ZA200601972B - Oxygen-scavenging compositions and the application thereof in packaging and containers - Google Patents
Oxygen-scavenging compositions and the application thereof in packaging and containers Download PDFInfo
- Publication number
- ZA200601972B ZA200601972B ZA200601972A ZA200601972A ZA200601972B ZA 200601972 B ZA200601972 B ZA 200601972B ZA 200601972 A ZA200601972 A ZA 200601972A ZA 200601972 A ZA200601972 A ZA 200601972A ZA 200601972 B ZA200601972 B ZA 200601972B
- Authority
- ZA
- South Africa
- Prior art keywords
- protic solvent
- halogen compound
- oxygen
- deposited
- hydrolysable halogen
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 60
- 238000004806 packaging method and process Methods 0.000 title description 12
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 29
- 239000001301 oxygen Substances 0.000 claims abstract description 29
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 29
- -1 Lewis acid salt Chemical class 0.000 claims abstract description 18
- 229910052751 metal Inorganic materials 0.000 claims abstract description 17
- 239000002184 metal Substances 0.000 claims abstract description 17
- 230000002000 scavenging effect Effects 0.000 claims abstract description 17
- 239000002923 metal particle Substances 0.000 claims abstract description 13
- 239000002904 solvent Substances 0.000 claims abstract description 11
- 239000003960 organic solvent Substances 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000002841 Lewis acid Substances 0.000 claims abstract 5
- 150000007517 lewis acids Chemical class 0.000 claims abstract 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 62
- 239000003586 protic polar solvent Substances 0.000 claims description 39
- 150000002366 halogen compounds Chemical class 0.000 claims description 36
- 229910052742 iron Inorganic materials 0.000 claims description 30
- 239000002245 particle Substances 0.000 claims description 26
- 229920000728 polyester Polymers 0.000 claims description 25
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 17
- 229920000642 polymer Polymers 0.000 claims description 17
- 150000001875 compounds Chemical class 0.000 claims description 15
- 239000007788 liquid Substances 0.000 claims description 15
- KKEYFWRCBNTPAC-UHFFFAOYSA-N terephthalic acid group Chemical group C(C1=CC=C(C(=O)O)C=C1)(=O)O KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 14
- 125000003118 aryl group Chemical group 0.000 claims description 13
- 229920001577 copolymer Polymers 0.000 claims description 12
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims description 12
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 9
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 7
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 7
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 6
- 239000002516 radical scavenger Substances 0.000 claims description 5
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 4
- 239000004952 Polyamide Substances 0.000 claims description 4
- KYTZHLUVELPASH-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid Chemical class C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 KYTZHLUVELPASH-UHFFFAOYSA-N 0.000 claims description 4
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- 229920000098 polyolefin Polymers 0.000 claims description 4
- 230000005540 biological transmission Effects 0.000 claims description 3
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- 239000004417 polycarbonate Substances 0.000 claims description 3
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 3
- 239000004800 polyvinyl chloride Substances 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 229910052801 chlorine Inorganic materials 0.000 claims description 2
- 239000007791 liquid phase Substances 0.000 claims description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims 4
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 claims 4
- 230000003993 interaction Effects 0.000 claims 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 3
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 2
- XHXFXVLFKHQFAL-UHFFFAOYSA-N phosphoryl trichloride Chemical compound ClP(Cl)(Cl)=O XHXFXVLFKHQFAL-UHFFFAOYSA-N 0.000 claims 2
- 229910019213 POCl3 Inorganic materials 0.000 claims 1
- 238000002835 absorbance Methods 0.000 claims 1
- 229920006149 polyester-amide block copolymer Polymers 0.000 claims 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims 1
- 238000001704 evaporation Methods 0.000 abstract description 3
- 239000007787 solid Substances 0.000 abstract description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 11
- 239000000047 product Substances 0.000 description 10
- 238000006116 polymerization reaction Methods 0.000 description 9
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 8
- 230000004888 barrier function Effects 0.000 description 7
- 239000003054 catalyst Substances 0.000 description 7
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 7
- 150000002148 esters Chemical class 0.000 description 7
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 6
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 6
- 150000002009 diols Chemical class 0.000 description 6
- 239000000463 material Substances 0.000 description 6
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- 125000001931 aliphatic group Chemical group 0.000 description 4
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 4
