WO2022038893A1 - 硬化性樹脂、硬化性樹脂組成物、及び、硬化物 - Google Patents
硬化性樹脂、硬化性樹脂組成物、及び、硬化物 Download PDFInfo
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- WO2022038893A1 WO2022038893A1 PCT/JP2021/023889 JP2021023889W WO2022038893A1 WO 2022038893 A1 WO2022038893 A1 WO 2022038893A1 JP 2021023889 W JP2021023889 W JP 2021023889W WO 2022038893 A1 WO2022038893 A1 WO 2022038893A1
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2150/00—Compositions for coatings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
- C08J2367/03—Polyesters derived from dicarboxylic acids and dihydroxy compounds the dicarboxylic acids and dihydroxy compounds having the hydroxy and the carboxyl groups directly linked to aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2369/00—Characterised by the use of polycarbonates; Derivatives of polycarbonates
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
- H05K2201/01—Dielectrics
- H05K2201/0137—Materials
- H05K2201/0145—Polyester, e.g. polyethylene terephthalate [PET], polyethylene naphthalate [PEN]
Definitions
- the present invention provides a cured product, a varnish, a prepreg, a laminate, and a circuit board obtained by a curable resin composition containing a curable resin having a specific structure, the curable resin, a radical polymerization initiator, and a flame retardant. Regarding.
- vinyl group-containing curable resins having various chemical structures have been conventionally proposed.
- a curable resin for example, a curable resin such as divinylbenzyl ether of bisphenol, polyvinylbenzyl ether of novolak, and a polyphenylene ether resin containing aliphatic unsaturatedity have been proposed (for example, Patent Document 1). See ⁇ 3).
- the vinyl group-containing curable resin including the conventional polyvinyl benzyl ether can withstand the low dielectric loss tangent required for the electric insulating material application, especially the high frequency electric insulating material application, and the lead-free soldering process. It did not give a cured product having both heat resistance.
- flame retardancy is also required for electrically insulating materials such as printed circuit boards, but if a large amount of flame retardant is added to satisfy the flame retardancy, the flame retardancy and dielectric properties will be inferior. At the same time, the current situation was that they were not satisfied.
- the problem to be solved by the present invention is flame retardancy by using a curable resin composition containing a curable resin having a specific structure, the curable resin, a radical polymerization initiator, and a flame retardant.
- a curable resin composition containing a curable resin having a specific structure, the curable resin, a radical polymerization initiator, and a flame retardant.
- the present inventors have made a curable resin that can contribute to heat resistance and low dielectric properties, and the curable resin, a radical polymerization initiator, and a flame retardant.
- the cured product obtained from the curable resin composition containing the above has been found to be excellent in flame retardancy, heat resistance, and low dielectric property, and the present invention has been completed.
- the present invention has at least one reactivity selected from the group consisting of a repeating unit represented by the following general formula (1) and a (meth) acryloyloxy group, a vinylbenzyl ether group, and an allyl ether group.
- the present invention relates to a resin composition containing a curable resin having a group as a terminal structure, the curable resin, a radical polymerization initiator (B), and a flame retardant (C).
- Ra and Rb each independently represent an alkyl group having 1 to 12 carbon atoms, an aryl group, an aralkyl group, or a cycloalkyl group.
- K represents an integer of 0 to 3
- X represents an integer of 0 to 3.
- Y represents the following general formula (2) or (3).
- Z represents an alicyclic group, an aromatic group, or a heterocyclic group.
- the above general formula (1) is preferably represented by the following general formula (1A).
- Z is a benzene ring.
- the reactive group is preferably a methacryloyloxy group.
- the curable resin of the present invention preferably has a weight average molecular weight of 500 to 50,000.
- the curable resin composition of the present invention preferably further contains a curable resin (D) other than the curable resin.
- the component (B) is a dialkyl peroxide-based organic peroxide.
- the component (C) contains a phosphorus-based flame retardant represented by any of the following general formulas (P-1) to (P-5).
- P-1 a phosphorus-based flame retardant represented by any of the following general formulas (P-1) to (P-5).
- R 11 independently represents an alkyl group, an aryl group, an aralkyl group, or a cycloalkyl group having 1 to 12 carbon atoms
- R 12 is an alkylene group or an arylene group.
- M c + represents a c-valent metal ion
- R 16 independently represents an alkyl group having 1 to 12 carbon atoms, an aryl group, an aralkyl group, or a cycloalkyl group, and forms a cyclic structure together with a phosphorus atom.
- R 17 represents a vinyl group, a vinylbenzyl group, or a (meth) acryloyloxy group, and f and g independently represent 0 or 1, respectively.
- R 18 independently represents an alkyl group having 1 to 12 carbon atoms, an aryl group, an aralkyl group, or a cycloalkyl group, and forms a cyclic structure together with a phosphorus atom.
- R 19 represents a divalent group having an arylene structure
- R 20 represents a (meth) acryloyloxy group, a vinylbenzyl ether group, or an allyl ether group
- h represents 0 or 1. .
- the curable resin composition of the present invention comprises a group in which the component (D) is composed of an epoxy resin, a phenol resin, an active ester resin, a cyanate ester resin, a maleimide resin, a benzoxazine resin, a polyphenylene ether resin, and a vinyl resin. It is preferably at least one curable resin of choice.
- the present invention relates to a cured product obtained by subjecting the curable resin composition to a curing reaction.
- the present invention relates to a varnish obtained by diluting the curable resin composition with an organic solvent.
- the present invention relates to a prepreg having a reinforcing base material and a semi-cured product of the varnish impregnated in the reinforcing base material.
- the present invention relates to a laminate having a base material and a layer containing the cured product.
- the present invention relates to a circuit board obtained by laminating the prepreg and copper foil and heat-pressing molding.
- the curable resin of the present invention is excellent in heat resistance and low dielectric property, and the cured product obtained by the curable resin composition containing the curable resin, the radical polymerization initiator, and the flame retardant is flame-retardant. It is useful because it has excellent properties, heat resistance, and low dielectric properties.
- the curable resin of the present invention is at least one selected from the group consisting of a repeating unit represented by the following general formula (1), a (meth) acryloyloxy group, a vinylbenzyl ether group, and an allyl ether group.
- the present invention relates to a curable resin having a reactive group (crosslinking group) as a terminal structure.
- a curable resin having as a terminal structure is referred to as a curable resin (A) (also referred to as “component (A)”).
- Ra and Rb each independently represent an alkyl group having 1 to 12 carbon atoms, an aryl group, an aralkyl group, or a cycloalkyl group.
- k represents an integer of 0 to 3.
- X represents a hydrocarbon group.
- Y represents the following general formula (2) or (3).
- Z represents an alicyclic group, an aromatic group, or a heterocyclic group.
- the ester bond or carbonate bond contained in the component (A) has lower molecular motility than the ether group or the like, and thus has low dielectric properties ( It is derived from the reactive group (bridge group) due to the presence of the substituents Ra and Rb (particularly Ra) at a position adjacent to the reactive group (bridge group).
- the polarity is constrained by the steric obstacle of Ra, and a cured product having a lower dielectric tangent can be obtained. Further, by having a reactive group (crosslinking group) in the component (A), the obtained cured product has excellent heat resistance and further has an ester bond or a carbonate bond having low molecular motility. It is possible to obtain a cured product having not only low dielectric properties but also a high glass transition temperature.
- Ra and Rb independently represent an alkyl group having 1 to 12 carbon atoms, an aryl group, an aralkyl group, or a cycloalkyl group, and preferably an alkyl having 1 to 4 carbon atoms. It is a group, an aryl group, or a cycloalkyl group.
- Ra and Rb are alkyl groups having 1 to 12 carbon atoms or the like, the flatness in the vicinity of the benzene ring in the general formula (1) is lowered, and the crystallinity is lowered, so that the solvent solubility is improved and the solvent solubility is improved. , The melting point is lowered, which is a preferable embodiment.
- the substituents Ra and Rb are present at positions adjacent to the reactive group (crosslinking group)
- the polarity derived from the reactive group (crosslinking group) is the steric hindrance of Ra. It is preferable to obtain a cured product which is constrained by obstacles and has a low dielectric ad tangent.
- k represents an integer of 0 to 3, preferably an integer of 0 to 1.
- the flatness in the vicinity of the benzene ring in the general formula (1) is lowered, and the crystallinity is lowered, so that the solvent solubility is improved and the melting point is lowered, which is a preferable embodiment.
- k represents an integer of 0 to 3, preferably an integer of 0 to 1.
- X may be a hydrocarbon group, but it is preferably represented by the structures of the following general formulas (4) to (6) from the viewpoint of easy availability of industrial raw materials.
- the structure of the following general formula (4) is more preferable because it has a good balance between heat resistance and low dielectric properties.
- R 1 and R 2 are independently represented by a hydrogen atom, an alkyl group having 1 to 12 carbon atoms, an aryl group, an aralkyl group, or a cycloalkyl group. Alternatively, R 1 and R 2 may be combined together to form a cyclic skeleton.
- n represents an integer of 0 to 2, preferably an integer of 0 to 1. When n is within the above range, high heat resistance is obtained, which is a preferable embodiment.
- Y represents the general formula (2) or (3), and is preferably the general formula (2) from the viewpoint of heat resistance.
- Z is represented by an alicyclic group, an aromatic group, or a heterocyclic group in order to obtain a highly heat-resistant cured product, and is preferably represented by the following general formula (7).
- the structure is represented by (11), and the structure (benzene ring) of the following general formula (7) is more preferable from the viewpoint of cost and heat resistance.
- the component (A) preferably has at least one reactive group (crosslinking group) selected from the group consisting of a (meth) acryloyloxy group, a vinylbenzyl ether group, and an allyl ether group as a terminal structure.
- a methacryloyloxy group has a low dielectric positive tangent in the obtained cured product.
- the methacryloyloxy group forms an ester bond, whereas the vinylbenzyl ether group and the allyl ether group form an ether bond, and tend to have high molecular motility and high dielectric positivity.
- the general formula (1) is preferably a repeating unit represented by the following general formula (1A), and the reactive group is preferably a methacryloyloxy group. Having a methacryloyloxy group as the terminal structure is preferable because the obtained cured product has a low dielectric loss tangent.
- Rc preferably represents a hydrogen atom or a methyl group, and more preferably a hydrogen atom. Since the Rc is a hydrogen atom or the like, the polarity becomes low, which is a preferable embodiment.
- Ra, Rb, and Y are the same as in the general formula (1).
- the component (A) has a repeating unit represented by the general formula (1) (or a repeating unit represented by the general formula (1A)) and the reactive group (crosslinking group) as a terminal structure.
- a repeating unit represented by the general formula (1) or a repeating unit represented by the general formula (1A)
- the reactive group crosslinking group
- other repeating units (structures) may be included as long as the characteristics of the component (A) are not impaired.
- the weight average molecular weight (Mw) of the component (A) is preferably 500 to 50,000, more preferably 1000 to 10000, and even more preferably 1500 to 5000. When it is within the above range, the solvent solubility is improved and the processing workability is good, which is preferable.
- Examples of the production method include a method of reacting in an organic solvent such as an interfacial polymerization method, a method of reacting in a molten state such as melt polymerization, and the like.
- Interfacial polymerization method a solution (organic phase) in which a divalent carboxylic acid halide and a cross-linking group-introducing agent used for introducing a reactive group (bridging group) having a terminal structure are dissolved in an organic solvent incompatible with water is used. Is mixed with an alkaline aqueous solution (aqueous phase) containing a dihydric phenol, a polymerization catalyst and an antioxidant, and the polymerization reaction is carried out while stirring at a temperature of 50 ° C. or lower for 1 to 8 hours.
- a solution (organic phase) in which a cross-linking group-introducing agent used for introducing a reactive group (cross-linking group) having a terminal structure is dissolved in an organic solvent incompatible with water is used.
- examples thereof include a method in which phosgen is blown into an alkaline aqueous solution (aqueous phase) containing a divalent phenol, a polymerization catalyst and an antioxidant, and the polymerization reaction is carried out while stirring at a temperature of 50 ° C. or lower for 1 to 8 hours.
- a solvent that is incompatible with water and dissolves polyarylate is preferable.
- a solvent that is incompatible with water and dissolves polyarylate.
- examples of such a solvent include methylene chloride, 1,2-dichloroethane, chloroform, carbon tetrachloride, chlorobenzene, 1,1,2,2-tetrachloroethane, 1,1,1-trichloroethane, o-, m-, p.
- -Chloroform solvents such as dichlorobenzene, aromatic hydrocarbons such as toluene, benzene and xylene, or tetrahydrofuran can be mentioned, and methylene chloride is preferable because it is easy to use in production.
- alkaline aqueous solution used for the aqueous phase examples include an aqueous solution of sodium hydroxide and an aqueous solution of potassium hydroxide.
- Antioxidants are used to prevent the oxidation of divalent phenol components.
- examples of the antioxidant include sodium hydrosulfite, L-ascorbic acid, erythorbic acid, catechin, tocophenol, and butylhydroxyanisole. Of these, sodium hydrosulfite is preferable because it has excellent water solubility.
