WO2021246615A1 - 유체를 포함하는 가압장치 및 이를 이용한 전극 및 전극 및 전극조립체 제조방법 - Google Patents
유체를 포함하는 가압장치 및 이를 이용한 전극 및 전극 및 전극조립체 제조방법 Download PDFInfo
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- WO2021246615A1 WO2021246615A1 PCT/KR2021/001974 KR2021001974W WO2021246615A1 WO 2021246615 A1 WO2021246615 A1 WO 2021246615A1 KR 2021001974 W KR2021001974 W KR 2021001974W WO 2021246615 A1 WO2021246615 A1 WO 2021246615A1
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- WO
- WIPO (PCT)
- Prior art keywords
- pressing
- contact
- shape
- electrode
- unit
- Prior art date
Links
- 239000012530 fluid Substances 0.000 title claims abstract description 23
- 238000004519 manufacturing process Methods 0.000 title claims description 7
- 238000000034 method Methods 0.000 claims abstract description 15
- 238000003825 pressing Methods 0.000 claims description 80
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
- 239000007774 positive electrode material Substances 0.000 description 8
- -1 LiV 3 O 8 Chemical class 0.000 description 7
- 238000010586 diagram Methods 0.000 description 7
- 229910052782 aluminium Inorganic materials 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- 230000008859 change Effects 0.000 description 5
- 239000004020 conductor Substances 0.000 description 5
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- 229910052742 iron Inorganic materials 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000007773 negative electrode material Substances 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
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- 239000010949 copper Substances 0.000 description 3
- 239000011572 manganese Substances 0.000 description 3
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- 229920002943 EPDM rubber Polymers 0.000 description 2
- 229910015645 LiMn Inorganic materials 0.000 description 2
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- 239000004698 Polyethylene Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000011149 active material Substances 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
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- 238000000429 assembly Methods 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- 150000001875 compounds Chemical group 0.000 description 2
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- 239000000835 fiber Substances 0.000 description 2
- 239000010408 film Substances 0.000 description 2
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- 229910052748 manganese Inorganic materials 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000007784 solid electrolyte Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 229910015902 Bi 2 O 3 Inorganic materials 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 229910005793 GeO 2 Inorganic materials 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- 229910000733 Li alloy Inorganic materials 0.000 description 1
- 229910007969 Li-Co-Ni Inorganic materials 0.000 description 1
- 229910008163 Li1+x Mn2-x O4 Inorganic materials 0.000 description 1
- 229910015643 LiMn 2 O 4 Inorganic materials 0.000 description 1
- 229910013709 LiNi 1-x M Inorganic materials 0.000 description 1
- 229910006555 Li—Co—Ni Inorganic materials 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- 229920000265 Polyparaphenylene Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 229910006404 SnO 2 Inorganic materials 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- QDDVNKWVBSLTMB-UHFFFAOYSA-N [Cu]=O.[Li] Chemical compound [Cu]=O.[Li] QDDVNKWVBSLTMB-UHFFFAOYSA-N 0.000 description 1
- KLARSDUHONHPRF-UHFFFAOYSA-N [Li].[Mn] Chemical compound [Li].[Mn] KLARSDUHONHPRF-UHFFFAOYSA-N 0.000 description 1
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical class [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 description 1
- 239000006230 acetylene black Substances 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 229910001420 alkaline earth metal ion Inorganic materials 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical compound [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 229910021383 artificial graphite Inorganic materials 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000006231 channel black Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
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- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 description 1
- 150000002019 disulfides Chemical class 0.000 description 1
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- 239000006260 foam Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 239000006232 furnace black Substances 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- PVADDRMAFCOOPC-UHFFFAOYSA-N germanium monoxide Inorganic materials [Ge]=O PVADDRMAFCOOPC-UHFFFAOYSA-N 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 230000010220 ion permeability Effects 0.000 description 1
- 239000003273 ketjen black Substances 0.000 description 1
