ZA200302273B - Continuous process for the preparation of a stable herbicidal aqueous suspension concentrate composition. - Google Patents
Continuous process for the preparation of a stable herbicidal aqueous suspension concentrate composition. Download PDFInfo
- Publication number
- ZA200302273B ZA200302273B ZA200302273A ZA200302273A ZA200302273B ZA 200302273 B ZA200302273 B ZA 200302273B ZA 200302273 A ZA200302273 A ZA 200302273A ZA 200302273 A ZA200302273 A ZA 200302273A ZA 200302273 B ZA200302273 B ZA 200302273B
- Authority
- ZA
- South Africa
- Prior art keywords
- process according
- mixture
- group
- suspension concentrate
- aqueous suspension
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims description 35
- 239000007900 aqueous suspension Substances 0.000 title claims description 18
- 239000012141 concentrate Substances 0.000 title claims description 16
- 238000002360 preparation method Methods 0.000 title claims description 12
- 230000002363 herbicidal effect Effects 0.000 title claims description 11
- 238000010924 continuous production Methods 0.000 title description 3
- 238000000034 method Methods 0.000 claims description 36
- 239000005591 Pendimethalin Substances 0.000 claims description 29
- CHIFOSRWCNZCFN-UHFFFAOYSA-N pendimethalin Chemical compound CCC(CC)NC1=C([N+]([O-])=O)C=C(C)C(C)=C1[N+]([O-])=O CHIFOSRWCNZCFN-UHFFFAOYSA-N 0.000 claims description 29
- 239000013078 crystal Substances 0.000 claims description 11
- 239000000575 pesticide Substances 0.000 claims description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 8
- 239000004009 herbicide Substances 0.000 claims description 8
- 239000004094 surface-active agent Substances 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 7
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 5
- 239000003755 preservative agent Substances 0.000 claims description 5
- ZRYCRPNCXLQHPN-UHFFFAOYSA-N 3-hydroxy-2-methylbenzaldehyde Chemical compound CC1=C(O)C=CC=C1C=O ZRYCRPNCXLQHPN-UHFFFAOYSA-N 0.000 claims description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- 239000007798 antifreeze agent Substances 0.000 claims description 4
- 230000002335 preservative effect Effects 0.000 claims description 4
- 239000002562 thickening agent Substances 0.000 claims description 4
- SQAINHDHICKHLX-UHFFFAOYSA-N 1-naphthaldehyde Chemical compound C1=CC=C2C(C=O)=CC=CC2=C1 SQAINHDHICKHLX-UHFFFAOYSA-N 0.000 claims description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 3
- 239000002518 antifoaming agent Substances 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- -1 ethyl 4-iso- thiazolin-3one Chemical compound 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 239000000375 suspending agent Substances 0.000 claims description 3
- 239000005631 2,4-Dichlorophenoxyacetic acid Substances 0.000 claims description 2
- NUPJIGQFXCQJBK-UHFFFAOYSA-N 2-(4-isopropyl-4-methyl-5-oxo-4,5-dihydro-1H-imidazol-2-yl)-5-(methoxymethyl)nicotinic acid Chemical compound OC(=O)C1=CC(COC)=CN=C1C1=NC(C)(C(C)C)C(=O)N1 NUPJIGQFXCQJBK-UHFFFAOYSA-N 0.000 claims description 2
- CLQMBPJKHLGMQK-UHFFFAOYSA-N 2-(4-isopropyl-4-methyl-5-oxo-4,5-dihydro-1H-imidazol-2-yl)nicotinic acid Chemical compound N1C(=O)C(C(C)C)(C)N=C1C1=NC=CC=C1C(O)=O CLQMBPJKHLGMQK-UHFFFAOYSA-N 0.000 claims description 2
- CABMTIJINOIHOD-UHFFFAOYSA-N 2-[4-methyl-5-oxo-4-(propan-2-yl)-4,5-dihydro-1H-imidazol-2-yl]quinoline-3-carboxylic acid Chemical compound N1C(=O)C(C(C)C)(C)N=C1C1=NC2=CC=CC=C2C=C1C(O)=O CABMTIJINOIHOD-UHFFFAOYSA-N 0.000 claims description 2
- IAJOBQBIJHVGMQ-UHFFFAOYSA-N 2-amino-4-[hydroxy(methyl)phosphoryl]butanoic acid Chemical compound CP(O)(=O)CCC(N)C(O)=O IAJOBQBIJHVGMQ-UHFFFAOYSA-N 0.000 claims description 2
