WO2022230771A1 - 転がり軸受 - Google Patents
転がり軸受 Download PDFInfo
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- WO2022230771A1 WO2022230771A1 PCT/JP2022/018566 JP2022018566W WO2022230771A1 WO 2022230771 A1 WO2022230771 A1 WO 2022230771A1 JP 2022018566 W JP2022018566 W JP 2022018566W WO 2022230771 A1 WO2022230771 A1 WO 2022230771A1
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- Prior art keywords
- mass
- less
- surface layer
- rolling bearing
- ball
- Prior art date
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- 238000005096 rolling process Methods 0.000 title claims abstract description 146
- 239000002344 surface layer Substances 0.000 claims abstract description 92
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 80
- 239000010959 steel Substances 0.000 claims abstract description 80
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 45
- 239000002244 precipitate Substances 0.000 claims description 40
- 229910052757 nitrogen Inorganic materials 0.000 claims description 23
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 21
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 19
- 229910052799 carbon Inorganic materials 0.000 claims description 19
- 229910001566 austenite Inorganic materials 0.000 claims description 15
- 230000000717 retained effect Effects 0.000 claims description 15
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 13
- 239000011651 chromium Substances 0.000 claims description 13
- 229910052750 molybdenum Inorganic materials 0.000 claims description 13
- 239000011733 molybdenum Substances 0.000 claims description 13
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 12
- 229910052804 chromium Inorganic materials 0.000 claims description 12
- 229910052742 iron Inorganic materials 0.000 claims description 12
- 239000011572 manganese Substances 0.000 claims description 11
- 229910052710 silicon Inorganic materials 0.000 claims description 11
- 239000010703 silicon Substances 0.000 claims description 11
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 10
- 229910052748 manganese Inorganic materials 0.000 claims description 10
- 229910052720 vanadium Inorganic materials 0.000 claims description 10
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 10
- 239000012535 impurity Substances 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 6
- 230000005540 biological transmission Effects 0.000 claims description 3
- 230000002093 peripheral effect Effects 0.000 description 50
- 239000000523 sample Substances 0.000 description 44
- 239000000203 mixture Substances 0.000 description 30
- 239000001257 hydrogen Substances 0.000 description 21
- 229910052739 hydrogen Inorganic materials 0.000 description 21
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 20
- 229910000734 martensite Inorganic materials 0.000 description 17
- 238000010438 heat treatment Methods 0.000 description 14
- 238000000034 method Methods 0.000 description 13
- 238000005121 nitriding Methods 0.000 description 13
- 238000012360 testing method Methods 0.000 description 12
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 238000001816 cooling Methods 0.000 description 7
- 230000002028 premature Effects 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 238000010791 quenching Methods 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 230000000171 quenching effect Effects 0.000 description 5
- 238000005496 tempering Methods 0.000 description 5
- 239000013078 crystal Substances 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- 238000000349 field-emission scanning electron micrograph Methods 0.000 description 4
- 150000004767 nitrides Chemical class 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- -1 iron carbides Chemical class 0.000 description 3
- 230000035515 penetration Effects 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 230000009466 transformation Effects 0.000 description 3
- 238000005275 alloying Methods 0.000 description 2
- 230000001186 cumulative effect Effects 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 150000001247 metal acetylides Chemical class 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 238000007545 Vickers hardness test Methods 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 238000005255 carburizing Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000007730 finishing process Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- FXNGWBDIVIGISM-UHFFFAOYSA-N methylidynechromium Chemical group [Cr]#[C] FXNGWBDIVIGISM-UHFFFAOYSA-N 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C8/06—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
- C23C8/08—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases only one element being applied
- C23C8/24—Nitriding
- C23C8/26—Nitriding of ferrous surfaces
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/06—Surface hardening
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/18—Hardening; Quenching with or without subsequent tempering
- C21D1/25—Hardening, combined with annealing between 300 degrees Celsius and 600 degrees Celsius, i.e. heat refining ("Vergüten")
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/74—Methods of treatment in inert gas, controlled atmosphere, vacuum or pulverulent material
- C21D1/76—Adjusting the composition of the atmosphere
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/38—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for roll bodies
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/40—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for rings; for bearing races
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/22—Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/24—Ferrous alloys, e.g. steel alloys containing chromium with vanadium
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C8/80—After-treatment
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16C—SHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
- F16C19/00—Bearings with rolling contact, for exclusively rotary movement
- F16C19/02—Bearings with rolling contact, for exclusively rotary movement with bearing balls essentially of the same size in one or more circular rows
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16C—SHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
- F16C19/00—Bearings with rolling contact, for exclusively rotary movement
- F16C19/02—Bearings with rolling contact, for exclusively rotary movement with bearing balls essentially of the same size in one or more circular rows
- F16C19/10—Bearings with rolling contact, for exclusively rotary movement with bearing balls essentially of the same size in one or more circular rows for axial load mainly
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16C—SHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
- F16C33/00—Parts of bearings; Special methods for making bearings or parts thereof
- F16C33/02—Parts of sliding-contact bearings
- F16C33/04—Brasses; Bushes; Linings
- F16C33/06—Sliding surface mainly made of metal
- F16C33/12—Structural composition; Use of special materials or surface treatments, e.g. for rust-proofing
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16C—SHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
- F16C33/00—Parts of bearings; Special methods for making bearings or parts thereof
- F16C33/30—Parts of ball or roller bearings
- F16C33/32—Balls
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16C—SHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
- F16C33/00—Parts of bearings; Special methods for making bearings or parts thereof
- F16C33/30—Parts of ball or roller bearings
- F16C33/34—Rollers; Needles
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16C—SHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
- F16C33/00—Parts of bearings; Special methods for making bearings or parts thereof
- F16C33/30—Parts of ball or roller bearings
- F16C33/58—Raceways; Race rings
- F16C33/583—Details of specific parts of races
- F16C33/585—Details of specific parts of races of raceways, e.g. ribs to guide the rollers
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16C—SHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
- F16C33/00—Parts of bearings; Special methods for making bearings or parts thereof
- F16C33/30—Parts of ball or roller bearings
- F16C33/58—Raceways; Race rings
- F16C33/62—Selection of substances
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16C—SHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
- F16C33/00—Parts of bearings; Special methods for making bearings or parts thereof
- F16C33/30—Parts of ball or roller bearings
- F16C33/58—Raceways; Race rings
- F16C33/64—Special methods of manufacture
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/001—Austenite
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/008—Martensite
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16C—SHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
- F16C2204/00—Metallic materials; Alloys
- F16C2204/60—Ferrous alloys, e.g. steel alloys
- F16C2204/66—High carbon steel, i.e. carbon content above 0.8 wt%, e.g. through-hardenable steel
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16C—SHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
- F16C2204/00—Metallic materials; Alloys
- F16C2204/60—Ferrous alloys, e.g. steel alloys
- F16C2204/70—Ferrous alloys, e.g. steel alloys with chromium as the next major constituent
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16C—SHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
- F16C2240/00—Specified values or numerical ranges of parameters; Relations between them
- F16C2240/40—Linear dimensions, e.g. length, radius, thickness, gap
- F16C2240/70—Diameters; Radii
- F16C2240/76—Osculation, i.e. relation between radii of balls and raceway groove
Definitions
- the present invention relates to rolling bearings.