- polymerization catalyst examples include quaternary ammonium salts such as tri-n-butylbenzylammonium halide, tetra-n-butylammonium halide, trimethylbenzylammonium halide, and triethylbenzylammonium halide; and tri-n-butylbenzylphosphonium halide.
- quaternary ammonium salts such as tri-n-butylbenzylammonium halide, tetra-n-butylammonium halide, trimethylbenzylammonium halide, and triethylbenzylammonium halide
- tri-n-butylbenzylphosphonium halide Tetra-n-butylphosphonium halide, trimethylbenzylphosphonium halide, quaternary phosphonium salt such as triethylbenzylphosphonium halide and the like.
- tri-n-butylbenzylammonium halide, trimethylbenzylammonium halide, tetra-n-butylammonium halide, tri-n-butylbenzylphosphonium halide, and tetra can be obtained because a polymer having a high molecular weight and a low acid value can be obtained.
- -N-Butylphosphonium halide is preferred.
- the amount of the polymerization catalyst added is preferably 0.01 to 5.0 mol%, more preferably 0.1 to 1.0 mol%, based on the number of moles of the divalent phenol used for the polymerization.
- the amount of the polymerization catalyst added is 0.01 mol% or more, the effect of the polymerization catalyst can be obtained and the molecular weight of the polyarylate resin becomes high, which is preferable.
- it is 5.0 mol% or less, the hydrolysis reaction of the divalent aromatic carboxylic acid halide is suppressed, and the molecular weight of the polyarylate resin is increased, which is preferable.
- divalent phenol examples include 2,2-bis (4-hydroxy-3,5-dimethylphenyl) propane, 2,2-bis (4-hydroxy-3,6-dimethylphenyl) propane, and 2,2-.
- divalent carboxylic acid halide examples include terephthalic acid halide, isophthalic acid halide, orthophthalic acid halide, diphenylic acid halide, biphenyl-4,4'-dicarboxylic acid halide, 1,4-naphthalenedicarboxylic acid halide, and 2,3-.
- Naphthalenedicarboxylic acid halide 2,6-naphthalenedicarboxylic acid halide, 2,7-naphthalenedicarboxylic acid halide, 1,8-naphthalenedicarboxylic acid halide, 1,5-naphthalenedicarboxylic acid halide, diphenyl ether-2,2'-dicarboxylic acid Halide, diphenyl ether-2,3'-dicarboxylic acid halide, diphenyl ether-2,4'-dicarboxylic acid halide, diphenyl ether-3,3'-dicarboxylic acid halide, diphenyl ether-3,4'-dicarboxylic acid halide, diphenyl ether-4, Examples thereof include 4'-dicarboxylic acid halide, 1,4-cyclohexanedicarboxylic acid halide, and 1,3-cyclohexanedicarboxylic acid halide.
- the terminal structure of the component (A) has at least one reactive group selected from the group consisting of a (meth) acryloyloxy group, a vinylbenzyl ether group, and an allyl ether group, and these reactive groups (
- a cross-linking group-introducing agent can be used to introduce the cross-linking group).
- the cross-linking group introducing agent for example, anhydrous (meth) acrylic acid, (meth) acrylic acid chloride, chloromethylstyrene, chlorostyrene, allyl chloride, allyl bromide and the like can be reacted, and in particular, the terminal thereof.
- the cured product obtained by the curable resin composition containing a curable resin having a methacryloyloxy group introduced is an anhydrous (meth) acrylic acid or (meth) acrylic acid chloride from the viewpoint of having a low dielectric positive tangent. Is more preferable to use.
- a reactive group can be introduced into the curable resin, and the thermosetting property has a low dielectric constant and a low dielectric loss tangent, which is a preferable embodiment.
- Examples of the anhydrous (meth) acrylic acid include methacrylic anhydride and methacrylic anhydride.
- examples of the (meth) acrylic acid chloride include methacrylic acid chloride and acrylic acid chloride.
- examples of chloromethylstyrene include p-chloromethylstyrene and m-chloromethylstyrene
- examples of chlorostyrene include p-chlorostyrene and m-chlorostyrene.
- Examples of allyl chloride include 3-chloro-1-propene
- examples of allyl bromide include 3-bromo-1-propene. These may be used alone or in combination. Of these, it is particularly preferable to use methacrylic anhydride or methacrylic acid chloride, which can obtain a cured product having a lower dielectric loss tangent.
- the melt polymerization method includes acetylation of the raw material dihydric phenol and then transacetic acid polymerization of the acetylated dihydric phenol and the divalent carboxylic acid, or transesterification of the dihydric phenol and the carbonic acid ester. Examples include methods of reaction.
- the aromatic dicarboxylic acid component, the divalent phenol component, and acetic anhydride are put into the reaction vessel. Then, nitrogen substitution is performed, and the mixture is stirred under an inert atmosphere at a temperature of 100 to 240 ° C., preferably 120 to 180 ° C. for 5 minutes to 8 hours, preferably 30 minutes to 5 hours under normal pressure or pressure.
- the molar ratio of acetic anhydride to the hydroxyl group of the divalent phenol component is preferably 1.00 to 1.20.
- the deacetic acid polymerization reaction is a reaction in which an acetylated dihydric phenol and a divalent carboxylic acid are reacted and polycondensed.
- the temperature was maintained at 240 ° C. or higher, preferably 260 ° C. or higher, more preferably 280 ° C. or higher, 500 Pa or lower, preferably 260 Pa or lower, more preferably 130 Pa or lower, for 30 minutes or longer. Stir.
- the temperature is 240 ° C. or higher, the decompression degree is 500 Pa or lower, or the holding time is 30 minutes or longer, the deacetic acid reaction proceeds sufficiently and the amount of acetic acid in the obtained polyarylate resin can be reduced. , The overall polymerization time can be shortened and the deterioration of polymer color tone can be suppressed.
- a catalyst in the acetylation reaction and the deacetic acid polymerization reaction, it is preferable to use a catalyst as needed.
- the catalyst include organic titanium acid compounds such as tetrabutyl titanate; zinc acetate; alkali metal salts such as potassium acetate; alkaline earth metal salts such as magnesium acetate; antimony trioxide; hydroxybutyltin oxide, tin octylate and the like.
- Organic tin compounds examples include heterocyclic compounds such as N-methylimidazole.
- the amount of the catalyst added is usually 1.0 mol% or less, more preferably 0.5 mol% or less, still more preferably 0.2 mol% or less, based on all the monomer components of the obtained polyarylate resin. Is.
- the reaction is carried out at a temperature of 120 to 260 ° C., preferably 160 to 200 ° C. for 0.1 to 5 hours, preferably 0.5 to 6 hours, at a pressure of normal pressure to 1 Torr.
- the catalyst for the transesterification reaction for example, salts of zinc, tin, zirconium, and lead are preferably used, and these can be used alone or in combination.
- Specific examples of the ester exchange catalyst include zinc acetate, zinc benzoate, zinc 2-ethylhexanate, tin chloride (II), tin chloride (IV), tin acetate (II), tin acetate (IV), and dibutyltin.
- Dilaurate, dibutyltin oxide, dibutyltin dimethoxyde, zirconium acetylacetonate, zirconium oxyacetate, zirconium tetrabutoxide, lead acetate (II), lead acetate (IV) and the like are used. These catalysts are used at a ratio of 0.000001 to 0.1 mol%, preferably 0.00001 to 0.01 mol%, based on a total of 1 mol of divalent phenol.
- the divalent phenol in the above-mentioned interfacial polymerization method can be used in the same manner.
- divalent carboxylic acid examples include terephthalic acid, isophthalic acid, orthophthalic acid, diphenylic acid, biphenyl-4,4'-dicarboxylic acid, 1,4-naphthalenedicarboxylic acid, 2,3-naphthalenedicarboxylic acid, and 2,6.
- Examples of the carbonic acid ester include diphenyl carbonate, ditril carbonate, bis (chlorophenyl) carbonate, m-cresyl carbonate, dinaphthyl carbonate, bis (diphenyl) carbonate, diethyl carbonate, dimethyl carbonate, dibutyl carbonate, dicyclohexyl carbonate and the like. Be done.
- the terminal structure of the component (A) has at least one reactive group selected from the group consisting of a (meth) acryloyloxy group, a vinylbenzyl ether group, and an allyl ether group, and these reactive groups (
- a cross-linking group-introducing agent can be used to introduce the cross-linking group), and as the cross-linking group-introducing agent, the cross-linking group-introducing agent in the above-mentioned interfacial polymerization method can be similarly used.
- the present invention relates to a curable resin composition containing the curable resin (A), a radical polymerization initiator (B) and a flame retardant (C) described later. Since the curable resin has excellent solvent solubility, the curable resin composition can be easily prepared and has excellent handleability, and the curable resin composition contributes to flame retardancy, heat resistance, and low dielectric property. It can be and is useful.
- the curable resin composition of the present invention preferably further contains a curable resin (D) (also referred to as "component (D)”) other than the component (A).
- a curable resin (D) also referred to as "component (D)
- component (D) also referred to as "component (D)
- the component (D) includes an epoxy resin, a phenol resin, an active ester resin, a cyanate ester resin, a maleimide resin, a benzoxazine resin, and a polyphenylene ether resin from the viewpoints of high heat resistance, high adhesion, low thermal expansion, and compatibility. , And at least one curable resin selected from the group consisting of vinyl resins.
- the epoxy resin examples include dicyclopentadiene type epoxy resin, bisphenol A type epoxy resin, bisphenol F type epoxy resin, bisphenol S type epoxy resin, phenol novolac type epoxy resin, cresol novolac type epoxy resin, and bisphenol A novolak type epoxy.
- phenolic resin examples include phenol novolac, o-cresol novolak, p-cresol novolak, t-butylphenol novolak, dicyclopentadiencresol, polyparavinylphenol, bisphenol A type novolak, phenol aralkyl resin, naphthol aralkyl resin, and biphenyl.
- Examples of the active ester resin include active ester compounds obtained by reacting a carboxylic acid compound and / or a thiocarboxylic acid compound with a hydroxy compound and / or a thiol compound.
- cyanate ester resin examples include bis (4-cyanatophenyl) ethane, 2,2-bis (4-cyanatophenyl) propane, and 2,2 bis (3,5 dimethyl-4-cyanatophenyl) methane. , 2,2-Bis (4-Cyanatophenyl) -1,1,1,3,3,3-hexafluoropropane, ⁇ , ⁇ '-bis (4-Cyanatophenyl) -m-diisopropylbenzene, phenol Examples thereof include cyanate esterified products of the added dicyclopentadiene polymer.
- maleimide resin examples include 4,4'diphenylmethane bismaleimide, m phenylene bismaleimide, bisphenol A, diphenyl ether bismaleimide, 3,3' dimethyl, 5,5', diethyl 4,4', diphenylmethane bismaleimide, 4-methyl 1, 3 Phenylene bismaleimide, 1,6'bismaleimide (2,2,4 trimethyl) hexane can be mentioned.
- benzoxazine resin examples include Fa-type benzoxazine compounds and diaminodiphenylmethane obtained by reacting a bisphenol compound with an amine compound (for example, aniline) such as bisphenol A type benzoxazine compound and bisphenol F type benzoxazine compound.
- an amine compound for example, aniline
- examples thereof include Pd-type benzoxazine compounds obtained by reacting a phenyldiamine compound with a phenol compound, such as a type benzoxazine compound.
- polyphenylene ether resin examples include poly (2,6-dimethyl-1,4-phenylene) ether, poly (2,6-dimethyl-1,4-phenylene) ether and polystyrene alloyed polymers, and poly (2). , 6-Dimethyl-1,4-phenylene) ether and styrene-butadiene copolyma alloyed polymers and the like.
- vinyl resin examples include trialkenyl isocyanurate compounds such as triallyl isocyanurate, polybutadiene resins having 1,2-butadiene, cis-1,4 butadiene, and trans-1,4 butadiene repeating units, and vinyl in the molecule.
- vinylbenzyl compounds such as styrene having a benzyl group and divinylbenzene.
- a maleimide resin, a cyanate ester resin, a polyphenylene ether resin, and a vinyl resin are particularly preferable because they reduce the dielectric loss tangent.
- the curable resin composition of the present invention preferably contains 0 to 80 parts by mass of the component (D), more preferably 0 to 60 parts by mass, with respect to 100 parts by mass of the component (A). ..
- the component (D) can be blended within a range that does not impair the characteristics of the present invention, and is appropriately used when it is desired to impart the characteristics derived from the component (D) within a range that does not exceed the component (A). can do.
- the curable resin composition of the present invention is characterized by containing a radical polymerization initiator (B) (also referred to as "component (B)").
- B radical polymerization initiator
- component (B) examples include isobutyl peroxide, ⁇ , ⁇ 'bis (neodecanoylperoxy) diisopropylbenzene, cumylperoxyneodecanoate, and di-n-propylperoxydicarbonate 1,1.
- dialkyl peroxide-based organic peroxide because the cross-linking density is improved.
- ⁇ ⁇ '-bis (t-butylperoxy) diisopropylbenzene, dicumyl peroxide, 2,5 -Dimethyl-2,5-di (t-butylperoxy) hexane, t-butylcumyl peroxide, di-t-butyl peroxide, 2,5-dimethyl-2,5-di (t-butylperoxy)
- hexin-3 is more preferred.
