AR092355A1 - Fluoruros de fluoropicolinoilo y procesos para su preparacion - Google Patents
Fluoruros de fluoropicolinoilo y procesos para su preparacionInfo
- Publication number
- AR092355A1 AR092355A1 ARP130102596A ARP130102596A AR092355A1 AR 092355 A1 AR092355 A1 AR 092355A1 AR P130102596 A ARP130102596 A AR P130102596A AR P130102596 A ARP130102596 A AR P130102596A AR 092355 A1 AR092355 A1 AR 092355A1
- Authority
- AR
- Argentina
- Prior art keywords
- compound
- formula
- halo
- group
- alkyl
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D213/54—Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/55—Acids; Esters
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/79—Acids; Esters
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/79—Acids; Esters
- C07D213/803—Processes of preparation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/79—Acids; Esters
- C07D213/803—Processes of preparation
- C07D213/807—Processes of preparation by oxidation of pyridines or condensed pyridines
Abstract
Reivindicación 1: Un proceso para la preparación de un compuesto fórmula (1) en donde: R se selecciona del grupo que consta de halo; alquilo, cicloalquilo; alquenilo; alquinilo; alcóxido y arilo sustituido con 0 a 5 sustituyentes seleccionados en forma independiente del grupo que consta de halo, alquilo C₁₋₄, haloalquilo C₁₋₄, alcóxido C₁₋₄ y haloalcóxido C₁₋₄; m es 0, 1, 2 ó 3; y n es 1, 2, 3 ó 4; en donde la suma de m y n resulta inferior o igual a 4; que consiste en la fluoración de un compuesto de la fórmula (2) en la que R, m y n son como se han descripto anteriormente; con una fuente de iones de fluoruro para producir el compuesto de la fórmula (1). Reivindicación 15: El proceso de la reivindicación 1 para la preparación de un compuesto de la fórmula (3) en la que: R es flúor o fenilo sustituido con 0 a 5 sustituyentes seleccionados en forma independiente del grupo que consta de halo, alquilo C₁₋₄, haloalquilo C₁₋₄, alcoxi C₁₋₄ y haloalcoxi C₁₋₄; y n es 1 ó 2; que comprende hacer reaccionar un compuesto de fórmula (4) en donde R y n son como se definieron anteriormente; con fluoruro de potasio en presencia de un éter corona y un solvente. Reivindicación 20: Un compuesto de la fórmula (1) en la que: R se selecciona del grupo que consta de halo; alquilo; cicloalquilo; alquenilo; alquinilo; alcoxi y arilo sustituido con 0 a 5 sustituyentes seleccionados en forma independiente del grupo que consta de halo, alquilo C₁₋₄, haloalquilo C₁₋₄, alcoxi C₁₋₄ y haloalcoxi C₁₋₄; m es 0,1, 2 ó 3; y n es 0, 1, 2, 3 ó 4; en donde la suma de m y n resulta entre 1 y 4.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201261675229P | 2012-07-24 | 2012-07-24 |
Publications (1)
Publication Number | Publication Date |
---|---|
AR092355A1 true AR092355A1 (es) | 2015-04-15 |
Family
ID=48998691
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP130102596A AR092355A1 (es) | 2012-07-24 | 2013-07-22 | Fluoruros de fluoropicolinoilo y procesos para su preparacion |
Country Status (22)
Country | Link |
---|---|
US (2) | US9045427B2 (es) |
EP (1) | EP2877452B1 (es) |
JP (1) | JP6062050B2 (es) |
KR (1) | KR101946680B1 (es) |
CN (1) | CN104583183B (es) |
AR (1) | AR092355A1 (es) |
AU (1) | AU2013293204B2 (es) |
BR (1) | BR112015001445B8 (es) |
CA (1) | CA2879518C (es) |
CO (1) | CO7200264A2 (es) |
ES (1) | ES2641724T3 (es) |
HK (1) | HK1210465A1 (es) |
IL (1) | IL236817B (es) |
IN (1) | IN2015DN01482A (es) |
MX (1) | MX351309B (es) |
NZ (1) | NZ704104A (es) |
PL (1) | PL2877452T3 (es) |
RU (1) | RU2627659C2 (es) |
TW (1) | TWI586650B (es) |
UY (1) | UY34945A (es) |
WO (1) | WO2014018506A1 (es) |
ZA (1) | ZA201500601B (es) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TW201609651A (zh) | 2013-11-12 | 2016-03-16 | 陶氏農業科學公司 | 用於氟化化合物之過程(一) |
TW201609652A (zh) | 2013-11-12 | 2016-03-16 | 陶氏農業科學公司 | 用於氟化化合物之過程(三) |