- 239000006233 lamp black Substances 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000001989 lithium alloy Substances 0.000 description 1
- 229910002102 lithium manganese oxide Inorganic materials 0.000 description 1
- QEXMICRJPVUPSN-UHFFFAOYSA-N lithium manganese(2+) oxygen(2-) Chemical group [O-2].[Mn+2].[Li+] QEXMICRJPVUPSN-UHFFFAOYSA-N 0.000 description 1
- VROAXDSNYPAOBJ-UHFFFAOYSA-N lithium;oxido(oxo)nickel Chemical compound [Li+].[O-][Ni]=O VROAXDSNYPAOBJ-UHFFFAOYSA-N 0.000 description 1
- URIIGZKXFBNRAU-UHFFFAOYSA-N lithium;oxonickel Chemical compound [Li].[Ni]=O URIIGZKXFBNRAU-UHFFFAOYSA-N 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
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- 238000012986 modification Methods 0.000 description 1
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- 229910021382 natural graphite Inorganic materials 0.000 description 1
- 229910021470 non-graphitizable carbon Inorganic materials 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 229920001197 polyacetylene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
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- 239000010703 silicon Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
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- 239000008107 starch Substances 0.000 description 1
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- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- TXEYQDLBPFQVAA-UHFFFAOYSA-N tetrafluoromethane Chemical compound FC(F)(F)F TXEYQDLBPFQVAA-UHFFFAOYSA-N 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical group 0.000 description 1
- 229910001935 vanadium oxide Inorganic materials 0.000 description 1
- 235000015041 whisky Nutrition 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B30—PRESSES
- B30B—PRESSES IN GENERAL
- B30B3/00—Presses characterised by the use of rotary pressing members, e.g. rollers, rings, discs
- B30B3/005—Roll constructions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B30—PRESSES
- B30B—PRESSES IN GENERAL
- B30B5/00—Presses characterised by the use of pressing means other than those mentioned in the preceding groups
- B30B5/02—Presses characterised by the use of pressing means other than those mentioned in the preceding groups wherein the pressing means is in the form of a flexible element, e.g. diaphragm, urged by fluid pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B30—PRESSES
- B30B—PRESSES IN GENERAL
- B30B15/00—Details of, or accessories for, presses; Auxiliary measures in connection with pressing
- B30B15/0052—Details of, or accessories for, presses; Auxiliary measures in connection with pressing for fluid driven presses
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B30—PRESSES
- B30B—PRESSES IN GENERAL
- B30B15/00—Details of, or accessories for, presses; Auxiliary measures in connection with pressing
- B30B15/16—Control arrangements for fluid-driven presses
- B30B15/24—Control arrangements for fluid-driven presses controlling the movement of a plurality of actuating members to maintain parallel movement of the platen or press beam
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/04—Construction or manufacture in general
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/04—Construction or manufacture in general
- H01M10/0404—Machines for assembling batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/04—Construction or manufacture in general
- H01M10/0468—Compression means for stacks of electrodes and separators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/04—Construction or manufacture in general
- H01M10/0481—Compression means other than compression means for stacks of electrodes and separators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/043—Processes of manufacture in general involving compressing or compaction
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/043—Processes of manufacture in general involving compressing or compaction
- H01M4/0433—Molding
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/043—Processes of manufacture in general involving compressing or compaction
- H01M4/0435—Rolling or calendering
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Definitions
- the present invention relates to a pressurizing device containing a fluid and a pressurizing method using the same, and more specifically, to a pressurizing device including a pressure adjusting unit containing a fluid, wherein the pressure applied varies depending on the shape of an object to be pressurized, and using the same It relates to the pressurization method.
- Secondary batteries that can store electric energy produced due to the development of alternative energy due to air pollution and energy depletion caused by the use of fossil fuels.
- Secondary batteries that can be charged and discharged are closely used in daily life, such as being used in mobile devices, electric vehicles, hybrid electric vehicles, and the like.