- 238000002425 crystallisation Methods 0.000 description 4
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- 150000005690 diesters Chemical class 0.000 description 4
- 239000003792 electrolyte Substances 0.000 description 4
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- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 4
- 239000011780 sodium chloride Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 229940123973 Oxygen scavenger Drugs 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 125000005907 alkyl ester group Chemical group 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 230000008021 deposition Effects 0.000 description 3
- 150000001991 dicarboxylic acids Chemical class 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
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- 239000004645 polyester resin Substances 0.000 description 3
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 3
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- 239000011347 resin Substances 0.000 description 3
- 239000007790 solid phase Substances 0.000 description 3
- 229920001169 thermoplastic Polymers 0.000 description 3
- QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 description 2
- VLDPXPPHXDGHEW-UHFFFAOYSA-N 1-chloro-2-dichlorophosphoryloxybenzene Chemical compound ClC1=CC=CC=C1OP(Cl)(Cl)=O VLDPXPPHXDGHEW-UHFFFAOYSA-N 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
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- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 2
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- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 description 2
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- FYSNRJHAOHDILO-UHFFFAOYSA-N thionyl chloride Chemical compound ClS(Cl)=O FYSNRJHAOHDILO-UHFFFAOYSA-N 0.000 description 2
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- 235000011285 magnesium acetate Nutrition 0.000 description 1
- 150000002690 malonic acid derivatives Chemical class 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 235000013372 meat Nutrition 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000010128 melt processing Methods 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 229910001507 metal halide Inorganic materials 0.000 description 1
- 150000005309 metal halides Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 125000002734 organomagnesium group Chemical group 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- BBJSDUUHGVDNKL-UHFFFAOYSA-J oxalate;titanium(4+) Chemical class [Ti+4].[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O BBJSDUUHGVDNKL-UHFFFAOYSA-J 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
- PVADDRMAFCOOPC-UHFFFAOYSA-N oxogermanium Chemical compound [Ge]=O PVADDRMAFCOOPC-UHFFFAOYSA-N 0.000 description 1
- VDGJOQCBCPGFFD-UHFFFAOYSA-N oxygen(2-) silicon(4+) titanium(4+) Chemical compound [Si+4].[O-2].[O-2].[Ti+4] VDGJOQCBCPGFFD-UHFFFAOYSA-N 0.000 description 1
- 229920006280 packaging film Polymers 0.000 description 1
- 239000012785 packaging film Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229920003207 poly(ethylene-2,6-naphthalate) Polymers 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000012667 polymer degradation Methods 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
- 150000003609 titanium compounds Chemical class 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 description 1
- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
- 150000003755 zirconium compounds Chemical class 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L3/00—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
- A23L3/34—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
- A23L3/3409—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of gases, e.g. fumigation; Compositions or apparatus therefor
- A23L3/3418—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of gases, e.g. fumigation; Compositions or apparatus therefor in a controlled atmosphere, e.g. partial vacuum, comprising only CO2, N2, O2 or H2O
- A23L3/3427—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of gases, e.g. fumigation; Compositions or apparatus therefor in a controlled atmosphere, e.g. partial vacuum, comprising only CO2, N2, O2 or H2O in which an absorbent is placed or used
- A23L3/3436—Oxygen absorbent
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L3/00—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
- A23L3/34—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/16—Metallic particles coated with a non-metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D81/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
- B65D81/24—Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants
- B65D81/26—Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants with provision for draining away, or absorbing, or removing by ventilation, fluids, e.g. exuded by contents; Applications of corrosion inhibitors or desiccators
- B65D81/266—Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants with provision for draining away, or absorbing, or removing by ventilation, fluids, e.g. exuded by contents; Applications of corrosion inhibitors or desiccators for absorbing gases, e.g. oxygen absorbers or desiccants
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/32—Hydrogen storage
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1334—Nonself-supporting tubular film or bag [e.g., pouch, envelope, packet, etc.]