- the curable resin composition of the present invention preferably contains 0.05 to 30 parts by mass of the component (B) with respect to 100 parts by mass of the component (A), preferably 0.1 to 20 parts by mass. It is more preferable, and it is further preferable to contain 0.5 to 10 parts by mass.
- the content of the component (B) is 0.05 parts by mass or more, a sufficiently cured cured product can be obtained, and when it is 30 parts by mass or less, deterioration of the inductive characteristics can be suppressed, which is preferable.
- the curable resin composition of the present invention is characterized by containing a flame retardant (C) (also referred to as “component (C)").
- the cured product obtained by using the curable resin composition containing the component (C) is excellent in flame retardancy and is a preferable embodiment.
- the component (C) can be used without particular limitation, and examples thereof include phosphorus-based flame retardants, nitrogen compounds, silicone-based flame retardants, metal hydroxides, polysilanes, and the like, and examples of the phosphorus-based flame retardants are organic. Phosphorus-based flame retardants, reactive organic phosphorus-based flame retardants, organic nitrogen-containing phosphorus compounds and the like are preferable.
- organophosphorus flame retardant examples include phenanthren-type phosphorus compounds such as HCA, HCA-HQ and HCA-NQ manufactured by Sanko Co., Ltd., and phosphorus-containing benzoxazines such as HFB-2006M manufactured by Showa Polymer Co., Ltd. Compound, Leofos 30, 50, 65, 90, 110, TPP, RPD, BAPP, CPD, TCP, TXP, TBP, TOP, KP140, TIBP, FP-800 manufactured by Ajinomoto Fine Techno Co., Ltd.
- phosphoric acid ester compounds such as PX-200 manufactured by Daihachi Chemical Co., Ltd.
- organic phosphinates such as OP930, OP935, OP945 manufactured by Clariant Co., Ltd. , FX289, FX305 and other phosphorus-containing epoxy resins manufactured by Toto Kasei Co., Ltd., phosphorus-containing phenoxy resins such as ERF001 manufactured by Toto Kasei Co., Ltd., and phosphorus-containing epoxy resins such as YL7613 manufactured by Japan Epoxy Resin Co., Ltd. Can be mentioned.
- Examples of the reactive organophosphorus flame retardant include MC-2, MC-4, S-2, S-4, V1, V2, V3, V4, V5 and W-1o manufactured by Katayama Chemical Industry Co., Ltd. , W-2h, W-2o, W-3o, W-4o and the like.
- organic nitrogen-containing phosphorus compound examples include phosphoric acid ester amide compounds such as SP670 and SP703 manufactured by Shikoku Kasei Kogyo Co., Ltd., SPB100 and SPEL00 manufactured by Otsuka Chemical Co., Ltd., and FP- manufactured by Fushimi Seisakusho Co., Ltd. Examples thereof include phosphazene compounds such as serials.
- Examples of the metal hydroxide include magnesium hydroxide such as UD65, UD650, and UD653 manufactured by Ube Material Industries Ltd., and B-30, B-325, B-315, and B- of Tomoe Kogyo Co., Ltd.
- Examples thereof include aluminum hydroxide such as 308, B-303, and UFH-20.
- Examples of polysilane include SI-10, SI-20, SI-30 manufactured by Osaka Gas Chemical Co., Ltd.
- a general flame-retardant agent tends to have a high dielectric positive contact due to its use, but as the component (C), PX manufactured by Daihachi Chemical Co., Ltd., particularly from the viewpoint of being able to reduce the dielectric positive contact.
- C the component
- PX manufactured by Daihachi Chemical Co., Ltd.
- -200 and other phosphoric acid ester compounds OP930, OP935, OP945 organic phosphinates manufactured by Clariant Co., Ltd., MC-2, MC-4, S-2, S-4, manufactured by Katayama Chemical Industry Co., Ltd.
- a reactive organophosphorus flame retardant such as V1, V2, V3, V4, V5, W-1o, W-2h, W-2o, W-3o and W-4o.
- a phosphorus-based flame retardant represented by any of the following general formulas (P-1) to (P-5).
- R 11 independently represents an alkyl group, an aryl group, an aralkyl group, or a cycloalkyl group having 1 to 12 carbon atoms, and is preferable from the viewpoint of low dielectric positive tangent. It is a phenyl group having a substituent at the 2,6 position, and particularly preferably a 2,6-dimethylphenyl group.
- R 12 represents an alkylene group or an arylene group, and is preferably a phenylene group from the viewpoint of heat resistance.
- a represents an integer of 0 to 3, and is preferably 0 or 1 from the viewpoint of flame retardancy.
- R 13 independently represents an alkyl group, an aryl group, an aralkyl group, or a cycloalkyl group having 1 to 12 carbon atoms, and is preferable from the viewpoint of low dielectric constant. It is a methyl group, an ethyl group, a propyl group, a butyl group, a cyclohexyl group, a benzyl group, and a phenyl group.
- M b + represents a b-valent metal ion, and examples of the metal include aluminum, magnesium, sodium, potassium, and calcium, and aluminum is preferable from the viewpoint of flame retardancy.
- b represents an integer of 1 to 3, and is preferably 3 from the viewpoint of flame retardancy.
- R 14 independently represents an alkyl group, an aryl group, an aralkyl group, or a cycloalkyl group having 1 to 12 carbon atoms, and is preferable from the viewpoint of low dielectric constant. It is a methyl group, an ethyl group, a propyl group, a butyl group, a cyclohexyl group, a benzyl group, and a phenyl group.
- R 15 represents an alkylene group or an arylene group, and is preferably a phenylene group from the viewpoint of heat resistance.
- M c + represents a c-valent metal ion, and examples of the metal include aluminum, magnesium, sodium, potassium, and calcium, and aluminum is preferable from the viewpoint of flame retardancy.
- R 16 independently represents an alkyl group, an aryl group, an aralkyl group, or a cycloalkyl group having 1 to 12 carbon atoms, and is preferably phenyl from the viewpoint of heat resistance. It is the basis.
- a cyclic structure may be formed together with a phosphorus atom, and R 17 represents a vinyl group, a vinylbenzyl group, or a (meth) acryloyloxy group, and is preferably a vinyl group or a vinylbenzyl group from the viewpoint of low dielectric positive tangent.
- Is. f and g independently indicate 0 or 1, respectively.
- Examples of the phosphorus-based flame retardant that forms a cyclic structure together with the phosphorus atom include the following general formula (P1). (P1)
- R 18 independently represents an alkyl group, an aryl group, an aralkyl group, or a cycloalkyl group having 1 to 12 carbon atoms, and is preferably phenyl from the viewpoint of heat resistance. It is a group.
- a cyclic structure may be formed together with the phosphorus atom, and R 19 represents a divalent group having an arylene structure, and is preferably a phenyl group from the viewpoint of heat resistance.
- R 20 represents a (meth) acryloyloxy group, a vinylbenzyl ether group, or an allyl ether group, and is preferably a vinylbenzyl ether group from the viewpoint of low dielectric positivity.
- h indicates 0 or 1.
- Examples of the phosphorus-based flame retardant that forms a cyclic structure together with the phosphorus atom include the following general formula (P2). (P2)
- the curable resin composition of the present invention preferably contains 0.05 to 300 parts by mass of the component (C) with respect to 100 parts by mass of the component (A), preferably 0.1 to 200 parts by mass. Is more preferable, and it is more preferably contained in an amount of 1 to 100 parts by mass, and further preferably contained in an amount of 5 to 50 parts by mass.
- the content of the component (C) is 0.05 parts by mass or more, the flame retardancy of the obtained cured product is excellent, and when it is 300 parts by mass or less, deterioration of the dielectric property can be suppressed, which is preferable. ..
- the curable resin composition of the present invention contains other resins, curing agents, curing accelerators, and the like. It can be used without particular limitation as long as the object of the invention is not impaired.
- the curable resin composition can be obtained by heating or the like without blending a curing agent or a curing accelerator. However, for example, when the component (D) is blended together, it is separately blended. , Curing agent, curing accelerator and the like can be blended.
- thermoplastic resin In addition to the above-mentioned component (A) and component (D), a thermoplastic resin may be blended, if necessary.
- the thermoplastic resin include styrene butadiene resin, styrene-butadiene-styrene block resin, styrene-isoprene-styrene resin, styrene-maleic anhydride resin, acrylonitrile butadiene resin, polybutadiene resin or their hydrogenated resin, and acrylic. Resin, silicone resin and the like can be used.
- the characteristics derived from the resin can be imparted to the cured product, which is a preferable embodiment.
- the performance that can be imparted can contribute to imparting formability, high frequency characteristics, conductor adhesiveness, solder heat resistance, adjustment of glass transition temperature, coefficient of thermal expansion, smear removal property, and the like.
- curing agent examples include amine compounds, amide compounds, acid anhydride compounds, phenolic compounds, cyanate ester compounds and the like. These curing agents may be used alone or in combination of two or more.
- ⁇ Curing accelerator As the curing accelerator, various substances can be used, and examples thereof include phosphorus compounds, tertiary amines, imidazoles, organic acid metal salts, Lewis acids, amine complex salts and the like. In particular, when used as a semiconductor encapsulating material, phosphorus compounds such as triphenylphosphine or imidazoles are preferable because they are excellent in curability, heat resistance, electrical properties, moisture resistance reliability and the like. These curing accelerators can be used alone or in combination of two or more.
- organic phosphine compounds TPP, TPP-K, TPP-S, TPTP. -S (Hokuko Kagaku Kogyo Co., Ltd.), amines: dicyandiamide, diaminodiphenylethane, guanylurea, Novacure (Asahi Kasei Kogyo Co., Ltd.), Fujicure (Fuji Kasei Kogyo Co., Ltd.) and other amine adduct compounds, 1,8 -Diazabicyclo [5,4,0] undecene-7, 4-dimethylaminopyridine (DMAP), benzyldimethylamine, 2,4,6-tris (dimethylaminomethyl) phenol, etc., imidazoles: 2-phenylimidazole, 1 -Cyanoethyl-2-methylimidazole, 1-cyanoe
- An inorganic filler can be added to the curable resin composition of the present invention, if necessary.
- the inorganic filler include silica (molten silica, crystalline silica), alumina, barium sulfate, talc, kleni, mica powder, aluminum hydroxide, magnesium hydroxide, calcium carbonate, magnesium carbonate, magnesium oxide, boron nitride, and hoe.
- examples thereof include aluminum hydroxide, barium titanate, strontium titanate, calcium titanate, magnesium titanate, bismuth titanate, titanium oxide, barium zirconate, and calcium zirconate.
- the surface may be treated with a silane coupling agent.
- the blending amount of the inorganic filler is particularly large, it is preferable to use fused silica.
- the molten silica can be used in either a crushed form or a spherical shape, but in order to increase the blending amount of the molten silica and suppress the increase in the melt viscosity of the molding material, it is better to mainly use the spherical one. preferable. Further, in order to increase the blending amount of spherical silica, it is preferable to appropriately adjust the particle size distribution of spherical silica.
- ⁇ Other compounding agents Various compounding agents such as a silane coupling agent, a mold release agent, a pigment, and an emulsifier can be added to the curable resin composition of the present invention, if necessary.
- the present invention relates to a cured product obtained by subjecting the curable resin composition to a curing reaction.
- the curable resin composition in addition to the component (A), the component (B), and the component (C), each component such as the component (D) and the curing agent is uniformly mixed according to the purpose. It can be easily made into a cured product by the same method as a conventionally known method.
- the cured product include molded products such as laminates, cast products, adhesive layers, coating films, and films.
- thermosetting and ultraviolet curing reactions examples include thermosetting and ultraviolet curing reactions.
- the thermosetting reaction is easily carried out even without a catalyst, but the reaction proceeds even faster by using the component (B). Can be made to.
- a polymerization initiator, a catalyst, or the like can also be used.
- the present invention relates to a varnish obtained by diluting the curable resin composition with an organic solvent.
- a method for preparing the varnish a known method can be used, and the curable resin composition can be a resin varnish dissolved (diluted) in an organic solvent.
- the present invention relates to a prepreg having a reinforcing base material and a semi-cured product of the varnish impregnated in the reinforcing base material.
- the curable resin composition is semi-cured (or uncured).
- organic solvent examples include toluene, xylene, N, N-dimethylformamide, N, N-dimethylacetamide, N-methyl-2-pyrrolidone, methyl ethyl ketone (MEK), methyl isobutyl ketone, dioxane, tetrahydrofuran and the like. , Alone, or as a mixed solvent of two or more kinds.
- the reinforcing base material impregnated with the varnish is an inorganic fiber such as glass fiber, polyester fiber, polyamide fiber, a woven fabric or non-woven fabric made of organic fiber, a mat, paper or the like, and these may be used alone or. , Can be used in combination.
- the mass ratio of the curable resin composition and the reinforcing base material in the prepreg is not particularly limited, but usually, the curable resin composition (resin content in the prepreg) is 20 to 60% by mass. It is preferable to prepare.