- Secondary batteries which are used as an energy source for various electronic devices that are indispensable in modern society, are installed and used in various devices such as mobile devices and electric vehicles.
- Various types of battery cells are being demanded in accordance with the needs of users and the diversity of shapes of mounted devices.
- Various types of battery cells may be formed by accommodating an electrode having a shape corresponding to the case or an electrode assembly stacked thereon in a case having a generally curved shape.
- an electrode active material it is necessary to apply an electrode active material to one or both sides of an electrode current collector formed in a certain shape, and then pressurize it.
- various types of electrode assemblies also have to go through a lamination process in order to improve their bonding strength after stacking various types of electrodes and separators.
- FIG. 1 is a schematic diagram of a pressurizing device according to the prior art.
- the pressurizing device 20 In order to pressurize the object 10 for pressurization, the pressurizing device 20 according to the prior art has a flat shape in which the pressurizing portion, which is a portion in contact with the object 10, is flat. However, the pressing device 20 having a flat pressing unit does not apply a constant force to the object 10 having various heights or various shapes.
- Patent Document 1 a pattern is formed on the surface of the roll member so that the compressive force transmitted to the electrode and the separator is applied only to some regions, but this is a form of compressing only a part, and there is a problem in that the entire object cannot be pressed uniformly at once. .
- Patent Document 1 Korean Patent Publication No. 2017-0099213 (2017.08.31)
- An object of the present invention is to solve the above problems, and an object of the present invention is to provide a pressing device capable of applying a uniform pressing force to an object to be pressed.
- Another object of the present invention is to reduce the production cost by shortening the electrode or electrode assembly manufacturing process and reducing the defect rate.
- the pressing device is located between a contact part whose shape or position is changed according to the shape of an object to be pressed, a pressing part for applying a certain force to the contact part, and the contact part and the pressing part, It may include a pressure control unit containing the fluid.
- the contact portion may have a pattern capable of applying different pressure to the object according to the shape of the object.
- the pattern may be an oblique shape, an X shape, or a dot shape having a plurality of minute protrusions.
- the contact portion may be composed of a plurality of protrusions that move individually.
- the pressure adjusting unit may be individually connected to the contact unit.
- the pressurizing unit may be individually connected to the pressure adjusting unit or may be integrally connected to each other.
- the pressure adjusting unit may be composed of a fluid connected to the plurality of protrusions.
- the pressure control unit may contain less than 90% of the fluid therein.
- the pressing device may include an upper roll including the contact part, the pressing part, and the pressure adjusting part, and a lower roll having the same configuration as the upper roll.
- the present invention provides an electrode and an electrode assembly manufacturing method, (S1) preparing an electrode or an electrode assembly, which is an object to be pressurized, (S2) placing the object in the pressurizing device, and (S3) the subject object using the pressurizing device It may include the step of pressurizing.
- the pressing device may be deformed depending on the shape of the object, or the pressing force applied to the contact portion in contact with the object may vary.
- the present invention provides a unit cell comprising the above-mentioned electrode or electrode assembly.
- the present invention also provides a battery module or battery pack including the unit cell. Also provided is a device in which the unit cell, the battery module, or the battery pack is mounted.
- one or two or more non-conflicting configurations among the above configurations may be selected and combined.
- the pressing device includes a contact part whose shape changes depending on the shape of the object to be pressed, a pressing part for applying a certain force to the contact part, and a force applied from the pressing part according to the shape of the object.
- a constant pressing force is provided to the object irrespective of the shape of the object, including a pressure adjusting part that is differently adjusted to change the shape of the contact part.
- the object subjected to a constant pressing force may be uniformly joined while maintaining a constant shape. Through this, it is possible to obtain an object that is uniformly joined in all parts and maintains a constant shape. In addition, defects in a specific part of the object are significantly reduced.
- FIG. 1 is a schematic diagram of a pressurizing device according to the prior art.
- FIG. 2 is a schematic diagram of a pressing device according to the present invention.
