ZA200400972B - Non-zeolitic nanocomposite materials for solid acid catalysis. - Google Patents

Non-zeolitic nanocomposite materials for solid acid catalysis. Download PDF

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Publication number
ZA200400972B
ZA200400972B ZA200400972A ZA200400972A ZA200400972B ZA 200400972 B ZA200400972 B ZA 200400972B ZA 200400972 A ZA200400972 A ZA 200400972A ZA 200400972 A ZA200400972 A ZA 200400972A ZA 200400972 B ZA200400972 B ZA 200400972B
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South Africa
Prior art keywords
metal
catalytic compound
oxide
isomerization
dopant
Prior art date
Application number
ZA200400972A
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English (en)
Inventor
Jackie Y Ying
Jinsuo Xu
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Massachusetts Inst Technology
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Publication of ZA200400972B publication Critical patent/ZA200400972B/en

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00—Reforming naphtha
    • C10G35/04—Catalytic reforming
    • C10G35/06—Catalytic reforming characterised by the catalyst used
    • C10G35/085—Catalytic reforming characterised by the catalyst used containing platinum group metals or compounds thereof
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ZA200400972A 2001-08-07 2004-02-05 Non-zeolitic nanocomposite materials for solid acid catalysis. ZA200400972B (en)

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US (2) US6767859B2 (ko)
EP (1) EP1423193A4 (ko)
JP (1) JP2004537404A (ko)
KR (1) KR20040019394A (ko)
CN (1) CN1564711A (ko)
AR (1) AR035089A1 (ko)
BR (1) BR0211759A (ko)
CA (1) CA2456324A1 (ko)
EA (1) EA005912B1 (ko)
MX (1) MXPA04001273A (ko)
WO (1) WO2003013722A1 (ko)
ZA (1) ZA200400972B (ko)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7414007B2 (en) * 2002-09-13 2008-08-19 Uop Llc Isomerization catalyst and process
AU2003272375A1 (en) 2002-09-13 2004-04-30 Uop Llc Isomerization catalyst and process
ATE464120T1 (de) * 2002-09-25 2010-04-15 Haldor Topsoe As Verfahren zur isomerisierung von c7+ paraffinen und katalysator dafür
DE10319439A1 (de) * 2003-04-30 2004-11-18 Basf Ag Aktivierte Metathesekatalysatoren
US7825064B2 (en) 2003-06-03 2010-11-02 William Marsh Rice University Supported catalysts using nanoparticles as the support material
US7494953B2 (en) 2003-09-17 2009-02-24 Haldor Topsoe A/S Process for the preparation of an isomerisation catalyst
WO2005057163A2 (en) 2003-10-20 2005-06-23 William Marsh Rice University Method to fabricate microcapsules from polymers and charged nanoparticles
US7304199B2 (en) * 2004-04-14 2007-12-04 Abb Lummus Global Inc. Solid acid catalyst and method of using same
CN101052465A (zh) * 2004-10-26 2007-10-10 环球油品公司 异构化催化剂及方法
US20060270885A1 (en) * 2005-05-31 2006-11-30 Boyer Christopher C Normal heptane isomerization
US20070119748A1 (en) * 2005-11-28 2007-05-31 Konrad Herbst Process for the preparation of a paraffin isomerization catalyst
US7833933B2 (en) * 2005-11-28 2010-11-16 Haldor Topsøe A/S Process for the preparation of a paraffin isomerization catalyst
US20070167663A1 (en) * 2006-01-13 2007-07-19 Catalytic Distillation Technologies Isomerization of N-heptane in naphtha cuts
US20080032886A1 (en) * 2006-08-03 2008-02-07 Abb Lummus Global, Inc. Doped solid acid catalyst composition, process of conversion using same and conversion products thereof
US7659438B1 (en) 2009-02-17 2010-02-09 Conocophillips Company Isomerization of wet hexanes
US8426666B2 (en) * 2009-02-17 2013-04-23 Phillips 66 Company Isomerization of wet hexanes
US8153548B2 (en) 2010-04-19 2012-04-10 King Fahd University Of Petroleum & Minerals Isomerization catalyst
US8366907B2 (en) * 2010-08-02 2013-02-05 Battelle Memorial Institute Deoxygenation of fatty acids for preparation of hydrocarbons
DE102010050312A1 (de) 2010-11-03 2012-05-03 Süd-Chemie AG Ammoniak-Oxidationskatalysator mit geringer N2O Nebenproduktbildung
CN102407145B (zh) * 2011-10-24 2013-07-10 复旦大学 一种正庚烷异构化反应的催化剂及其制备方法
RU2486005C1 (ru) * 2012-02-03 2013-06-27 Федеральное Государственное Автономное Образовательное Учреждение Высшего Профессионального Образования "Сибирский Федеральный Университет" Оксидный катализатор для изомеризации легких бензиновых фракций
US10155908B2 (en) 2012-03-07 2018-12-18 Research Triangle Institute Catalyst compositions and use thereof in catalytic biomass pyrolysis
CN104822451B (zh) * 2012-12-04 2017-05-31 研究三角协会 催化剂组合物及其在催化生物质热解中的用途
CN108079988A (zh) * 2016-11-23 2018-05-29 中国科学院大连化学物理研究所 C5、c6烷烃异构化的催化剂及制备和应用
JP7158953B2 (ja) * 2017-08-18 2022-10-24 中国石油化工股▲ふん▼有限公司 重質芳香族炭化水素から軽質芳香族炭化水素を製造するための触媒、その製造方法及び適用
CN108940327B (zh) * 2018-06-02 2021-08-31 太原理工大学 一种硫碳基固体酸催化剂的制备方法
CN115397951A (zh) * 2019-08-02 2022-11-25 阿布扎比炼油公司泰克瑞尔 用于轻质重整产物的苯饱和/异构化的单反应器方法