- the conditions for the heat treatment of the prepreg are appropriately selected depending on the type and amount of the organic solvent, catalyst, and various additives used, but are usually at a temperature of 80 to 220 ° C. for 3 minutes to 30 minutes. It is done under such conditions.
- the present invention relates to a laminate having a base material and a layer containing the cured product.
- the laminate formed from the layer containing the cured product (cured product layer) has a low dielectric constant, a low dielectric loss tangent, and high heat resistance, and is therefore preferable because it can be used for a high-frequency-compatible printed circuit board or the like.
- the base material used for the laminate may be an inorganic material such as metal or glass, an organic material such as plastic or wood, or the like, and may be used in a timely manner depending on the intended use.
- glass fiber E glass, D glass, S glass, Q.
- Glass, spherical glass, NE glass, L glass, T glass, inorganic fiber quartz, total aromatic polyamide: polyparaphenylene terephthalamide (Kevlar (registered trademark), manufactured by DuPont Co., Ltd.), copolyparaphenylene 3,4 'Oxydiphenylene terephthalamide (Technora (registered trademark), manufactured by Teijin Techno Products Co., Ltd.), Polyester: 2,6-hydroxynaphthoic acid, parahydroxybenzoic acid (Vectran (registered trademark), manufactured by Klaret Co., Ltd.), Zexion ( Registered trademark (manufactured by KB Salen), organic fiber: polyparaphenylene benzoxazole (Zylon (registered trademark), manufactured by Toyo Spinning Co., Ltd.), polyimide and the like.
- the shape of the laminated body may be a flat plate, a sheet, a three-dimensional structure, or a three-dimensional shape. It may have any shape depending on the purpose, such as one having a curvature on the entire surface or a part thereof. Further, there are no restrictions on the hardness, thickness, etc. of the base material. Further, the cured product of the present invention may be used as a base material, and the cured product of the present invention may be further laminated.
- the laminate When the laminate is used for a circuit board or a semiconductor package substrate, it is preferable to laminate a metal foil, and examples of the metal foil include copper foil, aluminum foil, gold foil, and silver foil, and copper is good in processability. It is preferable to use foil.
- the layer containing the cured product may be formed by directly coating or molding on the base material, or the already molded product may be laminated.
- the coating method is not particularly limited, and the spray method, spin coating method, dip method, roll coating method, blade coating method, doctor roll method, doctor blade method, curtain coating method, slit coating method, etc. Examples include a screen printing method and an inkjet method.
- direct molding in-mold molding, insert molding, vacuum forming, extrusion laminating molding, press molding and the like can be mentioned.
- the cured product of the present invention may be laminated by applying a precursor that can be the base material and curing the cured product, and the precursor that can be the base material or the curable resin composition of the present invention can be used. It may be cured after being bonded in an uncured or semi-cured state.
- the precursor that can be the base material is not particularly limited, and various curable resin compositions and the like can also be used.
- the cured product obtained from the curable resin composition of the present invention is excellent in flame retardancy, heat resistance, and dielectric properties, it can be suitably used for heat-resistant members and electronic members.
- it can be suitably used for varnishes, prepregs, circuit boards, semiconductor encapsulants, semiconductor devices, build-up films, build-up boards, adhesives, resist materials and the like used in the manufacture of prepregs.
- it can be suitably used for a matrix resin of a fiber reinforced resin, and is particularly suitable as a flame-retardant and highly heat-resistant prepreg.
- the heat-resistant members and electronic members thus obtained can be suitably used for various purposes, for example, industrial mechanical parts, general mechanical parts, automobile / railway / vehicle parts, space / aviation-related parts, electronic / electrical parts, and the like.
- industrial mechanical parts for example, industrial mechanical parts, general mechanical parts, automobile / railway / vehicle parts, space / aviation-related parts, electronic / electrical parts, and the like.
- Examples include, but are not limited to, building materials, containers / packaging materials, daily necessities, sports / leisure products, and housing materials for wind power generation.
- the present invention relates to a circuit board obtained by laminating the prepreg and copper foil and heat-pressing molding. Specifically, as a method for obtaining a circuit board from the curable resin composition of the present invention, the above prepregs are laminated by a conventional method, copper foils are appropriately laminated, and the temperature is 170 to 300 ° C. under a pressure of 1 to 10 MPa. A method of heat-pressing molding for 10 minutes to 3 hours can be mentioned.
- the semiconductor encapsulant preferably contains the curable resin composition.
- the curable resin composition is further mixed with a curing accelerator as an optional component and a compounding agent such as an inorganic filler. If necessary, a method of sufficiently melting and mixing the resin with an extruder, a feeder, a roll, or the like until the mixture becomes uniform can be mentioned.
- fused silica is usually used as the inorganic filler, but when used as a high thermal conductivity semiconductor encapsulant for power transistors and power ICs, crystalline silica, alumina, and silicon nitride, which have higher thermal conductivity than fused silica, are used. It is preferable to use high-filling silicon or the like, or to use fused silica, crystalline silica, alumina, silicon nitride, or the like. It is preferable to use an inorganic filler in the range of 30 to 95 parts by mass per 100 parts by mass of the curable resin composition, and above all, improvement of flame retardancy, moisture resistance and solder crack resistance, and linear expansion. In order to reduce the coefficient, 70 parts by mass or more is more preferable, and 80 parts by mass or more is further preferable.
- the semiconductor device preferably contains a cured product obtained by heat-curing the semiconductor encapsulant.
- the semiconductor encapsulant is cast, or molded using a transfer molding machine, an injection molding machine, or the like, and further. Examples thereof include a method of heat curing at 50 to 250 ° C. for 2 to 10 hours.
- step 1 first, the curable resin composition appropriately mixed with rubber, filler, etc. is applied to a circuit board on which a circuit is formed by a spray coating method, a curtain coating method, or the like, and then cured.
- step 2 if necessary, the circuit board coated with the curable resin composition is drilled with a predetermined through-hole portion or the like, treated with a roughening agent, and the surface thereof is washed with hot water. Concavities and convexities are formed on the substrate, and a metal such as copper is plated.
- step 3 the operations of steps 1 and 2 are sequentially repeated as desired, and the resin insulating layer and the conductor layer having a predetermined circuit pattern are alternately built up to form a build-up substrate.
- the through-hole portion may be drilled after the outermost resin insulating layer is formed.
- the build-up substrate in the present invention is coarsely formed by heat-pressing a copper foil with a resin, which is a semi-cured resin composition on a copper foil, onto a wiring board on which a circuit is formed at 170 to 300 ° C. It is also possible to produce a build-up substrate by omitting the steps of forming a chemical surface and plating.
- the build-up film preferably contains the curable resin composition.
- a curable resin composition is applied on a support film and then dried to form a resin composition layer on the support film.
- the method can be mentioned.
- the curable resin composition of the present invention is used for a build-up film, the film is softened under the temperature conditions of laminating (usually 70 to 140 ° C.) in the vacuum laminating method, and is present on the circuit board at the same time as laminating the circuit board. It is important to show fluidity (resin flow) capable of filling the via hole or through hole with the resin, and it is preferable to blend each of the above components so as to exhibit such characteristics.
- the diameter of the through hole of the circuit board is usually 0.1 to 0.5 mm, and the depth is usually 0.1 to 1.2 mm, and it is usually preferable to enable resin filling in this range.
- a varnished resin composition is prepared by blending an organic solvent, and then the varnished resin composition is applied to the surface of the support film (Y). Further, a method of forming the resin composition layer (X) by further drying the organic solvent by heating, blowing hot air, or the like can be mentioned.
- organic solvent used here examples include ketones such as acetone, methyl ethyl ketone and cyclohexanone, acetates such as ethyl acetate, butyl acetate, cellosolve acetate, propylene glycol monomethyl ether acetate and carbitol acetate, cellosolve and butyl carbitol.
- ketones such as acetone, methyl ethyl ketone and cyclohexanone
- acetates such as ethyl acetate, butyl acetate, cellosolve acetate, propylene glycol monomethyl ether acetate and carbitol acetate, cellosolve and butyl carbitol.
- Carbitols, aromatic hydrocarbons such as toluene and xylene, dimethylformamide, dimethylacetamide, N-methylpyrrolidone and the like are preferably used, and the non-volatile content is 30 to
- the thickness of the resin composition layer (X) to be formed usually needs to be equal to or larger than the thickness of the conductor layer. Since the thickness of the conductor layer of the circuit board is usually in the range of 5 to 70 ⁇ m, the thickness of the resin composition layer (X) is preferably 10 to 100 ⁇ m.
- the resin composition layer (X) in the present invention may be protected by a protective film described later. By protecting with a protective film, it is possible to prevent dust and the like from adhering to the surface of the resin composition layer and scratches.
- the support film and protective film include polyolefins such as polyethylene, polypropylene and polyvinyl chloride, polyesters such as polyethylene terephthalate (PET) and polyethylene naphthalate, polycarbonates and polyimides, and metal foils such as release paper, copper foil and aluminum foil. And so on.
- the support film and the protective film may be subjected to a mold release treatment in addition to the mud treatment and the corona treatment.
- the thickness of the support film is not particularly limited, but is usually 10 to 150 ⁇ m, preferably 25 to 50 ⁇ m.
- the thickness of the protective film is preferably 1 to 40 ⁇ m.
- the support film (Y) is peeled off after being laminated on a circuit board or after forming an insulating layer by heat curing. If the support film (Y) is peeled off after the resin composition layer constituting the build-up film is heat-cured, it is possible to prevent the adhesion of dust and the like in the curing step. When peeling after curing, the support film is usually subjected to a mold release treatment in advance.
- a multilayer printed circuit board can be manufactured from the build-up film obtained as described above.
- the resin composition layer (X) is protected by a protective film, after peeling off the resin composition layer (X), the resin composition layer (X) is placed on one or both sides of the circuit board so as to be in direct contact with the circuit board.
- laminating by the vacuum laminating method.
- the laminating method may be a batch method or a continuous method using a roll. If necessary, the build-up film and the circuit board may be heated (preheated) as necessary before laminating.
- the crimping temperature is preferably 70 to 140 ° C.
- the crimping pressure is 1 to 11 kgf / cm 2 (9.8 ⁇ 10 4 to 107.9 ⁇ 10 4 N / m 2 ). It is preferable to laminate under a reduced air pressure of 20 mmHg (26.7 hPa) or less.
- Examples of the method for obtaining a conductive paste from the curable resin composition of the present invention include a method for dispersing conductive particles in the composition.
- the conductive paste can be a paste resin composition for circuit connection or an anisotropic conductive adhesive depending on the type of the conductive particles used.
- Measuring device "HLC-8320 GPC” manufactured by Tosoh Corporation Column: Guard column “HXL-L” manufactured by Tosoh Corporation + “TSK-GEL G2000HXL” manufactured by Tosoh Corporation + “TSK-GEL G2000HXL” manufactured by Tosoh Corporation + “TSK-GEL G3000HXL” manufactured by Tosoh Corporation + Tosoh Corporation Made by “TSK-GEL G4000HXL” Detector: RI (Differential Refractometer) Data processing: "GPC Workstation EcoSEC-WorkStation” manufactured by Tosoh Corporation Measurement conditions: Column temperature 40 ° C Developing solvent Tetrahydrofuran Flow rate 1.0 ml / min Standard: The following monodisperse polystyrene with a known molecular weight was used in accordance with the measurement manual of the above-mentioned "GPC workstation EcoSEC-WorkStation".
- Example 1 In a reaction vessel equipped with a stirrer, add 113.8 parts by mass of 2,2-bis (4-hydroxy-3,5-dimethylphenyl) propane, 64.0 parts by mass of sodium hydroxide, and 0 parts of trin butylbenzylammonium chloride. .25 parts by mass and 2000 parts by mass of pure water were charged and dissolved to prepare an aqueous phase. An organic phase was prepared by dissolving 30.5 parts by mass of terephthalic acid dichloride, 30.5 parts by mass of isophthalic acid dichloride, and 20.9 parts by mass of methacrylic acid chloride in 1500 parts by mass of methylene chloride.
- the aqueous phase was stirred in advance, and the organic phase was added to the aqueous phase under strong stirring and reacted at 20 ° C. for 5 hours. After that, stirring was stopped, the aqueous phase and the organic phase were separated, and the organic phase was washed with pure water 10 times. Then, methylene chloride was distilled from the organic phase under reduced pressure using an evaporator, and the polymer obtained by the reaction was dried. The obtained polymer was dried under reduced pressure to obtain a curable resin having the following repeating unit, having a methacryloyloxy group at the terminal, and having a weight average molecular weight of 3100.
- Example 2 Except that the 2,2-bis (4-hydroxy-3,5-dimethylphenyl) propane in Example 1 was changed to 102.5 parts by mass of bis (4-hydroxy-3,5-dimethylphenyl) methane.
- the synthesis was carried out in the same manner as in Example 1 to obtain a curable resin having the following repeating unit, having a methacryloyloxy group at the terminal, and having a weight average molecular weight of 2900.
- Example 3 Except for changing 2,2-bis (4-hydroxy-3,5-dimethylphenyl) propane in Example 1 to 141.0 parts by mass of 2,2-bis (2-hydroxy-5-biphenylyl) propane.
