WO2022248215A1 - Method for producing alkali sulfonyl imide salts - Google Patents
Method for producing alkali sulfonyl imide salts Download PDFInfo
- Publication number
- WO2022248215A1 WO2022248215A1 PCT/EP2022/062660 EP2022062660W WO2022248215A1 WO 2022248215 A1 WO2022248215 A1 WO 2022248215A1 EP 2022062660 W EP2022062660 W EP 2022062660W WO 2022248215 A1 WO2022248215 A1 WO 2022248215A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- salt
- imide
- bis
- ppm
- onium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B21/00—Nitrogen; Compounds thereof
- C01B21/082—Compounds containing nitrogen and non-metals and optionally metals
- C01B21/087—Compounds containing nitrogen and non-metals and optionally metals containing one or more hydrogen atoms
- C01B21/093—Compounds containing nitrogen and non-metals and optionally metals containing one or more hydrogen atoms containing also one or more sulfur atoms
- C01B21/0935—Imidodisulfonic acid; Nitrilotrisulfonic acid; Salts thereof
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B21/00—Nitrogen; Compounds thereof
- C01B21/082—Compounds containing nitrogen and non-metals and optionally metals
- C01B21/086—Compounds containing nitrogen and non-metals and optionally metals containing one or more sulfur atoms
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B21/00—Nitrogen; Compounds thereof
- C01B21/082—Compounds containing nitrogen and non-metals and optionally metals
- C01B21/087—Compounds containing nitrogen and non-metals and optionally metals containing one or more hydrogen atoms
- C01B21/092—Compounds containing nitrogen and non-metals and optionally metals containing one or more hydrogen atoms containing also one or more metal atoms
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/54—Electrolytes
- H01G11/58—Liquid electrolytes
- H01G11/62—Liquid electrolytes characterised by the solute, e.g. salts, anions or cations therein
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0568—Liquid materials characterised by the solutes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/54—Electrolytes
- H01G11/58—Liquid electrolytes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Definitions
- EP 3203570 (Nippon Shokubai Co., Ltd.) discloses a method producing an electrolyte solution material containing a fluorosulfonylimide salt and a solvent, characterized in decompressing and/or heating a solution containing the fluorosulfonylimide salt and the electrolyte solution solvent to volatilize a fluorosulfonylimide salt production solvent.
- Step c) may be carried out at a temperature of between 0°C and 50°C, for example between 15°C and 35°C, and preferably at about room temperature.
- F- a fluoride (F-) content of below 100 ppm, preferably below 50 ppm, more preferably below 40 ppm, more preferably below 30 ppm, more preferably below 20 ppm;
- the alkali salt of FSI of the present invention is an alkali metal salt, preferably a lithium salt of bis(fluorosulfonyl)imide, Li + (FS02)2N ⁇ (LiFSI).
- the lithium salt of bis(fluorosulfonyl)imide may be characterized by the following impurity profile:
- a tri-necked 250m L glass flask was equipped with a thermometer, a mechanically-stirred 4-blades shaft and a screw-type solid-addition head, and was connected to a KOH-scrubber via PTFE tubing.
- the system was flushed with Argon over 30 min before use.
- Bis(chlorosulfonyl)imide (52.6 g, 243 mmol) was melted in a glovebox and canulated under Argon into the flask, then was pre-heated at about 50°C.
- Anhydrous ammonium chloride 13 g, 243 mmol was loaded into the solid dosing screw-type glass apparatus, and was gradually added over 0.5h under argon stripping and constant stirring.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Electrochemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Manufacturing & Machinery (AREA)
- General Chemical & Material Sciences (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Physics & Mathematics (AREA)
- Power Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US18/564,470 US20240246818A1 (en) | 2021-05-26 | 2022-05-10 | Method for producing alkali sulfonyl imide salts |
| JP2023571740A JP2024519378A (ja) | 2021-05-26 | 2022-05-10 | アルカリスルホニルイミド塩を生成する方法 |
| KR1020237039733A KR20240012388A (ko) | 2021-05-26 | 2022-05-10 | 알칼리 설포닐 이미드 염의 제조 방법 |
| EP22728544.2A EP4347484A1 (en) | 2021-05-26 | 2022-05-10 | Method for producing alkali sulfonyl imide salts |
| CN202280037074.5A CN117751090A (zh) | 2021-05-26 | 2022-05-10 | 用于生产磺酰亚胺碱盐的方法 |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP21305685 | 2021-05-26 | ||
