ZA200006538B - Cellulose substrates with transparentized area and method of making same. - Google Patents
Cellulose substrates with transparentized area and method of making same. Download PDFInfo
- Publication number
- ZA200006538B ZA200006538B ZA200006538A ZA200006538A ZA200006538B ZA 200006538 B ZA200006538 B ZA 200006538B ZA 200006538 A ZA200006538 A ZA 200006538A ZA 200006538 A ZA200006538 A ZA 200006538A ZA 200006538 B ZA200006538 B ZA 200006538B
- Authority
- ZA
- South Africa
- Prior art keywords
- catalyst
- substrate
- transparentizing
- cellulosic substrate
- free radical
- Prior art date
Links
- 239000000758 substrate Substances 0.000 title claims description 176
- 238000004519 manufacturing process Methods 0.000 title description 11
- 229920002678 cellulose Polymers 0.000 title description 3
- 239000001913 cellulose Substances 0.000 title description 3
- 239000000203 mixture Substances 0.000 claims description 153
- 239000000463 material Substances 0.000 claims description 92
- 229920000647 polyepoxide Polymers 0.000 claims description 75
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims description 69
- 239000011951 cationic catalyst Substances 0.000 claims description 69
- 150000001875 compounds Chemical class 0.000 claims description 60
- 239000011953 free-radical catalyst Substances 0.000 claims description 60
- 229960000834 vinyl ether Drugs 0.000 claims description 59
- 239000000654 additive Substances 0.000 claims description 58
- 239000000470 constituent Substances 0.000 claims description 43
- 230000005855 radiation Effects 0.000 claims description 35
- 230000000996 additive effect Effects 0.000 claims description 26
- 150000003254 radicals Chemical class 0.000 claims description 25
- 125000002091 cationic group Chemical group 0.000 claims description 23
- 239000003054 catalyst Substances 0.000 claims description 20
- 239000007788 liquid Substances 0.000 claims description 16
- -1 fluoroalkyl vinyl ether Chemical compound 0.000 claims description 15
- 239000000178 monomer Substances 0.000 claims description 10
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 8
- 239000007787 solid Substances 0.000 claims description 8
- ZDQNWDNMNKSMHI-UHFFFAOYSA-N 1-[2-(2-prop-2-enoyloxypropoxy)propoxy]propan-2-yl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COCC(C)OC(=O)C=C ZDQNWDNMNKSMHI-UHFFFAOYSA-N 0.000 claims description 7
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 7
- 239000001294 propane Substances 0.000 claims description 7
- FEIQOMCWGDNMHM-UHFFFAOYSA-N 5-phenylpenta-2,4-dienoic acid Chemical compound OC(=O)C=CC=CC1=CC=CC=C1 FEIQOMCWGDNMHM-UHFFFAOYSA-N 0.000 claims description 6
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 claims description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 5
- 239000005977 Ethylene Substances 0.000 claims description 5
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 5
- 229920000147 Styrene maleic anhydride Polymers 0.000 claims description 5
- 125000000524 functional group Chemical group 0.000 claims description 5
- 229920000728 polyester Polymers 0.000 claims description 5
- JQXYBDVZAUEPDL-UHFFFAOYSA-N 2-methylidene-5-phenylpent-4-enoic acid Chemical compound OC(=O)C(=C)CC=CC1=CC=CC=C1 JQXYBDVZAUEPDL-UHFFFAOYSA-N 0.000 claims description 4
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 4
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 4
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 claims description 4
- 229910052740 iodine Inorganic materials 0.000 claims description 4
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 3
- 239000012965 benzophenone Substances 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 229920006395 saturated elastomer Polymers 0.000 claims description 3
- 229910052717 sulfur Inorganic materials 0.000 claims description 3
- 125000004434 sulfur atom Chemical group 0.000 claims description 3
- PIZHFBODNLEQBL-UHFFFAOYSA-N 2,2-diethoxy-1-phenylethanone Chemical compound CCOC(OCC)C(=O)C1=CC=CC=C1 PIZHFBODNLEQBL-UHFFFAOYSA-N 0.000 claims description 2
- NLGDWWCZQDIASO-UHFFFAOYSA-N 2-hydroxy-1-(7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-yl)-2-phenylethanone Chemical compound OC(C(=O)c1cccc2Oc12)c1ccccc1 NLGDWWCZQDIASO-UHFFFAOYSA-N 0.000 claims description 2
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical group C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- 238000006467 substitution reaction Methods 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- CYIGRWUIQAVBFG-UHFFFAOYSA-N 1,2-bis(2-ethenoxyethoxy)ethane Chemical compound C=COCCOCCOCCOC=C CYIGRWUIQAVBFG-UHFFFAOYSA-N 0.000 claims 1