- FIG 3 is a schematic view showing the pressing device according to the present invention in the form of a pressing roll.
- FIG. 4 is a schematic view of the inside of the pressurizing device according to the first embodiment of the present invention.
- FIG. 5 is a schematic view of the inside of the pressurizing device according to the second embodiment of the present invention.
- FIG. 6 is a photograph showing the shape of the contact portion pattern according to the present invention.
- Figure 2 is a schematic diagram of the pressing device according to the present invention
- Figure 3 is a schematic diagram showing the pressing device according to the present invention in the form of a pressing roll.
- Figure 4 is a schematic diagram of the inside of the pressing device according to the first embodiment of the present invention
- Figure 5 is a schematic diagram of the inside of the pressing device according to the second embodiment of the present invention.
- the pressing device 200 according to the present invention is characterized in that it applies uniform pressure to the object 100 irrespective of the shape of the object 100 .
- the object 100 may be an electrode coated with an active material on one or both surfaces of an electrode current collector, or an electrode assembly formed in this way, that is, an electrode assembly including a positive electrode and a negative electrode and a separator is laminated therebetween.
- the positive electrode includes a positive electrode active material layer applied to at least one surface of a positive electrode current collector.
- the positive electrode active material layer may be prepared by applying a positive electrode mixture in which a positive electrode active material, a conductive material, and a binder are mixed, and if necessary, a filler may be further added to the positive electrode mixture.
- the positive electrode current collector is generally manufactured to have a thickness of 3 ⁇ m to 500 ⁇ m, and is not particularly limited as long as it has high conductivity without causing chemical change in the battery, for example, stainless steel, aluminum, nickel, One selected from titanium and carbon, nickel, titanium, or silver surface-treated on the surface of aluminum or stainless steel may be used, and specifically aluminum may be used.
- the positive electrode current collector may form fine irregularities on its surface to increase adhesion with the positive electrode active material layer, and various forms such as a film, a sheet, a foil, a net, a porous body, a foam, and a non-woven body are possible.
- the conductive material is typically added in an amount of 0.1 wt% to 30 wt% based on the total weight of the mixture including the positive electrode active material.
- a conductive material is not particularly limited as long as it has conductivity without causing a chemical change in the battery.
- graphite such as natural graphite or artificial graphite
- carbon black such as carbon black, acetylene black, Ketjen black, channel black, furnace black, lamp black, and summer black
- conductive fibers such as carbon fibers and metal fibers
- metal powders such as carbon fluoride, aluminum, and nickel powder
- conductive whiskeys such as zinc oxide and potassium titanate
- conductive metal oxides such as titanium oxide
- Conductive materials such as polyphenylene derivatives may be used.
- the binder included in the positive electrode is a component that assists in bonding between the active material and the conductive material and bonding to the current collector, and is typically added in an amount of 0.1 to 30% by weight based on the total weight of the mixture including the positive active material.
- binders include polyvinylidene fluoride, polyvinyl alcohol, carboxymethylcellulose (CMC), starch, hydroxypropylcellulose, regenerated cellulose, polyvinylpyrrolidone, tetrafluoroethylene, polyethylene , polypropylene, ethylene-propylene-diene terpolymer, sulfonated ethylene-propylene diene monomer, styrene-butadiene rubber, fluororubber, and various copolymers.
- the negative electrode is prepared by coating the negative electrode active material on one side or both sides of the negative electrode current collector and drying the negative electrode active material layer on one side. If necessary, the components as described above may be optionally further included.
- the negative electrode is a single-sided negative electrode in which the negative electrode active material layer is present only on one surface of the negative electrode current collector, the space occupied by the negative electrode in the pouch-type secondary battery is reduced, thereby improving the capacity of the pouch-type secondary battery.