- CAAMSDWKXXPUJR-UHFFFAOYSA-N 3,5-dihydro-4H-imidazol-4-one Chemical compound O=C1CNC=N1 CAAMSDWKXXPUJR-UHFFFAOYSA-N 0.000 claims description 2
- PVSGXWMWNRGTKE-UHFFFAOYSA-N 5-methyl-2-[4-methyl-5-oxo-4-(propan-2-yl)-4,5-dihydro-1H-imidazol-2-yl]pyridine-3-carboxylic acid Chemical compound N1C(=O)C(C(C)C)(C)N=C1C1=NC=C(C)C=C1C(O)=O PVSGXWMWNRGTKE-UHFFFAOYSA-N 0.000 claims description 2
- 239000005504 Dicamba Substances 0.000 claims description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 2
- 239000005561 Glufosinate Substances 0.000 claims description 2
- 239000005562 Glyphosate Substances 0.000 claims description 2
- 239000005566 Imazamox Substances 0.000 claims description 2
- 239000005981 Imazaquin Substances 0.000 claims description 2
- 229920001732 Lignosulfonate Polymers 0.000 claims description 2
- 239000005574 MCPA Substances 0.000 claims description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 2
- WHKUVVPPKQRRBV-UHFFFAOYSA-N Trasan Chemical compound CC1=CC(Cl)=CC=C1OCC(O)=O WHKUVVPPKQRRBV-UHFFFAOYSA-N 0.000 claims description 2
- 150000001558 benzoic acid derivatives Chemical class 0.000 claims description 2
- 239000004202 carbamide Substances 0.000 claims description 2
- 239000004927 clay Substances 0.000 claims description 2
- IWEDIXLBFLAXBO-UHFFFAOYSA-N dicamba Chemical compound COC1=C(Cl)C=CC(Cl)=C1C(O)=O IWEDIXLBFLAXBO-UHFFFAOYSA-N 0.000 claims description 2
- 235000011187 glycerol Nutrition 0.000 claims description 2
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 claims description 2
- 229940097068 glyphosate Drugs 0.000 claims description 2
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 claims description 2
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 claims description 2
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims description 2
- 229920005646 polycarboxylate Polymers 0.000 claims description 2
- 235000010232 propyl p-hydroxybenzoate Nutrition 0.000 claims description 2
- 239000004405 propyl p-hydroxybenzoate Substances 0.000 claims description 2
- QELSKZZBTMNZEB-UHFFFAOYSA-N propylparaben Chemical compound CCCOC(=O)C1=CC=C(O)C=C1 QELSKZZBTMNZEB-UHFFFAOYSA-N 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims description 2
- 235000010234 sodium benzoate Nutrition 0.000 claims description 2
- 239000004299 sodium benzoate Substances 0.000 claims description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims 2
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 claims 2
- 239000008098 formaldehyde solution Substances 0.000 claims 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 2
- IZUPBVBPLAPZRR-UHFFFAOYSA-N pentachlorophenol Chemical compound OC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl IZUPBVBPLAPZRR-UHFFFAOYSA-N 0.000 claims 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims 2
- NIFDAHUNJVFZAY-UHFFFAOYSA-N 1-nitropropane-1,3-diol Chemical compound OCCC(O)[N+]([O-])=O NIFDAHUNJVFZAY-UHFFFAOYSA-N 0.000 claims 1
- DBHODFSFBXJZNY-UHFFFAOYSA-N 2,4-dichlorobenzyl alcohol Chemical compound OCC1=CC=C(Cl)C=C1Cl DBHODFSFBXJZNY-UHFFFAOYSA-N 0.000 claims 1
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 claims 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- XVOKUMIPKHGGTN-UHFFFAOYSA-N Imazethapyr Chemical compound OC(=O)C1=CC(CC)=CN=C1C1=NC(C)(C(C)C)C(=O)N1 XVOKUMIPKHGGTN-UHFFFAOYSA-N 0.000 claims 1
- 229910019142 PO4 Inorganic materials 0.000 claims 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims 1
- DMSMPAJRVJJAGA-UHFFFAOYSA-N benzo[d]isothiazol-3-one Chemical compound C1=CC=C2C(=O)NSC2=C1 DMSMPAJRVJJAGA-UHFFFAOYSA-N 0.000 claims 1
- 229960004698 dichlorobenzyl alcohol Drugs 0.000 claims 1
- 235000010292 orthophenyl phenol Nutrition 0.000 claims 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 1