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP03425549A EP1506718A1 (fr) | 2003-08-14 | 2003-08-14 | Compositions désoxygénantes et leur application dans les emballages et dans les boites |
Publications (1)
Publication Number | Publication Date |
---|---|
ZA200601972B true ZA200601972B (en) | 2007-05-30 |
Family
ID=33560917
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ZA200601972A ZA200601972B (en) | 2003-08-14 | 2004-08-11 | Oxygen-scavenging compositions and the application thereof in packaging and containers |
Country Status (15)
Country | Link |
---|---|
US (1) | US20060208218A1 (fr) |
EP (2) | EP1506718A1 (fr) |
JP (2) | JP4961616B2 (fr) |
KR (1) | KR101141531B1 (fr) |
CN (1) | CN1867269B (fr) |
AT (1) | ATE504217T1 (fr) |
AU (1) | AU2004264368C1 (fr) |
BR (1) | BRPI0412965A (fr) |
CA (1) | CA2535428A1 (fr) |
DE (1) | DE602004032148D1 (fr) |
ES (1) | ES2364049T3 (fr) |
MX (1) | MXPA06001798A (fr) |
RU (1) | RU2352182C2 (fr) |
WO (1) | WO2005016762A2 (fr) |
ZA (1) | ZA200601972B (fr) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BRPI0608033A2 (pt) * | 2005-02-28 | 2009-11-03 | M & G Polimeri Italia Spa | composição recuperadora de oxigênio ativada por água |
US7951419B2 (en) * | 2005-07-21 | 2011-05-31 | Multisorb Technologies, Inc. | Dry-coated oxygen-scavenging particles and methods of making them |
WO2007096422A1 (fr) * | 2006-02-25 | 2007-08-30 | M & G Polimeri Italia S.P.A. | Procédé de création d'une particule captant l'oxygène |
US8815360B2 (en) | 2007-08-28 | 2014-08-26 | Cryovac, Inc. | Multilayer film having passive and active oxygen barrier layers |
US9452592B2 (en) | 2007-08-28 | 2016-09-27 | Cryovac, Inc. | Multilayer film having an active oxygen barrier layer with radiation enhanced active barrier properties |
PL2417056T3 (pl) * | 2009-04-09 | 2018-06-29 | Colormatrix Holdings, Inc. | Kompozycja do pochłaniania tlenu, pojemnik, opakowanie i zamknięcie zawierające kompozycję |
EP2386598B1 (fr) * | 2010-05-12 | 2013-02-13 | Holland Colours N. V. | Compositions désoxygénantes |
US9161396B2 (en) | 2010-09-28 | 2015-10-13 | Koninklijke Philips N.V. | Light-emitting arrangement |
UA83861U (uk) * | 2013-08-06 | 2013-09-25 | Віталій Степанович Олексюк | Упаковка для неочищеного насіння соняшнику |
WO2021156908A1 (fr) * | 2020-02-03 | 2021-08-12 | 東洋製罐グループホールディングス株式会社 | Structure double |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1010548B (zh) * | 1987-06-20 | 1990-11-28 | 北京市食品研究所 | 袋装发酵泡菜的制作方法 |
JPS6463039A (en) * | 1987-09-01 | 1989-03-09 | Nippon Steel Corp | Production of deoxidant |
JP2754595B2 (ja) * | 1987-12-02 | 1998-05-20 | 三菱瓦斯化学株式会社 | 脱酸素剤包装体 |
JPH02298343A (ja) * | 1989-05-12 | 1990-12-10 | Toagosei Chem Ind Co Ltd | 酸素吸収剤の製造法 |
JPH0657319B2 (ja) * | 1990-08-03 | 1994-08-03 | 東洋製罐株式会社 | 酸素吸収剤及び該酸素吸収剤を用いた樹脂組成物並びに樹脂組成物からなるフィルム又はシート,包装用容器 |
US5744056A (en) * | 1993-07-16 | 1998-04-28 | Amoco Corporation | Oxygen-scavenging compositions and articles |
US5893233A (en) * | 1994-05-03 | 1999-04-13 | Board Of Regents Of The University Of Wisconsin System On Behalf Of The University Of Wisconsin-Milwaukee | Displacement of zebra mussels |