| EP21305685.6 | 2021-05-26 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2022248215A1 true WO2022248215A1 (en) | 2022-12-01 |
Family
ID=76325473
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/EP2022/062660 Ceased WO2022248215A1 (en) | 2021-05-26 | 2022-05-10 | Method for producing alkali sulfonyl imide salts |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20240246818A1 (enExample) |
| EP (1) | EP4347484A1 (enExample) |
| JP (1) | JP2024519378A (enExample) |
| KR (1) | KR20240012388A (enExample) |
| CN (1) | CN117751090A (enExample) |
| WO (1) | WO2022248215A1 (enExample) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP4470972A1 (en) * | 2023-06-02 | 2024-12-04 | Specialty Operations France | Process for producing onium salts of bis(fluorosulfonyl)imide |
| WO2025032030A1 (en) * | 2023-08-07 | 2025-02-13 | Specialty Operations France | High purity ammonium bis(fluorosulfonyl)imide and method for its manufacturing |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116747900B (zh) * | 2023-05-25 | 2025-08-29 | 厦门中科易工化学科技有限公司 | 一种氯化铵蒸氨联产氯乙烯的方法 |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2674395A1 (en) | 2011-02-10 | 2013-12-18 | Nippon Soda Co., Ltd. | Process for production of fluorosulfonylimide ammonium salt |
| WO2015158979A1 (fr) | 2014-04-18 | 2015-10-22 | Arkema France | Preparation d'imides contenant un groupement fluorosulfonyle |
| WO2017090877A1 (ko) | 2015-11-26 | 2017-06-01 | 임광민 | 리튬 비스(플루오르술포닐)이미드의 신규한 제조방법 |
| EP3203570A1 (en) | 2014-10-03 | 2017-08-09 | Nippon Shokubai Co., Ltd. | Method for manufacturing electrolyte material |
| WO2019229361A2 (fr) | 2018-06-01 | 2019-12-05 | Arkema France | Procede de preparation d'un sel de lithium de bis(fluorosulfonyl)imide |
| WO2020099527A1 (en) | 2018-11-16 | 2020-05-22 | Solvay Sa | Method for producing alkali sulfonyl imide salts |
| KR102181108B1 (ko) * | 2019-09-11 | 2020-11-20 | (주)부흥산업사 | 리튬 비스(플루오로술포닐)이미드와 그 제조방법 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2016124735A (ja) * | 2014-12-26 | 2016-07-11 | 株式会社日本触媒 | フルオロスルホニルイミド化合物の製造方法 |
| KR102275418B1 (ko) * | 2018-07-09 | 2021-07-12 | 이피캠텍 주식회사 | 리튬 비스플루오로술포닐이미드의 제조방법 |
| CN109941978B (zh) * | 2019-04-25 | 2020-08-18 | 浙江科峰锂电材料科技有限公司 | 制备双氟磺酰亚胺铵及双氟磺酰亚胺碱金属盐的方法 |
-
2022
- 2022-05-10 JP JP2023571740A patent/JP2024519378A/ja active Pending
- 2022-05-10 CN CN202280037074.5A patent/CN117751090A/zh active Pending
- 2022-05-10 EP EP22728544.2A patent/EP4347484A1/en active Pending
- 2022-05-10 US US18/564,470 patent/US20240246818A1/en active Pending
- 2022-05-10 WO PCT/EP2022/062660 patent/WO2022248215A1/en not_active Ceased
- 2022-05-10 KR KR1020237039733A patent/KR20240012388A/ko active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2674395A1 (en) | 2011-02-10 | 2013-12-18 | Nippon Soda Co., Ltd. | Process for production of fluorosulfonylimide ammonium salt |
| WO2015158979A1 (fr) | 2014-04-18 | 2015-10-22 | Arkema France | Preparation d'imides contenant un groupement fluorosulfonyle |
| EP3203570A1 (en) | 2014-10-03 | 2017-08-09 | Nippon Shokubai Co., Ltd. | Method for manufacturing electrolyte material |
| WO2017090877A1 (ko) | 2015-11-26 | 2017-06-01 | 임광민 | 리튬 비스(플루오르술포닐)이미드의 신규한 제조방법 |
| WO2019229361A2 (fr) | 2018-06-01 | 2019-12-05 | Arkema France | Procede de preparation d'un sel de lithium de bis(fluorosulfonyl)imide |
| WO2020099527A1 (en) | 2018-11-16 | 2020-05-22 | Solvay Sa | Method for producing alkali sulfonyl imide salts |
| KR102181108B1 (ko) * | 2019-09-11 | 2020-11-20 | (주)부흥산업사 | 리튬 비스(플루오로술포닐)이미드와 그 제조방법 |
Non-Patent Citations (1)
| Title |
|---|
| INTERNATIONAL UNION OF PURE AND APPLIED CHEMISTRY: "IUPAC Gold Book - onium compounds", 24 February 2014 (2014-02-24), XP055380674, Retrieved from the Internet <URL:http://goldbook.iupac.org/html/O/O04291.html> [retrieved on 20170612] * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP4470972A1 (en) * | 2023-06-02 | 2024-12-04 | Specialty Operations France | Process for producing onium salts of bis(fluorosulfonyl)imide |
| WO2025032030A1 (en) * | 2023-08-07 | 2025-02-13 | Specialty Operations France | High purity ammonium bis(fluorosulfonyl)imide and method for its manufacturing |
Also Published As
| Publication number | Publication date |
|---|---|
| US20240246818A1 (en) | 2024-07-25 |
| JP2024519378A (ja) | 2024-05-10 |
| CN117751090A (zh) | 2024-03-22 |
| KR20240012388A (ko) | 2024-01-29 |
| EP4347484A1 (en) | 2024-04-10 |
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