- rolling members such as raceway members and rolling elements of rolling bearings have been made of high carbon chromium bearing steel (SUJ2, SUJ3, etc.) specified in JIS standards (JIS G 4805:2008). Further, in order to improve the durability of the surface of the rolling member, the surface of the rolling member has conventionally been subjected to nitriding treatment.
- SUJ2, SUJ3, etc. high carbon chromium bearing steel
- the environment in which rolling bearings are used has become even more severe. Therefore, sufficient durability may not be obtained simply by forming the rolling contact member from a general steel material such as SUJ2 or SUJ3 and subjecting the surface layer portion to nitriding treatment.
- the rolling members are made of steel containing a large amount of silicon (Si) and manganese (Mn). By doing so, it is possible to improve wear resistance and seizure resistance in an environment involving sliding contact and in an environment where lubricating oil is depleted.
- Patent Documents 1 to 3 may have insufficient durability of the rolling members depending on the application.
- the addition of chromium to the steel material may cause carbides in the steel to coarsen.
- Coarse carbide may become a source of stress concentration and a starting point of premature flaking.
- the passive film has the effect of suppressing the diffusion of hydrogen into the steel, but it also has the effect of promoting the adsorption of hydrogen.
- the rolling bearing described in Patent Document 3 When the rolling bearing described in Patent Document 3 is used intermittently, hydrogen dissipates when the bearing is stopped, so delaying the penetration of hydrogen into the steel with a passive film is effective in preventing early flaking. is.
- a large amount of hydrogen is adsorbed on the passive film, and the amount of hydrogen that penetrates into the steel increases, resulting in premature flaking. easier.
- the present invention has been made in view of the problems of the prior art as described above. More specifically, the present invention provides a rolling bearing that can have a longer life.
- a rolling bearing includes a plurality of balls and two raceway members.
- the balls and track members have contact surfaces. At least one of the ball and the track member has a surface layer formed in a region up to 20 ⁇ m deep from the contact surface.
- the member having the surface layer formed on the contact surface is made of quenched steel.
- the steel contains 0.70 to 1.10 mass percent carbon, 0.15 to 0.35 mass percent silicon, and 0.30 to 0.60 mass percent manganese. , containing 1.30 to 1.60% by mass of chromium, 0.01 to 0.50% by mass of molybdenum, and 0.01 to 0.50% by mass of vanadium In addition, the remainder consists of iron and unavoidable impurities.
- the nitrogen content in the surface layer is 0.2% by mass or more and 0.8% by mass or less.
- the raceway surface which is the contact surface of the raceway member, forms a partial arc in a cross-sectional view passing through the central axis of the rolling bearing and parallel to the central axis.
- the diameter of the partial arc is 1.01 to 1.08 times the diameter of the ball.
- the steel comprises 0.90 mass percent or more and 1.10 mass percent or less carbon, 0.20 mass percent or more and 0.30 mass percent or less silicon, and 0.40 mass percent or more and 0.50 mass percent.
- 1.40 to 1.60 mass percent chromium, 0.20 to 0.30 mass percent molybdenum, and 0.20 to 0.30 mass percent of vanadium, and the balance may consist of iron and unavoidable impurities.
- the nitrogen content in the surface layer portion may be 0.3% by mass or more and 0.5% by mass or less.
- the total area ratio of the precipitates in the surface layer portion may be 1% or more and 10% or less.
- the volume ratio of the retained austenite amount at a position 50 ⁇ m deep from the contact surface where the surface layer portion is formed may be 20% or more and 40% or less.
- the hardness at a position 50 ⁇ m deep from the contact surface where the surface layer is formed may be 653 Hv or more and 800 Hv or less.
- a total of 80 or more precipitates having a particle size of 0.50 ⁇ m or less are present per 100 ⁇ m 2 in the surface layer.
- the total area ratio of the precipitates in the surface layer portion may be 2% or more and 7% or less.
- the volume ratio of the retained austenite amount at a position 50 ⁇ m deep from the contact surface where the surface layer portion is formed may be 25% or more and 35% or less.
- the hardness at a position 50 ⁇ m deep from the contact surface where the surface layer is formed may be 653 Hv or more and 800 Hv or less.
- a rolling bearing includes a plurality of balls and two raceway members.
- the balls and track members have contact surfaces. At least one of the ball and the track member has a surface layer formed in a region up to 20 ⁇ m deep from the contact surface.
- the member having the surface layer formed on the contact surface is made of quenched steel.
- the steel contains 0.70 to 1.10 mass percent carbon, 0.15 to 0.35 mass percent silicon, and 0.30 to 0.60 mass percent manganese. , containing 1.30 to 1.60% by mass of chromium, 0.01 to 0.50% by mass of molybdenum, and 0.01 to 0.50% by mass of vanadium In addition, the remainder consists of iron and unavoidable impurities.
- the nitrogen content in the surface layer is 0.2% by mass or more and 0.8% by mass or less.
- the raceway member is an inner ring and an outer ring.
- the outer diameter of the inner ring and the inner diameter of the outer ring are equal to or greater than the value obtained by subtracting the diameter of the ball from the pitch circle diameter of the ball and equal to or less than the value obtained by adding the diameter of the ball to the pitch circle diameter of the ball, respectively.
- the thickness of the outer ring is set so that the tensile stress applied to the outer ring is 700 MPa or less.
- At least one of the combined roughness of the first raceway surface, which is the contact surface of the inner ring, and the rolling contact surface, which is the contact surface of the ball, and the combined roughness of the second raceway surface, which is the contact surface of the outer ring, and the rolling contact surface 0.05 ⁇ m or more.
- the contact angle of the ball with the first raceway surface and the second raceway surface is less than 30°.
- the rolling bearing may be for a vehicle transmission, a vehicle accessory, or a vehicle motor.
- the rolling bearing according to one aspect of the present invention and the rolling bearing according to another aspect of the present invention, it is possible to extend the service life.
- FIG. 1 is a cross-sectional view of a rolling bearing 100;
- FIG. 3A to 3C are process diagrams showing a method of manufacturing the rolling bearing 100;
- 4 is a graph showing the distribution of carbon and nitrogen contents in the surface layer portions of the inner ring and outer ring of Sample 1.
- FIG. 5 is a graph showing the distribution of carbon and nitrogen content in the surface layer portions of the inner ring and the outer ring of Sample 2.
- FIG. 4 shows representative cross-sectional FE-SEM images of the surface layer portions of the inner ring and outer ring of Sample 1.
- FIG. 4 shows representative cross-sectional FE-SEM images of the surface layers of the inner and outer rings of Sample 2.
- FIG. It is a graph which shows a rolling contact fatigue life test result. It is a sectional view of rolling bearing 100A.
