AR081506A1 - Procedimiento para la produccion de acido formico - Google Patents

Procedimiento para la produccion de acido formico

Info

Publication number
AR081506A1
AR081506A1 ARP100102278A ARP100102278A AR081506A1 AR 081506 A1 AR081506 A1 AR 081506A1 AR P100102278 A ARP100102278 A AR P100102278A AR P100102278 A ARP100102278 A AR P100102278A AR 081506 A1 AR081506 A1 AR 081506A1
Authority
AR
Argentina
Prior art keywords
formic acid
liquid phase
amine
tertiary amine
free
Prior art date
Application number
ARP100102278A
Other languages
English (en)
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Publication of AR081506A1 publication Critical patent/AR081506A1/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
    • C07C51/44—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
    • C07C53/02—Formic acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/62—Reductions in general of inorganic substrates, e.g. formal hydrogenation, e.g. of N2
    • B01J2231/625—Reductions in general of inorganic substrates, e.g. formal hydrogenation, e.g. of N2 of CO2
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0237—Amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • B01J31/2414—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom comprising aliphatic or saturated rings
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

Reivindicación 1: Procedimiento para la producción de ácido fórmico por hidrogenación de dióxido de carbono en la presencia de un catalizador que contiene un elemento de los Grupos 8, 9 ó 10 del Sistema Periódico, una amina terciaria (l) y un solvente polar (III) bajo una presión de 0,2 bis 30 MPa abs y una temperatura de 20 a 200ºC con formación de dos fases líquidas, separación de una de las fases líquidas (A) enriquecida en el aducto ácido fórmico/amina (II) con respecto a la otra fase líquida (B), y reconducción de la fase líquida (B) hacia el reactor de hidrogenación, caracterizado porque (a) como amina terciaria (l) se emplea una amina que bajo una presión de 1013 hPa abs presenta un punto de ebullición que es superior en por lo menos 5ºC al punto de ebullición del ácido fórmico y que se halla enriquecida en la fase líquida (B); (b) como solvente polar (III) se emplea un solvente cuyo factor electrostático tiene un valor ³ 200×10-30 Cm y que bajo una presión de 1013 hPa abs presenta un punto de ebullición que es superior en al menos 5ºC al punto de ebullición del ácido fórmico y que se halla enriquecido en la fase líquida (A); (c) en una unidad de destilación se desdobla térmicamente el aducto ácido fórmico/amina (II) de la fase líquida separada (A), en ácido fórmico libre y amina terciaria libre (l); (d) se retira por destilación el ácido fórmico libre; y (e) se reconducen hacia el reactor de hidrogenación la amina terciaria libre (l) contenida en el sumidero de la unidad de destilación y el solvente polar (III).
ARP100102278A 2009-06-26 2010-06-25 Procedimiento para la produccion de acido formico AR081506A1 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP09008399 2009-06-26
EP10157452 2010-03-24

Publications (1)

Publication Number Publication Date
AR081506A1 true AR081506A1 (es) 2012-10-03

Family

ID=43127814

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP100102278A AR081506A1 (es) 2009-06-26 2010-06-25 Procedimiento para la produccion de acido formico

Country Status (13)