- Example 3 Except for changing 2,2-bis (4-hydroxy-3,5-dimethylphenyl) propane in Example 1 to 141.0 parts by mass of 2,2-bis (2-hydroxy-5-biphenylyl) propane.
- Example 3 was synthesized by the same method as in Example 1 to obtain a curable resin having the following repeating unit, having a methacryloyloxy group at the terminal, and having a weight average molecular weight of 3200.
- Example 4 2,2-Bis (4-hydroxy-3,5-dimethylphenyl) propane in Example 1 and 2,2-bis (4-hydroxy-3-cyclohexyl-6-methylphenyl) propane by 157.0 parts by mass.
- the synthesis was carried out in the same manner as in Example 1 above to obtain a curable resin having the following repeating unit, having a methacryloyloxy group at the terminal, and having a weight average molecular weight of 3200.
- Example 5 The amount of 2,2-bis (4-hydroxy-3,5-dimethylphenyl) propane in Example 1 is 113.8 parts by mass of 2,2-bis (4-hydroxy-3,5,6-trimethylphenyl) propane.
- the synthesis was carried out in the same manner as in Example 1 above, except that a curable resin having the following repeating unit, having a methacryloyloxy group at the terminal, and having a weight average molecular weight of 3100 was obtained.
- Example 6 The 2,2-bis (4-hydroxy-3,5-dimethylphenyl) propane in Example 1 was changed to 129.8 parts by mass of 1,1-bis (4-hydroxy-3,5-dimethylphenyl) cyclohexane. The synthesis was carried out in the same manner as in Example 1 above to obtain a curable resin having the following repeating unit, having a methacryloyloxy group at the terminal, and having a weight average molecular weight of 3100.
- Example 7 The 2,2-bis (4-hydroxy-3,5-dimethylphenyl) propane in Example 1 is replaced with 1,4-bis (2- (4-hydroxy-3,5-dimethylphenyl) -2-propyl).
- the synthesis was carried out in the same manner as in Example 1 above except that the amount was changed to 161.0 parts by mass of benzene, and a curable resin having the following repeating unit, having a methacryloyloxy group at the terminal, and having a weight average molecular weight of 3500 was obtained. Obtained.
- Example 8 The synthesis was carried out in the same manner as in Example 1 except that the terephthalic acid dichloride and the isophthalic acid dichloride in Example 1 were changed to 62.7 parts by mass of 1,4-cyclohexanedicarboxylic acid dichloride, and the following repeating unit was carried out.
- a curable resin having a weight average molecular weight of 3100 and having a methacryloyloxy group at the terminal was obtained.
- Example 9 The synthesis was carried out in the same manner as in Example 1 except that the terephthalic acid dichloride and the isophthalic acid dichloride in Example 1 were changed to 88.5 parts by mass of diphenyl ether-4,4'-dicarboxylic acid dichloride, and the following was carried out.
- a curable resin having a repeating unit and having a methacryloyloxy group at the terminal and having a weight average molecular weight of 3500 was obtained.
- Example 10 In a reaction vessel equipped with a stirrer, a distillation column, and a decompression device, 113.8 parts by mass of 2,2-bis (4-hydroxy-3,5-dimethylphenyl) propane, 64.2 parts by mass of diphenyl carbonate, and tetramethylammonium. 0.01 part by mass of hydroxydue was charged, substituted with nitrogen, and then dissolved at 140 ° C. After stirring for 30 minutes, the internal temperature was raised to 180 ° C. and reacted at an internal pressure of 100 mmHg for 30 minutes to distill off the produced phenol.
- Example 11 The synthesis was carried out in the same manner as in Example 1 except that the methacrylic acid chloride in Example 1 was changed to 30.5 parts by mass of chloromethylstyrene, and it had the following repeating units and had vinyl benzyl ether at the end. A curable resin having a group and having a weight average molecular weight of 3100 was obtained.
- Example 12 The synthesis was carried out in the same manner as in Example 1 except that the methacrylic acid chloride in Example 1 was changed to 15.3 parts by mass of allyl chloride, having the following repeating unit and having an allyl ether group at the terminal. A curable resin having a weight average molecular weight of 3100 was obtained.
- Example 2 (Comparative Example 2) The above-mentioned embodiment except that 2,2-bis (4-hydroxy-3,5-dimethylphenyl) propane in Example 1 was changed to 91.3 parts by mass of 2,2-bis (4-hydroxyphenyl) propane.
- the synthesis was carried out in the same manner as in Example 1 to obtain a curable resin having the following repeating unit, having a methacryloyloxy group at the terminal, and having a weight average molecular weight of 3000.
- ⁇ Making a resin film (cured product)> The curable resins obtained in Examples and Comparative Examples were placed in a 5 cm square square mold, sandwiched between stainless steel plates, and set in a vacuum press. The pressure was increased to 1.5 MPa at normal pressure and normal temperature. Next, after reducing the pressure to 10 torr, the mixture was heated to a temperature 50 ° C. higher than the thermosetting temperature over 30 minutes. After allowing to stand for another 2 hours, the mixture was slowly cooled to room temperature to obtain a uniform resin film (cured product) having an average film thickness of 100 ⁇ m.
- Comparative Example 1 Since the resin obtained in Comparative Example 1 does not self-curing unlike other Examples and Comparative Examples, it was obtained in Comparative Example 1 with an epoxy resin (jER828, manufactured by Mitsubishi Chemical Corporation, bisphenol A type epoxy resin).
- the resin phenolic resin containing terminal hydroxyl groups
- 2-ethyl-4 which is a curing catalyst, is added to 100 parts by mass of the resin (total of the entire resin).
- -A resin film (cured product) was obtained by using a compound containing 0.2 parts by mass of methylimidazole.
- the dielectric constant and dielectric loss tangent at a frequency of 10 GHz by the split post dielectric resonator method using a network analyzer N5247A manufactured by Keysight Technology Co., Ltd. was measured.
- the dielectric loss tangent if it is 10.0 ⁇ 10 -3 or less, there is no practical problem, preferably 3.0 ⁇ 10 -3 or less, and more preferably 2.5 ⁇ 10 -3 or less. be.
- the dielectric constant is 3 or less, there is no problem in practical use, and it is preferably 2.7 or less, and more preferably 2.5 or less.
- ⁇ Making a resin film (cured product)> The curable resin compositions described in Tables 1 and 2 below were placed in a 10 cm square square mold, sandwiched between stainless steel plates, and set in a vacuum press. The pressure was increased to 1.5 MPa under normal pressure of 30 ° C. Next, the pressure was reduced to 10 torr, the mixture was heated to 100 ° C. for 30 minutes, and allowed to stand for 1 hour. Then, it was heated to 220 ° C. over 30 minutes and allowed to stand for 2 hours. Then, it was slowly cooled to 30 ° C. A uniform resin film (cured product) having an average film thickness of 100 ⁇ m was produced.
- the obtained resin film (cured product) was measured using a TG-DTA device (TG-8120) manufactured by Rigaku Co., Ltd. at a nitrogen flow of 20 mL / min and a temperature rise rate of 20 ° C./min, and 10%.
- the weight loss temperature (Td10) was measured.
- the 10% weight reduction temperature if it is 400 ° C. or higher, there is no practical problem, and it is preferably 410 ° C. or higher, and more preferably 420 ° C. or higher.
- the dielectric constant and dielectric loss tangent at a frequency of 10 GHz by the split post dielectric resonator method using a network analyzer N5247A manufactured by Keysight Technology Co., Ltd. was measured. If the dielectric loss tangent is 10.0 ⁇ 10 -3 or less, there is no practical problem, and preferably 3.0 ⁇ 10 -3 or less, more preferably 2.5 ⁇ 10 -3 . It is as follows. Further, when the dielectric constant is 3.0 or less, there is no problem in practical use, and it is preferably 2.7 or less, and more preferably 2.5 or less.
- V5 Katayama Chemical Industry Co., Ltd.
- V5 (9,10-dihydro-9-oxa-10-vinyl-10-phosphaphenanthrene-10-oxide)
- OP930 OP930 manufactured by Clariant Japan Co., Ltd.
- PX-200 PX-200 (resorcinol bis (di-2,6-xylenyl phosphate)) agent manufactured by Daihachi Chemical Industry Co., Ltd.
- DT-4000 DT-4000 (dicyclopentadiene type cyanate resin) manufactured by Lonza Japan Co., Ltd.
- SA9000 SA9000 manufactured by SABIC Japan GK (terminal methacryloyl-modified polyphenylene ether resin)
- BMI-5100 BMI-5100 manufactured by Daiwa Kasei Kogyo Co., Ltd. (3,3'-dimethyl-5,5'-diethyl-4,4'-diphenylmethanebismaleimide)
- the cured product obtained by using the curable resin can achieve both heat resistance and low dielectric properties, and there is no practical problem. It was confirmed that it was a level.
- Comparative Example 3 using the resin of Comparative Example 1
- the epoxy resin and the terminal hydroxyl group-containing phenol resin were used and reacted to generate hydroxyl groups, so that the dielectric properties were improved. It was confirmed that it would be higher.
- Comparative Example 4 using the curable resin of Comparative Example 2
- the dielectric properties are compared with those of Examples. It was confirmed that it would be higher.
- the cured product obtained by using the curable resin aims to improve flame retardancy, heat resistance, and low dielectric property. It was confirmed that there was no problem in practical use.
- Comparative Example 5 only the component (A) was used, in Comparative Example 6, the components (A) and (B) were used, and in Comparative Example 7, the component (A) and the component (B) were used.
- Comparative Example 8 a curable resin composition using only the component (A) and the component (C) and the component (A) having no desired structure (Ra and Rb) was used to prepare a cured product. Since it was produced, it was not possible to obtain one that satisfied all of flame retardancy, heat resistance, and low dielectric property at the same time.
- Comparative Example 5 and Comparative Example 7 since the component (B) which is the radical polymerization initiator was not used, the reactivity was lowered and a large amount of the low molecular weight component remained, so that the weight was reduced at the time of high temperature heating. It was confirmed that the heat resistance was inferior. Further, in Comparative Example 5 and Comparative Example 6, it was confirmed that the flame retardant was inferior because the component (C) which was a flame retardant was not blended.
- Comparative Example 8 since the component (A) having no desired structure (Ra and Rb) was used, the substituents Ra and Rb (particularly Ra) were placed at positions adjacent to the reactive group (crosslinking group). It was presumed that it did not exist and the polarity derived from the reactive group (crosslinking group) was less likely to be constrained by steric hindrance such as Ra, resulting in inferior dielectric properties.
- the cured product obtained by using the curable resin composition of the present invention is excellent in flame retardancy, heat resistance, and low dielectric property, and therefore can be suitably used for heat-resistant members and electronic members, and in particular, a prepreg. , Circuit boards, build-up films, build-up boards, etc., and can be suitably used for adhesives and resist materials. Further, it can be suitably used for a matrix resin of a fiber reinforced resin, and is suitable as a prepreg having high heat resistance.
