WO2021238600A1 - 一种锂离子电池用硅碳负极材料及其制备方法 - Google Patents
一种锂离子电池用硅碳负极材料及其制备方法 Download PDFInfo
- Publication number
- WO2021238600A1 WO2021238600A1 PCT/CN2021/091977 CN2021091977W WO2021238600A1 WO 2021238600 A1 WO2021238600 A1 WO 2021238600A1 CN 2021091977 W CN2021091977 W CN 2021091977W WO 2021238600 A1 WO2021238600 A1 WO 2021238600A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- silicon
- negative electrode
- electrode material
- carbon negative
- lithium ion
- Prior art date
Links
- HMDDXIMCDZRSNE-UHFFFAOYSA-N [C].[Si] Chemical compound [C].[Si] HMDDXIMCDZRSNE-UHFFFAOYSA-N 0.000 title claims abstract description 51
- 239000007773 negative electrode material Substances 0.000 title claims abstract description 43
- 229910001416 lithium ion Inorganic materials 0.000 title claims abstract description 34
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 title claims abstract description 33
- 238000002360 preparation method Methods 0.000 title claims abstract description 21
- 239000002243 precursor Substances 0.000 claims abstract description 33
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 29
- 239000005543 nano-size silicon particle Substances 0.000 claims abstract description 28
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 25
- 239000010439 graphite Substances 0.000 claims abstract description 25
- 239000011230 binding agent Substances 0.000 claims abstract description 19
- 238000000034 method Methods 0.000 claims abstract description 18
- 230000004927 fusion Effects 0.000 claims abstract description 13
- 238000000465 moulding Methods 0.000 claims abstract description 13
- 238000002156 mixing Methods 0.000 claims abstract description 8
- 239000010405 anode material Substances 0.000 claims description 14
- 239000002245 particle Substances 0.000 claims description 12
- 238000003763 carbonization Methods 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 6
- 239000012299 nitrogen atmosphere Substances 0.000 claims description 6
- 238000005245 sintering Methods 0.000 claims description 6
- 229910021383 artificial graphite Inorganic materials 0.000 claims description 5
- 229910021382 natural graphite Inorganic materials 0.000 claims description 5
- 239000003921 oil Substances 0.000 claims description 4
- 239000003245 coal Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 abstract description 4
- 230000002441 reversible effect Effects 0.000 abstract description 2
- 238000010000 carbonizing Methods 0.000 abstract 2
- 239000011148 porous material Substances 0.000 description 10
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 9
- 229910052744 lithium Inorganic materials 0.000 description 9
- 239000011295 pitch Substances 0.000 description 9
- 239000010426 asphalt Substances 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- 229910003481 amorphous carbon Inorganic materials 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000007772 electrode material Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000000462 isostatic pressing Methods 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 239000011300 coal pitch Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 239000011247 coating layer Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000009831 deintercalation Methods 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 230000005764 inhibitory process Effects 0.000 description 2
- 238000003780 insertion Methods 0.000 description 2
- 230000037431 insertion Effects 0.000 description 2
- 238000009830 intercalation Methods 0.000 description 2
- 238000011031 large-scale manufacturing process Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000007873 sieving Methods 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910001290 LiPF6 Inorganic materials 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000007841 coal based oil Substances 0.000 description 1
- 239000011889 copper foil Substances 0.000 description 1
- 238000013480 data collection Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000002687 intercalation Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000012982 microporous membrane Substances 0.000 description 1
- 239000004005 microsphere Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- -1 polypropylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000001878 scanning electron micrograph Methods 0.000 description 1