- the negative electrode active material examples include carbon such as non-graphitizable carbon and graphitic carbon; Li x Fe 2 O 3 (0 ⁇ x ⁇ 1), Li x WO 2 (0 ⁇ x ⁇ 1), Sn x Me 1-x Me' y O z (Me: Mn, Fe, Pb, Ge; Me' : metal composite oxides such as Al, B, P, Si, elements of Groups 1, 2, and 3 of the periodic table, halogen; 0 ⁇ x ⁇ 1;1 ⁇ y ⁇ 3;1 ⁇ z ⁇ 8); lithium metal; lithium alloy; silicon-based alloys; tin-based alloys; SnO, SnO 2 , PbO, PbO 2 , Pb 2 O 3 , Pb 3 O 4 , Sb 2 O 3 , Sb 2 O 4 , Sb 2 O 5 , GeO, GeO 2 , Bi 2 O 3 , Bi 2 O 4 , and metal oxides such as Bi 2 O 5 ; conductive polymers such as polyacetylene; A Li-Co
- the separator is interposed between the anode and the cathode, and an insulating thin film having high ion permeability and mechanical strength is used.
- the pore diameter of the separator is generally 0.01 ⁇ m to 10 ⁇ m, and the thickness is generally 5 ⁇ m to 300 ⁇ m.
- a separation membrane For example, olefin polymers, such as chemical-resistant and hydrophobic polypropylene; A sheet or non-woven fabric made of glass fiber or polyethylene is used.
- a solid electrolyte such as a polymer is used as the electrolyte, the solid electrolyte may also serve as a separator.
- the electrode assembly is a stacked electrode assembly composed of unit cells having a structure in which a rectangular anode and a cathode are stacked with a separator interposed therebetween, or unit cells are stacked with a separator interposed therebetween and attached to each other It may be formed of a lamination-stack type electrode assembly, but is not limited thereto.
- the electrode assembly is a jelly-roll-type electrode assembly or unit cells having a structure in which a separator is interposed between a long sheet-type positive electrode and a negative electrode, which reduces their electrolyte impregnation, and then is wound by a long separation film. It is preferable not to have the same structure as the stack-folding type electrode assembly.
- the pressing device according to the present invention presses the positive electrode, the negative electrode, or the electrode assembly as described above in the stacking direction.
- a pressing part 210 that applies a constant force within the pressing device 200 , a contact part 220 directly in contact with the object 100 , and the pressing part and a pressure regulator 230 positioned between the contact part and containing a fluid therein.
- the pressing device 200 may be moved toward the object 100 by the pressing unit 210 , and the contact portion 220 of the pressing unit 200 may be in contact with the entire outer surface of the object 100 . .
- the pressurizing unit 210 is not connected to the pressure adjusting unit as shown in FIG. 3 and can press the pressure adjusting unit and the contacting unit 220 at once. It may be in the form of being connected to another part.
- the pressurizing unit 210 may be in contact with the pressure adjusting unit 230 as shown in FIG. 2 .
- it may be in the form of pressing a roll including a contact unit 220 and a pressure control unit (not shown).
- the roll may have a form in which a contact portion is located on an outer surface portion and a pressure control portion is disposed inside the contact portion.
- the pressing unit 210 may be in the form of moving the pressing device 200 by physical mechanical force, and is located inside the pressing device and is a member of the pressing device, for example, the contact part 220 by hydraulic pressure or the like. and the pressure adjusting unit 230 may be moved and pressurized.
- the pressing unit 210 may generally allow the contact unit 220 to contact the object 100 with a force of 1 kg/mm to 100 kg/mm, but this is the thickness of the object 100 to be pressed, the object It may vary depending on the purpose to be achieved by the elastic force and pressure of (100).
- the contact portion 220 that directly comes into contact with the object 100 may have a deformable shape depending on the shape of the object 100 .
- the contact portion 220 is made of an elastic material, and the outer surface of the object 100 . Even including this curved shape, it may be deformed so as to be in close contact with the entire outer surface of the object.
- the shape of the contact part 220 may change according to the shape of the object 100 as shown in FIG. 2 .