- Rolling bearing 100 is, for example, a single plain seat thrust ball bearing. However, the rolling bearing 100 is not limited to this.
- the rolling bearing 100 is for, for example, a vehicle transmission, a vehicle accessory, or a vehicle motor.
- FIG. 1 is a cross-sectional view of the rolling bearing 100.
- the rolling bearing 100 has a central axis A as shown in FIG.
- FIG. 1 shows a cross section of the rolling bearing 100 passing through the central axis A and parallel to the central axis A.
- the rolling bearing 100 has a race member (bearing ring or washer) and rolling elements.
- raceway members are an inner ring (shaft washer) 10 and an outer ring (housing washer) 20, and rolling elements are balls 30.
- FIG. Rolling bearing 100 further has retainer 40 .
- the inner ring 10 has an annular (ring-like) shape.
- the inner ring 10 has a first surface 10a, a second surface 10b, an inner peripheral surface 10c, and an outer peripheral surface 10d.
- the first surface 10a and the second surface 10b constitute end surfaces in the direction along the central axis A (hereinafter referred to as "axial direction").
- the second surface 10b is the opposite surface of the first surface 10a in the axial direction.
- the first surface 10a has a raceway surface 10aa.
- the first surface 10a is recessed toward the second surface 10b on the raceway surface 10aa.
- the raceway surface 10aa is a partial arc.
- the diameter of this partial arc is 1.01 to 1.08 times the diameter of ball 30 .
- the raceway surface 10aa is a surface that contacts the balls 30 and constitutes a contact surface of the inner ring 10 .
- the inner peripheral surface 10c is a surface facing the central axis A side. One end in the axial direction of the inner peripheral surface 10c is continuous with the first surface 10a, and the other end in the axial direction is continuous with the second surface 10b.
- the outer peripheral surface 10d is a surface facing away from the central axis A. From another point of view, the outer peripheral surface 10d is opposite to the inner peripheral surface 10c in the direction perpendicular to the central axis A (hereinafter referred to as "radial direction"). One end in the axial direction of the outer peripheral surface 10d is continuous with the first surface 10a, and the other end in the axial direction is continuous with the second surface 10b.
- the outer ring 20 has a ring shape.
- the outer ring 20 has a first surface 20a, a second surface 20b, an inner peripheral surface 20c, and an outer peripheral surface 20d.
- the first surface 20a and the second surface 20b constitute end surfaces in the axial direction.
- the outer ring 20 is arranged such that the first surface 20a faces the first surface 10a.
- the second surface 20b is the opposite surface of the first surface 20a in the axial direction.
- the first surface 20a has a raceway surface 20aa.
- the first surface 20a is recessed toward the second surface 20b on the raceway surface 20aa.
- the raceway surface 20aa is a partial arc.
- the diameter of this partial arc is 1.01 to 1.08 times the diameter of ball 30 .
- the raceway surface 20 aa is a surface that contacts the ball 30 and constitutes a contact surface of the outer ring 20 .
- the inner peripheral surface 20c is a surface facing the central axis A side. One end in the axial direction of the inner peripheral surface 20c is continuous with the first surface 20a, and the other end in the axial direction is continuous with the second surface 20b.
- the outer peripheral surface 20d is a surface facing away from the central axis A. That is, the outer peripheral surface 20d is the opposite surface of the inner peripheral surface 20c in the radial direction.
- the outer peripheral surface 20d is connected to the first surface 20a at one end in the axial direction, and is connected to the second surface 20b at the other end in the axial direction.
- the ball 30 has a spherical shape.
- the number of balls 30 is plural.
- the ball 30 is arranged between the first surface 10a and the first surface 20a. More specifically, ball 30 is arranged between raceway surface 10aa and raceway surface 20aa.
- the surface of the ball 30 contacts the raceway surface 10aa and the raceway surface 20aa. That is, the surface of ball 30 is a contact surface (rolling surface).
- the cage 40 holds the ball 30.
- the retainer 40 holds the balls 30 so that the distance between two adjacent balls 30 in the direction along the circumference centered on the central axis A (hereinafter referred to as "circumferential direction") is within a certain range. .
- the inner ring 10, outer ring 20 and ball 30 are made of steel having a composition shown in Table 1 (hereinafter referred to as "first composition”).
- the inner ring 10, the outer ring 20 and the balls 30 may be made of steel having a composition shown in Table 2 (hereinafter referred to as "second composition”).
- the steel forming the inner ring 10, the outer ring 20 and the balls 30 is quenched. At least one of the inner ring 10, the outer ring 20 and the balls 30 should be made of steel of the first composition (second composition).
- Carbon (C) affects the hardness of the contact surfaces (raceway surface 10aa, raceway surface 20aa, and surface of ball 30) after quenching. If the carbon content in the steel is less than 0.70% by mass, it is difficult to ensure sufficient hardness at the contact surfaces. Moreover, when the carbon content in the steel is less than 0.70% by mass, it is necessary to supplement the carbon content in the surface by carburizing treatment or the like, which causes a decrease in production efficiency and an increase in manufacturing costs. If the carbon content in the steel exceeds 1.10% by mass, cracks (quench cracks) may occur during quenching. Therefore, the steel of the first composition has a carbon content of 0.70% by mass or more and 1.10% by mass or less.
- Silicon is added to ensure workability before deoxidizing and nitriding during steel refining. If the silicon content in the steel is less than 0.15 mass percent, the temper softening resistance will be insufficient. As a result, the hardness of the contact surface may decrease due to tempering after quenching or temperature rise during use of the rolling bearing 100 . If the silicon content in the steel exceeds 0.35% by mass, the steel becomes too hard, and the tool life of the cutting tool used for processing the inner ring 10 (outer ring 20, ball 30) may be shortened. . Moreover, in this case, the material cost of steel will rise. Therefore, in the steel of the first composition, the content of silicon is 0.15% by mass or more and 0.35% by mass or less.
- Manganese is added to ensure the hardenability and hardness of steel. If the manganese content in the steel is less than 0.30% by mass, it is difficult to ensure the hardenability and hardness of the steel. If the manganese content in the steel exceeds 0.60% by mass, the steel becomes too hard, and the tool life of the cutting tool used for processing the inner ring 10 (outer ring 20, ball 30) may be shortened. . Moreover, in this case, the material cost of steel will rise. Therefore, the steel of the first composition has a manganese content of 0.30% by mass or more and 0.60% by mass or less.
- Chromium is added to ensure hardenability of steel and to ensure hardness by forming fine precipitates accompanying nitriding treatment. If the chromium content in the steel is less than 1.30% by mass, it is difficult to ensure the hardenability and hardness of the steel. If the content of chromium in the steel exceeds 1.60% by mass, the precipitates are coarsened and may become starting points for fatigue fracture. Moreover, in this case, the material cost of steel will rise. Therefore, the steel of the first composition has a chromium content of 1.30% by mass or more and 1.60% by mass or less.