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Abstract
Description
(式中、Ra及びRbは、それぞれ独立に、炭素数1~12のアルキル基、アリール基、アラルキル基、または、シクロアルキル基を表す。kは、0~3の整数を示す。Xは、炭化水素基を表す。Yは、下記一般式(2)、または、(3)を表す。)
(式中、Zは、脂環式基、芳香族基、または、複素環基を表す。)
(上記一般式(P-1)中、R11は、それぞれ独立に炭素数1~12のアルキル基、アリール基、アラルキル基、または、シクロアルキル基を表し、R12は、アルキレン基またはアリーレン基を表し、aは、0~3の整数を示す。)
(上記一般式(P-2)中、R13は、それぞれ独立に炭素数1~12のアルキル基、アリール基、アラルキル基、または、シクロアルキル基を表し、Mb+は、b価の金属イオンを表し、bは、1~3の整数を示す。)
(上記一般式(P-3)中、R14は、それぞれ独立に炭素数1~12のアルキル基、アリール基、アラルキル基、または、シクロアルキル基を表し、R15は、アルキレン基またはアリーレン基を表し、Mc+は、c価の金属イオンを表し、c、d及びeは、それぞれ独立に1~3の整数を示し、c×d=2×eを満たす。)
(上記一般式(P-4)中、R16は、それぞれ独立に炭素数1~12のアルキル基、アリール基、アラルキル基、または、シクロアルキル基を表し、リン原子と共に環状構造を形成してもよく、R17は、ビニル基、ビニルベンジル基、又は、(メタ)アクリロイルオキシ基を表し、f及びgは、それぞれ独立に、0又は1を示す。)
(上記一般式(P-5)中、R18は、それぞれ独立に炭素数1~12のアルキル基、アリール基、アラルキル基、または、シクロアルキル基を表し、リン原子と共に環状構造を形成してもよく、R19は、アリーレン構造を有する2価の基を表し、R20は、(メタ)アクリロイルオキシ基、ビニルベンジルエーテル基、又は、アリルエーテル基を表し、hは、0又は1を示す。)
本発明の硬化性樹脂は、下記一般式(1)で表される繰り返し単位と、(メタ)アクリロイルオキシ基、ビニルベンジルエーテル基、及び、アリルエーテル基からなる群より選択される少なくとも1種の反応性基(架橋基)を末端構造として有する硬化性樹脂に関する。以下、下記一般式(1)で表される繰り返し単位と、(メタ)アクリロイルオキシ基、ビニルベンジルエーテル基、及び、アリルエーテル基からなる群より選択される少なくとも1種の反応性基(架橋基)を末端構造として有する硬化性樹脂を、硬化性樹脂(A)(「(A)成分」ともいう。)と呼ぶ。
前記(A)成分の製造方法を以下に説明する。
前記界面重合法としては、二価カルボン酸ハライドと末端構造である反応性基(架橋基)導入に使用される架橋基導入剤を水と相溶しない有機溶媒に溶解させた溶液(有機相)を、二価フェノール、重合触媒および酸化防止剤を含むアルカリ水溶液(水相)に混合し、50℃以下の温度で1~8時間撹拌しながら重合反応を行う方法が挙げられる。
また、別の前記界面重合法としては、末端構造である反応性基(架橋基)導入に使用される架橋基導入剤を水と相溶しない有機溶媒に溶解させた溶液(有機相)を、二価フェノール、重合触媒および酸化防止剤を含むアルカリ水溶液(水相)に混合した中にホスゲンを吹き込み、50℃以下の温度で1~8時間撹拌しながら重合反応をおこなう方法などが挙げられる。
前記溶融重合法としては、原料の二価フェノールをアセチル化した後、アセチル化された二価フェノールと二価カルボン酸とを脱酢酸重合する方法、または、二価フェノールと炭酸エステルとをエステル交換反応する方法が挙げられる。
本発明の硬化性樹脂組成物は、更に、前記(A)成分以外の硬化性樹脂(D)(「(D)成分」ともいう。)を含有することが好ましい。前記(D)成分を含む硬化性樹脂組成物を用いることで、それぞれの硬化性樹脂に基づく性能を付与した硬化物を得ることができ、好ましい態様となる。
本発明の硬化性樹脂組成物は、ラジカル重合開始剤(B)(「(B)成分」ともいう。)を含有することを特徴とする。前記(B)成分を含む硬化性樹脂組成物を用いることで、反応性が向上し、低分子量成分の残存が少なくなることで、耐熱性に優れた硬化物を得ることができ、好ましい態様となる。
本発明の硬化性樹脂組成物は、難燃剤(C)(「(C)成分」ともいう。)を含有することを特徴とする。前記(C)成分を含む硬化性樹脂組成物を用いて得られる硬化物は、難燃性に優れ、好ましい態様となる。
上記一般式(P-1)中、R11は、それぞれ独立に炭素数1~12のアルキル基、アリール基、アラルキル基、または、シクロアルキル基を表し、低誘電正接の点から、好ましくは、2,6位に置換基を有するフェニル基であり、特に好ましくは、2,6-ジメチルフェニル基である。R12は、アルキレン基またはアリーレン基を表し、耐熱性の点から、好ましくは、フェニレン基である。aは、0~3の整数を示し、難燃性の点から、好ましくは、0または1である。
上記一般式(P-2)中、R13は、それぞれ独立に炭素数1~12のアルキル基、アリール基、アラルキル基、または、シクロアルキル基を表し、低誘電率の点から、好ましくは、メチル基、エチル基、プロピル基、ブチル基、シクロヘキシル基、ベンジル基、フェニル基である。Mb+は、b価の金属イオンを表し、前記金属としては、アルミニウム、マグネシウム、ナトリウム、カリウム、カルシウムなどが挙げられ、難燃性の点から、好ましくは、アルミニウムである。bは、1~3の整数を示し、難燃性の点から、好ましくは、3である。
上記一般式(P-3)中、R14は、それぞれ独立に炭素数1~12のアルキル基、アリール基、アラルキル基、または、シクロアルキル基を表し、低誘電率の点から、好ましくは、メチル基、エチル基、プロピル基、ブチル基、シクロヘキシル基、ベンジル基、フェニル基である。R15は、アルキレン基またはアリーレン基を表し、耐熱性の点から、好ましくは、フェニレン基である。Mc+は、c価の金属イオンを表し、前記金属としては、アルミニウム、マグネシウム、ナトリウム、カリウム、カルシウムなどが挙げられ、難燃性の点から、好ましくは、アルミニウムである。c、d及びeは、それぞれ独立に1~3の整数を示し、難燃性の点から、好ましくは、cは3、dは2、eは3であり、c×d=2×eを満たすことが好ましい。
上記一般式(P-4)中、R16は、それぞれ独立に炭素数1~12のアルキル基、アリール基、アラルキル基、または、シクロアルキル基を表し、耐熱性の点から、好ましくは、フェニル基である。リン原子と共に環状構造を形成してもよく、R17は、ビニル基、ビニルベンジル基、又は、(メタ)アクリロイルオキシ基を表し、低誘電正接の点から、好ましくは、ビニル基、ビニルベンジル基である。f及びgは、それぞれ独立に、0又は1を示す。なお、前記リン原子と共に環状構造を形成するリン系難燃剤としては、下記一般式(P1)などが挙げられる。
上記一般式(P-5)中、R18は、それぞれ独立に炭素数1~12のアルキル基、アリール基、アラルキル基、または、シクロアルキル基を表し、耐熱性の点から、好ましくは、フェニル基である。リン原子と共に環状構造を形成してもよく、R19は、アリーレン構造を有する2価の基を表し、耐熱性の点から、好ましくは、フェニル基である。R20は、(メタ)アクリロイルオキシ基、ビニルベンジルエーテル基、又は、アリルエーテル基を表し、低誘電正接の点から、好ましくは、ビニルベンジルエーテル基である。hは、0又は1を示す。なお、前記リン原子と共に環状構造を形成するリン系難燃剤としては、下記一般式(P2)などが挙げられる。
本発明の硬化性樹脂組成物には、前記(A)成分、(B)成分、(C)成分、及び、(D)成分に加えて、その他樹脂、硬化剤、硬化促進剤等を、本発明の目的を損なわない範囲で特に限定なく使用できる。前記硬化性樹脂組成物は、硬化剤や硬化促進剤を配合することなく、加熱等により硬化物を得ることができるが、例えば、前記(D)成分などを併せて配合する際には、別途、硬化剤や硬化促進剤などを配合することができる。
前記(A)成分や(D)成分だけでなく、必要に応じて、熱可塑性樹脂を配合してもよい。前記熱可塑性樹脂としては、例えば、スチレンブタジエン樹脂、スチレン-ブタジエン-スチレンブロック樹脂、スチレン-イソプレン-スチレン樹脂、スチレン-無水マレイン酸樹脂、アクリロニトリルブタジエン樹脂、ポリブタジエン樹脂あるいはそれらの水素添加した樹脂、アクリル樹脂、及び、シリコーン樹脂などを用いることができる。前記熱可塑性樹脂を使用することで、その樹脂に起因する特性を硬化物に付与することができ、好ましい態様となる。例えば、付与できる性能としては、成形性、高周波特性、導体接着性、半田耐熱性、ガラス転移温度の調整、熱膨張係数、スミア除去性の付与などに寄与することができる。
前記硬化剤としては、例えば、アミン系化合物、アミド系化合物、酸無水物系化合物、フェノ-ル系化合物、シアネートエステル化合物などが挙げられる。これらの硬化剤は、単独でも2種類以上の併用でも構わない。
前記硬化促進剤としては、種々のものが使用できるが、例えば、リン系化合物、第3級アミン、イミダゾール類、有機酸金属塩、ルイス酸、アミン錯塩等が挙げられる。特に半導体封止材料用途として使用する場合には、硬化性、耐熱性、電気特性、耐湿信頼性等に優れる点から、トリフェニルフォスフィン等のリン系化合物、又は、イミダゾール類が好ましい。これらの硬化促進剤は、単独で用いることも2種以上を併用することもできる。
本発明の硬化性樹脂組成物には、必要に応じて、無機充填剤を配合することができる。前記無機充填剤として、例えば、シリカ(溶融シリカ、結晶シリカ)、アルミナ、硫酸バリウム、タルク、クレニ、雲母粉、水酸化アルミニウム、水酸化マグネシウム、炭酸カルシウム、炭酸マグネシウム、酸化マグネシウム、窒化ホウ素、ホウ酸アルミニウム、チタン酸バリウム、チタン酸ストロンチウム、チタン酸カルシウム、チタン酸マグネシウム、チタン酸ビスマス、酸化チタン、ジルコン酸バリウム、ジルコン酸カルシウムなどが挙げられる。またシランカップリング剤で表面処理をしてもよい。前記無機充填剤の配合量を特に大きくする場合は、溶融シリカを用いることが好ましい。前記溶融シリカは破砕状、球状のいずれでも使用可能であるが、溶融シリカの配合量を高め、かつ、成形材料の溶融粘度の上昇を抑制するためには、球状のものを主に用いる方が好ましい。更に球状シリカの配合量を高めるためには、球状シリカの粒度分布を適当に調整することが好ましい。
本発明の硬化性樹脂組成物は、必要に応じて、シランカップリング剤、離型剤、顔料、乳化剤等の種々の配合剤を添加することができる。
本発明は、前記硬化性樹脂組成物を硬化反応させて得られる硬化物に関する。前記硬化性樹脂組成物は、前記(A)成分、(B)成分、及び、(C)成分に加えて、目的に応じて、前記(D)成分や硬化剤等の各成分を均一に混合することにより得られ、従来知られている方法と同様の方法で容易に硬化物とすることができる。前記硬化物としては、積層物、注型物、接着層、塗膜、フィルム等の成形硬化物が挙げられる。
本発明は、前記硬化性樹脂組成物を有機溶剤で希釈したものであるワニスに関する。前記ワニスの調製方法としては、公知の方法を使用でき、前記硬化性樹脂組成物を、有機溶剤に溶解(希釈)した樹脂ワニスとすることができる。
本発明は、補強基材、及び、前記補強基材に含浸した前記ワニスの半硬化物を有するプリプレグに関する。前記ワニス(樹脂ワニス)を補強基材に含浸させ、前記ワニス(樹脂ワニス)を含浸させた補強基材を熱処理することにより、前記硬化性樹脂組成物を半硬化(あるいは未硬化)させることで、プリプレグとすることができる。
本発明は、基材と、前記硬化物を含む層を有する積層体に関する。前記硬化物を含む層(硬化物層)より形成される積層体は、低誘電率、低誘電正接、高耐熱性であるため、高周波対応プリント基板などに使用することができ、好ましい。
本発明の硬化性樹脂組成物により得られる硬化物が難燃性、耐熱性、及び、誘電特性に優れることから、耐熱部材や電子部材に好適に使用可能である。特に、プリプレグの製造に使用されるワニス、プリプレグ、回路基板、半導体封止材、半導体装置、ビルドアップフィルム、ビルドアップ基板、接着剤やレジスト材料などに好適に使用できる。また、繊維強化樹脂のマトリクス樹脂にも好適に使用でき、難燃性で高耐熱性のプリプレグとして特に適している。こうして得られる耐熱部材や電子部材は、各種用途に好適に使用可能であり、例えば、産業用機械部品、一般機械部品、自動車・鉄道・車両等部品、宇宙・航空関連部品、電子・電気部品、建築材料、容器・包装部材、生活用品、スポーツ・レジャー用品、風力発電用筐体部材等が挙げられるが、これらに限定される物ではない。
本発明は、前記プリプレグ、及び、銅箔を積層し、加熱圧着成型して得られる回路基板に関する。具体的には、本発明の硬化性樹脂組成物から回路基板を得る方法としては、上記プリプレグを、常法により積層し、適宜銅箔を重ねて、1~10MPaの加圧下に170~300℃で10分~3時間、加熱圧着成型させる方法が挙げられる。
半導体封止材としては、前記硬化性樹脂組成物を含有することが好ましい。具体的には、本発明の硬化性樹脂組成物から半導体封止材を得る方法としては、前記硬化性樹脂組成物に、更に任意成分である硬化促進剤、および無機充填剤等の配合剤とを必要に応じて押出機、ニ-ダ、ロ-ル等を用いて均一になるまで充分に溶融混合する方法が挙げられる。その際、無機充填剤としては、通常、溶融シリカが用いられるが、パワートランジスタ、パワーIC用高熱伝導半導体封止材として用いる場合は、溶融シリカよりも熱伝導率の高い結晶シリカ,アルミナ,窒化ケイ素などの高充填化、または溶融シリカ、結晶性シリカ、アルミナ、窒化ケイ素などを用いるとよい。その充填率は、硬化性樹脂組成物100質量部当たり、無機充填剤を30~95質量部の範囲で用いることが好ましく、中でも、難燃性や耐湿性や耐ハンダクラック性の向上、線膨張係数の低下を図るためには、70質量部以上がより好ましく、80質量部以上であることがさらに好ましい。