- the contact part 220 is deformed according to the shape of the object 100 by the force applied from the pressing part 210 .
- the pressure adjusting unit 230 contains a fluid therein, the pressure applied by the pressurizing unit 210 is distributed according to the shape of the object 100 , thereby forming the contact unit 220 . to be deformed to correspond to the external shape of the object 100 .
- the late pressing force F2 applied by the pressure adjusting unit 230 is the initial pressing force F1 applied by the pressing unit 210 according to the shape applied to the object 100 is the pressure adjusting unit ( 230), so that the contact portion 220 presses the entire area of the object 100 by being appropriately dispersed by the fluid.
- the height of the contact portion 220 may vary as shown in FIGS. 4 and 5 . That is, the shape of the pressure adjusting part 230 containing the fluid therein is changed, so that the protrusion or depression of the contact part can be adjusted.
- the pressure device 200 may have a form in which one pressure adjusting unit 230 is connected to a plurality of contact units 220 . That is, the pressure control unit 230 is a single member connected to the contact unit 220 formed of the plurality of protrusions, and the inside thereof may be made of a fluid.
- the fluid layer since less than 90% of the fluid is contained in the fluid layer, it may have a structure in which the fluid can move by the pressing part 210 and the contact part 220 .
- the contact part 220 is the internal member of the pressing device 200 , that is, the contact part 220 , the pressing part 220 , the pressing part 210 and the pressure adjusting part 230 move as one unit.
- the pressing device 200 may operate in such a way that it protrudes to the outside of one surface or is recessed into the inside.
- the pressure adjusting unit 230 may be individually connected to the contact unit 220 . That is, the pressure adjusting unit 230 may be individually connected to the contact portions 220 constituting each pattern to adjust the shape or position of the contact portions 220 .
- the pressurizing unit 210 is individually connected to the pressure adjusting unit 230 as shown in FIG. 5 , that is, 1:1, or as shown in FIG. 4 , a plurality of pressurizing units 210 are one pressure adjusting unit. It may be integrally connected to the unit 230 .
- the range of movement or shape deformation of the contact unit 220 may be larger.
- the contact unit 220 may exist as a separate member from the pressure control unit 230 , but the contact unit 220 and the pressure control unit 230 may be integrally formed.
- the contact part 220 is configured with a plurality of protrusions that move individually, so that the range of movement may vary depending on the shape of the object 100 .
- the contact part 220 may have a shape in which a pattern having a different height depending on the shape of the object 100 exists.
- FIG. 6 is a photograph showing the shape of the contact portion pattern according to the present invention.
- the contact portion 220 may be an oblique (a), an X-shaped (b), or a dot-shaped (c) in which a plurality of minute protrusions are present.
- the oblique shape may be used when the shape of the object 100 has the same shape as the pattern of the contact part 220 and has a constant height or has the same shape based on a specific reference line.
- the X-shaped (b) can be used when pressing the object 100 having a certain pattern and having a different height
- the dot (c) is used when pressing the amorphous object 100 .
- the interval or size of the pattern may vary depending on the shape of the object 100, in general, the interval of the pattern is preferably 1 mm to 100 mm. If the interval of the pattern is smaller than the above range, it may be difficult to finely adjust or form the contact portion 220 with the pattern by the fluid, and if the interval between the patterns is larger than the above range, through a constant pressing force to be achieved by the present invention It can be difficult to achieve uniformity of bonding.
- the contact portion 220 may be heated while pressing at the same time. This makes it possible to easily perform lamination to increase the bonding strength of the positive electrode, the negative electrode, or the electrode assembly.
- the pressurizing device may have a form in which one pressure adjusting unit 230 is connected to a plurality of contact units 220 as shown in FIG. 4 . That is, the pressure adjusting unit 230 may consist of a single fluid layer connected to the contact unit 220 formed with the plurality of protrusions.
- the fluid layer since less than 90% of the fluid is contained in the fluid layer, it may have a structure in which the fluid can move by the pressing part 210 and the contact part 220 .
