AR095078A1 - Método para potenciar propiedades de formación de espuma en composiciones de limpieza a través del uso de polímeros anfifílicos, no iónicos y dichas composiciones - Google Patents
Método para potenciar propiedades de formación de espuma en composiciones de limpieza a través del uso de polímeros anfifílicos, no iónicos y dichas composicionesInfo
- Publication number
- AR095078A1 AR095078A1 ARP140100779A ARP140100779A AR095078A1 AR 095078 A1 AR095078 A1 AR 095078A1 AR P140100779 A ARP140100779 A AR P140100779A AR P140100779 A ARP140100779 A AR P140100779A AR 095078 A1 AR095078 A1 AR 095078A1
- Authority
- AR
- Argentina
- Prior art keywords
- weight
- another aspect
- alkyl
- group
- monomers present
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 2
- 230000015572 biosynthetic process Effects 0.000 title 1
- 238000004140 cleaning Methods 0.000 title 1
- 239000006260 foam Substances 0.000 title 1
- 229920000831 ionic polymer Polymers 0.000 title 1
- 230000003389 potentiating effect Effects 0.000 title 1
- 239000000178 monomer Substances 0.000 abstract 12
- 125000000217 alkyl group Chemical group 0.000 abstract 5
- 125000002252 acyl group Chemical group 0.000 abstract 2
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- 229920001567 vinyl ester resin Polymers 0.000 abstract 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 abstract 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 125000002947 alkylene group Chemical group 0.000 abstract 1
- 239000003945 anionic surfactant Substances 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 abstract 1
- SYGWYBOJXOGMRU-UHFFFAOYSA-N chembl233051 Chemical compound C1=CC=C2C3=CC(C(N(CCN(C)C)C4=O)=O)=C5C4=CC=CC5=C3SC2=C1 SYGWYBOJXOGMRU-UHFFFAOYSA-N 0.000 abstract 1
- 238000004132 cross linking Methods 0.000 abstract 1
- 238000005187 foaming Methods 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 125000005504 styryl group Chemical group 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
- 125000003107 substituted aryl group Chemical group 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
- A61K8/8182—Copolymers of vinyl-pyrrolidones. Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
- A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0094—High foaming compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/54—Polymers characterized by specific structures/properties
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- General Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Chemical & Material Sciences (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Detergent Compositions (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Dispersion Chemistry (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201361774868P | 2013-03-08 | 2013-03-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR095078A1 true AR095078A1 (es) | 2015-09-16 |
Family
ID=50424734
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP140100779A AR095078A1 (es) | 2013-03-08 | 2014-03-10 | Método para potenciar propiedades de formación de espuma en composiciones de limpieza a través del uso de polímeros anfifílicos, no iónicos y dichas composiciones |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US9867768B2 (OSRAM) |
| EP (1) | EP2964187B1 (OSRAM) |
| JP (1) | JP6444899B2 (OSRAM) |
| KR (1) | KR20150126894A (OSRAM) |
| CN (1) | CN105025876A (OSRAM) |