- 239000002210 silicon-based material Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000011232 storage material Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/386—Silicon or alloys based on silicon
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
- H01M4/366—Composites as layered products
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
- H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/628—Inhibitors, e.g. gassing inhibitors, corrosion inhibitors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/021—Physical characteristics, e.g. porosity, surface area
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
- H01M2004/027—Negative electrodes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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KR1020227013148A KR20220104684A (ko) | 2020-05-26 | 2021-05-07 | 리튬 이온 전지용 실리콘-탄소 음극재 및 그 제조 방법 |
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CN202010456796.7 | 2020-05-26 | ||
CN202010456796.7A CN111725504B (zh) | 2020-05-26 | 2020-05-26 | 一种锂离子电池用硅碳负极材料及其制备方法 |
Publications (1)
Publication Number | Publication Date |
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WO2021238600A1 true WO2021238600A1 (zh) | 2021-12-02 |
Family
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Family Applications (1)
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PCT/CN2021/091977 WO2021238600A1 (zh) | 2020-05-26 | 2021-05-07 | 一种锂离子电池用硅碳负极材料及其制备方法 |
Country Status (3)
Country | Link |
---|---|
KR (1) | KR20220104684A (ko) |
CN (1) | CN111725504B (ko) |
WO (1) | WO2021238600A1 (ko) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114744166A (zh) * | 2022-02-25 | 2022-07-12 | 深圳市翔丰华科技股份有限公司 | 预锂化硅氧复合材料的制备方法 |
CN117174836A (zh) * | 2023-11-03 | 2023-12-05 | 陕西晶泰新能源科技有限公司 | 一种锂离子电池氧化亚硅负极的预镁化中间缓冲层 |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111725504B (zh) * | 2020-05-26 | 2021-10-29 | 深圳市翔丰华科技股份有限公司 | 一种锂离子电池用硅碳负极材料及其制备方法 |
CN112290006A (zh) * | 2020-11-23 | 2021-01-29 | 山东硅纳新材料科技有限公司 | 一种简单高效的硅碳负极材料制备方法 |
CN114436238B (zh) * | 2021-12-28 | 2023-07-18 | 深圳市翔丰华科技股份有限公司 | 锂离子电池用低膨胀硅碳负极材料的制备方法 |
CN114538432B (zh) * | 2022-02-09 | 2024-01-09 | 上海杉杉新材料有限公司 | 石墨负极材料、其前驱体、其生料前驱体及其制备方法和应用 |
Citations (6)
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CN103855369A (zh) * | 2012-12-05 | 2014-06-11 | 上海杉杉科技有限公司 | 一种锂电池负极材料及其制备方法 |
US20170342578A1 (en) * | 2014-11-11 | 2017-11-30 | William Marsh Rice University | A new class of electrocatalysts |
CN107785560A (zh) * | 2017-11-15 | 2018-03-09 | 国联汽车动力电池研究院有限责任公司 | 一种高性能硅碳负极材料及其制备方法 |
CN108682830A (zh) * | 2018-06-11 | 2018-10-19 | 清华大学深圳研究生院 | 一种锂离子电池硅碳复合负极材料及其制备方法 |
CN108963208A (zh) * | 2018-06-22 | 2018-12-07 | 清华大学深圳研究生院 | 一种硅碳负极材料的制备方法及锂离子电池 |
CN111725504A (zh) * | 2020-05-26 | 2020-09-29 | 深圳市翔丰华科技股份有限公司 | 一种锂离子电池用硅碳负极材料及其制备方法 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103633307B (zh) * | 2013-12-20 | 2015-06-17 | 大连宏光锂业股份有限公司 | 一种锂离子电池硅碳复合负极材料生产方法 |
CN106257716B (zh) * | 2016-08-30 | 2019-01-11 | 浙江超威创元实业有限公司 | 一种硅碳复合负极材料的制备方法及锂离子电池 |
CN106784833A (zh) * | 2016-12-26 | 2017-05-31 | 国联汽车动力电池研究院有限责任公司 | 硅碳负极材料及其制备方法 |
-
2020
- 2020-05-26 CN CN202010456796.7A patent/CN111725504B/zh active Active
-
2021
- 2021-05-07 WO PCT/CN2021/091977 patent/WO2021238600A1/zh active Application Filing
- 2021-05-07 KR KR1020227013148A patent/KR20220104684A/ko unknown
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103855369A (zh) * | 2012-12-05 | 2014-06-11 | 上海杉杉科技有限公司 | 一种锂电池负极材料及其制备方法 |
US20170342578A1 (en) * | 2014-11-11 | 2017-11-30 | William Marsh Rice University | A new class of electrocatalysts |
CN107785560A (zh) * | 2017-11-15 | 2018-03-09 | 国联汽车动力电池研究院有限责任公司 | 一种高性能硅碳负极材料及其制备方法 |
CN108682830A (zh) * | 2018-06-11 | 2018-10-19 | 清华大学深圳研究生院 | 一种锂离子电池硅碳复合负极材料及其制备方法 |
CN108963208A (zh) * | 2018-06-22 | 2018-12-07 | 清华大学深圳研究生院 | 一种硅碳负极材料的制备方法及锂离子电池 |
CN111725504A (zh) * | 2020-05-26 | 2020-09-29 | 深圳市翔丰华科技股份有限公司 | 一种锂离子电池用硅碳负极材料及其制备方法 |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114744166A (zh) * | 2022-02-25 | 2022-07-12 | 深圳市翔丰华科技股份有限公司 | 预锂化硅氧复合材料的制备方法 |
CN117174836A (zh) * | 2023-11-03 | 2023-12-05 | 陕西晶泰新能源科技有限公司 | 一种锂离子电池氧化亚硅负极的预镁化中间缓冲层 |
Also Published As
Publication number | Publication date |
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KR20220104684A (ko) | 2022-07-26 |
CN111725504A (zh) | 2020-09-29 |
CN111725504B (zh) | 2021-10-29 |
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