AR039414A1 - Procedimiento para la obtencion de formiato de metilo - Google Patents
Procedimiento para la obtencion de formiato de metiloInfo
- Publication number
- AR039414A1 AR039414A1 ARP030101312A ARP030101312A AR039414A1 AR 039414 A1 AR039414 A1 AR 039414A1 AR P030101312 A ARP030101312 A AR P030101312A AR P030101312 A ARP030101312 A AR P030101312A AR 039414 A1 AR039414 A1 AR 039414A1
- Authority
- AR
- Argentina
- Prior art keywords
- reactor
- gas stream
- procedure
- obtaining
- gas
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
- C07C69/04—Formic acid esters
- C07C69/06—Formic acid esters of monohydroxylic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Procedimiento para la obtención de formiato de metilo por reacción de metanol con monóxido de carbono a una presión de 0,5 a 10 Mpa abs y una temperatura de 50 a 150° C, en presencia de un alcoholato de metal como catalizador, en un reactor en el cual se elimina del reactor una corriente de gas, se separa de esta corriente de gas el formiato de metilo arrastrado por condensación y se recicla la restante corriente de gas parcial o completamente como corriente de gas de circulación al reactor, cuyo procedimiento está caracterizado porque por lo menos en un sector del reactor, en el que el gas circula básicamente en una dirección, se regula una velocidad de gas de tubo vacío media de 1 a 20 cm/s.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10217528A DE10217528A1 (de) | 2002-04-19 | 2002-04-19 | Verfahren zur Herstellung von Methylformiat |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR039414A1 true AR039414A1 (es) | 2005-02-16 |
Family
ID=28798593
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP030101312A AR039414A1 (es) | 2002-04-19 | 2003-04-15 | Procedimiento para la obtencion de formiato de metilo |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US7053239B2 (es) |
| EP (1) | EP1499579A1 (es) |
| JP (1) | JP4550431B2 (es) |
| KR (1) | KR100974123B1 (es) |
| CN (1) | CN1271038C (es) |
| AR (1) | AR039414A1 (es) |
| AU (1) | AU2003226810A1 (es) |
| BR (1) | BR0308912A (es) |
| DE (1) | DE10217528A1 (es) |
| MY (1) | MY138058A (es) |
| NO (1) | NO329097B1 (es) |
| WO (1) | WO2003089398A1 (es) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10321733A1 (de) * | 2003-05-14 | 2004-12-02 | Basf Ag | Verfahren zur Herstellung von ameisensauren Formiaten |
| CN1300094C (zh) * | 2004-05-14 | 2007-02-14 | 中国科学院大连化学物理研究所 | 一种二甲醚选择氧化制备甲酸甲酯的方法 |
| DE102009047503A1 (de) | 2008-12-10 | 2010-07-01 | Basf Se | Verfahren zur Herstellung von Methylformiat und Furan aus nachwachsenden Rohstoffen |
| US8957244B2 (en) * | 2012-11-26 | 2015-02-17 | Basf Se | Process for preparing methyl formate by reaction of methanol with carbon monoxide in the presence of a catalyst system comprising alkali metal formate and alkali metal alkoxide |
| CN103691451B (zh) * | 2014-01-07 | 2015-04-15 | 中国科学院福建物质结构研究所 | 一种气相甲醇羰基化合成甲酸甲酯的催化剂及其制备方法和应用 |
| EP3092072B1 (en) | 2014-01-07 | 2022-03-02 | Fujian Institute Of Research On The Structure Of Matter, Chinese Academy Of Sciences | A process for vapor-phase methanol carbonylation to methyl formate |
| CN109320410A (zh) * | 2018-11-22 | 2019-02-12 | 湖南湘硕化工有限公司 | 一种甲酸的制备方法 |
| KR20240086011A (ko) | 2022-12-09 | 2024-06-18 | 주식회사 현대폴리텍 | 고순도 메틸 포메이트 생산을 위한 효율적 촉매독 제거 장치 및 방법 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE863046C (de) | 1942-12-06 | 1953-01-15 | Degussa | Verfahren zur Herstellung von Estern der Ameisensaeure mit aliphatischen Alkoholen |
| DE880588C (de) * | 1943-08-03 | 1953-06-22 | Degussa | Verfahren zur Herstellung von Ameisensaeurealkylestern |
| DE926785C (de) | 1952-09-02 | 1955-04-25 | Knapsack Ag | Verfahren zur kontinuierlichen Herstellung von Estern der Ameisen-saeure durch Umsetzung von Kohlenoxyd mit aliphatischen Alkoholen, insbesondere Methylalkohol |
| DE1046602B (de) | 1957-12-13 | 1958-12-18 | Basf Ag | Verfahren zur kontinuierlichen Herstellung von Ameisensaeuremethylester |
| DE1147214B (de) | 1961-03-16 | 1963-04-18 | Basf Ag | Verfahren zur kontinuierlichen Herstellung von Ameisensaeuremethylester |
| GB1511961A (en) | 1976-03-12 | 1978-05-24 | Ucb Sa | Process for the production of methyl formate |
| US4661624A (en) | 1984-08-13 | 1987-04-28 | Chang Tsuan Y | Process for the production of methyl formate |
| DE3621362A1 (de) | 1986-06-26 | 1988-01-28 | Basf Ag | Verfahren zur herstellung von alkylformiaten |
| DE19506555A1 (de) | 1995-02-24 | 1996-08-29 | Basf Ag | Verfahren zur kontinuierlichen Herstellung von Methylformiat |
-
2002
- 2002-04-19 DE DE10217528A patent/DE10217528A1/de not_active Withdrawn
-
2003
- 2003-04-15 BR BR0308912-6A patent/BR0308912A/pt not_active IP Right Cessation
- 2003-04-15 AU AU2003226810A patent/AU2003226810A1/en not_active Abandoned
- 2003-04-15 KR KR1020047016706A patent/KR100974123B1/ko not_active IP Right Cessation
- 2003-04-15 CN CNB038088614A patent/CN1271038C/zh not_active Expired - Fee Related
- 2003-04-15 JP JP2003586119A patent/JP4550431B2/ja not_active Expired - Fee Related
- 2003-04-15 AR ARP030101312A patent/AR039414A1/es active IP Right Grant
- 2003-04-15 US US10/511,088 patent/US7053239B2/en not_active Expired - Fee Related
- 2003-04-15 WO PCT/EP2003/003902 patent/WO2003089398A1/de active Application Filing
- 2003-04-15 EP EP03746771A patent/EP1499579A1/de not_active Withdrawn
- 2003-04-17 MY MYPI20031440A patent/MY138058A/en unknown
-
2004
- 2004-10-19 NO NO20044447A patent/NO329097B1/no not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| NO329097B1 (no) | 2010-08-23 |
| CN1271038C (zh) | 2006-08-23 |
| US7053239B2 (en) | 2006-05-30 |
| NO20044447L (no) | 2004-11-18 |
| BR0308912A (pt) | 2005-01-04 |
| US20050143598A1 (en) | 2005-06-30 |
| MY138058A (en) | 2009-04-30 |
| WO2003089398A1 (de) | 2003-10-30 |
| CN1646469A (zh) | 2005-07-27 |
| DE10217528A1 (de) | 2003-11-06 |
| KR100974123B1 (ko) | 2010-08-04 |
| AU2003226810A1 (en) | 2003-11-03 |
| JP2006511440A (ja) | 2006-04-06 |
| JP4550431B2 (ja) | 2010-09-22 |
| EP1499579A1 (de) | 2005-01-26 |
| KR20040111533A (ko) | 2004-12-31 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Grant, registration |