半導体装置としては、前記半導体封止材を加熱硬化した硬化物を含むことが好ましい。具体的には、本発明の硬化性樹脂組成物から半導体装置を得る半導体パッケージ成形としては、上記半導体封止材を注型、または、トランスファー成形機、射出成形機などを用いて成形し、さらに50~250℃で、2~10時間の間、加熱硬化する方法が挙げられる。
本発明の硬化性樹脂組成物からビルドアップ基板を得る方法としては、工程1~3を経由する方法が挙げられる。工程1では、まず、ゴム、フィラーなどを適宜配合した前記硬化性樹脂組成物を、回路を形成した回路基板にスプレーコーティング法、カーテンコーティング法等を用いて塗布した後、硬化させる。工程2では、必要に応じて、硬化性樹脂組成物が塗布された回路基板に所定のスルーホール部等の穴あけを行った後、粗化剤により処理し、その表面を湯洗することによって、前記基板に凹凸を形成させ、銅などの金属をめっき処理する。工程3では、工程1~2の操作を所望に応じて順次繰り返し、樹脂絶縁層及び所定の回路パターンの導体層を交互にビルドアップしてビルドアップ基板を成形する。なお、前記工程において、スルーホール部の穴あけは、最外層の樹脂絶縁層の形成後に行うとよい。また、本発明におけるビルドアップ基板は、銅箔上で当該樹脂組成物を半硬化させた樹脂付き銅箔を、回路を形成した配線基板上に、170~300℃で加熱圧着することで、粗化面を形成、メッキ処理の工程を省き、ビルドアップ基板を作製することも可能である。
ビルドアップフィルムとしては、前記硬化性樹脂組成物を含有することが好ましい。本発明の硬化性樹脂組成物からビルドアップフィルムを得る方法としては、例えば、支持フィルム上に硬化性樹脂組成物を塗布したのち、乾燥させて、支持フィルムの上に樹脂組成物層を形成する方法が挙げられる。本発明の硬化性樹脂組成物をビルドアップフィルムに用いる場合、該フィルムは、真空ラミネート法におけるラミネートの温度条件(通常70~140℃)で軟化し、回路基板のラミネートと同時に、回路基板に存在するビアホール或いはスルーホール内の樹脂充填が可能な流動性(樹脂流れ)を示すことが肝要であり、このような特性を発現するよう前記各成分を配合することが好ましい。
本発明の硬化性樹脂組成物から導電ペーストを得る方法としては、例えば、導電性粒子を該組成物中に分散させる方法が挙げられる。上記導電ペーストは、用いる導電性粒子の種類によって、回路接続用ペースト樹脂組成物や異方性導電接着剤とすることができる。
以下の測定装置、測定条件を用いて測定し、以下に示す合成方法で得られた硬化性樹脂のGPCチャートを得た。前記GPCチャートの結果より、硬化性樹脂の重量平均分子量(Mw)を算出した(GPCチャートは図示せず)。
測定装置 :東ソー株式会社製「HLC-8320 GPC」
カラム:東ソー株式会社製ガードカラム「HXL-L」+東ソー株式会社製「TSK-GEL G2000HXL」+東ソー株式会社製「TSK-GEL G2000HXL」+東ソー株式会社製「TSK-GEL G3000HXL」+東ソー株式会社製「TSK-GEL G4000HXL」
検出器:RI(示差屈折計)
データ処理:東ソー株式会社製「GPCワークステーション EcoSEC-WorkStation」
測定条件:カラム温度 40℃
展開溶媒 テトラヒドロフラン
流速 1.0ml/分
標準:前記「GPCワークステーション EcoSEC-WorkStation」の測定マニュアルに準拠して、分子量が既知の下記の単分散ポリスチレンを用いた。
(使用ポリスチレン)
東ソー株式会社製「A-500」
東ソー株式会社製「A-1000」
東ソー株式会社製「A-2500」
東ソー株式会社製「A-5000」
東ソー株式会社製「F-1」
東ソー株式会社製「F-2」
東ソー株式会社製「F-4」
東ソー株式会社製「F-10」
東ソー株式会社製「F-20」
東ソー株式会社製「F-40」
東ソー株式会社製「F-80」
東ソー株式会社製「F-128」
試料:実施例及び比較例で得られた硬化性樹脂の固形分換算で1.0質量%のテトラヒドロフラン溶液をマイクロフィルターでろ過したもの(50μl)。
撹拌装置を備えた反応容器に、2,2-ビス(4-ヒドロキシ-3,5-ジメチルフェニル)プロパン113.8質量部、水酸化ナトリウム64.0質量部、トリ n ブチルベンジルアンモニウムクロライドを0.25質量部、純水2000質量部を仕込み、溶解させ、水相を調製した。塩化メチレン1500質量部に、テレフタル酸ジクロリド30.5質量部、イソフタル酸ジクロリド30.5質量部、メタクリル酸クロリド20.9質量部を溶解させ、有機相を調製した。
水相をあらかじめ撹拌しておき、有機相を水相中に強撹拌下で添加し、20℃で5時間反応させた。この後、撹拌を停止し、水相と有機相を分離し、有機相を純水で10回洗浄した。この後、有機相から塩化メチレンをエバポレーターで減圧蒸留し、反応により得られたポリマーを乾固させた。得られたポリマーを、減圧乾燥し、下記繰り返し単位を有し、末端にメタクリロイルオキシ基を有する重量平均分子量が3100の硬化性樹脂を得た。
上記実施例1における2,2-ビス(4-ヒドロキシ-3,5-ジメチルフェニル)プロパンを、ビス(4-ヒドロキシ-3,5-ジメチルフェニル)メタン102.5質量部に変更した以外は、上記実施例1と同様の方法で合成を実施し、下記繰り返し単位を有し、末端にメタクリロイルオキシ基を有する重量平均分子量が2900の硬化性樹脂を得た。
上記実施例1における2,2-ビス(4-ヒドロキシ-3,5-ジメチルフェニル)プロパンを、2,2-ビス(2-ヒドロキシ-5-ビフェニルイル)プロパン141.0質量部に変更した以外は、上記実施例1と同様の方法で合成を実施し、下記繰り返し単位を有し、末端にメタクリロイルオキシ基を有する重量平均分子量が3200の硬化性樹脂を得た。
上記実施例1における2,2-ビス(4-ヒドロキシ-3,5-ジメチルフェニル)プロパンを、2,2-ビス(4-ヒドロキシ-3-シクロヘキシル-6-メチルフェニル)プロパン157.0質量部に変更した以外は、上記実施例1と同様の方法で合成を実施し、下記繰り返し単位を有し、末端にメタクリロイルオキシ基を有する重量平均分子量が3200の硬化性樹脂を得た。
上記実施例1における2,2-ビス(4-ヒドロキシ-3,5-ジメチルフェニル)プロパンを、2,2-ビス(4-ヒドロキシ-3,5,6-トリメチルフェニル)プロパン113.8質量部に変更した以外は、上記実施例1と同様の方法で合成を実施し、下記繰り返し単位を有し、末端にメタクリロイルオキシ基を有する重量平均分子量が3100の硬化性樹脂を得た。
上記実施例1における2,2-ビス(4-ヒドロキシ-3,5-ジメチルフェニル)プロパンを、1,1-ビス(4-ヒドロキシ-3,5-ジメチルフェニル)シクロヘキサン129.8質量部に変更した以外は、上記実施例1と同様の方法で合成を実施し、下記繰り返し単位を有し、末端にメタクリロイルオキシ基を有する重量平均分子量が3100の硬化性樹脂を得た。
上記実施例1における2,2-ビス(4-ヒドロキシ-3,5-ジメチルフェニル)プロパンを、1,4-ビス(2-(4-ヒドロキシ-3,5-ジメチルフェニル)-2-プロピル)ベンゼン161.0質量部に変更した以外は、上記実施例1と同様の方法で合成を実施し、下記繰り返し単位を有し、末端にメタクリロイルオキシ基を有する重量平均分子量が3500の硬化性樹脂を得た。
上記実施例1におけるテレフタル酸ジクロリドとイソフタル酸ジクロリドを、1,4-シクロヘキサンジカルボン酸ジクロリド62.7質量部に変更した以外は、上記実施例1と同様の方法で合成を実施し、下記繰り返し単位を有し、末端にメタクリロイルオキシ基を有する重量平均分子量が3100の硬化性樹脂を得た。
上記実施例1におけるテレフタル酸ジクロリドとイソフタル酸ジクロリドを、ジフェニルエーテル-4,4’-ジカルボン酸ジクロリド88.5質量部に変更した以外は、上記実施例1と同様の方法で合成を実施し、下記繰り返し単位を有し、末端にメタクリロイルオキシ基を有する重量平均分子量が3500の硬化性樹脂を得た。
撹拌装置、蒸留塔、減圧装置を備えた反応容器に、2,2-ビス(4-ヒドロキシ-3,5-ジメチルフェニル)プロパン113.8質量部、炭酸ジフェニル64.2質量部、テトラメチルアンモニウムヒドロキシド質量部0.01質量部を仕込み、窒素置換した後、140℃で溶解した。30分間撹拌後、内温を180℃に昇温し,内圧100mmHgで30分間反応させ、生成するフェノールを溜去した。つづいて内温を200℃に昇温しつつ、徐々に減圧し、50mmHgで30分間フェノールを溜去しつつ反応させた。さらに220℃、1mmHgまで徐々に昇温、減圧し、同温度、同圧力条件下で30分間反応させた。得られた固形分をメタノールで洗浄した後、減圧乾燥し、中間体化合物を得た。
温度計、冷却管、撹拌機を取り付けた200mLフラスコに、トルエン20g及び前記中間体化合物22gを混合して約85℃に加熱した。ジメチルアミノピリジン0.19gを添加した。固体がすべて溶解したと思われる時点で、無水メタクリル酸30.6gを徐々に添加した。得られた溶液を連続混合しながら85℃に3時間維持した。次に、溶液を室温に冷却して、1Lのビーカー中マグネチックスターラーで激しく撹拌したメタノール中に滴下した。得られた沈殿物を減圧濾過後乾燥し、下記繰り返し単位を有し、末端にメタクリロイルオキシ基を有する重量平均分子量が2700の硬化性樹脂を得た。
上記実施例1におけるメタクリル酸クロリドを、クロロメチルスチレン30.5質量部に変更した以外は、上記実施例1と同様の方法で合成を実施し、下記繰り返し単位を有し、末端にビニルベンジルエーテル基を有する重量平均分子量が3100の硬化性樹脂を得た。
上記実施例1におけるメタクリル酸クロリドを、塩化アリル15.3質量部に変更した以外は、上記実施例1と同様の方法で合成を実施し、下記繰り返し単位を有し、末端にアリルエーテル基を有する重量平均分子量が3100の硬化性樹脂を得た。
撹拌装置を備えた反応容器に、2,2-ビス(4-ヒドロキシ-3,5-ジメチルフェニル)プロパン113.8質量部、水酸化ナトリウム64.0質量部、トリ n ブチルベンジルアンモニウムクロライドを0.25質量部、純水2000質量部を仕込み、溶解させ、水相を調製した。塩化メチレン1500質量部に、テレフタル酸ジクロリド30.5質量部、イソフタル酸ジクロリド30.5質量部を溶解させ、有機相を調製した。
水相をあらかじめ撹拌しておき、有機相を水相中に強撹拌下で添加し、20℃で5時間反応させた。この後、撹拌を停止し、水相と有機相を分離し、有機相を10%酢酸水溶液で洗浄した後、さらに純水で10回洗浄した。この後、有機相から塩化メチレンをエバポレーターで減圧蒸留し、反応により得られたポリマーを乾固させた。得られたポリマーを、減圧乾燥し、下記繰り返し単位を有し、末端にフェニル基を有する重量平均分子量が2800の樹脂を得た。
上記実施例1における2,2-ビス(4-ヒドロキシ-3,5-ジメチルフェニル)プロパンを、2,2-ビス(4-ヒドロキシフェニル)プロパン91.3質量部に変更した以外は、上記実施例1と同様の方法で合成を実施し、下記繰り返し単位を有し、末端にメタクリロイルオキシ基を有する重量平均分子量が3000の硬化性樹脂を得た。
実施例、及び、比較例で得られた硬化性樹脂を5cm角の正方形の型枠に入れ、ステンレス板で挟み、真空プレスにセットした。常圧常温下で1.5MPaまで加圧した。次に10torrまで減圧後、熱硬化温度より50℃高い温度まで30分かけて加温した。さらに2時間静置後、室温まで徐冷し、平均膜厚が100μmの均一な樹脂フィルム(硬化物)を得た。
なお、比較例1で得られた樹脂は、その他実施例及び比較例と異なり、自己硬化しないため、エポキシ樹脂(jER828、三菱化学社製、ビスフェノールA型エポキシ樹脂)と比較例1で得られた樹脂(末端水酸基含有フェノール樹脂)を、フェノール性水酸基当量/エポキシ当量が1になるように配合し、更に樹脂(樹脂全体の合計)100質量部に対して、硬化触媒である2-エチル-4-メチルイミダゾール0.2質量部を配合したものを使用し、樹脂フィルム(硬化物)を得た。
得られた樹脂フィルム(硬化物)の面内方向の誘電特性について、キーサイト・テクノロジー社のネットワークアナライザーN5247Aを用いて、スプリットポスト誘電体共振器法により、周波数10GHzについて誘電率、及び、誘電正接を測定した。
前記誘電正接としては、10.0×10-3以下であれば、実用上問題がなく、好ましくは、3.0×10-3以下であり、より好ましくは2.5×10-3以下である。
また、前記誘電率としては、3以下であれば、実用上問題がなく、好ましくは、2.7以下であることが好ましく、より好ましくは、2.5以下である。
得られた樹脂フィルム(硬化物)について、パーキンエルマー製DSC装置(Pyris Diamond)を用い、30℃から20℃/分の昇温条件で測定した際に観測される発熱ピーク温度(熱硬化温度)の観測後、それより50℃高い温度で30分間保持した。ついで、20℃/分の降温条件で30℃まで試料を冷却し、さらに、再度20℃/分の昇温条件で昇温し、樹脂フィルム(硬化物)のガラス転移点温度(Tg)(℃)を測定した。
前記ガラス転移点温度(Tg)としては、100℃以上であれば、実用上問題がなく、好ましくは、150℃以上、より好ましくは、190℃以上である。
上記実施例、及び、比較例で得られた硬化性樹脂を用いて、下記表2、及び、表3に記載の配合内容(原料、配合量)の硬化性樹脂組成物、及び、下記に示す条件(温度、時間など)に基づき、評価用の試料(樹脂フィルム(硬化物))を作製し、これらを実施例及び比較例として、評価を行った。表2、及び、表3中に示す硬化性樹脂は、具体的には、実施例1で得られた硬化性樹脂を、硬化性樹脂(A1)、実施例2で得られた硬化性樹脂を、硬化性樹脂(A2)、実施例11で得られた硬化性樹脂を、硬化性樹脂(A3)、比較例2で得られた硬化性樹脂を、硬化性樹脂(A4)とした。