- UMJOLBQCILNLDC-UHFFFAOYSA-N 1-(2-tert-butylphenyl)-2,2,2-trichloroethanone Chemical compound CC(C)(C)C1=CC=CC=C1C(=O)C(Cl)(Cl)Cl UMJOLBQCILNLDC-UHFFFAOYSA-N 0.000 claims 1
- 125000002947 alkylene group Chemical group 0.000 claims 1
- 125000004429 atom Chemical group 0.000 claims 1
- 125000005520 diaryliodonium group Chemical group 0.000 claims 1
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N dimethylmethane Natural products CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 238000000034 method Methods 0.000 description 38
- 238000007639 printing Methods 0.000 description 18
- 238000001723 curing Methods 0.000 description 17
- 230000008569 process Effects 0.000 description 15
- 230000035515 penetration Effects 0.000 description 13
- 239000002904 solvent Substances 0.000 description 11
- 238000000227 grinding Methods 0.000 description 9
- 239000000126 substance Substances 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 230000006835 compression Effects 0.000 description 7
- 238000007906 compression Methods 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 7
- 239000000976 ink Substances 0.000 description 7
- 239000011248 coating agent Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 238000004132 cross linking Methods 0.000 description 6
- 230000008901 benefit Effects 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 4
- 230000005012 migration Effects 0.000 description 4
- 238000013508 migration Methods 0.000 description 4
- 239000011941 photocatalyst Substances 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 3
- 238000003490 calendering Methods 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 238000012719 thermal polymerization Methods 0.000 description 3
- XFCMNSHQOZQILR-UHFFFAOYSA-N 2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOC(=O)C(C)=C XFCMNSHQOZQILR-UHFFFAOYSA-N 0.000 description 2
- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- 244000028419 Styrax benzoin Species 0.000 description 2
- 235000000126 Styrax benzoin Nutrition 0.000 description 2
- 235000008411 Sumatra benzointree Nutrition 0.000 description 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 229960002130 benzoin Drugs 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 125000003636 chemical group Chemical group 0.000 description 2
- 238000010894 electron beam technology Methods 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 235000019382 gum benzoic Nutrition 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000000123 paper Substances 0.000 description 2
- 239000003495 polar organic solvent Substances 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000003847 radiation curing Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- HIYIGPVBMDKPCR-UHFFFAOYSA-N 1,1-bis(ethenoxymethyl)cyclohexane Chemical compound C=COCC1(COC=C)CCCCC1 HIYIGPVBMDKPCR-UHFFFAOYSA-N 0.000 description 1
- OAMHTTBNEJBIKA-UHFFFAOYSA-N 2,2,2-trichloro-1-phenylethanone Chemical compound ClC(Cl)(Cl)C(=O)C1=CC=CC=C1 OAMHTTBNEJBIKA-UHFFFAOYSA-N 0.000 description 1
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 229920000298 Cellophane Polymers 0.000 description 1
- 206010073306 Exposure to radiation Diseases 0.000 description 1
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 description 1
- 150000008062 acetophenones Chemical class 0.000 description 1
- HFBMWMNUJJDEQZ-UHFFFAOYSA-N acryloyl chloride Chemical compound ClC(=O)C=C HFBMWMNUJJDEQZ-UHFFFAOYSA-N 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 229940052303 ethers for general anesthesia Drugs 0.000 description 1
- MHCLJIVVJQQNKQ-UHFFFAOYSA-N ethyl carbamate;2-methylprop-2-enoic acid Chemical class CCOC(N)=O.CC(=C)C(O)=O MHCLJIVVJQQNKQ-UHFFFAOYSA-N 0.000 description 1
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000011086 glassine Substances 0.000 description 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N hexane Substances CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical class I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000007641 inkjet printing Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000007648 laser printing Methods 0.000 description 1
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 description 1
- 239000011344 liquid material Substances 0.000 description 1
- VHRYZQNGTZXDNX-UHFFFAOYSA-N methacryloyl chloride Chemical compound CC(=C)C(Cl)=O VHRYZQNGTZXDNX-UHFFFAOYSA-N 0.000 description 1
