ZA200507925B - Process for the preparation of a hydrogen-rich stream - Google Patents
Process for the preparation of a hydrogen-rich stream Download PDFInfo
- Publication number
- ZA200507925B ZA200507925B ZA200507925A ZA200507925A ZA200507925B ZA 200507925 B ZA200507925 B ZA 200507925B ZA 200507925 A ZA200507925 A ZA 200507925A ZA 200507925 A ZA200507925 A ZA 200507925A ZA 200507925 B ZA200507925 B ZA 200507925B
- Authority
- ZA
- South Africa
- Prior art keywords
- methanol
- shift
- hydrogen
- process according
- catalyst
- Prior art date
Links
- 229910052739 hydrogen Inorganic materials 0.000 title claims description 41
- 239000001257 hydrogen Substances 0.000 title claims description 40
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims description 36
- 238000000034 method Methods 0.000 title claims description 35
- 230000008569 process Effects 0.000 title claims description 33
- 238000002360 preparation method Methods 0.000 title claims description 5
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 201
- 239000003054 catalyst Substances 0.000 claims description 49
- 239000007789 gas Substances 0.000 claims description 42
- 239000007788 liquid Substances 0.000 claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 13
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 12
- 239000010949 copper Substances 0.000 claims description 12
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 11
- 229910052802 copper Inorganic materials 0.000 claims description 11
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 6
- 239000004411 aluminium Substances 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 6
- 229930195733 hydrocarbon Natural products 0.000 claims description 6
- 150000002430 hydrocarbons Chemical class 0.000 claims description 6
- 239000011701 zinc Substances 0.000 claims description 6
- 229910052725 zinc Inorganic materials 0.000 claims description 6
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 5
- 229910052804 chromium Inorganic materials 0.000 claims description 5
- 239000011651 chromium Substances 0.000 claims description 5
- 238000002407 reforming Methods 0.000 claims description 5
- 239000004215 Carbon black (E152) Substances 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 description 21
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 14
- 230000015572 biosynthetic process Effects 0.000 description 13
- 238000004519 manufacturing process Methods 0.000 description 11
- 238000003786 synthesis reaction Methods 0.000 description 10
- 229940105305 carbon monoxide Drugs 0.000 description 8
- 238000000629 steam reforming Methods 0.000 description 8
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 239000000446 fuel Substances 0.000 description 6
- 235000010210 aluminium Nutrition 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 5
- 229940057952 methanol Drugs 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 229910002090 carbon oxide Inorganic materials 0.000 description 4
- 229940107218 chromium Drugs 0.000 description 4
- 235000012721 chromium Nutrition 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000003345 natural gas Substances 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 238000002309 gasification Methods 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 208000012839 conversion disease Diseases 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- 239000002028 Biomass Substances 0.000 description 1
- 206010037660 Pyrexia Diseases 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 238000003421 catalytic decomposition reaction Methods 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000001651 catalytic steam reforming of methanol Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 230000002301 combined effect Effects 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- GBMDVOWEEQVZKZ-UHFFFAOYSA-N methanol;hydrate Chemical compound O.OC GBMDVOWEEQVZKZ-UHFFFAOYSA-N 0.000 description 1
- TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000004449 solid propellant Substances 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/48—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
- C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