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3879484A (en) * 1969-02-25 1975-04-22 Universal Oil Prod Co Hydrocarbon isomerization process
US3997618A (en) * 1970-03-20 1976-12-14 Engelhard Minerals & Chemicals Corporation Process for isomerizing alkyl benzenes
US3878089A (en) * 1972-03-10 1975-04-15 Universal Oil Prod Co Hydrocarbon conversion with a multimetallic catalytic composite
US4152246A (en) * 1973-11-23 1979-05-01 Compagnie Francaise De Raffinage Catalyzed processes for the hydrotreatment of hydrocarbons
US4197188A (en) * 1977-09-14 1980-04-08 Uop Inc. Hydrocarbon conversion with an attenuated superactive multimetallic catalytic composite
US4207209A (en) * 1977-10-26 1980-06-10 Hitachi, Ltd. Sintered cataltyic or absorbent metallic product and method for sintering metallic powders
JPS61153140A (ja) * 1984-12-26 1986-07-11 Res Assoc Util Of Light Oil 固体酸触媒の製造方法
EP0174836B1 (en) * 1984-09-10 1992-06-17 Research Association For Utilization Of Light Oil Solid strong acid catalyst
JPS61153141A (ja) * 1984-12-26 1986-07-11 Res Assoc Util Of Light Oil 固体酸触媒の製造方法
JPS6168137A (ja) * 1984-09-10 1986-04-08 Res Assoc Util Of Light Oil 固体酸触媒の製造方法
JPS61220738A (ja) * 1985-03-25 1986-10-01 Res Assoc Util Of Light Oil 固体強酸触媒の製造方法
US4808563A (en) * 1986-03-24 1989-02-28 The Standard Oil Company Molybdenum-tungsten-containing catalyst for methane conversion process
US4753916A (en) * 1986-09-17 1988-06-28 E. I. Du Pont De Nemours And Company Metal oxides of molybdenum or molybdenum and tungsten
EP0362960A3 (en) * 1988-10-05 1990-06-27 Sakai Chemical Industry Co., Ltd., Use of a catalyst composition for denitrization and denitrizing catalysts
DE4003939A1 (de) * 1990-02-09 1991-08-14 Degussa Katalysator fuer die reinigung der abgase von brennkraftmaschinen
CA2103876A1 (en) * 1992-08-27 1994-02-28 Stuart Leon Soled Group viii metal containing tungsten oxide silica modified zirconia as acid catalyst
ES2181957T3 (es) 1996-07-23 2003-03-01 Degussa Catalizador multimetalico y procedimiento para la preparacion de aminas aromaticas sustituidas.
JPH10195001A (ja) * 1997-01-09 1998-07-28 Japan Energy Corp メチルシクロペンタン含有炭化水素の製造方法
US6127432A (en) * 1998-01-29 2000-10-03 Union Carbide Chemicals & Plastics Technology Corporation Processes for preparing oxygenates and catalysts therefor
DE19813171C1 (de) * 1998-03-25 1999-11-25 Basf Ag Verfahren zur Herstellung von Spinell-Extrudaten

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