- Molybdenum is added to ensure hardenability of steel and to ensure hardness by forming fine precipitates accompanying nitriding treatment. Since molybdenum has a strong affinity for carbon, it precipitates as undissolved carbide in steel during nitriding treatment. Since this undissolved carbide of molybdenum becomes a precipitation nucleus during quenching, molybdenum increases the amount of precipitates after quenching.
- the content of molybdenum in the steel is less than 0.01% by mass, it is difficult to ensure the hardenability and hardness of the steel. If the content of molybdenum in the steel exceeds 0.50% by mass, the precipitates are coarsened and may become starting points for fatigue fracture. Moreover, in this case, the material cost of steel also rises. Therefore, in the steel of the first composition, the content of molybdenum is 0.01% by mass or more and 0.50% by mass or less.
- Vanadium is added to ensure hardenability of steel and to ensure hardness by forming fine precipitates accompanying nitriding treatment. If the vanadium content in the steel is less than 0.01% by mass, it is difficult to ensure the hardenability and hardness of the steel. If the vanadium content in the steel exceeds 0.50% by mass, the precipitates are coarsened and may become starting points for fatigue fracture. In this case, the material cost of steel also increases. Therefore, in the steel of the first composition, the vanadium content is 0.01% by mass or more and 0.50% by mass or less.
- inner ring 10, outer ring 20 and ball 30 have surface layer portions 50 on their surfaces.
- the surface layer portion 50 is a region from the surfaces of the inner ring 10, the outer ring 20 and the ball 30 to a depth of 20 ⁇ m.
- the surface layer part 50 should just be formed in the contact surface of the inner ring
- the surface layer portion 50 may be formed on at least one of the inner ring 10 , the outer ring 20 and the balls 30 .
- the surface layer portion 50 is a portion formed by nitriding treatment.
- the nitrogen content in the surface layer portion 50 is 0.2% by mass or more and 0.8% by mass or less. If the nitrogen content in the surface layer portion 50 is less than 0.2% by mass, it is difficult to ensure the durability of the contact surface. If the nitrogen content in the surface layer portion 50 exceeds 0.8% by mass, the time required for the nitriding treatment will be prolonged, increasing the manufacturing cost. Therefore, the nitrogen content in the surface layer portion 50 is set to 0.2% by mass or more and 0.8% by mass or less.
- the nitrogen content in the surface layer portion 50 is preferably 0.3% by mass or more and 0.5% by mass or less.
- the nitrogen content in the surface layer 50 is measured by an electron probe microanalyzer (EPMA).
- EPMA electron probe microanalyzer
- a total of 60 or more precipitates having a particle size of 0.5 ⁇ m or less exist per 100 ⁇ m 2 in the surface layer portion 50 .
- a total of 80 or more precipitates having a grain size of 0.5 ⁇ m or less exist per 100 ⁇ m 2 in the surface layer portion 50 .
- the total area ratio of precipitates in the surface layer portion 50 is preferably 1% or more and 10% or less. In a cross-sectional view perpendicular to the contact surface, the total area ratio of precipitates in the surface layer portion 50 is more preferably 2% or more and 7% or less.
- the precipitates in the surface layer portion 50 are, for example, carbonitrides and nitrides.
- Carbonitrides include iron carbides, iron carbides in which carbon is replaced with nitrogen, and iron carbides in which iron is replaced by an alloying element other than iron.
- Nitrides are nitrides of iron.
- the precipitates in the surface layer portion 50 may be carbides, carbonitrides or nitrides of alloying elements contained in the steel.
- the area ratio of the precipitate is obtained by acquiring a cross-sectional image of the surface layer 50 at a magnification of 5000 using a field emission scanning electron microscope (FE-SEM), binarizing the cross-sectional image, It is calculated by performing image processing on the binarized cross-sectional image. Note that cross-sectional images of the surface layer 50 are obtained in three or more fields of view, and the area ratio is the average value of the plurality of cross-sectional images.
- FE-SEM field emission scanning electron microscope
- the grain size of each precipitate is obtained by obtaining the area of each precipitate using the same method as above and multiplying the square root of the value obtained by dividing the area by ⁇ by 2.
- the volume fraction of retained austenite in the steel forming the inner ring 10, the outer ring 20 and the balls 30 is preferably 20% or more and 40% or less at a depth of 50 ⁇ m from the contact surface. This can improve the durability of the contact surface (particularly, the durability of the contact surface in an environment containing foreign matter). If the volume fraction of retained austenite is less than 25%, the durability of the contact surface may be insufficient. Moreover, when the volume fraction of retained austenite exceeds 35%, there is concern about secular change due to decomposition of retained austenite.
- the volume ratio of retained austenite in the steel forming the inner ring 10, outer ring 20 and ball 30 is more preferably 25% or more and 35% or less at a depth of 50 ⁇ m from the contact surface.
- the amount of retained austenite in the steel at a depth of 50 ⁇ m from the contact surface is measured by X-ray diffraction. More specifically, the amount of retained austenite in the steel at a depth of 50 ⁇ m from the contact surface is measured using MSF-3M manufactured by Rigaku Corporation.
- the hardness at a position where the depth from the contact surface is 50 ⁇ m is preferably 653 Hv or more and 800 Hv or less. If the hardness at the position where the depth from the contact surface is 50 ⁇ m is less than 653 Hv, the durability of the contact surface may be insufficient. On the other hand, if the hardness at a depth of 50 ⁇ m from the contact surface exceeds 800 Hv, the ductility and toughness are reduced, and premature damage may occur.
- the hardness at the position where the depth from the contact surface of the inner ring 10, outer ring 20 and ball 30 is 50 ⁇ m is measured by the Vickers hardness test method specified in the JIS standard (JIS Z 2244:2009). Moreover, the load at the time of measurement is set to 300 gf.
- the steel of the surface layer portion 50 has martensite block grains.
- Two adjacent martensite block grains have a crystal orientation difference of 15° or more at the grain boundary. From another point of view, even if there is a location with a deviation in crystal orientation, if the difference in crystal orientation is less than 15°, the location is different from the grain boundary of the martensite block grain. not considered. Grain boundaries of martensite block grains are determined by an EBSD (Electron Back Scattered Diffraction) method.
- EBSD Electro Back Scattered Diffraction
- the average grain size of martensite block grains with a comparative area ratio of 30% is 2.0 ⁇ m or less.
- the average grain size of martensite block grains with a comparative area ratio of 50% is preferably 1.5 ⁇ m or less.
- the average grain size of martensite block grains with a comparative area ratio of 30 percent (50 percent) is measured by the following method.
- martensite block grains included in the observation field are specified by the EBSD method.
- This observation field of view is an area of 50 ⁇ m ⁇ 35 ⁇ m.
- Second, the area of each martensite block grain included in the observation field is analyzed from the crystal orientation data obtained by the EBSD method.
- each martensite block grain included in the observation field is added in descending order of area. This addition is performed until thirty percent (50 percent) of the total area of martensite block grains contained in the field of view is reached.
- the equivalent circle diameter is calculated for each of the martensite block grains subjected to the above addition. This equivalent circle diameter is the square root of the value obtained by dividing the area of martensite block grains by ⁇ /4.