CA2165709A1 (fr) * | 1994-12-27 | 1996-06-28 | Tadatoshi Ogawa | Absorbeur d'oxygene |
JPH1180555A (ja) * | 1997-09-02 | 1999-03-26 | Kishimoto Akira | 酸素吸収性樹脂組成物及び包装容器 |
JP3460789B2 (ja) * | 1998-02-24 | 2003-10-27 | 三菱瓦斯化学株式会社 | 脱酸素性多層フィルム |
US6333087B1 (en) * | 1998-08-27 | 2001-12-25 | Chevron Chemical Company Llc | Oxygen scavenging packaging |
JP3785830B2 (ja) * | 1998-10-05 | 2006-06-14 | 味の素株式会社 | 鉄系酸素吸収性樹脂組成物及びこれを用いた包装材料・容器 |
JP4893978B2 (ja) * | 1999-02-26 | 2012-03-07 | 東亞合成株式会社 | 脱酸素性容器 |
JP2002080647A (ja) * | 2000-09-07 | 2002-03-19 | Mitsubishi Gas Chem Co Inc | 脱酸素剤樹脂組成物及びシート |
JP2002201360A (ja) * | 2000-12-28 | 2002-07-19 | Powdertech Co Ltd | 酸素吸収組成物、該組成物からなるフィルムまたはシート及び該組成物からなる層を有する酸素吸収積層フィルムまたはシート、該フィルムまたはシートからなる包装容器 |
US7687124B2 (en) * | 2001-07-26 | 2010-03-30 | M&G Usa Corporation | Oxygen-scavenging containers having low haze |
US7740926B2 (en) * | 2001-07-26 | 2010-06-22 | M&G Usa Corporation | Oxygen-scavenging containers |
-
2003
- 2003-08-14 EP EP03425549A patent/EP1506718A1/fr not_active Withdrawn
-
2004
- 2004-08-11 EP EP04763988A patent/EP1659888B1/fr not_active Not-in-force
- 2004-08-11 JP JP2006522976A patent/JP4961616B2/ja not_active Expired - Fee Related
- 2004-08-11 CA CA002535428A patent/CA2535428A1/fr not_active Abandoned
- 2004-08-11 CN CN200480030193XA patent/CN1867269B/zh not_active Expired - Fee Related
- 2004-08-11 DE DE602004032148T patent/DE602004032148D1/de active Active
- 2004-08-11 AT AT04763988T patent/ATE504217T1/de not_active IP Right Cessation
- 2004-08-11 US US10/568,212 patent/US20060208218A1/en not_active Abandoned
- 2004-08-11 ES ES04763988T patent/ES2364049T3/es active Active
- 2004-08-11 ZA ZA200601972A patent/ZA200601972B/en unknown
- 2004-08-11 AU AU2004264368A patent/AU2004264368C1/en not_active Ceased
- 2004-08-11 WO PCT/EP2004/008982 patent/WO2005016762A2/fr active Search and Examination
- 2004-08-11 RU RU2006107916/13A patent/RU2352182C2/ru not_active IP Right Cessation
- 2004-08-11 MX MXPA06001798A patent/MXPA06001798A/es active IP Right Grant
- 2004-08-11 KR KR1020067003104A patent/KR101141531B1/ko not_active IP Right Cessation
- 2004-08-11 BR BRPI0412965-2A patent/BRPI0412965A/pt active Search and Examination
-
2011
- 2011-10-14 JP JP2011227329A patent/JP5416187B2/ja not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
RU2006107916A (ru) | 2007-09-20 |
CN1867269B (zh) | 2011-02-02 |
EP1506718A1 (fr) | 2005-02-16 |
JP2012067307A (ja) | 2012-04-05 |
DE602004032148D1 (de) | 2011-05-19 |
WO2005016762A3 (fr) | 2005-04-28 |
AU2004264368B2 (en) | 2009-07-02 |
JP2007502336A (ja) | 2007-02-08 |
CN1867269A (zh) | 2006-11-22 |
AU2004264368A1 (en) | 2005-02-24 |
ES2364049T3 (es) | 2011-08-23 |
RU2352182C2 (ru) | 2009-04-20 |
JP5416187B2 (ja) | 2014-02-12 |
MXPA06001798A (es) | 2006-05-04 |
ATE504217T1 (de) | 2011-04-15 |
KR101141531B1 (ko) | 2012-05-04 |
JP4961616B2 (ja) | 2012-06-27 |
BRPI0412965A (pt) | 2006-09-26 |
WO2005016762A2 (fr) | 2005-02-24 |
KR20060109423A (ko) | 2006-10-20 |
US20060208218A1 (en) | 2006-09-21 |
EP1659888A2 (fr) | 2006-05-31 |
EP1659888B1 (fr) | 2011-04-06 |
CA2535428A1 (fr) | 2005-02-24 |
AU2004264368C1 (en) | 2009-12-17 |
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