- the pressure adjusting unit 230 may be individually connected to the contact unit 220 as shown in FIG. 5 . That is, the pressure adjusting unit 230 may be individually connected to the contact portions 220 constituting each pattern to adjust the shape or position of the contact portions 220 .
- the pressurizing unit 210 may be individually connected to the pressure adjusting unit 230 or may be integrally connected to each other.
- the range of movement or shape deformation of the contact unit 220 may be larger.
- the pressurizing unit 210 may be in a form not connected to the pressure adjusting unit 230 .
- the contact unit 220 may exist as a separate member from the pressure control unit 230 , but the contact unit 220 and the pressure control unit 230 may be integrally formed.
- the pressing device 200 may pressurize only in one direction of the object 100 depending on the shape of the object 100 , but in order to press the three-dimensional object 100 , the above-mentioned pressing part 210 ) , may be composed of an upper roll and a lower roll including the contact portion 220, the pressure control portion (230).
- the electrode and electrode assembly manufacturing method comprises the steps of (S1) preparing an electrode or an electrode assembly, which is an object to be pressed (S2) arranging the object in a pressing device corresponding to any one of the above descriptions (S3) and pressing the object with the pressing device.
- the pressing device may press the object from one side or both sides.
- the direction in which the pressing device presses the object may vary depending on the shape of the object.
- the pressing device may be deformed depending on the shape of the object, or the pressing force applied to the contact part contacting the object may be changed according to the shape of the object.
- the pressing device since the pressing device has a different shape depending on the shape of the object, a constant pressure can be applied to the object.
- the object can be uniformly joined, so that the defect rate of the object is also reduced, and objects having various shapes can be formed.
- the present invention provides a unit cell comprising the above-mentioned electrode or electrode assembly.
- the present invention also provides a battery module or battery pack including the unit cell. Also provided is a device in which the unit cell, the battery module, or the battery pack is mounted.
- the device may be an electronic device including a large-capacity battery, such as an electric vehicle, a hybrid vehicle, or a plug-in hybrid electric vehicle.
- a large-capacity battery such as an electric vehicle, a hybrid vehicle, or a plug-in hybrid electric vehicle.
- the pressing device includes a contact part whose shape changes depending on the shape of the object to be pressed, a pressing part for applying a certain force to the contact part, and a force applied from the pressing part according to the shape of the object.
- a constant pressing force is provided to the object irrespective of the shape of the object, including a pressure adjusting part that is differently adjusted to change the shape of the contact part.
- the object subjected to a constant pressing force may be uniformly joined while maintaining a constant shape. Through this, it is possible to obtain an object that is uniformly joined in all parts and maintains a constant shape. In addition, defects in a specific part of the object are significantly reduced.
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- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
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Abstract
Description
Claims (11)
- 가압하고자 하는 대상체의 형태에 따라 형상 또는 위치가 변경되는 접촉부;상기 접촉부에 일정한 힘을 가하는 가압부; 및상기 접촉부와 가압부 사이에 위치하고, 내부에 유체를 포함하는 압력조절부;를 포함하는 가압장치.
- 제1항에 있어서,상기 접촉부는 대상체의 형태에 따라 대상체에 가하는 압력을 달리 가할 수 있는 패턴이 존재하는 것을 특징으로 하는 가압장치.
- 제2항에 있어서,상기 패턴은 사선형, X자형, 다수의 미세한 돌기가 존재하는 닷 형인 것을 특징으로 하는 가압장치.
- 제1항에 있어서,상기 접촉부는 개별로 움직이는 다수 개의 돌기로 구성된 것을 특징으로 하는 가압장치.
- 제4항에 있어서,상기 압력조절부는 상기 접촉부에 개별로 연결되어 있는 것을 특징으로 하는 가압장치.
- 제5항에 있어서,상기 가압부는 상기 압력조절부에 개별로 연결되거나 일체로 연결되어 있는 것을 특징으로 하는 가압장치.
