-cicloalquil-C₁₋₈-alquilo, C₄₋₁₀-cicloalquenil-C₁₋₈-alquilo, bis-[C₁₋₈-alquil]aminocarbonil-C₁₋₈-alquilo, C₁₋₈-alquil-aminocarbonil-C₁₋₈-alquilo, aril-C₁₋₈-alquilaminocarbonil-C₁₋₈-alquilo, bis-[C₁₋₈-alquil]amino-C₂₋₆-alquilo, C₁₋₈-alquil-amino-C₂₋₆-alquilo, aril-C₁₋₈-alquil-amino-C₂₋₆-alquilo, R¹⁴S-C₁₋₈-alquilo, R¹⁴(O)S-C₁₋₈-alquilo, R¹⁴O₂S-C₁₋₈-alquilo, hidroxicarbonil-C₁₋₈-alquilo, heterociclilo, heterociclil-C₁₋₈-alquilo, tris-[C₁₋₈-alquil]silil-C₁₋₈-alquilo, bis-[C₁₋₈-alquil](aril)sililC₁₋₈-alquilo, [C₁₋₈-alquil]-bis-(aril)silil-C₁₋₈-alquilo, C₁₋₈-alquilcarboniloxi-C₁₋₈-alquilo, C₃₋₈-cicloalquilcarboniloxi-C₁₋₈-alquilo, arilcarboniloxi-C₁₋₈-alquilo, heteroarilcarboniloxi-C₁₋₈-alquilo, heterociclilcarboniloxi-C₁₋₈-alquilo, ariloxi-C₁₋₈-alquilo, heteroariloxi-C₁₋₈-alquilo, C₁₋₈-alcoxicarbonilo, R¹⁴ significa hidrógeno, C₁₋₈-alquilo, C₂₋₈-alquenilo, C₂₋₈-alquinilo, C₁₋₈-cianoalquilo, C₁₋₁₀-haloalquilo, C₂₋₈-haloalquenilo, C₃₋₈-haloalquinilo, C₃₋₁₀-cicloalquilo, C₃₋₁₀-halocicloalquilo, C₄₋₁₀-cicloalquenilo, C₄₋₁₀-halocicloalquenilo, C₁₋₈-alcoxi-C₁₋₈-alquilo, C₁₋₈-alcoxi-C₁₋₈-haloalquilo, arilo, aril-C₁₋₈-alquilo, heteroarilo, heteroaril-C₁₋₈-alquilo, heterociclil-C₁₋₈-alquilo, C₃₋₈-cicloalquil-C₁₋₈-alquilo, C₄₋₁₀-cicloalquenil-C₁₋₈-alquilo, bis-[C₁₋₈-alquil]amino, C₁₋₈-alquil-amino, aril-C₁₋₈-amino, aril-C₁₋₆-alquil-amino, aril-[C₁₋₈-alquil]amino; C₃₋₈-cicloalquil-amino, C₃₋₈-cicloalquil-[C₁₋₈-alquil]amino; N-acetidinilo, N-pirrolidinilo, N-piperidinilo, N-morfolinilo, R¹⁵ y R¹⁶ independientemente uno de otro significan hidrógeno, C₁₋₈-alquilo, C₂₋₈-alquenilo, C(O)R¹³, C(O)OR¹³, C(O)NR¹¹R¹², SO₂R¹⁴, o R¹⁵ y R¹⁶ con el átomo de nitrógeno al que están enlazados, conforman un grupo imino sustituido opcionalmente por hidrógeno, C₁₋₈-alquilo, aril-C₁₋₈-alquilo, C₃₋₈-cicloalquilo, arilo, heteroarilo, heterociclilo, C₁₋₈-alcoxicarbonil-C₁₋₈-alquilo, aril-C₁₋₈-alcoxicarbonil-C₁₋₈-alquilo y X e Y independientemente uno de otro significan O (oxígeno) o S (azufre).
ARP200102042A 2019-07-22 2020-07-21 N-fenil-n-amino-uracilos sustituidos, además de sus sales y su uso como sustancias activas herbicidas AR119447A1 (es)

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EP4230620A1 (de) 2022-02-22 2023-08-23 Bayer Aktiengesellschaft Substituierte n-amino-n´-benzoesäureuracile sowie deren salze und ihre verwendung als herbizide wirkstoffe
WO2023161172A1 (de) 2022-02-22 2023-08-31 Bayer Aktiengesellschaft Substituierte n-benzoesäureuracile sowie deren salze und ihre verwendung als herbizide wirkstoffe
WO2024104956A1 (de) 2022-11-16 2024-05-23 Bayer Aktiengesellschaft Substituierte cycloalkylsulfanylphenyluracile sowie deren salze und ihre verwendung als herbizide wirkstoffe
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