- 150000002924 oxiranes Chemical class 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- IMACFCSSMIZSPP-UHFFFAOYSA-N phenacyl chloride Chemical compound ClCC(=O)C1=CC=CC=C1 IMACFCSSMIZSPP-UHFFFAOYSA-N 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 229920001909 styrene-acrylic polymer Polymers 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000012780 transparent material Substances 0.000 description 1
- 230000007723 transport mechanism Effects 0.000 description 1
- 125000005409 triarylsulfonium group Chemical group 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 150000007964 xanthones Chemical class 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/26—Agents rendering paper transparent or translucent
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/18—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only forming new compounds in situ, e.g. within the pulp or paper, by chemical reaction with itself, or other added substances, e.g. by grafting on the fibres
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H25/00—After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
- D21H25/04—Physical treatment, e.g. heating, irradiating
- D21H25/06—Physical treatment, e.g. heating, irradiating of impregnated or coated paper
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
- Y10T428/24934—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including paper layer
Landscapes
- Laminated Bodies (AREA)
- Paper (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
- Wrappers (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/104,573 US6103355A (en) | 1998-06-25 | 1998-06-25 | Cellulose substrates with transparentized area and method of making same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA200006538B true ZA200006538B (en) | 2002-02-11 |
Family
ID=22301200
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200006538A ZA200006538B (en) | 1998-06-25 | 2000-11-10 | Cellulose substrates with transparentized area and method of making same. |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US6103355A (fr) |
| EP (1) | EP1088132A1 (fr) |
| JP (1) | JP2002519526A (fr) |
| AU (1) | AU752118B2 (fr) |
| BR (1) | BR9911501A (fr) |
| CA (1) | CA2334314C (fr) |
| WO (1) | WO1999067465A1 (fr) |
| ZA (1) | ZA200006538B (fr) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8133421B2 (en) * | 1999-02-23 | 2012-03-13 | Warsaw Orthopedic, Inc. | Methods of making shaped load-bearing osteoimplant |
| US6358596B1 (en) * | 1999-04-27 | 2002-03-19 | The Standard Register Company | Multi-functional transparent secure marks |
| US6902770B1 (en) * | 2000-04-28 | 2005-06-07 | Infoseal L.L.C. | Method of transparentizing paper subtrate and paper assembly with transparentized window |
| JP4298217B2 (ja) * | 2002-04-18 | 2009-07-15 | 日華化学株式会社 | 紙用透明化剤及び透明紙の製造方法 |
| JP4162421B2 (ja) * | 2002-04-16 | 2008-10-08 | 日華化学株式会社 | 紙用透明化剤及び透明紙の製造方法 |
| US6677022B2 (en) | 2001-05-22 | 2004-01-13 | The Standard Register Company | Integrated waterproof card or label and method thereof |
| US20030015866A1 (en) * | 2001-07-19 | 2003-01-23 | Cioffi Mark M. | Integrated optical viewer for secure documents |
| US6607813B2 (en) | 2001-08-23 | 2003-08-19 | The Standard Register Company | Simulated security thread by cellulose transparentization |
| JP3676731B2 (ja) * | 2001-12-11 | 2005-07-27 | 大阪印刷インキ製造株式会社 | 透明加工紙およびその製造方法 |
| US20030181978A1 (en) * | 2002-03-25 | 2003-09-25 | Brown Kelly R. | Channeled biomedical foams and method for producing same |
| US20050252955A1 (en) * | 2004-05-17 | 2005-11-17 | Kiyoshi Sugai | Recyclable single-sheet mailer |
| US7641116B2 (en) * | 2005-10-31 | 2010-01-05 | Pitney Bowes Inc. | Vote by mail envelope |
| US7922208B2 (en) * | 2006-12-11 | 2011-04-12 | Pitney Bowes Inc. | Method and system for protecting privacy of signatures on mail ballots |
| US7673790B2 (en) * | 2007-06-25 | 2010-03-09 | Pitney Bowes Inc. | Vote by mail envelope that protects integrity of ballot during signature verification |
| US9623622B2 (en) | 2010-02-24 | 2017-04-18 | Michael Baines | Packaging materials and methods |
Family Cites Families (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL87862C (fr) * | 1951-08-20 | |||
| US3043805A (en) * | 1958-08-05 | 1962-07-10 | Du Pont | Polymeric amides and their preparation |
| US3261686A (en) * | 1963-04-23 | 1966-07-19 | Du Pont | Photopolymerizable compositions and elements |
| US3380831A (en) * | 1964-05-26 | 1968-04-30 | Du Pont | Photopolymerizable compositions and elements |