下記表1、及び、表2に記載の配合内容の硬化性樹脂組成物を10cm角の正方形の型枠に入れ、ステンレス板で挟み、真空プレスにセットした。常圧30℃下で1.5MPaまで加圧した。次に10torrまで減圧後、100℃まで30分かけて加温し、1時間静置した。その後、220℃まで30分かけて加温し、2時間静置した。その後、30℃まで徐冷した。平均膜厚が100μmの均一な樹脂フィルム(硬化物)を作製した。
得られた樹脂フィルム(硬化物)について、パーキンエルマー製DSC装置(Pyris Diamond)を用い、30℃から20℃/分の昇温条件で測定した際に観測される発熱ピーク温度(熱硬化温度)の観測後、それより50℃高い温度で30分間保持した。ついで、20℃/分の降温条件で30℃まで試料を冷却し、さらに、再度20℃/分の昇温条件で昇温し、樹脂フィルム(硬化物)のガラス転移点温度(Tg)(℃)を測定した。なお、前記ガラス転移点温度(Tg)としては、100℃以上であれば、実用上問題がなく、好ましくは、150℃以上、より好ましくは、200℃以上である。
得られた樹脂フィルム(硬化物)について、株式会社リガク製TG-DTA装置(TG-8120)を用いて、20mL/分の窒素流下、20℃/分の昇温速度で測定を行い、10%重量減少温度(Td10)を測定した。なお、10%重量減少温度としては、400℃以上であれば、実用上問題がなく、好ましくは、410℃以上であり、より好ましくは、420℃以上である。
得られた樹脂フィルム(硬化物)の面内方向の誘電特性について、キーサイト・テクノロジー社のネットワークアナライザーN5247Aを用いて、スプリットポスト誘電体共振器法により、周波数10GHzについて誘電率、及び、誘電正接を測定した。なお、前記誘電正接としては、10.0×10-3以下であれば、実用上問題がなく、好ましくは、3.0×10-3以下であり、より好ましくは2.5×10-3以下である。また、前記誘電率としては、3.0以下であれば、実用上問題がなく、好ましくは、2.7以下であることが好ましく、より好ましくは、2.5以下である。
樹脂フィルムを幅13mm、長さ100mmの短冊状に切断して難燃性評価用の試験片とした。UL94、20mm垂直燃焼試験を行い、以下の基準で評価した。なお、難燃性は、V-1であれば、実用上問題がなく、好ましくは、V-0である。
○:UL94 V-0
△:UL94 V-1
×:UL94 V-1未満
V5:片山化学工業株式会社V5(9,10-ジヒドロ-9-オキサ-10-ビニル-10-フォスファフェナントレン-10-オキシド)
OP930:クラリアントジャパン株式会社製OP930(アルミニウムトリス(ジエチルフォスフィネート))
PX-200:大八化学工業株式会社製PX-200(レゾルシノールビス(ジ-2,6-キシレニルホスフェート))剤
DT-4000:ロンザジャパン株式会社製DT-4000(ジシクロペンタジエン型シアネート樹脂)、
SA9000:SABICジャパン合同会社製SA9000(末端メタクリロイル変性ポリフェニレンエーテル樹脂)
BMI-5100:大和化成工業株式会社製BMI-5100(3,3'-ジメチル-5,5'-ジエチル-4,4'-ジフェニルメタンビスマレイミド)
Claims (15)
- 前記Zが、ベンゼン環である請求項1または2に記載の硬化性樹脂。
- 前記反応性基が、メタクリロイルオキシ基である請求項1~3のいずれかに記載の硬化性樹脂。
- 前記硬化性樹脂の重量平均分子量が、500~50000である請求項1~4のいずれかに記載の硬化性樹脂。
- 請求項1~5のいずれかに記載の硬化性樹脂、
ラジカル重合開始剤(B)、及び、
難燃剤(C)を含有する硬化性樹脂組成物。
- 更に、請求項1~5いずれかに記載の硬化性樹脂以外の硬化性樹脂(D)を含有する請求項6に記載の硬化性樹脂組成物。
- 前記(B)成分が、ジアルキルパーオキサイド系の有機過酸化物である請求項6または7に記載の硬化性樹脂組成物。
- 前記(C)成分が、下記一般式(P-1)~(P-5)のいずれかで表されるリン系難燃剤を含有する請求項6~8のいずれかに記載の硬化性樹脂組成物。
(上記一般式(P-1)中、R11は、それぞれ独立に炭素数1~12のアルキル基、アリール基、アラルキル基、または、シクロアルキル基を表し、R12は、アルキレン基またはアリーレン基を表し、aは、0~3の整数を示す。)
(上記一般式(P-2)中、R13は、それぞれ独立に炭素数1~12のアルキル基、アリール基、アラルキル基、または、シクロアルキル基を表し、Mb+は、b価の金属イオンを表し、bは、1~3の整数を示す。)
(上記一般式(P-3)中、R14は、それぞれ独立に炭素数1~12のアルキル基、アリール基、アラルキル基、または、シクロアルキル基を表し、R15は、アルキレン基またはアリーレン基を表し、Mc+は、c価の金属イオンを表し、c、d及びeは、それぞれ独立に1~3の整数を示し、c×d=2×eを満たす。)
(上記一般式(P-4)中、R16は、それぞれ独立に炭素数1~12のアルキル基、アリール基、アラルキル基、または、シクロアルキル基を表し、リン原子と共に環状構造を形成してもよく、R17は、ビニル基、ビニルベンジル基、又は、(メタ)アクリロイルオキシ基を表し、f及びgは、それぞれ独立に、0又は1を示す。)
(上記一般式(P-5)中、R18は、それぞれ独立に炭素数1~12のアルキル基、アリール基、アラルキル基、または、シクロアルキル基を表し、リン原子と共に環状構造を形成してもよく、R19は、アリーレン構造を有する2価の基を表し、R20は、(メタ)アクリロイルオキシ基、ビニルベンジルエーテル基、又は、アリルエーテル基を表し、hは、0又は1を示す。) - 前記(D)成分が、エポキシ樹脂、フェノール樹脂、活性エステル樹脂、シアネートエステル樹脂、マレイミド樹脂、ベンゾオキサジン樹脂、ポリフェニレンエーテル樹脂、及び、ビニル樹脂からなる群より選択される少なくとも1種の硬化性樹脂である請求項7~9のいずれかに記載の硬化性樹脂組成物。
- 請求項6~10のいずれかに記載の硬化性樹脂組成物を硬化反応させて得られる硬化物。
- 請求項6~10のいずれかに記載の硬化性樹脂組成物を有機溶剤で希釈したものであるワニス。
- 補強基材、及び、前記補強基材に含浸した請求項12に記載のワニスの半硬化物を有するプリプレグ。
- 基材と、請求項11に記載の硬化物を含む層を有する積層体。
- 請求項13に記載のプリプレグ、及び、銅箔を積層し、加熱圧着成型して得られる回路基板。
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WO2023089976A1 (ja) * | 2021-11-18 | 2023-05-25 | Dic株式会社 | 硬化性樹脂、硬化性樹脂組成物、及び、硬化物 |
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Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH04298527A (ja) * | 1991-03-28 | 1992-10-22 | Neos Co Ltd | 含フッ素ポリアリレート |
WO1997020878A1 (fr) * | 1995-12-04 | 1997-06-12 | Idemitsu Kosan Co., Ltd. | Resine de polycarbonate, resine de polycarbonate reticulee et photorecepteur electrophotographique |
JP2006002019A (ja) * | 2004-06-17 | 2006-01-05 | Sanyo Chem Ind Ltd | 難燃性エポキシ樹脂組成物 |
JP2011021079A (ja) * | 2009-07-14 | 2011-02-03 | Chisso Corp | インクジェット用インク |
JP2012251039A (ja) * | 2011-06-01 | 2012-12-20 | Asahi Kasei Chemicals Corp | リサイクル樹脂組成物およびその製造方法 |
WO2016098488A1 (ja) * | 2014-12-15 | 2016-06-23 | Dic株式会社 | 熱硬化性樹脂組成物、その硬化物、及びこれに用いる活性エステル樹脂 |
WO2020189598A1 (ja) * | 2019-03-19 | 2020-09-24 | 本州化学工業株式会社 | 末端(メタ)アクリレートポリカーボネートオリゴマー |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4707558A (en) | 1986-09-03 | 1987-11-17 | The Dow Chemical Company | Monomers and oligomers containing a plurality of vinylbenzyl ether groups, method for their preparation and cured products therefrom |
JPH0710902B2 (ja) | 1987-09-04 | 1995-02-08 | 昭和高分子株式会社 | 硬化性樹脂組成物 |
JP4017769B2 (ja) * | 1997-10-07 | 2007-12-05 | 株式会社クラレ | プリント配線基板基材およびその製造方法 |
US6384176B1 (en) | 2000-07-10 | 2002-05-07 | General Electric Co. | Composition and process for the manufacture of functionalized polyphenylene ether resins |
JP2004276411A (ja) * | 2003-03-14 | 2004-10-07 | Kanegafuchi Chem Ind Co Ltd | 積層体、プリント配線板、およびプリント配線板の製造方法 |
JP4298527B2 (ja) | 2004-01-26 | 2009-07-22 | 日立Geニュークリア・エナジー株式会社 | ジェットポンプ差圧計測管の補修装置 |
JP5140929B2 (ja) | 2006-01-31 | 2013-02-13 | 住友ベークライト株式会社 | 樹脂組成物及び樹脂組成物を使用して作製した半導体装置 |
JP5640656B2 (ja) * | 2010-10-29 | 2014-12-17 | 日本ゼオン株式会社 | プリプレグ及び積層体 |
JP2012141605A (ja) | 2010-12-16 | 2012-07-26 | Toagosei Co Ltd | 黒色感光性組成物、ソルダーレジスト及び感光性ドライフィルム |
JP7073184B2 (ja) | 2018-05-02 | 2022-05-23 | 三菱エンジニアリングプラスチックス株式会社 | ミリ波レーダー用カバー及びミリ波レーダー |
-
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Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH04298527A (ja) * | 1991-03-28 | 1992-10-22 | Neos Co Ltd | 含フッ素ポリアリレート |
WO1997020878A1 (fr) * | 1995-12-04 | 1997-06-12 | Idemitsu Kosan Co., Ltd. | Resine de polycarbonate, resine de polycarbonate reticulee et photorecepteur electrophotographique |
JP2006002019A (ja) * | 2004-06-17 | 2006-01-05 | Sanyo Chem Ind Ltd | 難燃性エポキシ樹脂組成物 |
JP2011021079A (ja) * | 2009-07-14 | 2011-02-03 | Chisso Corp | インクジェット用インク |
JP2012251039A (ja) * | 2011-06-01 | 2012-12-20 | Asahi Kasei Chemicals Corp | リサイクル樹脂組成物およびその製造方法 |
WO2016098488A1 (ja) * | 2014-12-15 | 2016-06-23 | Dic株式会社 | 熱硬化性樹脂組成物、その硬化物、及びこれに用いる活性エステル樹脂 |
WO2020189598A1 (ja) * | 2019-03-19 | 2020-09-24 | 本州化学工業株式会社 | 末端(メタ)アクリレートポリカーボネートオリゴマー |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2023008079A1 (ja) * | 2021-07-29 | 2023-02-02 | Dic株式会社 | 硬化性樹脂組成物、および、硬化物 |
WO2023089976A1 (ja) * | 2021-11-18 | 2023-05-25 | Dic株式会社 | 硬化性樹脂、硬化性樹脂組成物、及び、硬化物 |
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