| AR (1) | AR095078A1 (OSRAM) |
| BR (1) | BR112015021509A2 (OSRAM) |
| TW (1) | TWI607081B (OSRAM) |
| WO (1) | WO2014138327A1 (OSRAM) |
Families Citing this family (46)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2015100122A1 (en) * | 2013-12-23 | 2015-07-02 | Lubrizol Advanced Materials, Inc. | Suspension and stability agent for antidandruff hair care compositions |
| SG10201408339WA (en) * | 2014-12-12 | 2016-07-28 | Hock Cheong Automec Pte Ltd | A cleaning system and a method of cleaning a subject |
| CN107249558A (zh) * | 2014-12-18 | 2017-10-13 | 路博润先进材料公司 | 用于去屑护发组合物的两亲性悬浮剂和稳定剂 |
| WO2016172409A1 (en) | 2015-04-23 | 2016-10-27 | The Procter & Gamble Company | Delivery of surfactant soluble anti-dandruff agent |
| WO2017059255A1 (en) | 2015-10-01 | 2017-04-06 | PhotoDynamic Inc. | Novel polygonum cuspidatum extracts and their use as photodynamic inactivating agents |
| KR101626919B1 (ko) * | 2015-11-13 | 2016-06-13 | (주)리치케미칼 | 실리콘프리 샴푸 조성물 |
| AU2016366172B2 (en) * | 2015-12-08 | 2022-02-24 | Kemira Oyj | Liquid polymer compositions |
| CN108697609A (zh) | 2016-03-03 | 2018-10-23 | 宝洁公司 | 气溶胶去头皮屑组合物 |
| KR102643088B1 (ko) * | 2016-09-07 | 2024-03-04 | 주식회사 엘지생활건강 | 보습 효과가 우수한 세정제 조성물 |
| EP3528897A1 (en) | 2016-10-21 | 2019-08-28 | The Procter & Gamble Company | Dosage of foam for delivering consumer desired dosage volume, surfactant amount, and scalp health agent amount in an optimal formulation space |
| WO2018075847A1 (en) | 2016-10-21 | 2018-04-26 | The Procter & Gamble Company | Concentrated shampoo dosage of foam designating hair volume benefits |
| EP3528899B1 (en) | 2016-10-21 | 2024-04-10 | The Procter & Gamble Company | Dosage of foam for delivering consumer desired dosage volume and surfactant amount in an optimal formulation space |
| EP3528898A1 (en) | 2016-10-21 | 2019-08-28 | The Procter and Gamble Company | Concentrated shampoo dosage of foam designating hair conditioning benefits |
| CA3038128C (en) | 2016-10-21 | 2021-10-12 | The Procter & Gamble Company | Stable compact shampoo products with low viscosity and viscosity reducing agent |
| EP3528895A1 (en) | 2016-10-21 | 2019-08-28 | The Procter & Gamble Company | Concentrated shampoo dosage of foam for providing hair care benefits |
| US11141370B2 (en) | 2017-06-06 | 2021-10-12 | The Procter And Gamble Company | Hair compositions comprising a cationic polymer mixture and providing improved in-use wet feel |
| US11679073B2 (en) | 2017-06-06 | 2023-06-20 | The Procter & Gamble Company | Hair compositions providing improved in-use wet feel |
| US11224567B2 (en) * | 2017-06-06 | 2022-01-18 | The Procter And Gamble Company | Hair compositions comprising a cationic polymer/silicone mixture providing improved in-use wet feel |
| JP7154235B2 (ja) * | 2017-06-16 | 2022-10-17 | ダウ グローバル テクノロジーズ エルエルシー | オイルクレンザー組成物 |
| EP3688128B1 (en) * | 2017-09-28 | 2021-05-26 | Lubrizol Advanced Materials, Inc. | Polymeric thickener for iridescent liquid hand soap compositions |
| BR112020006666A2 (pt) * | 2017-10-05 | 2020-09-24 | Lubrizol Advanced Materials, Inc. | artigo dissolvível de dose unitária estruturado, e, processo para preparar um artigo dissolvível de dose unitária estruturado. |
| EP3694479A1 (en) | 2017-10-10 | 2020-08-19 | The Procter and Gamble Company | A method of treating hair or skin with a personal care composition in a foam form |