Country Link
EP (1) EP2445860B1 (es)
JP (1) JP5734286B2 (es)
KR (1) KR20120047239A (es)
CN (1) CN102574762B (es)
AR (1) AR081506A1 (es)
BR (1) BRPI1015062A2 (es)
CA (1) CA2765430A1 (es)
MY (1) MY159513A (es)
PL (1) PL2445860T3 (es)
RU (1) RU2012102459A (es)
SG (1) SG176855A1 (es)
WO (1) WO2010149507A2 (es)
ZA (1) ZA201200526B (es)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8901350B2 (en) 2010-06-29 2014-12-02 Basf Se Process for the preparation of formic acid
US8877965B2 (en) 2010-06-29 2014-11-04 Basf Se Process for preparing formic acid by reaction of carbon dioxide with hydrogen
US8791297B2 (en) 2010-06-29 2014-07-29 Basf Se Process for preparing formic acid by reaction of carbon dioxide with hydrogen
WO2012034991A1 (de) * 2010-09-17 2012-03-22 Basf Se Verfahren zur herstellung von formamiden
CA2821642A1 (en) * 2010-12-21 2012-06-28 Basf Se Method for producing formic acid by reacting carbon dioxide with hydrogen
DE102011000077A1 (de) 2011-01-11 2012-07-12 Rheinisch-Westfälische Technische Hochschule Aachen CO2-Hydrierungsverfahren zu Ameisensäure
RU2013158468A (ru) 2011-06-09 2015-07-20 Басф Се Способ получения муравьиной кислоты
US8742171B2 (en) 2011-06-09 2014-06-03 Basf Se Process for preparing formic acid
WO2013004577A1 (de) 2011-07-07 2013-01-10 Basf Se Verfahren zur herstellung von ameisensäure durch umsetzung von kohlendioxid mit wasserstoff
DE102012014159A1 (de) 2011-07-27 2013-01-31 Basf Se Verfahren zur Herstellung von Methylformiat
DE102012016959A1 (de) 2011-09-09 2013-03-14 Basf Se Verfahren zur Herstellung von Ameisensäure durch Umsetzung von Kohlendioxid mit Wasserstoff
IN2014DN03122A (es) * 2011-10-07 2015-05-22 Basf Se
DE102012021568A1 (de) 2011-11-10 2013-05-16 Basf Se Eisenkomplexverbindungen enthaltend Eisen und mindestens einen Phosphanliganden mit mindestens einem organischen Rest mit mindestens 12 Kohlenstoffatomen, Verfahren zur Herstellung von Ameisensäure und Verwendung der Eisenkomplexverbindungen als Katalysatoren für die Hydrierung von Kohlendioxid
US8946462B2 (en) 2011-11-10 2015-02-03 Basf Se Process for preparing formic acid by reaction of carbon dioxide with hydrogen
BR112014010923A2 (pt) * 2011-11-10 2017-04-18 Basf Se processo para a preparação de ácido fórmico, complexo de metal de transição, e, uso de um complexo de metal transição
DE102011087302A1 (de) * 2011-11-29 2013-05-29 Bayer Technology Services Gmbh Verfahren zur Umsetzung von Kohlendioxid und Bikarbonaten zu Ameisensäurederivaten unter Verwendung eines katalytischen Systems
US8835683B2 (en) * 2011-12-20 2014-09-16 Basf Se Process for preparing formic acid
EP2794539B1 (de) * 2011-12-20 2015-05-27 Basf Se Verfahren zur herstellung von ameisensäure
DE102012112404A1 (de) 2011-12-22 2013-06-27 Basf Se Verfahren zur kombinierten Herstellung von Ameisensäure, Methylformiat, Formamidverbindungen und Metallformiaten
CN102614769B (zh) * 2012-03-05 2014-04-16 华北电力大学（保定） 一种常压下将烟气中二氧化碳转化为甲酸的方法
WO2013186156A1 (en) 2012-06-11 2013-12-19 Basf Se Process for preparing formic acid
WO2015121476A1 (de) * 2014-02-17 2015-08-20 Bayer Technology Services Gmbh Verfahren zur hydrierung von kohlenstoffdioxid zu formiat
DE102015208706A1 (de) 2015-05-11 2016-11-17 Basf Se Verfahren zur Herstellung von Ameisensäure
DE102015208708A1 (de) 2015-05-11 2016-11-17 Basf Se Verfahren zur Herstellung von Ameisensäure
CN106380392B (zh) * 2016-08-29 2019-06-18 成都天成碳一化工有限公司 一种甲酸制备装置及其制备方法
CN110121490B (zh) * 2017-01-18 2022-04-08 株式会社大赛璐 乙酸的制备方法
JPWO2023163050A1 (es) 2022-02-25 2023-08-31
CN116808949B (zh) * 2023-08-29 2023-11-03 昆明贵金属研究所 二氧化碳加氢制甲酸连续反应装置

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4474959A (en) * 1982-05-22 1984-10-02 Bp Chemicals Limited Production of formate salts from carbon dioxide, hydrogen and amines
GB8401005D0 (en) * 1984-01-14 1984-02-15 Bp Chem Int Ltd Formate salts
GB8424672D0 (en) * 1984-09-29 1984-11-07 Bp Chem Int Ltd Production of formic acid
NZ227890A (en) * 1988-02-17 1992-02-25 Bp Chemical Ltd Production of formic acid from a nitrogenous base, carbon dioxide and hydrogen
DE68920933T2 (de) * 1988-08-20 1995-05-24 Bp Chem Int Ltd Produktion von Formiat-Salzen von Stickstoffbasen.
DE4227394A1 (de) * 1992-08-19 1994-02-24 Basf Ag Verfahren zur Herstellung von Ameisensäure aus Kohlenmonoxid und Wasser
DE102004040789A1 (de) * 2004-08-23 2006-03-02 Basf Ag Verfahren zur Herstellung von Ameisensäure
CA2681508A1 (en) * 2007-03-23 2008-10-02 Basf Se Process for preparing formic acid

Also Published As

Publication number Publication date
WO2010149507A3 (de) 2011-03-17
CN102574762B (zh) 2014-08-13
JP5734286B2 (ja) 2015-06-17
CA2765430A1 (en) 2010-12-29
SG176855A1 (en) 2012-01-30
PL2445860T3 (pl) 2013-10-31
ZA201200526B (en) 2013-03-27
JP2012530747A (ja) 2012-12-06
EP2445860A2 (de) 2012-05-02
MY159513A (en) 2017-01-13
EP2445860B1 (de) 2013-05-29
CN102574762A (zh) 2012-07-11
RU2012102459A (ru) 2013-08-10
KR20120047239A (ko) 2012-05-11
WO2010149507A2 (de) 2010-12-29
BRPI1015062A2 (pt) 2016-04-19

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