| US3469982A (en) * | 1968-09-11 | 1969-09-30 | Jack Richard Celeste | Process for making photoresists |
| US3661576A (en) * | 1970-02-09 | 1972-05-09 | Brady Co W H | Photopolymerizable compositions and articles |
| US3936557A (en) * | 1971-05-18 | 1976-02-03 | American Can Company | Epoxide blend for polymerizable coating compositions and process |
| US3813261A (en) * | 1971-07-23 | 1974-05-28 | Andrews Paper & Chem Co Inc | Transparentized fibrous materials and process for making same |
| US3936577A (en) * | 1971-12-15 | 1976-02-03 | E. I. Du Pont De Nemours & Company | Method for concomitant particulate diamond deposition in electroless plating, and the product thereof |
| US4128437A (en) * | 1973-11-26 | 1978-12-05 | Sumitomo Chemical Company, Limited | Transparentizing agent for paper |
| US4319009A (en) * | 1978-01-03 | 1982-03-09 | The Dow Chemical Company | Cycloaliphatic acrylate compositions |
| US4362848A (en) * | 1978-10-13 | 1982-12-07 | The Dow Chemical Co. | Cycloaliphatic acrylate compositions |
| US4198465A (en) * | 1978-11-01 | 1980-04-15 | General Electric Company | Photocurable acrylic coated polycarbonate articles |
| US4237185A (en) * | 1979-01-22 | 1980-12-02 | The Richardson Company | Radiation curable transparentizing resin systems, methods and products |
| US4271227A (en) * | 1979-04-26 | 1981-06-02 | Andrews Paper & Chemical Co., Inc. | Transparent fibrous sheets and process for making |
| US4279717A (en) * | 1979-08-03 | 1981-07-21 | General Electric Company | Ultraviolet curable epoxy silicone coating compositions |
| FR2524026B1 (fr) * | 1982-03-25 | 1985-09-13 | Arjomari Prioux | Matieres cellulosiques transparentisees et leurs applications, leur procede de fabrication et les compositions de transparentisation correspondantes |
| US4416950A (en) * | 1982-04-29 | 1983-11-22 | Andrews Paper & Chemical Co. | Transparent fibrous sheets |
| US4526803A (en) * | 1983-06-20 | 1985-07-02 | Baxter Travenol Laboratories, Inc. | Transparentizing |
| US4569888A (en) * | 1984-07-13 | 1986-02-11 | Andrews Paper & Chemical Co., Inc. | Transparentized paper sheet |
| GB2172550B (en) * | 1985-01-24 | 1988-11-16 | Svecia Antiqua Ltd | A method for the manufacture of a material in the form of paper sheets or a paper web provided with a watermarklike pattern. |
| US4761435A (en) * | 1986-10-03 | 1988-08-02 | Desoto, Inc. | Polyamine-polyene ultraviolet coatings |
| US4729506A (en) * | 1987-02-04 | 1988-03-08 | Transkrit Corporation | Mailer with transparent patch |
| US5055354A (en) * | 1989-07-27 | 1991-10-08 | Phomat Reprographics, Inc. | Transparentized paper and method for its manufacture |
| US5207871A (en) * | 1991-06-13 | 1993-05-04 | Dsm N.V. | Process for making transparent paper using a UV curable compositions of maleate, vinyl monomer and an allyl compound |
| US5232812A (en) * | 1992-09-18 | 1993-08-03 | Xerox Corporation | Method of forming images using curable liquid |
| JPH06280198A (ja) * | 1993-03-25 | 1994-10-04 | Toyo Ink Mfg Co Ltd | 紙用透明化処理剤 |
| US5418205A (en) * | 1993-04-15 | 1995-05-23 | The Standard Register Company | Cellulosic substrate with transparentized portion and carbonless imaging |
| US5663264A (en) * | 1993-12-27 | 1997-09-02 | Hitachi Chemical Company, Ltd. | Transparent resin and plastic lens |
| JP2949121B2 (ja) * | 1995-03-13 | 1999-09-13 | 桐山 義行 | 紫外線硬化方法 |
| JPH09119095A (ja) * | 1995-09-18 | 1997-05-06 | Xerox Corp | ベラムペーパのための硬化性樹脂透明化システム |
-
1998
- 1998-06-25 US US09/104,573 patent/US6103355A/en not_active Expired - Lifetime
-
1999
- 1999-06-09 AU AU44316/99A patent/AU752118B2/en not_active Ceased
- 1999-06-09 WO PCT/US1999/013047 patent/WO1999067465A1/fr active IP Right Grant
- 1999-06-09 CA CA002334314A patent/CA2334314C/fr not_active Expired - Fee Related
- 1999-06-09 BR BR9911501-8A patent/BR9911501A/pt not_active Application Discontinuation
- 1999-06-09 EP EP99927409A patent/EP1088132A1/fr not_active Withdrawn
- 1999-06-09 JP JP2000556102A patent/JP2002519526A/ja active Pending
-
2000
- 2000-11-10 ZA ZA200006538A patent/ZA200006538B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JP2002519526A (ja) | 2002-07-02 |
| WO1999067465A1 (fr) | 1999-12-29 |
| US6103355A (en) | 2000-08-15 |
| CA2334314A1 (fr) | 1999-12-29 |
| BR9911501A (pt) | 2001-03-20 |
| AU752118B2 (en) | 2002-09-05 |
| EP1088132A1 (fr) | 2001-04-04 |
| CA2334314C (fr) | 2007-01-09 |
| AU4431699A (en) | 2000-01-10 |
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