- the average value of the circle-equivalent diameters of the martensite block grains subjected to the above addition is regarded as the average grain size of the martensite block grains with a comparative area ratio of 30% (50%).
- FIG. 2 is a process diagram showing a manufacturing method of the rolling bearing 100.
- the method of manufacturing the rolling bearing 100 includes a preparation step S1, a heat treatment step S2, a finishing step S3, and an assembly step S4.
- the heat treatment step S2 is performed after the preparation step S1.
- the finishing step S3 is performed after the heat treatment step S2.
- the assembling step S4 is performed after the finishing step S3.
- members to be processed to be subjected to the heat treatment step S2 and the finishing step S3 are prepared.
- a ring-shaped member is prepared when the inner ring 10 and the outer ring 20 are to be formed, and a spherical member is prepared when the ball 30 is to be formed.
- the member to be processed is made of steel of the first composition or the second composition.
- the heat treatment step S2 includes a heating step S21, a cooling step S22, and a tempering step S23.
- the heating step S21 the member to be processed is held at a temperature equal to or higher than the A1 transformation point for a predetermined period of time. Further, in the heating step S21, the member to be processed is also subjected to nitriding treatment. This nitriding treatment is carried out by performing the above heating and holding in an atmospheric gas containing a nitrogen source gas (for example, ammonia gas).
- a nitrogen source gas for example, ammonia gas
- the cooling step S22 is performed after the heating step S21.
- the member to be processed is cooled to a temperature below the Ms transformation point. This cooling is performed, for example, by oil cooling.
- the tempering step S23 is performed after the cooling step S22. In the tempering step S23, the member to be processed is held at a temperature lower than the A1 transformation point for a predetermined period of time.
- finishing step S3 finishing (grinding/polishing) and cleaning of the member to be processed are performed.
- the inner ring 10, the outer ring 20 and the balls 30 are prepared.
- the assembly step S4 the inner ring 10, the outer ring 20 and the balls 30 are assembled together with the retainer 40. As shown in FIG. As described above, the rolling bearing 100 having the structure shown in FIG. 1 is manufactured.
- the contact surfaces of the inner ring 10, the outer ring 20, and the balls 30 are formed with the surface layer portion 50 that has undergone nitriding treatment, so damage such as cracks occurs on the contact surfaces (and directly below them). It's hard. Further, in the rolling bearing 100, the inner ring 10, the outer ring 20 and the balls 30 are made of steel of the first composition or the second composition. It is possible to ensure the hardness of the surface (and directly under it), and to prevent these precipitates from becoming a source of stress concentration (starting point of crack generation). Thus, according to the rolling bearing 100, it is possible to extend the life of the rolling bearing.
- the rolling bearing 100 since fine precipitates are deposited on the surface layer portion 50 and the hardness of the contact surface is ensured, formation of a new metal surface on the contact surface is suppressed. Therefore, in the rolling bearing 100, hydrogen is less likely to be generated on the contact surface. In addition, in the rolling bearing 100, fine precipitates are deposited on the surface layer portion 50, and the vicinity of the precipitates becomes a trap site for hydrogen. Therefore, in the rolling bearing 100, premature flaking damage due to hydrogen embrittlement is less likely to occur. Thus, according to the rolling bearing 100, it is possible to extend the life of the rolling bearing.
- raceway surface 10aa (raceway surface 20aa) is 1.08 times or less the diameter of ball 30
- the contact surface between raceway surface 10aa (raceway surface 20aa) and ball 30 is The pressure can be reduced, and oil film breakage between the raceway surface 10aa (raceway surface 20aa) and the balls 30 is less likely to occur. Therefore, in the rolling bearing 100, wear on the contact surface and formation of a new metal surface on the contact surface are suppressed, and premature flaking damage due to hydrogen embrittlement is less likely to occur.
- rolling bearing 100 since the diameter of the partial arc of raceway surface 10aa (raceway surface 20aa) is 1.01 times or more the diameter of ball 30, the distance between raceway surface 10aa (raceway surface 20aa) and ball 30 is The contact area does not become too small, and the torque loss of the rolling bearing 100 can be suppressed. Thus, the rolling bearing 100 can maintain bearing characteristics (torque loss) while forming an appropriate oil film.
- the martensite block grains are refined so that the average grain size at a comparative area ratio of 30% is 2.0 ⁇ m or less, by increasing the toughness of the surface layer portion 50, The shear resistance of the contact surfaces (specifically, the raceway surface 10da, the raceway surface 20ca and the surfaces of the balls 30) is improved. Therefore, in this case, the durability of rolling bearing 100 can be further improved.
- Examples of the rolling bearing 100 are described below.
- Samples 1, 2 and 3 were prepared as rolling bearing samples.
- Samples 1, 2 and 3 are single thrust ball bearings of JIS standard 51106 model number with an inner diameter of 30 mm, an outer diameter of 47 mm and a width of 11 mm.
- the inner ring and outer ring of Sample 1 were made of steel with the composition shown in Table 3.
- the compositions shown in Table 3 are within the range of the first composition and the second composition.
- the inner and outer rings of Sample 2 and the inner and outer rings of Sample 3 were made of steel having the composition shown in Table 4.
- the compositions shown in Table 4 are within the composition range of SUJ2 defined in the JIS standard, and are outside the ranges of the first composition and the second composition.
- the balls of Samples 1, 2 and 3 were made of stainless steel (SUS440C).
- the inner and outer rings of sample 1 and the inner and outer rings of sample 2 were subjected to the heat treatment step S2.
- the inner ring and outer ring of Sample 3 were not subjected to the heat treatment step S2. More specifically, the inner ring and outer ring of Sample 3 were quenched and tempered, but not nitrided.
- FIG. 3 is a graph showing the distribution of carbon and nitrogen contents in the surface layer portions of the inner ring and outer ring of Sample 1.
- FIG. 4 is a graph showing the distribution of the carbon and nitrogen content in the surface layer portions of the inner ring and outer ring of Sample 2.
- the horizontal axis is the distance from the surface (unit: mm), and the vertical axis is the carbon and nitrogen content (unit: mass percent).
- the nitrogen content in the surface layer of the inner and outer rings of Sample 1 and the inner and outer rings of Sample 2 is 0.3% by mass or more and 0.5% by mass or less. Met.
- the nitrogen content in the surface layer portions of the inner and outer rings of Sample 3 was 0% by mass (no nitrogen was contained).
- the total area ratio of precipitates was 2.2% or more and 7.0% or less.
- the total area ratio of precipitates was 1.2% or more and 4.0% or less.
- the total area ratio of precipitates was 0.07% or more and 0.24% or less.
- the total number of precipitates in the surface layers of the inner and outer rings of Sample 1 was 66 or more and 425 or less per 100 ⁇ m 2 .
- the total number of precipitates was 29 or more and 81 or less per 100 ⁇ m 2 .
- the total number of precipitates was 8 or more and 50 or less per 100 ⁇ m 2 .