| MX384631B (es) | 2017-10-10 | 2025-03-14 | Procter & Gamble | Composición de limpieza personal clara libre de sulfato que comprende sal inorgánica inferior. |
| WO2019074991A1 (en) | 2017-10-10 | 2019-04-18 | The Procter & Gamble Company | COMPACT SHAMPOO COMPOSITION COMPRISING ANIONIC AMINO ACID SURFACTANTS AND CATIONIC POLYMERS |
| MX388495B (es) | 2017-10-10 | 2025-03-20 | Procter & Gamble | Composición de champú compacto que contiene surfactantes libres de sulfato. |
| US10912732B2 (en) | 2017-12-20 | 2021-02-09 | The Procter And Gamble Company | Clear shampoo composition containing silicone polymers |
| WO2019197626A1 (de) * | 2018-04-13 | 2019-10-17 | Evonik Degussa Gmbh | Opake zusammensetzung enthaltend ethylenglykoldistearat |
| JP7277083B2 (ja) * | 2018-06-12 | 2023-05-18 | ロレアル | 発泡性組成物 |
| WO2020005309A1 (en) | 2018-06-29 | 2020-01-02 | The Procter & Gamble Company | Low surfactant aerosol antidandruff composition |
| US12226505B2 (en) | 2018-10-25 | 2025-02-18 | The Procter & Gamble Company | Compositions having enhanced deposition of surfactant-soluble anti-dandruff agents |
| EP4069375A1 (en) | 2019-12-06 | 2022-10-12 | The Procter & Gamble Company | Sulfate free composition with enhanced deposition of scalp active |
| WO2021173203A1 (en) | 2020-02-27 | 2021-09-02 | The Procter & Gamble Company | Anti-dandruff compositions with sulfur having enhanced efficacy and aesthetics |
| CN115315243B (zh) * | 2020-03-24 | 2024-06-07 | 罗门哈斯公司 | 毛发清洁剂 |
| US11583478B2 (en) * | 2020-08-13 | 2023-02-21 | Godrej Consumer Products Limited | Reconstitutable powder |
| KR20230084578A (ko) * | 2020-10-14 | 2023-06-13 | 아반토 퍼포먼스 머티리얼즈, 엘엘씨 | 막 파열 조성물 및 이의 제조 방법과 사용 방법 |
| WO2022109094A1 (en) | 2020-11-23 | 2022-05-27 | The Procter & Gamble Company | Personal care compositions free of sulfated surfactants |
| CN114573802B (zh) * | 2020-12-02 | 2024-03-26 | 中国石油天然气股份有限公司 | 一种表面活性剂及其制备方法 |
| EP4255375B1 (en) | 2020-12-04 | 2025-08-13 | The Procter & Gamble Company | Hair care composition comprising malodor reduction materials |
| CN114751829B (zh) * | 2021-01-12 | 2024-07-26 | 中国石油天然气股份有限公司 | 含金刚烷结构的可聚合非离子表面活性剂及制备方法 |
| JP7645682B2 (ja) * | 2021-03-31 | 2025-03-14 | 株式会社フジミインコーポレーテッド | 表面処理組成物、表面処理組成物の製造方法、表面処理方法、及び半導体基板の製造方法 |
| WO2022226262A1 (en) * | 2021-04-22 | 2022-10-27 | Ethox Chemicals, Llc | Improved composition for wetting of hydrophobic soils |
| US12409125B2 (en) | 2021-05-14 | 2025-09-09 | The Procter & Gamble Company | Shampoo compositions containing a sulfate-free surfactant system and sclerotium gum thickener |
| US11986543B2 (en) | 2021-06-01 | 2024-05-21 | The Procter & Gamble Company | Rinse-off compositions with a surfactant system that is substantially free of sulfate-based surfactants |
| WO2023083995A1 (en) | 2021-11-12 | 2023-05-19 | Clariant International Ltd | Hand dish-washing composition containing ethoxylated glycerol esters |
| WO2023108097A1 (en) | 2021-12-09 | 2023-06-15 | The Procter & Gamble Company | Sulfate free personal cleansing composition comprising effective preservation |
| KR102802865B1 (ko) * | 2022-04-14 | 2025-04-30 | 엘지전자 주식회사 | 웨트 클리닝을 위한 세제 조성물 |
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| US20070009463A1 (en) | 2005-07-06 | 2007-01-11 | Niebauer Michael F | Rheology profile for a personal care composition |
