ZA201200526B - Method for producing formic acid - Google Patents

Method for producing formic acid

Info

Publication number
ZA201200526B
ZA201200526B ZA2012/00526A ZA201200526A ZA201200526B ZA 201200526 B ZA201200526 B ZA 201200526B ZA 2012/00526 A ZA2012/00526 A ZA 2012/00526A ZA 201200526 A ZA201200526 A ZA 201200526A ZA 201200526 B ZA201200526 B ZA 201200526B
Authority
ZA
South Africa
Prior art keywords
formic acid
producing formic
producing
acid
formic
Prior art date
Application number
ZA2012/00526A
Inventor
Thomas Schaub
Rocco Paciello
Klaus-Dieter Mohl
Daniel Schneider
Martin Schafer
Stefan Rittinger
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Publication of ZA201200526B publication Critical patent/ZA201200526B/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
    • C07C51/44—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
    • C07C53/02—Formic acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/62—Reductions in general of inorganic substrates, e.g. formal hydrogenation, e.g. of N2
    • B01J2231/625—Reductions in general of inorganic substrates, e.g. formal hydrogenation, e.g. of N2 of CO2
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0237—Amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • B01J31/2414—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom comprising aliphatic or saturated rings
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
ZA2012/00526A 2009-06-26 2012-01-23 Method for producing formic acid ZA201200526B (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP09008399 2009-06-26
EP10157452 2010-03-24
PCT/EP2010/058208 WO2010149507A2 (en) 2009-06-26 2010-06-11 Method for producing formic acid

Publications (1)

Publication Number Publication Date
ZA201200526B true ZA201200526B (en) 2013-03-27

Family

ID=43127814

Family Applications (1)

Application Number Title Priority Date Filing Date
ZA2012/00526A ZA201200526B (en) 2009-06-26 2012-01-23 Method for producing formic acid

Country Status (13)

Country Link
EP (1) EP2445860B1 (en)
JP (1) JP5734286B2 (en)
KR (1) KR20120047239A (en)
CN (1) CN102574762B (en)
AR (1) AR081506A1 (en)
BR (1) BRPI1015062A2 (en)
CA (1) CA2765430A1 (en)
MY (1) MY159513A (en)
PL (1) PL2445860T3 (en)
RU (1) RU2012102459A (en)
SG (1) SG176855A1 (en)
WO (1) WO2010149507A2 (en)
ZA (1) ZA201200526B (en)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8877965B2 (en) 2010-06-29 2014-11-04 Basf Se Process for preparing formic acid by reaction of carbon dioxide with hydrogen
US8901350B2 (en) 2010-06-29 2014-12-02 Basf Se Process for the preparation of formic acid
US8791297B2 (en) 2010-06-29 2014-07-29 Basf Se Process for preparing formic acid by reaction of carbon dioxide with hydrogen
WO2012034991A1 (en) * 2010-09-17 2012-03-22 Basf Se Method for producing formamides
RU2013133653A (en) * 2010-12-21 2015-01-27 Басф Се METHOD FOR PRODUCING FORMIC ACID AS A RESULT OF INTERACTION OF CARBON DIOXIDE WITH HYDROGEN
DE102011000077A1 (en) 2011-01-11 2012-07-12 Rheinisch-Westfälische Technische Hochschule Aachen CO2 hydrogenation process to formic acid
CA2837764A1 (en) 2011-06-09 2012-12-13 Basf Se Process for preparing formic acid
US8742171B2 (en) 2011-06-09 2014-06-03 Basf Se Process for preparing formic acid
WO2013004577A1 (en) 2011-07-07 2013-01-10 Basf Se Process for the preparation of formic acid by reacting carbon dioxide with hydrogen
DE102012014159A1 (en) 2011-07-27 2013-01-31 Basf Se Preparing methyl formate comprises e.g. homogeneous-catalyzed reaction of mixture of e.g. hydrogen, catalyst and tertiary amine compound, phase separation of hydrogenated mixture, and extraction of catalyst residue with the compound
DE102012016959A1 (en) 2011-09-09 2013-03-14 Basf Se Preparing formic acid, comprises e.g. reacting a reaction mixture comprising carbon dioxide, hydrogen, polar solvent and tertiary amine in presence of cationic complex catalyst into hydrogenation mixture including formic acid-amine-adduct
KR20140074373A (en) * 2011-10-07 2014-06-17 바스프 에스이 Method for producing formic acid by reacting carbon dioxide with hydrogen
EP2776448A1 (en) * 2011-11-10 2014-09-17 Basf Se Process for the preparation of formic acid by reaction of carbon dioxide with hydrogen
US8946462B2 (en) 2011-11-10 2015-02-03 Basf Se Process for preparing formic acid by reaction of carbon dioxide with hydrogen
DE102012021568A1 (en) 2011-11-10 2013-05-16 Basf Se New iron complex containing iron and phosphine ligand with specific organic group useful as catalyst for homogeneous-catalyzed conversion of reaction mixture e.g. containing hydrogen and carbon dioxide to form formic acid amine adduct
DE102011087302A1 (en) * 2011-11-29 2013-05-29 Bayer Technology Services Gmbh Process for the conversion of carbon dioxide and bicarbonates to formic acid derivatives using a catalytic system
EP2794539B1 (en) * 2011-12-20 2015-05-27 Basf Se Method for producing formic acid
US8835683B2 (en) * 2011-12-20 2014-09-16 Basf Se Process for preparing formic acid
DE102012112404A1 (en) 2011-12-22 2013-06-27 Basf Se Combined preparation of two target products comprising formic acid, methyl formate, formamide compounds or metal formate, comprises e.g. providing formic acid-amine adduct, and thermally splitting it to formic acid and tertiary amine
CN102614769B (en) * 2012-03-05 2014-04-16 华北电力大学（保定） Method for converting carbon dioxide in smoke into formic acid under normal pressure
EP2858970A1 (en) 2012-06-11 2015-04-15 Basf Se Process for preparing formic acid
WO2015121476A1 (en) * 2014-02-17 2015-08-20 Bayer Technology Services Gmbh Method for hydrogenating carbon dioxide into formate
DE102015208706A1 (en) 2015-05-11 2016-11-17 Basf Se Process for the preparation of formic acid
DE102015208708A1 (en) 2015-05-11 2016-11-17 Basf Se Process for the preparation of formic acid
CN106380392B (en) * 2016-08-29 2019-06-18 成都天成碳一化工有限公司 A kind of formic acid preparation facilities and preparation method thereof
MX2019008474A (en) * 2017-01-18 2019-09-18 Daicel Corp Acetic acid production method.
CN116808949B (en) * 2023-08-29 2023-11-03 昆明贵金属研究所 Continuous reaction device for preparing formic acid by carbon dioxide hydrogenation