- FIG. 5 is a representative cross-sectional FE-SEM image of the inner and outer ring surface layers of Sample 1.
- FIG. 6 shows representative cross-sectional FE-SEM images of the inner and outer ring surface layers of Sample 2.
- FIG. 5 in the surface layer portions of the inner ring and the outer ring of Sample 1, the precipitates were fine (the grain size of most of the precipitates was 0.5 ⁇ m or less).
- the precipitates were not refined in the surface layer portions of the inner ring and the outer ring of Sample 2 (most of the precipitates had particle sizes exceeding 0.5 ⁇ m). .
- the volume ratio of retained austenite at a depth of 50 ⁇ m from the contact surfaces of the inner and outer rings of Sample 1 was 29.8% or more and 30.8% or less.
- the volume ratio of retained austenite at the position where the depth from the contact surface of the inner ring and the outer ring of sample 2 is 50 ⁇ m was 30.2% or more and 31.4% or less.
- the volume ratio of retained austenite at the position where the depth from the contact surface of the inner ring and the outer ring of sample 3 is 50 ⁇ m was 9.7% or more and 11.5% or less.
- the hardness of Sample 1 at a depth of 50 ⁇ m from the contact surfaces of the inner and outer rings was 755 Hv or more and 759 Hv or less.
- the hardness of Sample 2 at a depth of 50 ⁇ m from the contact surfaces of the inner ring and the outer ring was 749 Hv or more and 758 Hv or less.
- the hardness of Sample 3 at a depth of 50 ⁇ m from the contact surfaces of the inner ring and the outer ring was 735 Hv or more and 765 Hv or less.
- Rolling contact fatigue life test A rolling contact fatigue life test was performed on samples 1, 2 and 3. As shown in Table 7, in the rolling contact fatigue life test, the maximum contact surface pressure is 2.3 GPa, rapid acceleration/deceleration is performed between 0 rpm and 2500 rpm, and polyglycol and pure water are mixed. It was performed under the condition that it was lubricated using a
- FIG. 7 is a graph showing rolling contact fatigue life test results.
- the horizontal axis is life (unit: hours), and the vertical axis is cumulative failure probability (unit: percent).
- the rolling contact fatigue life of sample 2 was longer than the rolling contact fatigue life of sample 3 when compared by L10 life (the time at which the cumulative failure probability reached 10 %). From this comparison result, the rolling contact fatigue life is improved by performing the nitriding treatment so that the nitrogen content in the surface layer portion 50 is 0.2% by mass or more and 0.8% by mass or less. was also shown.
- the rolling contact fatigue life of sample 1 was longer than the rolling contact fatigue life of sample 2 when compared by L10 life. From this comparison result, by forming at least one of the inner ring 10, the outer ring 20 and the ball 30 from the steel of the first composition, the precipitates are finely dispersed in the surface layer portion 50, thereby improving the rolling contact fatigue life. It was also shown experimentally.
- Hydrogen permeation characteristics of the raceway members (inner and outer rings) of Samples 1 and 3 were evaluated by the following method.
- the raceway members of Sample 1 and Sample 3 before being subjected to the rolling contact fatigue life test were heated from room temperature to 400° C., so that the rolling contact fatigue life test was performed. was measured.
- samples after being subjected to the rolling contact fatigue life test for 50 hours were heated from room temperature to 400° C. for the raceway members of samples 1 and 3 after being subjected to the rolling contact fatigue life test for 50 hours. The amount of hydrogen released from the track members of Sample 1 and Sample 3 was measured.
- roller bearing 100A (Configuration of rolling bearing according to second embodiment)
- rolling bearing 100A The configuration of the rolling bearing (hereinafter referred to as "rolling bearing 100A") according to the second embodiment will be described below.
- FIG. 8 is a cross-sectional view of the rolling bearing 100A.
- FIG. 8 shows a cross section of the rolling bearing 100A in a cross section passing through the central axis A and parallel to the central axis A.
- the rolling bearing 100A has race members and rolling elements.
- the raceway members and the rolling elements have surface layer portions 50 on their surfaces.
- the raceway member and the rolling elements are made of steel of the first composition or steel of the second composition. Regarding these points, the configuration of the rolling bearing 100A is common to the configuration of the rolling bearing 100. As shown in FIG.
- the rolling bearing 100A is, for example, a deep groove ball bearing. However, the rolling bearing 100A may be an angular ball bearing.
- the raceway members of the rolling bearing 100A are the inner ring 60 and the outer ring 70 .
- Balls 80 are the rolling elements of the rolling bearing 100A.
- Rolling bearing 100A further has retainer 90 .
- the inner ring 60 has a ring shape.
- the inner ring 60 has a first surface 60a, a second surface 60b, an inner peripheral surface 60c, and an outer peripheral surface 60d.
- the first surface 60a and the second surface 60b form end surfaces of the inner ring 60 in the axial direction.
- the second surface 60b is the opposite surface of the first surface 60a.
- the inner peripheral surface 60c is a surface facing the central axis A side. One end in the axial direction of the inner peripheral surface 60c is continuous with the first surface 60a, and the other end in the axial direction is continuous with the second surface 60b.
- the outer peripheral surface 60d is a surface facing away from the central axis A. As shown in FIG. That is, the outer peripheral surface 60d is the opposite surface of the inner peripheral surface 60c in the radial direction. One end in the axial direction of the outer peripheral surface 60d is continuous with the first surface 60a, and the other end in the axial direction is continuous with the second surface 60b.
- the outer peripheral surface 60d has a raceway surface 60da.
- the outer peripheral surface 60d is recessed toward the inner peripheral surface 60c on the raceway surface 60da.
- the raceway surface 60da is a partial arc.
- the raceway surface 60 da is a surface that contacts the ball 80 and constitutes a contact surface of the inner ring 60 .
- the outer ring 70 has a ring shape.
- the outer ring 70 has a first surface 70a, a second surface 70b, an inner peripheral surface 70c, and an outer peripheral surface 70d.
- the outer ring 70 is arranged such that the inner peripheral surface 70c faces the outer peripheral surface 60d.
- the first surface 70a and the second surface 70b form end surfaces of the outer ring 70 in the axial direction.
- the second surface 70b is the opposite surface of the first surface 70a.
- the inner peripheral surface 70c is a surface facing the central axis A side. One end in the axial direction of the inner peripheral surface 70c is continuous with the first surface 70a, and the other end in the axial direction is continuous with the second surface 70b.
- the outer peripheral surface 70d is a surface facing away from the central axis A. As shown in FIG. That is, the outer peripheral surface 70d is the opposite surface of the inner peripheral surface 70c in the radial direction. One end in the axial direction of the outer peripheral surface 70d is continuous with the first surface 70a, and the other end in the axial direction is continuous with the second surface 70b.
- the inner peripheral surface 70c has a raceway surface 70ca.
- the inner peripheral surface 70c is recessed toward the outer peripheral surface 70d on the raceway surface 70ca.
- the raceway surface 70ca is a partial arc.