| US7786027B2 (en) | 2006-05-05 | 2010-08-31 | The Procter & Gamble Company | Functionalized substrates comprising perfume microcapsules |
| WO2008004343A1 (fr) * | 2006-07-04 | 2008-01-10 | Kao Corporation | Composition de nettoyage de la peau |
| GB0617024D0 (en) | 2006-08-30 | 2006-10-11 | Unilever Plc | Hair treatment compositions incorporating hair substantive polymers |
| JP5778889B2 (ja) | 2006-11-09 | 2015-09-16 | ルブリゾル アドバンスド マテリアルズ， インコーポレイテッド | 刺激緩和ポリマーおよびその使用 |
| JP5245347B2 (ja) * | 2006-11-22 | 2013-07-24 | ライオン株式会社 | 毛髪化粧料 |
| US8105996B2 (en) | 2007-03-30 | 2012-01-31 | The Procter & Gamble Company | Multiphase personal care composition comprising a structuring |
| US8349300B2 (en) | 2007-04-19 | 2013-01-08 | The Procter & Gamble Company | Personal care compositions containing at least two cationic polymers and an anionic surfactant |
| FR2920969B1 (fr) | 2007-09-14 | 2009-12-18 | Oreal | Compositions cosmetiques contenant un copolymere cationique, une silicone aminee et un polymere cationique et leurs utilisations. |
| FR2920978B1 (fr) * | 2007-09-14 | 2012-04-27 | Oreal | Composition cosmetique comprenant un copolymere cationique et un amidon et procede de traitement cosmetique. |
| US9968535B2 (en) | 2007-10-26 | 2018-05-15 | The Procter & Gamble Company | Personal care compositions comprising undecyl sulfates |
| WO2009112420A1 (en) | 2008-03-14 | 2009-09-17 | Unilever Plc | Conditioning shampoo composition |
| EP2512685B1 (en) * | 2009-12-18 | 2015-07-22 | The Procter and Gamble Company | Personal care composition foaming product |
| BR112012024084A2 (pt) | 2010-03-26 | 2016-08-23 | Unilever Nv | composição de xampu método de fabricação de uma composição de xampu |
| US8338348B2 (en) | 2010-12-21 | 2012-12-25 | Johnson & Johnson Consumer Companies, Inc. | Skin cleansing compositions with polyglycerol esters and hydrophobically modified polymers |
| JP6162121B2 (ja) * | 2011-09-13 | 2017-07-12 | ルブリゾル アドバンスド マテリアルズ， インコーポレイテッド | 界面活性剤応答性エマルジョン重合ミクロゲル |
| KR101974993B1 (ko) * | 2011-09-13 | 2019-05-03 | 루브리졸 어드밴스드 머티어리얼스, 인코포레이티드 | 계면활성제 반응성 분산 중합된 마이크로-겔 |
| JP6438411B2 (ja) * | 2012-12-20 | 2018-12-12 | ルブリゾル アドバンスド マテリアルズ， インコーポレイテッド | 刺激緩和ポリマーおよびその使用 |
-
2014
- 2014-03-06 US US14/771,915 patent/US9867768B2/en active Active
- 2014-03-06 WO PCT/US2014/020982 patent/WO2014138327A1/en not_active Ceased
- 2014-03-06 CN CN201480012730.1A patent/CN105025876A/zh active Pending
- 2014-03-06 EP EP14714852.2A patent/EP2964187B1/en not_active Not-in-force
- 2014-03-06 JP JP2015561633A patent/JP6444899B2/ja not_active Expired - Fee Related
- 2014-03-06 KR KR1020157027314A patent/KR20150126894A/ko not_active Ceased
- 2014-03-06 BR BR112015021509A patent/BR112015021509A2/pt not_active Application Discontinuation
- 2014-03-07 TW TW103107799A patent/TWI607081B/zh not_active IP Right Cessation
- 2014-03-10 AR ARP140100779A patent/AR095078A1/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JP6444899B2 (ja) | 2018-12-26 |
| BR112015021509A2 (pt) | 2017-07-18 |
| EP2964187B1 (en) | 2018-08-15 |
| TW201500543A (zh) | 2015-01-01 |
| WO2014138327A1 (en) | 2014-09-12 |
| TWI607081B (zh) | 2017-12-01 |
| US20160022566A1 (en) | 2016-01-28 |
| US9867768B2 (en) | 2018-01-16 |
| EP2964187A1 (en) | 2016-01-13 |
| KR20150126894A (ko) | 2015-11-13 |
| CN105025876A (zh) | 2015-11-04 |
| JP2016512200A (ja) | 2016-04-25 |
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