- 239000010452 phosphate Substances 0.000 claims 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical compound O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 claims 1
- PTMHPRAIXMAOOB-UHFFFAOYSA-N phosphoramidic acid Chemical compound NP(O)(O)=O PTMHPRAIXMAOOB-UHFFFAOYSA-N 0.000 claims 1
- 229960004838 phosphoric acid Drugs 0.000 claims 1
- 235000011007 phosphoric acid Nutrition 0.000 claims 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 229920002554 vinyl polymer Polymers 0.000 claims 1
- 239000004546 suspension concentrate Substances 0.000 description 7
- 239000000839 emulsion Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 239000002270 dispersing agent Substances 0.000 description 3
- 150000003871 sulfonates Chemical class 0.000 description 3
- 239000000080 wetting agent Substances 0.000 description 3
- 238000010923 batch production Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000000417 fungicide Substances 0.000 description 2
- 230000012010 growth Effects 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000002917 insecticide Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000008635 plant growth Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000002794 2,4-DB Substances 0.000 description 1
- UEJJHQNACJXSKW-UHFFFAOYSA-N 2-(2,6-dioxopiperidin-3-yl)-1H-isoindole-1,3(2H)-dione Chemical compound O=C1C2=CC=CC=C2C(=O)N1C1CCC(=O)NC1=O UEJJHQNACJXSKW-UHFFFAOYSA-N 0.000 description 1
- 101000742062 Bos taurus Protein phosphatase 1G Proteins 0.000 description 1
- HSSBORCLYSCBJR-UHFFFAOYSA-N Chloramben Chemical compound NC1=CC(Cl)=CC(C(O)=O)=C1Cl HSSBORCLYSCBJR-UHFFFAOYSA-N 0.000 description 1
- 101100345589 Mus musculus Mical1 gene Proteins 0.000 description 1
- 101100399552 Neisseria meningitidis serogroup B (strain MC58) lolD gene Proteins 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 230000009418 agronomic effect Effects 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000001010 compromised effect Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 101150114977 lolB gene Proteins 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- LZGUHMNOBNWABZ-UHFFFAOYSA-N n-nitro-n-phenylnitramide Chemical compound [O-][N+](=O)N([N+]([O-])=O)C1=CC=CC=C1 LZGUHMNOBNWABZ-UHFFFAOYSA-N 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 125000002924 primary amino group Chemical class [H]N([H])* 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/02—Amines; Quaternary ammonium compounds
- A01N33/12—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds containing nitrogen-to-oxygen bonds
- A01N33/18—Nitro compounds
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US22831600P | 2000-08-25 | 2000-08-25 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA200302273B true ZA200302273B (en) | 2004-07-15 |
Family
ID=22856665
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200302273A ZA200302273B (en) | 2000-08-25 | 2003-03-24 | Continuous process for the preparation of a stable herbicidal aqueous suspension concentrate composition. |
Country Status (18)
| Country | Link |
|---|---|
| US (1) | US6617280B2 (fr) |
| EP (1) | EP1313366B1 (fr) |
| AR (1) | AR030485A1 (fr) |
| AT (1) | ATE274300T1 (fr) |
| AU (1) | AU2001289832A1 (fr) |
| BG (1) | BG66154B1 (fr) |
| CZ (1) | CZ295651B6 (fr) |
| DE (1) | DE60105174T2 (fr) |
| DK (1) | DK1313366T3 (fr) |
| ES (1) | ES2225604T3 (fr) |
| HU (1) | HUP0300776A2 (fr) |
| IL (2) | IL154303A0 (fr) |
| PT (1) | PT1313366E (fr) |
| RU (1) | RU2003107843A (fr) |
| SK (1) | SK286830B6 (fr) |
| TR (1) | TR200402441T4 (fr) |
| WO (1) | WO2002015690A1 (fr) |
| ZA (1) | ZA200302273B (fr) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2346883T3 (es) * | 2003-04-14 | 2010-10-21 | Basf Se | Composicion acuosa fluida en forma de concentrado de pendimetalin. |