- the raceway surface 70ca is a surface that contacts the ball 80 and constitutes a contact surface of the outer ring 70 .
- the ball 80 has a spherical shape.
- the number of balls 80 is plural.
- the ball 80 is arranged between the outer peripheral surface 60d and the inner peripheral surface 70c. More specifically, ball 80 is arranged between raceway surface 60da and raceway surface 70ca.
- the surface of ball 80 contacts raceway surface 60da and raceway surface 70ca. That is, the surface of the ball 80 is a contact surface (rolling surface).
- the retainer 90 holds the balls 80 .
- the retainer 90 holds the balls 80 such that the distance between the two balls 80 adjacent in the circumferential direction is within a certain range.
- the outer diameter of the inner ring 60 be the outer diameter D1.
- the inner diameter of the outer ring 70 is defined as an inner diameter D2.
- the diameter of the ball 80 be diameter D3.
- the pitch circle diameter of the ball 80 be the pitch circle diameter D4.
- the pitch circle diameter is the diameter of a circle passing through the centers of the balls 80 arranged along the circumferential direction.
- the outer diameter D1 is equal to or larger than the value obtained by subtracting 0.7 times the diameter D3 from the pitch diameter D4.
- the inner diameter D2 is equal to or smaller than the pitch diameter D4 plus 0.7 times the diameter D3.
- thickness T be the thickness of the outer ring 70 .
- the thickness T is set so that the tensile stress applied to the outer ring 70 is 700 MPa or less.
- the combined roughness of the raceway surface 60da and the rolling surface of the ball 80 and the combined roughness of the raceway surface 70ca and the rolling surface of the ball 80 are 0.05 ⁇ m or less.
- the combined roughness of the raceway surface 60da (raceway surface 70ca) and the rolling surface of the ball 80 is defined as follows: R1 is the arithmetic average roughness of the raceway surface 60da (raceway surface 70ca); The average roughness is calculated by ⁇ (R 1 ⁇ 1.25) 2 +(R 2 ⁇ 1.25) 2 ⁇ 1/2 .
- the contact angle between the raceway surface 60da and the raceway surface 70ca of the ball 80 is 0°. However, when the rolling bearing 100A is an angular contact ball bearing, the contact angle between the raceway surface 60da and the raceway surface 70ca of the ball 80 is less than 30°.
- the surface layer portion 50 is formed on the contact surfaces of the inner ring 60, the outer ring 70 and the balls 80. Further, in the rolling bearing 100A, the inner ring 10, the outer ring 20 and the balls 30 are made of steel of the first composition or the second composition. Therefore, according to the rolling bearing 100A, similarly to the rolling bearing 100, it is possible to extend the life of the rolling bearing.
- raceway members such as inner and outer rings, rolling elements such as balls, and rolling bearings using them.
- 100 rolling bearing A central shaft, 10 inner ring, 10a first surface, 10aa raceway surface, 10b second surface, 10c inner peripheral surface, 10d outer peripheral surface, 20 outer ring, 20a first surface, 20aa raceway surface, 20b second surface , 20c inner peripheral surface, 20d outer peripheral surface, 30 ball, 40 cage, 50 surface layer portion, 100A rolling bearing, 60 inner ring, 60a first surface, 60b second surface, 60c inner peripheral surface, 60d outer peripheral surface, 60da raceway surface , 70 outer ring, 70a first surface, 70b second surface, 70c inner peripheral surface, 70ca raceway surface, 70d outer peripheral surface, 80 ball, 90 retainer, D1 outer diameter, D2 inner diameter, D3 diameter, D4 pitch diameter, S1 Preparation process, S2 heat treatment process, S3 finishing process, S4 assembly process, S21 heating process, S22 cooling process, S23 tempering process, T thickness.
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- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
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- Manufacturing & Machinery (AREA)
- Rolling Contact Bearings (AREA)
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Abstract
Description
以下に、第1実施形態に係る転がり軸受(以下「転がり軸受100」とする)の構成を説明する。転がり軸受100は、例えば、単式平面座スラスト玉軸受である。但し、転がり軸受100は、これに限られるものではない。転がり軸受100は、例えば、車両のトランスミッション用、車両の補機用又は車両のモータ用である。
内輪10、外輪20及び玉30は、表1に示される組成(以下「第1組成」とする)の鋼により形成されている。内輪10、外輪20及び玉30は、表2に示される組成(以下「第2組成」とする)の鋼により形成されていてもよい。内輪10、外輪20及び玉30を構成している鋼には、焼き入れが行われている。なお、内輪10、外輪20及び玉30の少なくともいずれかが、第1組成(第2組成)の鋼により形成されていればよい。