BR102014028164A2 (pt) * | 2013-11-12 | 2015-09-08 | Dow Agrosciences Llc | processo para fluoração de compostos |
TWI726900B (zh) | 2015-08-04 | 2021-05-11 | 美商陶氏農業科學公司 | 用於氟化化合物之過程 |
CN113233974A (zh) * | 2021-04-09 | 2021-08-10 | 山东领海生物科技有限公司 | 一种酰基氟化物的合成方法 |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SE385883B (sv) * | 1972-04-10 | 1976-07-26 | Ciba Geigy Ag | Forfarande for framstellning av nya pyridinkarbonsyraestrar |
JPS62181257A (ja) * | 1986-02-04 | 1987-08-08 | Asahi Glass Co Ltd | フルオロピリジン類の製造法 |
JP2520254B2 (ja) * | 1987-04-28 | 1996-07-31 | イハラケミカル工業株式会社 | 3,4,5−トリフルオロ安息香酸誘導体およびその製造方法 |
US4847442A (en) * | 1988-07-18 | 1989-07-11 | Allied-Signal Inc. | Process for the preparation of difluorobenzenes |
DK1498413T3 (da) * | 2000-01-14 | 2011-12-05 | Dow Agrosciences Llc | 4-aminopicolinater og deres anvendelse som herbicider |
US6297197B1 (en) * | 2000-01-14 | 2001-10-02 | Dow Agrosciences Llc | 4-aminopicolinates and their use as herbicides |
JP4608140B2 (ja) * | 2000-07-05 | 2011-01-05 | 石原産業株式会社 | ベンゾイルピリジン誘導体またはその塩、それらを有効成分として含有する殺菌剤、それらの製造方法ならびにそれらを製造するための中間体 |
AR037228A1 (es) | 2001-07-30 | 2004-11-03 | Dow Agrosciences Llc | Compuestos del acido 6-(aril o heteroaril)-4-aminopicolinico, composicion herbicida que los comprende y metodo para controlar vegetacion no deseada |
JP2003321406A (ja) * | 2002-04-30 | 2003-11-11 | Mitsubishi Gas Chem Co Inc | 高純度フルオロアルキルベンゼン誘導体及びその製造法 |
UA82358C2 (uk) | 2003-04-02 | 2008-04-10 | Дау Агросайенсиз Ллс | 6-алкіл або алкеніл-4-амінопіколінати гербіцидна композиція, спосіб боротьби з небажаною рослинністю |
DK1679003T3 (en) * | 2003-10-31 | 2015-05-11 | Ishihara Sangyo Kaisha | BACTERICID COMPOSITION AND PROCEDURE FOR COMBATING PLANT DISEASE |
JP5059779B2 (ja) | 2006-01-13 | 2012-10-31 | ダウ アグロサイエンシィズ エルエルシー | 6−(多置換アリール)−4−アミノピコリネートおよび除草剤としてのそれらの使用 |
TWI529163B (zh) | 2011-01-25 | 2016-04-11 | 陶氏農業科學公司 | 用於製備4-胺基-5-氟-3-鹵素-6-(經取代之)吡啶甲酸酯的方法 |
TWI537252B (zh) | 2011-01-25 | 2016-06-11 | 陶氏農業科學公司 | 用於製備4-胺基-5-氟-3-鹵素-6-(經取代之)吡啶甲酸酯的方法(一) |
AR091856A1 (es) * | 2012-07-24 | 2015-03-04 | Dow Agrosciences Llc | Proceso para la preparacion de 4-amino-5-fluor-3-halo-6-(substituido) picolinatos |
-
2013
- 2013-07-22 AR ARP130102596A patent/AR092355A1/es active IP Right Grant
- 2013-07-23 MX MX2015001138A patent/MX351309B/es active IP Right Grant
- 2013-07-23 CA CA2879518A patent/CA2879518C/en active Active
- 2013-07-23 CN CN201380042976.9A patent/CN104583183B/zh active Active
- 2013-07-23 NZ NZ704104A patent/NZ704104A/en unknown
- 2013-07-23 BR BR112015001445A patent/BR112015001445B8/pt active IP Right Grant
- 2013-07-23 AU AU2013293204A patent/AU2013293204B2/en active Active
- 2013-07-23 PL PL13750414T patent/PL2877452T3/pl unknown
- 2013-07-23 UY UY0001034945A patent/UY34945A/es active IP Right Grant
- 2013-07-23 ES ES13750414.8T patent/ES2641724T3/es active Active
- 2013-07-23 KR KR1020157004098A patent/KR101946680B1/ko active IP Right Grant
- 2013-07-23 RU RU2015106018A patent/RU2627659C2/ru active
- 2013-07-23 IN IN1482DEN2015 patent/IN2015DN01482A/en unknown
- 2013-07-23 US US13/949,053 patent/US9045427B2/en active Active
- 2013-07-23 EP EP13750414.8A patent/EP2877452B1/en active Active
- 2013-07-23 TW TW102126267A patent/TWI586650B/zh active
- 2013-07-23 WO PCT/US2013/051629 patent/WO2014018506A1/en active Application Filing
- 2013-07-23 JP JP2015524381A patent/JP6062050B2/ja active Active
-
2015
- 2015-01-20 IL IL236817A patent/IL236817B/en active IP Right Grant
- 2015-01-27 ZA ZA2015/00601A patent/ZA201500601B/en unknown
- 2015-02-05 CO CO15023712A patent/CO7200264A2/es unknown
- 2015-03-24 US US14/667,109 patent/US9376388B2/en active Active
- 2015-11-13 HK HK15111202.4A patent/HK1210465A1/xx unknown
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FG | Grant, registration |