WO2021229438A1 - Vêtement pouvant masquer des traces d'humidité corporelle et procédé de fabrication correspondant - Google Patents

Vêtement pouvant masquer des traces d'humidité corporelle et procédé de fabrication correspondant Download PDF

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Publication number
WO2021229438A1
WO2021229438A1 PCT/IB2021/054011 IB2021054011W WO2021229438A1 WO 2021229438 A1 WO2021229438 A1 WO 2021229438A1 IB 2021054011 W IB2021054011 W IB 2021054011W WO 2021229438 A1 WO2021229438 A1 WO 2021229438A1
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WIPO (PCT)
Prior art keywords
knitted fabric
hydrophobic
paste
surface finish
moisture
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PCT/IB2021/054011
Other languages
English (en)
Inventor
Martin BURKON
Pavel HRSTKA
Rene NEMECEK
Original Assignee
Cityzen S.R.O.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cityzen S.R.O. filed Critical Cityzen S.R.O.
Priority to EP21732507.5A priority Critical patent/EP4288601A1/fr
Publication of WO2021229438A1 publication Critical patent/WO2021229438A1/fr

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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0009—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using knitted fabrics
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/08—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with halogenated hydrocarbons
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
    • D06M14/02—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials on to materials of natural origin
    • D06M14/04—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials on to materials of natural origin of vegetal origin, e.g. cellulose or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/244—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
    • D06M15/256—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons containing fluorine
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D06M15/277—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof containing fluorine
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • D06M15/576—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them containing fluorine
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/16—Processes for the non-uniform application of treating agents, e.g. one-sided treatment; Differential treatment
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/047—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with fluoropolymers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • D06N3/142—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes mixture of polyurethanes with other resins in the same layer
    • D06N3/144—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes mixture of polyurethanes with other resins in the same layer with polyurethane and polymerisation products, e.g. acrylics, PVC
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/18—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials
    • D06N3/186—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials one of the layers is on one surface of the fibrous web and the other layer is on the other surface of the fibrous web
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2201/00—Chemical constitution of the fibres, threads or yarns
    • D06N2201/04—Vegetal fibres
    • D06N2201/042—Cellulose fibres, e.g. cotton
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00—Specially adapted uses
    • D06N2211/10—Clothing

