AR079898A2 - Preparacion de catalizador ziegler-natta y su uso para la polimerizacion de alquenos - Google Patents

Preparacion de catalizador ziegler-natta y su uso para la polimerizacion de alquenos

Info

Publication number
AR079898A2
AR079898A2 ARP110100117A ARP110100117A AR079898A2 AR 079898 A2 AR079898 A2 AR 079898A2 AR P110100117 A ARP110100117 A AR P110100117A AR P110100117 A ARP110100117 A AR P110100117A AR 079898 A2 AR079898 A2 AR 079898A2
Authority
AR
Argentina
Prior art keywords
support
magnesium
organo
mgr
mmol
Prior art date
Application number
ARP110100117A
Other languages
English (en)
Inventor
Frank Wolf Spaether
David Andrew Presken
Original Assignee
Novolen Tech Holdings Cv
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Novolen Tech Holdings Cv filed Critical Novolen Tech Holdings Cv
Publication of AR079898A2 publication Critical patent/AR079898A2/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/02—Carriers therefor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/651—Pretreating with non-metals or metal-free compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/06—Catalyst characterized by its size

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Un método para hacer un componente catalítico solido para un catalizador Ziegler-Natta que incluye poner en contacto un soporte poroso en partículas con una solucion de un compuesto precursor organo-magnesio soluble hidrocarburo en un solvente hidrocarburo; y hacer reaccionar dicho compuesto precursor organo-magnesio soluble hidrocarburo con una cantidad de alcohol alifático o aromático, estando dicha cantidad dentro de un rango aceptable de un equivalente molar de alcohol alifático o aromático calculado de acuerdo con la formula (1) EquAlcanol= 2(mmol MgR/g soporte) -2,1 - 0,55 % peso(H2O)/soporte)/ [mmol MgR/g soporte], en donde EquAlcanol = equivalente molar de alcanol alifático o aromático con respecto a la cantidad molar del precursor organo-magnesio, (mmol MgR/g soporte) = moles de precursor organo-magnesio por gramo de soporte solido en partículas, % peso(H2O)/soporte = porcentaje en peso del agua físicamente adsorbida en el soporte solido y dicho compuesto precursor magnesio orgánico es convertido en compuesto magnesio-oxígeno.
ARP110100117A 2004-09-07 2011-01-13 Preparacion de catalizador ziegler-natta y su uso para la polimerizacion de alquenos AR079898A2 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US10/935,211 US7329626B2 (en) 2004-09-07 2004-09-07 Ziegler-Natta catalyst, preparation, and use for the polymerization of alkenes

Publications (1)

Publication Number Publication Date
AR079898A2 true AR079898A2 (es) 2012-02-29

Family

ID=35501114

Family Applications (2)

Application Number Title Priority Date Filing Date
ARP050103709A AR052010A1 (es) 2004-09-07 2005-09-05 Preparacion de catalizador ziegler-natta y su uso para la polimerizacion de alquenos
ARP110100117A AR079898A2 (es) 2004-09-07 2011-01-13 Preparacion de catalizador ziegler-natta y su uso para la polimerizacion de alquenos

Family Applications Before (1)

Application Number Title Priority Date Filing Date
ARP050103709A AR052010A1 (es) 2004-09-07 2005-09-05 Preparacion de catalizador ziegler-natta y su uso para la polimerizacion de alquenos

Country Status (10)

