AR078354A1 - Heterociclos herbicidas oxo y sulfono bis-nitrogenados - Google Patents

Heterociclos herbicidas oxo y sulfono bis-nitrogenados

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Publication number
AR078354A1
AR078354A1 ARP100103305A AR078354A1 AR 078354 A1 AR078354 A1 AR 078354A1 AR P100103305 A ARP100103305 A AR P100103305A AR 078354 A1 AR078354 A1 AR 078354A1
Authority
AR
Argentina
Prior art keywords
cycloalkyl
alkyl
phenyl
alkoxyalkyl
optionally substituted
Prior art date
Application number
Other languages
English (en)
Inventor
Patrick Ryan Kovacs
Andrew Edmund Taggi
Brenton Todd Smith
Kanu Maganbhai Patel
Thomas Paul Selby
Original Assignee
Du Pont
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Du Pont filed Critical Du Pont
Priority to PCT/US2011/027737 priority Critical patent/WO2012033548A2/en
Publication of AR078354A1 publication Critical patent/AR078354A1/es
Priority to UY33944A priority patent/UY33944A/es

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    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
    • C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
    • C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
    • C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
    • C07D239/32—One oxygen, sulfur or nitrogen atom
    • C07D239/34—One oxygen atom
    • C07D239/36—One oxygen atom as doubly bound oxygen atom or as unsubstituted hydroxy radical
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
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  • Organic Chemistry (AREA)
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  • Health & Medical Sciences (AREA)
  • Environmental Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
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Abstract

Compuestos de la Formula 1, incluyendo a todos los estereoisomeros, N-oxidos, y sales de éstos, X es CH o N; Y es C(O) o S(O)2; siempre y cuando Y sea S(O)2, entonces X es CH; A es un radical que se selecciona entre el grupo que consiste en el grupo de formulas 2. También se describen las composiciones que contienen los compuestos de Formula 1 y los métodos para controlar la vegetacion no deseada que comprende poner en contacto la vegetacion no deseada o su entorno con una cantidad eficaz de un compuesto o una composicion de la invencion. Reivindicacion 1: Un compuesto caracterizado porque se selecciona entre la formula 1, N-oxidos y sales de ellos, en donde X es CH; Y es C(O); A es un radical que se selecciona entre el grupo que consiste en el grupo de formulas 2; B1 y B3 son cada uno independientemente un radical que se selecciona entre el grupo que consiste en el grupo de formulas 3; B2 es un radical que se selecciona entre el grupo que consiste en el grupo de formulas 4; R1 es fenilo, fenilsulfonilo, -W1(fenilo), -W1(S-fenilo), -W1(SO2-fenilo), -W2(SO2CH2-fenilo) o -W2(SCH2-fenilo), cada uno sustituido opcionalmente en miembros del anillo con hasta cinco sustituyentes seleccionados entre R21 o -G o -W2G; o ciano, hidroxi, amino, -C(=O)OH, -C(=O)NHCN, -C(=O)NHOH, -SO2NH2, -SO2NHCN, -SO2NHOH, - NHCHO, alquilo