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4474959A (en) * 1982-05-22 1984-10-02 Bp Chemicals Limited Production of formate salts from carbon dioxide, hydrogen and amines
GB8401005D0 (en) * 1984-01-14 1984-02-15 Bp Chem Int Ltd Formate salts
GB8424672D0 (en) * 1984-09-29 1984-11-07 Bp Chem Int Ltd Production of formic acid
NZ227890A (en) * 1988-02-17 1992-02-25 Bp Chemical Ltd Production of formic acid from a nitrogenous base, carbon dioxide and hydrogen
DE68920933T2 (en) * 1988-08-20 1995-05-24 Bp Chem Int Ltd Production of formate salts from nitrogen bases.
DE4227394A1 (en) * 1992-08-19 1994-02-24 Basf Ag Process for the production of formic acid from carbon monoxide and water
DE102004040789A1 (en) * 2004-08-23 2006-03-02 Basf Ag Process for the preparation of formic acid
JP2010521533A (en) * 2007-03-23 2010-06-24 ビーエーエスエフ ソシエタス・ヨーロピア Method for producing formic acid

Also Published As

Publication number Publication date
AR081506A1 (en) 2012-10-03
EP2445860B1 (en) 2013-05-29
SG176855A1 (en) 2012-01-30
MY159513A (en) 2017-01-13
CN102574762A (en) 2012-07-11
PL2445860T3 (en) 2013-10-31
KR20120047239A (en) 2012-05-11
JP5734286B2 (en) 2015-06-17
EP2445860A2 (en) 2012-05-02
CA2765430A1 (en) 2010-12-29
CN102574762B (en) 2014-08-13
WO2010149507A2 (en) 2010-12-29
BRPI1015062A2 (en) 2016-04-19
WO2010149507A3 (en) 2011-03-17
JP2012530747A (en) 2012-12-06
RU2012102459A (en) 2013-08-10

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