Country Link
US (2) US7329626B2 (es)
EP (1) EP1805230A1 (es)
JP (1) JP2008512506A (es)
KR (1) KR101116650B1 (es)
CN (1) CN101035818B (es)
AR (2) AR052010A1 (es)
BR (1) BRPI0514961A (es)
TW (1) TWI351410B (es)
WO (1) WO2006028736A1 (es)
ZA (1) ZA200701930B (es)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8138264B2 (en) * 2007-05-04 2012-03-20 Fina Technology, Inc. Bimodal polyethylene resins that have high stiffness and high ESCR
KR101898315B1 (ko) * 2011-08-25 2018-09-12 도호 티타늄 가부시키가이샤 올레핀류 중합용 고체 촉매 성분의 제조 방법, 올레핀류 중합용 촉매 및 올레핀류 중합체의 제조 방법
EP2679609A1 (en) 2012-06-28 2014-01-01 Lummus Novolen Technology Gmbh Sterically demanding dialkoxydialkylsilanes as external donors for ziegler catalysts for the polymerization of propylene
CN102775533B (zh) * 2012-08-08 2014-09-03 中国石油天然气股份有限公司 含有有机镁化合物的烯烃聚合催化剂及其制备方法和应用
EP2743073A1 (en) * 2012-12-12 2014-06-18 Basell Poliolefine Italia S.r.l. Propylene-based terpolymers
USD689502S1 (en) 2013-01-18 2013-09-10 Swift Distribution, Inc. Device support apparatus
US10696765B2 (en) 2014-02-07 2020-06-30 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and propylene polymer
US9593179B2 (en) 2014-02-07 2017-03-14 Eastman Chemical Company Amorphous propylene-ethylene copolymers
US11267916B2 (en) 2014-02-07 2022-03-08 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins
US10647795B2 (en) 2014-02-07 2020-05-12 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins
US10723824B2 (en) 2014-02-07 2020-07-28 Eastman Chemical Company Adhesives comprising amorphous propylene-ethylene copolymers
US10308740B2 (en) 2014-02-07 2019-06-04 Eastman Chemical Company Amorphous propylene-ethylene copolymers
CN103880990B (zh) * 2014-04-07 2016-05-11 北京化工大学 烯烃配位聚合催化剂及其制备方法
WO2015177764A1 (en) * 2014-05-22 2015-11-26 Reliance Industries Limited A shape controlled pro-catalyst and a process for preparing the same
KR102232100B1 (ko) * 2017-05-18 2021-03-25 바셀 폴리올레핀 이탈리아 에스.알.엘 올레핀의 중합용 촉매 성분
EP3489244A1 (en) 2017-11-28 2019-05-29 Scg Chemicals Co. Ltd. Magnesium compound, method for producing the same and use thereof
CN108677380B (zh) * 2018-04-24 2020-06-09 北京弘暖纤科技有限公司 气凝胶改性聚丙烯、超轻隔热保温熔喷非织造布及其制备方法

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1141368A (en) 1979-01-10 1983-02-15 Imperial Chemical Industries Limited Olefine polymerisation catalyst and the production and use thereof
ZA814680B (en) * 1980-07-14 1982-07-28 Ici Ltd Transition metal composition production and use
US4378304A (en) * 1981-06-03 1983-03-29 Chemplex Company Catalyst and methods
JPH072775B2 (ja) 1985-01-28 1995-01-18 東燃株式会社 オレフイン重合用触媒成分の製造法
JPS6354407A (ja) * 1986-08-25 1988-03-08 Toa Nenryo Kogyo Kk エチレン・プロピレン共重合体ゴムの製造法
DE3713943A1 (de) 1987-04-25 1988-11-03 Basf Ag Verfahren zum herstellen von homo- und copolymerisaten des propens mittels eines ziegler-natta-katalysatorsystems
DE3730717A1 (de) 1987-09-12 1989-03-23 Basf Ag Verfahren zum herstellen von homo- und copolymerisaten des propens mittels eines ziegler-natta-katalysatorsystems
DE3829519A1 (de) 1988-08-31 1990-03-01 Basf Ag Verfahren zum herstellen von homo- und copolymerisaten des propens mittels eines ziegler-natta-katalysatorsystems
ATE164598T1 (de) 1995-08-09 1998-04-15 Basf Ag Katalysatorsysteme vom typ der ziegler-natta- katalysatoren
DE19623226A1 (de) 1996-06-11 1997-12-18 Basf Ag Katalysatorsysteme vom Typ der Ziegler-Natta-Katalysatoren
DE19637370A1 (de) 1996-09-13 1998-03-19 Basf Ag Bei ihrer Herstellung modifizierte Ziegler-Natta-Katalysatorsysteme
DE19726796A1 (de) 1997-06-24 1999-01-07 Basf Ag Propylenpolymerisate
US6232255B1 (en) * 1999-09-16 2001-05-15 Equistar Chemicals, Lp Olefin polymerization catalyst system
GB0001914D0 (en) * 2000-01-27 2000-03-22 Borealis Polymers Oy Catalyst
DE60101041T2 (de) 2001-01-30 2004-08-26 Borealis Technology Oy Magnesium, Titanium, Halogen und Elektronendonor-enthaltende Kalalysatorkomponente und deren Herstellung

Also Published As

Publication number Publication date
WO2006028736A1 (en) 2006-03-16
TWI351410B (en) 2011-11-01
AR052010A1 (es) 2007-02-28
EP1805230A1 (en) 2007-07-11
ZA200701930B (en) 2008-08-27
KR101116650B1 (ko) 2012-03-07
BRPI0514961A (pt) 2008-07-01
US7893175B2 (en) 2011-02-22
US20060052237A1 (en) 2006-03-09
CN101035818A (zh) 2007-09-12
US7329626B2 (en) 2008-02-12
TW200621819A (en) 2006-07-01
JP2008512506A (ja) 2008-04-24
US20080097051A1 (en) 2008-04-24
CN101035818B (zh) 2011-08-17
KR20070111442A (ko) 2007-11-21

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