C1-10, alquenilo C2-10, alquinilo C2-10, haloalquilo C1-10, haloalquenilo C2-10, haloalquenilo C2-12, cicloalquilo C3-12, halocicloalquilo C3-12, alquilcicloalquilo C4-14, cicloalquilalquilo C4-14, cicloalquilcicloalquilo C6-18, halocicloalquilalquilo C4-14, alquilcicloalquilalquilo C5-16, cicloalquenilo C3-12, halocicloalquenilo C3-12, alcoxialquilo C2-12, alcoxialquenilo C3-12, alquilcicloalquilo C4-14, alcoxicicloalquilo C4-14, cicloalcoxialquilo C4-14, cicloalcoxialcoxialquilo C5-14, alcoxialcoxialquilo C3-14, alquiltioalquilo C2-12, alquilsulfinilalquilo C2-12, alquilsulfonilalquilo C2-12, alquilaminoalquilo C2-12, dialquilaminoalquilo C3-14, haloalquilaminoalquilo C2-12, cicloalquilaminoalquilo C4-14, alquilcarbonilo C2-12, haloalquilcarbonilo C2-12, cicloalquilcarbonilo C4-14, alcoxicarbonilo C2-12, cicloalcoxicarbonilo C4-16, cicloalquilalcoxicarbonilo C5-14, alquilaminocarbonilo C2-12, dialquilaminocarbonilo C3-14, cicloalquilaminocarbonilo C4-14, cianoalquilo C2-9, hidroxialquilo C1-10, cicloalquenilo C4-14, haloalcoxialquilo C2-12, alcoxihaloalquilo C2-12, haloalcoxihaloalquilo C2-12, halocicloalcoxialquilo C4-14, cicloalqueniloxialquilo C4-14, halocicloalqueniloxialquilo C4-14, dialcoxialquilo C3-14, alcoxialquilcarbonilo C3-14, alcoxicarbonilalquilo C3-14, haloalcoxicarbonilo C2-12, alcoxi C1-10, haloalcoxi C1-10, cicloalcoxi C3-12, halocicloalcoxi C3-12, cicloalquilalcoxi C4-14, alqueniloxi C2-10, haloalqueniloxi C2-10, alquiniloxi C2-10, haloalquiniloxi C3-10, alcoxialcoxi C2-12, alquilcarboniloxi C2-12, haloalquilcarboniloxi C2-12, cicloalquilcarboniloxi C4-14, alquilcarbonilalcoxi C3-14, alquiltio C1-10, haloalquiltio C1-10, cicloalquiltio C3-12, alquilsulfinilo C1-10, haloalquilsulfinilo C1-10, alquilsulfonilo C1-10, haloalquilsulfonilo C1-10, cicloalquilsulfonilo C3-12, alquilcarboniltio C2-12, alquil(tiocarbonil)tio C2-12, cicloalquilsulfinilo C3-12, alquilaminosulfonilo C1-10, dialquilaminosulfonilo C2-12, alquilamino C1-10, dialquilamino C2-12, haloalquilamino C1-10, halodialquilamino C2-12, cicloalquilamino C3-12, alquilcarbonilamino C2-12, haloalquilcarbonilamino C2-12, alquilsulfonilamino C1-10, haloalquilsulfonilamino C1-10 o cicloalquil(alquil)amino C4-14, W1 es alquileno C1-6, alquenileno C2-6 o alquinileno C2-6 es alquileno C1-6, R2 es fenilo o -W3(fenilo), cada uno sustituido opcionalmente en miembros del anillo con hasta cinco sustituyentes seleccionados entre R21 o -G o -W4G; o H, ciano, hidroxi, amino, nitro, -CHO, -C(=O)OH, -C(=O)NH2, -C(=S)NH2, -C(=O)NHCN, -C(=O)NHOH, -SH, -SO2NH2, -SO2NHCN, -SO2NHOH, -SF5, -NHCHO, -NHNH2, -NHOH, -NHCN, -NHC(=O)NH2, alquilo C1-6, alquenilo C2-6, alquinilo C2-6, haloalquilo C1-6, haloalquenilo C2-6, haloalquinilo C2-6, cicloalquilo C3-8, halocicloalquilo C3-8, alquilcicloalquilo C4-10, cicloalquilalquilo C4-10, cicloalquilcicloalquilo C6-14, halocicloalquilalquilo C4-10, alquilcicloalquilalquilo C5-12, cicloalquenilo C3-8, halocicloalquenilo C3-8, alcoxialquilo C2-8, alcoxialquenilo C3-10, cicloalcoxialquilo C4-10, alcoxialcoxialquilo C3-10, alquiltioalquilo C2-8, alquilsulfinilalquilo C2-8, alquilsulfonilalquilo