- C01B3/24—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
- C01B3/26—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/323—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
- C01B2203/0288—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step containing two CO-shift steps
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1076—Copper or zinc-based catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
- C01B2203/143—Three or more reforming, decomposition or partial oxidation steps in series
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/148—Details of the flowsheet involving a recycle stream to the feed of the process for making hydrogen or synthesis gas
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DKPA200300499 | 2003-04-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA200507925B true ZA200507925B (en) | 2006-12-27 |
Family
ID=33104008
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200507926A ZA200507926B (en) | 2003-04-01 | 2004-03-25 | Process for the preparation of a hydrogen-rich stream |
| ZA200507925A ZA200507925B (en) | 2003-04-01 | 2004-03-25 | Process for the preparation of a hydrogen-rich stream |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200507926A ZA200507926B (en) | 2003-04-01 | 2004-03-25 | Process for the preparation of a hydrogen-rich stream |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US7527781B2 (es) |
| EP (1) | EP1613553A1 (es) |
| JP (1) | JP2006521989A (es) |
| KR (1) | KR20060002903A (es) |
| CN (2) | CN1856441A (es) |
| AU (1) | AU2004226236A1 (es) |
| CA (1) | CA2520988A1 (es) |
| MX (1) | MXPA05010538A (es) |
| RU (1) | RU2005133161A (es) |
| WO (1) | WO2004087567A1 (es) |
| ZA (2) | ZA200507926B (es) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101123052B1 (ko) * | 2003-11-17 | 2012-03-15 | 할도르 토프쉐 에이/에스 | 요소 제조방법 |
| CA2496839A1 (en) | 2004-07-19 | 2006-01-19 | Woodland Chemical Systems Inc. | Process for producing ethanol from synthesis gas rich in carbon monoxide |
| CN101227975A (zh) * | 2005-06-15 | 2008-07-23 | 俄亥俄州立大学 | 用于从水气转化反应生产氢气的催化剂 |
| BRPI0710578B1 (pt) * | 2006-04-05 | 2016-11-29 | Woodland Biofuels Inc | método de produção de etanol a partir de gás de síntese |
| CN101177240B (zh) * | 2007-11-09 | 2010-04-07 | 清华大学 | 一种集成式二甲醚水蒸气重整制氢装置及方法 |
| JP2011507666A (ja) * | 2007-12-26 | 2011-03-10 | ネルコー ピューリタン ベネット エルエルシー | 生理学的パラメーターに対する履歴傾向アイコン |
| GB0914500D0 (en) * | 2009-08-19 | 2009-09-30 | Johnson Matthey Plc | Process |
| DE102013104893A1 (de) * | 2013-05-13 | 2014-11-13 | L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude | Verfahren zur Inbetriebnahme einer Vorreformierungsstufe |
| EP3647264B1 (de) * | 2018-10-31 | 2023-10-11 | L'air Liquide, Société Anonyme Pour L'Étude Et L'exploitation Des Procédés Georges Claude | Verfahren und anlage zum herstellen eines gereinigten und konvertierten synthesegases |
| CN112960645B (zh) * | 2019-12-14 | 2022-08-05 | 中国科学院大连化学物理研究所 | 一种自热重整制氢反应用水汽变换反应器及提高水汽变换反应co转化率的方法 |
| CN110980642B (zh) * | 2019-12-30 | 2021-12-24 | 北京蓝玖新能源科技有限公司 | 一种制氢设备及其工艺和应用 |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4091086A (en) * | 1976-12-20 | 1978-05-23 | Engelhard Minerals & Chemicals Corporation | Process for production of hydrogen |
| DK147705C (da) * | 1982-09-07 | 1985-05-13 | Haldor Topsoe As | Fremgangsmaade til fremstilling af carbonhydrider ud fra syntesegas |
| JPS59203702A (ja) | 1983-05-04 | 1984-11-17 | Mitsubishi Heavy Ind Ltd | 水素の製造法 |
| JP3020984B2 (ja) | 1990-03-02 | 2000-03-15 | 株式会社東芝 | 燃料電池発電装置 |
| JP2755804B2 (ja) * | 1990-08-27 | 1998-05-25 | 株式会社東芝 | 水素製造方法 |
| US5830425A (en) * | 1993-02-09 | 1998-11-03 | Sud-Chemie Ag | Chromium-free catalyst based on iron oxide for conversion of carbon monoxide |
| US5498370A (en) * | 1994-12-15 | 1996-03-12 | Amoco Corporation | Process for hydroshifting dimethyl ether |
| US5990040A (en) * | 1995-01-11 | 1999-11-23 | United Catalysts Inc. | Promoted and stabilized copper oxide and zinc oxide catalyst and preparation |
| DK173416B1 (da) * | 1995-07-21 | 2000-10-02 | Topsoe Haldor As | Fremgangsmåde til fremstilling af hydrogenrig gas |