- 제4항에 있어서,상기 압력조절부는 상기 다수 개의 돌기에 연결된 유체로 이루어진 것을 특징으로 하는 가압장치.
- 제1항에 있어서,상기 압력조절부는 내부에 유체를 90%미만으로 포함하는 가압장치.
- 제1항에 있어서,상기 접촉부, 상기 가압부, 상기 압력조절부를 포함하는 상부 롤; 및상기 상부 롤과 동일한 구성을 가지고 있는 하부 롤;을 포함하는 가압장치.
- (S1) 가압하고자 하는 대상체인 전극 또는 전극조립체를 준비하는 단계;(S2) 제1항 내지 제9항 중 어느 한 항에 따른 가압장치에 상기 대상체를 배치하는 단계; 및(S3) 상기 가압장치로 상기 대상체를 가압하는 단계;를 포함하는 전극 및 전극조립체 제조방법.
- 제10항에 있어서,상기 (S3) 단계에 있어서, 상기 가압장치는 상기 대상체의 형태에 따라 변형되거나 상기 대상체에 접촉하는 접촉부에 가해지는 가압력이 달라지는 것을 특징으로 하는 전극 및 전극조립체 제조방법.
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP21818335.8A EP4108441A4 (en) | 2020-06-03 | 2021-02-16 | PRESSURE DEVICE COMPRISING A FLUID, ELECTRODE USING SAME, AND MANUFACTURING METHOD FOR ELECTRODE AND ELECTRODE ASSEMBLY |
JP2022551361A JP7424571B2 (ja) | 2020-06-03 | 2021-02-16 | 流体を含む押圧装置及びこれを用いた電極及び電極組立体の製造方法 |
US17/914,102 US20230398758A1 (en) | 2020-06-03 | 2021-02-16 | Pressing Apparatus Including Fluid and Electrode and Electrode Assembly Manufacturing Method Using the Same |
CN202180011397.2A CN115038579A (zh) | 2020-06-03 | 2021-02-16 | 包括流体的按压设备以及使用该按压设备的电极和电极组件制造方法 |
Applications Claiming Priority (2)
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KR10-2020-0066918 | 2020-06-03 | ||
KR1020200066918A KR102689451B1 (ko) | 2020-06-03 | 2020-06-03 | 유체를 포함하는 가압장치 및 이를 이용한 전극 및 전극 및 전극조립체 제조방법 |
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WO2021246615A1 true WO2021246615A1 (ko) | 2021-12-09 |
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PCT/KR2021/001974 WO2021246615A1 (ko) | 2020-06-03 | 2021-02-16 | 유체를 포함하는 가압장치 및 이를 이용한 전극 및 전극 및 전극조립체 제조방법 |
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US (1) | US20230398758A1 (ko) |
EP (1) | EP4108441A4 (ko) |
JP (1) | JP7424571B2 (ko) |
KR (1) | KR102689451B1 (ko) |
CN (1) | CN115038579A (ko) |
WO (1) | WO2021246615A1 (ko) |
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- 2021-02-16 EP EP21818335.8A patent/EP4108441A4/en active Pending
- 2021-02-16 WO PCT/KR2021/001974 patent/WO2021246615A1/ko active Application Filing
- 2021-02-16 CN CN202180011397.2A patent/CN115038579A/zh active Pending
- 2021-02-16 US US17/914,102 patent/US20230398758A1/en active Pending
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Also Published As
Publication number | Publication date |
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EP4108441A4 (en) | 2023-10-11 |
JP7424571B2 (ja) | 2024-01-30 |
CN115038579A (zh) | 2022-09-09 |
EP4108441A1 (en) | 2022-12-28 |
KR102689451B1 (ko) | 2024-07-30 |
US20230398758A1 (en) | 2023-12-14 |
JP2023516938A (ja) | 2023-04-21 |
KR20210150035A (ko) | 2021-12-10 |
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