C2-8, alquilaminoalquilo C2-8, dialquilaminoalquilo C3-10, haloalquilaminoalquilo C2-8, cicloalquilaminoalquilo C4-10, alquilcarbonilo C2-8, haloalquilcarbonilo C2-8, cicloalquilcarbonilo C4-10, alcoxicarbonilo C2-8, cicloalcoxicarbonilo C4-10, cicloalquilalcoxicarbonilo C5-12, alquilaminocarbonilo C2-8, dialquilaminocarbonilo C3-10, cicloalquilaminocarbonilo C4-10, cianoalquilo C2-C5, hidroxialquilo C1-6, cicloalquenilalquilo C4-10, haloalcoxialquilo C2-8, alcoxihaloalquilo C2-8, haloalcoxihaloalquilo C2-8, halocicloalcoxialquilo C4-10, cicloalqueniloxialquilo C4-10, halocicloalqueniloxialquilo C4-10, dialcoxialquilo C3-10, alcoxialquilcarbonilo C3-10, alcoxicarbonilalquilo C3-10, haloalcoxicarbonilo C2-8, alcoxi C1-6, haloalcoxi C1-6, cicloalcoxi C3-8, halocicloalcoxi C3-8, cicloalquilalcoxi C4-10, alqueniloxi C2-6, haloalqueniloxi C2-6, alquiniloxi C2-6, haloalquiniloxi C3-6, alcoxialcoxi C2-8, alquilcarboniloxi C2-8, haloalquilcaboniloxi C2-8, cicloalquilcarboniloxi C4-10, alquilcarbonilalcoxi C3-10, alquiltio C1-6, haloalquiltio C1-6, cicloalquiltio C3-8, alquilsulfinilo C1-6, haloalquilsulfinilo C1-6, alquilsulfonilo C1-6, haloalquilsulfonilo C1-6, cicloalquilsulfonilo C3-8, trialquilsililo C3-8, cicloalqueniloxi C3-8, halocicloalqueniloxi C3-8, haloaIcoxialcoxi C2-8, alcoxihaloalcoxi C2-8, haloalcoxihaloalcoxi C2-8, alcoxicarbonilalcoxi C3-10, alquil(tiocarbonil)oxi C2-8, alquilcarboniltio C2-8, alquil(tiocarbonil)tio C2-8, cicloalquilsulfinilo C3-8, alquilaminosulfonilo C1-6, dialquilaminosulfonilo C2-8, halotrialquilsilio C3-10, alquilamino C1-6, dialquilamino C2-8, haloalquilamino C1-6, halodialquilamino C2-8, cicloalquilamino C3-8, alquilcarbonilamino C2-8, haloalquilcarbonilamino C2-8, alquilsulfonilamino C1-6, haloalquilsulfonilamino C1-6 o cicloalquil(alquil)amino C4-10 o R1 y R2 tomados junto a los átomos a los cuales se unen dan un anillo totalmente insaturado, parcialmente insaturado o insaturado de 5-, 6- o 7 miembros junto con miembros que consisten en hasta 2 átomos de oxígeno, 2 átomos de nitrogeno o 2 átomos de azufre o hasta dos grupos -S(O)-, -S(O)2-, -C(O)- opcionalmente sustituidos sobre los miembros del anillo que son átomos de carbono, seleccionados entre halogeno, ciano, alquilo C1-6, alquenilo C2-6, alquinilo C2-6, haloalquilo C1-6, cicloalquilo C3-8 y alcoxialquilo C2-8 y fenilo opcionalmente sustituido con hasta 5 sustituyentes seleccionados entre ciano, nitro, halogeno, alquilo C1-6, alcoxi C1-6 y haloalcoxi C1-6 y opcionalmente sustituidos sobre miembros del anillo que son nitrogeno con sustituyentes seleccionados entre H y alquilo C1-6 y fenilo opcionalmente sustituido con hasta 5 sustituyentes seleccionados entre ciano, nitro, halogeno, alquilo C1-6, alcoxi C1-6 y haloalcoxi C1-6; W3 es alquileno C1-6, alquenileno C2-6 o alquinileno C2-6; W4 es alquileno C1-6; R3 es H, halogeno, ciano, hidroxi, -O-M+, amino, nitro, -CHO, -C(=O)OH, -C(=O)NH2, -C(=S)NH2, -SH, -SO2NH2, -SO2NHCN, -SO2NHOH, -OCN, -SCN, -SF5, -NHNH2, -NHOH, -N=C=O, -N=C=S, alcoxi C1-6, haloalcoxi C1-6, cicloalcoxi C3-8, halocicloalcoxi C3-8, cicloalquilalcoxi