| GB9820608D0 (en) * | 1998-09-23 | 1998-11-11 | Ici Plc | Hydrogen |
| JP2000143209A (ja) * | 1998-11-05 | 2000-05-23 | Idemitsu Kosan Co Ltd | 一酸化炭素の転化方法および触媒 |
| DE10010069A1 (de) * | 2000-03-02 | 2001-09-20 | Xcellsis Gmbh | Verfahren zum Betreiben einer Gaserzeugungsvorrichtung bzw. eines Brennstoffzellensystems, Gaserzeugungsvorrichtung und Brennstoffzellensystem |
| DE10010070A1 (de) * | 2000-03-02 | 2001-09-20 | Xcellsis Gmbh | Gaserzeugungsvorrichtung |
| JP3496051B2 (ja) * | 2000-06-07 | 2004-02-09 | 独立行政法人産業技術総合研究所 | メタノールの酸化的水蒸気改質反応による水素ガス製造触媒及びその製造法 |
| DE10059674A1 (de) | 2000-12-01 | 2002-06-20 | Xcellsis Gmbh | Brennstoffzellensystem |
| DE10111198A1 (de) * | 2001-03-08 | 2002-09-19 | Basf Ag | Methanolreformierungskatalysator mit verringertem Volumenschwund |
| DE10111197A1 (de) * | 2001-03-08 | 2002-09-19 | Basf Ag | Verfahren zur Herstellung von Katalysatoren mit geringem Volumenschwund |
| JP2003010685A (ja) * | 2001-06-27 | 2003-01-14 | Nkk Corp | 水素製造触媒およびその製造方法ならびに水素を製造する方法 |
| JP4175452B2 (ja) * | 2001-08-07 | 2008-11-05 | 三菱重工業株式会社 | ジメチルエーテル改質触媒およびジメチルエーテル改質方法 |
-
2004
- 2004-03-25 CN CNA2004800090248A patent/CN1856441A/zh active Pending
- 2004-03-25 WO PCT/EP2004/003159 patent/WO2004087567A1/en not_active Application Discontinuation
- 2004-03-25 JP JP2006504860A patent/JP2006521989A/ja active Pending
- 2004-03-25 RU RU2005133161/15A patent/RU2005133161A/ru not_active Application Discontinuation
- 2004-03-25 CA CA002520988A patent/CA2520988A1/en not_active Abandoned
- 2004-03-25 AU AU2004226236A patent/AU2004226236A1/en not_active Abandoned
- 2004-03-25 ZA ZA200507926A patent/ZA200507926B/en unknown
- 2004-03-25 ZA ZA200507925A patent/ZA200507925B/en unknown
- 2004-03-25 KR KR1020057018604A patent/KR20060002903A/ko not_active Application Discontinuation
- 2004-03-25 US US10/548,802 patent/US7527781B2/en active Active
- 2004-03-25 MX MXPA05010538A patent/MXPA05010538A/es active IP Right Grant
- 2004-03-25 EP EP04723209A patent/EP1613553A1/en not_active Withdrawn
- 2004-03-25 CN CNB2004800088271A patent/CN1331731C/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JP2006521989A (ja) | 2006-09-28 |
| US7527781B2 (en) | 2009-05-05 |
| RU2005133161A (ru) | 2006-04-27 |
| CN1856441A (zh) | 2006-11-01 |
| KR20060002903A (ko) | 2006-01-09 |
| US20060165589A1 (en) | 2006-07-27 |
| MXPA05010538A (es) | 2005-11-23 |
| CN1768004A (zh) | 2006-05-03 |
| CN1331731C (zh) | 2007-08-15 |
| ZA200507926B (en) | 2006-12-27 |
| EP1613553A1 (en) | 2006-01-11 |
| AU2004226236A1 (en) | 2004-10-14 |
| CA2520988A1 (en) | 2004-10-14 |
| WO2004087567A1 (en) | 2004-10-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Vaidya et al. | Glycerol reforming for hydrogen production: a review | |
| EP2199254A1 (en) | Integrated gas refinery | |
| Zhang et al. | Process development of hydrogenous gas production for PEFC from biogas | |
| CN110177772B (zh) | 甲醇、氨和尿素的联合生产 | |
| NO20034284D0 (no) | Fremgangsmåte til fremstilling av syntesegass | |
| US7527781B2 (en) | Process for the preparation of a hydrogen-rich stream | |
| Van Bennekom et al. | Bench scale demonstration of the Supermethanol concept: The synthesis of methanol from glycerol derived syngas | |
| EP1613551B1 (en) | Process for the preparation of a hydrogen-rich stream | |
| Patcharavorachot et al. | Analysis of hydrogen production from methane autothermal reformer with a dual catalyst-bed configuration | |
| Katiyar et al. | Thermodynamic analysis for quantifying fuel cell grade H2 production by methanol steam reforming | |
| CA2546181C (en) | Process for the preparation of urea | |
| Daful et al. | Simulation of a NGCC Power Generation Plant for the Production of Electricity from CO 2 Emissions Part I: The Methanation Reactor | |
| MXPA06005449A (es) | Proceso para la preparacion de urea | |
| KR20240127968A (ko) | 수소-풍부 생성물을 생성하기 위한 방법 및 장치 | |
| AU2021226847A1 (en) | Co-production of methanol, ammonia and urea | |
| Ahmadi et al. | Efficient Recovery and Utilization of Co2 in a Methanol Plant by Innovative Combined Dry Reforming: Process Design and Environmental Assessment | |
| Tippawan et al. | Thermodynamic Evaluation of Ethanol Steam Reforming via Acetaldehyde as an Intermediate |