図1に示されるように、内輪10、外輪20及び玉30は、それらの表面において、表層部50を有している。表層部50は、内輪10、外輪20及び玉30の表面から深さが20μmまでの領域である。なお、表層部50は、少なくとも内輪10、外輪20及び玉30の接触面に形成されていればよい。また、表層部50は、内輪10、外輪20及び玉30の少なくともいずれかに形成されていればよい。
内輪10、外輪20及び玉30を構成している鋼中の残留オーステナイトの体積率は、接触面からの深さが50μmの位置において、20パーセント以上40パーセント以下であることが好ましい。これにより、接触面の耐久性(特に、異物混入環境下における接触面の耐久性)を改善することができる。なお、残留オーステナイトの体積率が25パーセント未満である場合、接触面の耐久性が不足するおそれがある。また、残留オーステナイトの体積率が35パーセントを超える場合、残留オーステナイトの分解に伴う経年変化が懸念される。
内輪10、外輪20及び玉30の接触面からの深さが50μmとなる位置における硬さは、653Hv以上800Hv以下であることが好ましい。接触面からの深さが50μmとなる位置における硬さが653Hv未満である場合、接触面の耐久性が不足するおそれがある。他方で、接触面からの深さが50μmとなる位置における硬さが800Hvを超える場合、延性及び靱性が低下し、早期損傷が生じるおそれがある。
表層部50の鋼は、マルテンサイトブロック粒を有している。隣り合う2つのマルテンサイトブロック粒は、粒界において、結晶方位の差が15°以上になっている。このことを別の観点から言えば、結晶方位にずれがある箇所が存在していても、結晶方位の差が15°未満である場合、当該箇所は、マルテンサイトブロック粒の結晶粒界とは見做されない。マルテンサイトブロック粒の粒界は、EBSD(Electron Back Scattered Diffraction)法により決定される。
以下に、転がり軸受100の製造方法を説明する。
以下に、転がり軸受100の効果を説明する。
以下に、転がり軸受100の実施例を説明する。
転がり軸受のサンプルとして、サンプル1、サンプル2及びサンプル3が準備された。サンプル1、サンプル2及びサンプル3は、内径30mm、外径47mm及び幅11mmのJIS規格51106型番の単式スラスト玉軸受である。
サンプル1、サンプル2及びサンプル3に対して、転動疲労寿命試験を行った。表7に示されるように、転動疲労寿命試験は、最大接触面圧が2.3GPa、0回転/分と2500回転/分との間で急加減速を行う、ポリグリコール及び純水を混合したものを用いて潤滑する、との条件で行われた。
サンプル1及びサンプル3の軌道部材(内輪及び外輪)の表層部への水素侵入特性を、以下の方法により評価した。この評価では、第1に、上記の転動疲労寿命試験に供される前のサンプル1及びサンプル3の軌道部材を室温から400℃まで加熱することにより、転動疲労寿命試験に供される前のサンプル1及びサンプル3の軌道部材からの水素放出量が測定された。第2に、転動疲労寿命試験に50時間供された後のサンプル1及びサンプル3の軌道部材を室温から400℃まで加熱することにより、転動疲労寿命試験に50時間供された後のサンプル1及びサンプル3の軌道部材からの水素放出量が測定された。
以下に、第2実施形態に係る転がり軸受(以下「転がり軸受100A」とする)の構成を説明する。
以下に、転がり軸受100Aの効果を説明する。
Claims (6)
- 転がり軸受であって、
複数の玉と、
2つの軌道部材とを備え、
前記玉及び前記軌道部材は、接触面を有し、
前記玉及び前記軌道部材のうちの少なくともいずれかは、前記接触面からの深さが20μmまでの領域に表層部が形成されており、
前記玉及び前記軌道部材のうちの前記接触面に前記表層部が形成されている部材は、焼き入れが行われた鋼製であり、
前記鋼は、0.70質量パーセント以上1.10質量パーセント以下の炭素と、0.15質量パーセント以上0.35質量パーセント以下のシリコンと、0.30質量パーセント以上0.60質量パーセント以下のマンガンと、1.30質量パーセント以上1.60質量パーセント以下のクロムと、0.01質量パーセント以上0.50質量パーセント以下のモリブデンと、0.01質量パーセント以上0.50質量パーセント以下のバナジウムとを含有するとともに、残部が鉄及び不可避不純物からなり、
前記表層部中における窒素の含有量は、0.2質量パーセント以上0.8質量パーセント以下であり、
前記軌道部材の前記接触面である軌道面は、前記転がり軸受の中心軸を通り、かつ前記中心軸に平行な断面視において、部分円弧になっており、
前記部分円弧の直径は、前記玉の直径の1.01倍以上1.08倍以下である、転がり軸受。 - 前記鋼は、0.90質量パーセント以上1.10質量パーセント以下の炭素と、0.20質量パーセント以上0.30質量パーセント以下のシリコンと、0.40質量パーセント以上0.50質量パーセント以下のマンガンと、1.40質量パーセント以上1.60質量パーセント以下のクロムと、0.20質量パーセント以上0.30質量パーセント以下のモリブデンと、0.20質量パーセント以上0.30質量パーセント以下のバナジウムとを含有するとともに、残部が鉄及び不可避不純物からなり、
前記表層部中における窒素の含有量は、0.3質量パーセント以上0.5質量パーセント以下である、請求項1に記載の転がり軸受。 - 前記表層部が形成されている前記接触面に直交している断面視において、前記表層部中には粒径が0.50μm以下の析出物が100μm2あたり合計して60個以上存在し、かつ、前記表層部での前記析出物の面積率の合計が1パーセント以上10パーセント以下であり、
前記表層部が形成されている前記接触面からの深さが50μmの位置での残留オーステナイト量の体積率は、20パーセント以上40パーセント以下であり、
前記表層部が形成されている前記接触面からの深さが50μmの位置での硬さは、653Hv以上800Hv以下である、請求項1又は請求項2に記載の転がり軸受。 - 前記表層部が形成されている前記接触面に直交している断面視において、前記表層部中には粒径が0.50μm以下の析出物が100μm2あたり合計して80個以上存在し、かつ、前記表層部での前記析出物の面積率の合計が2パーセント以上7パーセント以下であり、
前記表層部が形成されている前記接触面からの深さが50μmの位置での残留オーステナイト量の体積率は、25パーセント以上35パーセント以下であり、
前記表層部が形成されている前記接触面からの深さが50μmの位置での硬さは、653Hv以上800Hv以下である、請求項1又は請求項2に記載の転がり軸受。 - 転がり軸受であって、
複数の玉と、
2つの軌道部材とを備え、
前記玉及び前記軌道部材は、接触面を有し、
前記玉及び前記軌道部材のうちの少なくともいずれかは、前記接触面からの深さが20μmまでの領域に表層部が形成されており、
前記玉及び前記軌道部材のうちの前記接触面に前記表層部が形成されている部材は、焼き入れが行われた鋼製であり、
前記鋼は、0.70質量パーセント以上1.10質量パーセント以下の炭素と、0.15質量パーセント以上0.35質量パーセント以下のシリコンと、0.30質量パーセント以上0.60質量パーセント以下のマンガンと、1.30質量パーセント以上1.60質量パーセント以下のクロムと、0.01質量パーセント以上0.50質量パーセント以下のモリブデンと、0.01質量パーセント以上0.50質量パーセント以下のバナジウムとを含有するとともに、残部が鉄及び不可避不純物からなり、
前記表層部中における窒素の含有量は、0.2質量パーセント以上0.8質量パーセント以下であり、
前記軌道部材は、内輪及び外輪であり、
前記内輪の外径及び前記外輪の内径は、それぞれ、前記玉のピッチ円直径から前記玉の直径を減じた値以上及び前記玉のピッチ円直径に前記玉の直径を加えた値以下であり、
前記外輪の肉厚は、前記外輪に加わる引張応力が700MPa以下となるように設定されており、
前記内輪の前記接触面である第1軌道面と前記玉の前記接触面である転動面との合成粗さ及び前記外輪の前記接触面である第2軌道面と前記転動面との合成粗さの少なくともいずれかは、0.05μm以上であり、
前記玉の前記第1軌道面及び前記第2軌道面との接触角は、30°未満である、転がり軸受。 - 前記転がり軸受は、車両のトランスミッション用、車両の補機用又は車両のモータ用である、請求項1~請求項5のいずれか1項に記載の転がり軸受。
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US18/287,626 US20240183401A1 (en) | 2021-04-30 | 2022-04-22 | Rolling bearing |
CN202280032026.7A CN117280126A (zh) | 2021-04-30 | 2022-04-22 | 滚动轴承 |
EP22795684.4A EP4332248A1 (en) | 2021-04-30 | 2022-04-22 | Rolling bearing |
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2021
- 2021-04-30 JP JP2021077614A patent/JP7212100B2/ja active Active
-
2022
- 2022-04-22 CN CN202280032026.7A patent/CN117280126A/zh active Pending
- 2022-04-22 US US18/287,626 patent/US20240183401A1/en active Pending
- 2022-04-22 KR KR1020237039996A patent/KR20240004570A/ko unknown
- 2022-04-22 WO PCT/JP2022/018566 patent/WO2022230771A1/ja active Application Filing
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JP2000282178A (ja) | 1998-10-22 | 2000-10-10 | Nsk Ltd | 転がり軸受 |
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