| AR075093A1 (es) | 2008-10-14 | 2011-03-09 | Basf Se | Complejos cristalinos de pendimetalina y metazachlor, proceso para prepararlos y composiciones agricolas que los contienen. |
| US8420574B2 (en) * | 2009-04-20 | 2013-04-16 | Valent Biosciences Corporation | Plant growth enhancement with combinations of PESA and herbicides |
| PL2453739T3 (pl) * | 2009-07-14 | 2014-03-31 | Basf Se | Sposób wytwarzania wodnej zawiesiny organicznego związku pestycydowego |
| JP6189136B2 (ja) * | 2013-08-22 | 2017-08-30 | 竹本油脂株式会社 | 水性懸濁農薬組成物 |
| US10492490B2 (en) * | 2015-03-06 | 2019-12-03 | Board Of Trustees Of Michigan State University | Adjuvant compositions and related methods for reducing herbicide volatility |
| CN110699418B (zh) * | 2019-11-14 | 2023-06-06 | 浙江星博生物科技股份有限公司 | 以非诊断为目的基于gc-ms精子计数的检测方法 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3337964A1 (de) * | 1983-10-19 | 1985-05-02 | Hoechst Ag, 6230 Frankfurt | Verfahren zur herstellung von pflanzenschutzmittel-dispersionen |
| US4871392A (en) | 1986-05-23 | 1989-10-03 | American Cyanamid Company | Aqueous suspension concentrate compositions of pendimethalin |
| US5624884A (en) * | 1986-05-23 | 1997-04-29 | American Cyanamid Company | Aqueous suspension concentrate compositions of pendimethalin |
| DE3916465A1 (de) * | 1989-05-20 | 1990-11-22 | Bayer Ag | Herstellung kugelfoermiger dispersionen durch kristallisation von emulsionen |
| FR2670085B1 (fr) * | 1990-12-10 | 1996-12-13 | Rhone Poulenc Chimie | Suspensions phytosanitaires. |
-
2001
- 2001-08-24 TR TR2004/02441T patent/TR200402441T4/xx unknown
- 2001-08-24 AU AU2001289832A patent/AU2001289832A1/en not_active Abandoned
- 2001-08-24 WO PCT/EP2001/009787 patent/WO2002015690A1/fr active IP Right Grant
- 2001-08-24 AT AT01969640T patent/ATE274300T1/de active
- 2001-08-24 HU HU0300776A patent/HUP0300776A2/hu unknown
- 2001-08-24 EP EP01969640A patent/EP1313366B1/fr not_active Expired - Lifetime
- 2001-08-24 PT PT01969640T patent/PT1313366E/pt unknown
- 2001-08-24 ES ES01969640T patent/ES2225604T3/es not_active Expired - Lifetime
- 2001-08-24 DE DE2001605174 patent/DE60105174T2/de not_active Expired - Lifetime
- 2001-08-24 RU RU2003107843/15A patent/RU2003107843A/ru not_active Application Discontinuation
- 2001-08-24 US US09/938,371 patent/US6617280B2/en not_active Expired - Fee Related
- 2001-08-24 AR ARP010104063A patent/AR030485A1/es unknown
- 2001-08-24 CZ CZ2003862A patent/CZ295651B6/cs not_active IP Right Cessation
- 2001-08-24 DK DK01969640T patent/DK1313366T3/da active
- 2001-08-24 SK SK351-2003A patent/SK286830B6/sk not_active IP Right Cessation
- 2001-08-24 IL IL15430301A patent/IL154303A0/xx active IP Right Grant
-
2003
- 2003-02-05 IL IL154303A patent/IL154303A/en unknown
- 2003-02-18 BG BG107567A patent/BG66154B1/bg unknown
- 2003-03-24 ZA ZA200302273A patent/ZA200302273B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE60105174D1 (de) | 2004-09-30 |
| IL154303A (en) | 2007-06-03 |
| CZ295651B6 (cs) | 2005-09-14 |
| PT1313366E (pt) | 2004-10-29 |
| DE60105174T2 (de) | 2005-01-13 |
| US6617280B2 (en) | 2003-09-09 |
| ES2225604T3 (es) | 2005-03-16 |
| WO2002015690A1 (fr) | 2002-02-28 |
| US20020128154A1 (en) | 2002-09-12 |
| IL154303A0 (en) | 2003-09-17 |
| DK1313366T3 (da) | 2004-10-04 |
| RU2003107843A (ru) | 2004-07-27 |
| AR030485A1 (es) | 2003-08-20 |
| BG66154B1 (bg) | 2011-09-30 |
| HUP0300776A2 (hu) | 2005-11-28 |
| SK286830B6 (sk) | 2009-06-05 |
| EP1313366B1 (fr) | 2004-08-25 |
| TR200402441T4 (tr) | 2004-12-21 |
| PL361388A1 (en) | 2004-10-04 |
| ATE274300T1 (de) | 2004-09-15 |
| BG107567A (bg) | 2004-08-31 |
| AU2001289832A1 (en) | 2002-03-04 |
| CZ2003862A3 (cs) | 2003-06-18 |
| EP1313366A1 (fr) | 2003-05-28 |
| SK3512003A3 (en) | 2003-09-11 |
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