C4-10, alqueniloxi C2-6, haloalqueniloxi C2-6, alquiniloxi C2-6, haloalquiniloxi C3-6, alcoxialcoxi C2-8, alquilcarboniloxi C2-8, haloalquilcarboniloxi C2-8, cicloalquilcarboniloxi C4-10, alquilcarbonilalcoxi C3-10, alquiltio C1-6, haloalquiltio C1-6, cicloalquiltio C3-8, alquilsulfinilo C1-6, haloalquilsulfinilo C1-6, alquilsulfonilo C1-6, haloalquilsulfonilo C1-6, cicloalquilsulfonilo C3-8, alquilsulfoniloxi C1-6, alquilamino C1-6, dialquilamino C2-8, haloalquilamino C1-6, halodialquilamino C2-8, cicloalquilamino C3-8, alquilcarbonilamino C2-8, haloalquilcarbonilamino C2-8, alquilsulfonilamino C1-6 o haloalquilsulfonilamino C1-6 o benciloxi, feniloxi, bencilcarboniloxi, fenilcarboniloxi, fenilsulfoniloxi, bencilsulfoniloxi, feniltio, benciltio, fenilsulfinilo, bencilsulfinilo, fenilsulfonilo o bencilsulfonilo, cada uno opcionalmente sustituido en los miembros del anillo con hasta cinco sustituyentes seleccionados entre R21 M+ es un cation de metal alcalino o un cation de amonio; R4, R5, R6 y R7 son cada uno independientemente H, halogeno, hidroxi, alquilo C1-6, alquenilo C2-6, alquinilo C2-6, haloalquilo C1-6, alcoxi C1-6, haloalcoxi C1-6, cicloalcoxi C3-8 o halocicloalcoxi C3-8 o fenilo o bencilo, cada uno opcionalmente sustituido en los miembros del anillo con hasta cinco sustituyentes seleccionados entre R21 R8 es H, alquilo C1-6, alquenilo C2-6, alquinilo C2-6, haloalquilo C1-6, haloalquenilo C2-6, haloalquinilo C2-6, cicloalquilo C3-8 o halocicloalquilo C3-8 o bencilo opcionalmente sustituido en los miembros del anillo con hasta cinco sustituyentes seleccionados entre R21; R9 es H, alquilo C1-6, alquenilo C2-6, alquinilo C2-6, haloalquilo C1-6, haloalquenilo C2-6, haloalquinilo C2-6, cicloalquilo C3-8, halocicloalquilo C3-8, alquilcicloalquilo C4-10, cicloalquilalquilo C4-10, cicloalquilcicloalquilo C6-14, halocicloalquilalquilo C4-10, alquilcicloalquilalquilo C5-12, cicloalquenilo C3-8, halocicloalquenilo C3-8, alcoxialquilo C2-8, cicloalcoxialquilo C4-10, alcoxialcoxialquilo C3-10 o alquiltioalquilo C2-8; R10 es H, halogeno, ciano, hidroxi, amino, nitro, SH, -SO2NH2, -SO2NHCN, -SO2NHOH, -OCN, -SCN, -SF5, -NHCHO, -NHNH2, -N3, -NHOH, -NHCN, -NHC(=O)NH2, -N=C=O, -N=C=S, alquilo C1-6, alquenilo C2-6, alquinilo C2-6, haloalquilo C1-6, haloalquenilo C2-6, haloalquinilo C2-6, cicloalquilo C3-8, halocicloalquilo C3-8, alquilcicloalquilo C4-10, cicloalquilalquilo C4-10, ciclo
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BR112012005200A2 (pt) 2021-02-02
UY33944A (es) 2012-10-31
JP2013504575A (ja) 2013-02-07
CN102596933B (zh) 2014-09-17
IL218481A0 (en) 2012-04-30
WO2011031658A1 (en) 2011-03-17
GT201200067A (es) 2014-04-08
US20150105549A1 (en) 2015-04-16
AU2010292400B2 (en) 2016-09-08
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US20160024020A1 (en) 2016-01-28
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CA2771588A1 (en) 2011-03-17
US9187432B2 (en) 2015-11-17
MY161631A (en) 2017-04-28
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EP2475654A1 (en) 2012-07-18
US9630928B2 (en) 2017-04-25
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