Definitions

  • Clothing capable of masking traces of body moisture and the method of manufacture thereof
  • Office clothes and sportswear made of specially treated fabric with double-sided treatment.
  • Functional sportswear is adapted primarily to the rapid removal of sweat from the body to prevent long-term contact of moisture with the skin, which not only reduces the comfort of an athlete, but may also cause health problems in the form of chilling, cold, and the like. Functional sportswear usually does not focus on aesthetics but function. So, the result is, “I feel great, I feel being dry; however, everyone can see how sweaty I am.” Sportswear or fabrics intended for sportswear form an extensive state of the art, and we do not aim to discuss them extensively herein. We focus on clothing or fabrics that have double-sided surface finish with different properties.
  • the condition for one-way moisture direction is the arrangement of the hydrophilic and hydrophobic visible moisture-masking layer with respect to the user’s skin.
  • the reverse layer of the fabric/clothing intended for contact with the user’s skin is always hydrophobic so that moisture does not remain in it but only passes quickly to be drained away.
  • CN 100414 036 describes a fabric which is provided with a hydrophobic print on the reverse side, which covers 50 to 99% of the reverse side.
  • CN 101 845 702 describes a method for treating a fabric, the reverse side of which, like in CN 100414 036, is provided with a hydrophobic print which, unlike CN 100414036, covers the entire surface of the fabric reverse side.
  • the fabrics manufactured in accordance with CN 100414 036 or CN 101 845 702 are intended for the production of sportswear, fast removal of sweat from the body and fast drying.
  • CN 100414 036 and CN 101 845 702 address the problem: How to feel well during exercise/sport and be dry soon?
  • the clothing of this invention which is preferably worn directly on the user’s skin.
  • the clothing On the right side, the clothing is provided with a hydrophobic visible moisture-masking layer which is partially coated/soaked into the fabric; and on the reverse side, it is provided with a hydrophilic layer which quickly and efficiently receives and distributes the body moisture over the hydrophilic layer.
  • the wearer feels certain moisture compared to sports functional T-shirts, which does not, however, disturb the user’s comfort. The moisture is absorbed and distributed within the hydrophilic layer and evaporates through the hydrophobic layer.
  • An essential feature of the clothing of this invention is that no moisture reservoirs are formed in the right, surface, hydrophobic, visible moisture-masking layer, and the moisture does not accumulate there in any way; it only passes to the surface where it evaporates.
  • the hydrophobic layer is incorporated into at least 30% of the fabric thickness to be able to visually mask the moisture. Thus, no stains, maps or marks are visible on the right side, and the wearer may focus on the object of their interest, having peace of mind.
  • the clothing of this invention is preferably worn directly on the user’s skin.
  • This clothing preferably a T-shirt, underwear, comprises at least one layer of knitted fabric, which is provided with a hydrophobic surface finish of the knitted fabric, which can completely mask the body moisture of a user thereof, namely at least 2 times the weight of water compared to the actual weight of the knitted fabric and at the same time ensure gradual evaporation of moisture from the body.
  • a light T-shirt it masks up to 180 ml of sweat per m 2 , i.e., 140 ml of sweat for an average ready-made clothing.
  • the clothing When dressed, the clothing is designed so that the reverse side is in contact with the body skin and can distribute the discharged body moisture over the hydrophilic surface thereof, which is formed by hydrophilic treatment of the knitted fabric and serves as a reservoir of body moisture to distribute body moisture within hydrophilic area thereof and, at the same time, retain it therein; the boundary thereof is delimited by a hydrophobic surface area, which is formed by the hydrophobic treatment of the knitted fabric and serves to mask and enclose the moisture in the hydrophilic space of the knitted fabric.
  • this hydrophobic area allows moisture to evaporate from the hydrophilic area, water molecules pass freely through it but are not able to be trapped.
  • This hydrophobic surface finish of the knitted fabric preferably contains 4 to 10% wt. of hydrophobic mixture in the weight per square metre.
  • the hydrophobic surface finish of the knitted fabric leads to the outside of the clothing
  • the hydrophilic surface finish of the knitted fabric leads to the inside of the clothing and is intended to come into contact with the skin
  • the hydrophobic and hydrophilic surface finishes meet inside the knitted fabric layer, wherein the hydrophobic surface finish of the knitted fabric delimits the boundary of the hydrophilic surface finish of the knitted fabric.
  • the hydrophobic surface finish of the knitted fabric masks the moisture in the hydrophilic surface finish of the knitted fabric so well that it is not visible to a naked eye that the knitted fabric contains water; and, at the same time, the moisture is locked in the hydrophilic layer as it forms the boundary, beyond which the water does not rise along the fibres.
  • the clothing is made of knitted fabric - a textile flat knitted structure (hereinafter referred to as “knitted fabric”), which is treated on both sides and each side has different properties.
  • the right side of the knitted fabric is provided with a hydrophobic surface finish of the knitted fabric, visible, moisture-masking, which is applied in the form of a paste on/into the knitted fabric using a perforated rotary template.
  • the viscosity of the hydrophobic paste is adjusted so that the hydrophobic paste soaks up to 30 to 70% of the knitted fabric thickness, preferably to half the knitted fabric thickness, providing effective visual masking of body moisture and also ensuring distribution of moisture in the remaining 70 to 30% of the knitted fabric thickness.
  • a functional variant of the knitted fabric is a cotton knitted fabric with at least 90% wt. of cotton weighing at least 150 g/m 2 . It is always desirable to achieve the soaking of the hydrophobic paste to approximately half the knitted fabric thickness, but at least up to 30%, in order to form a visually masking hydrophobic layer.
  • the use of a knitted fabric is very preferable because the knitted fabric distributes moisture well, helping the clothing to function even better.
  • the whole knitted fabric is preferably treated with a softening solution or an antibacterial solution.
  • a softening solution By applying the softening solution, the hydrophilic properties and user comfort of the untreated reverse side of the knitted fabric are improved and the hydrophobic surface finish of the knitted fabric is softened.
  • the clothing such as urban T-shirts, shirts, T-shirts under shirts, or underwear or trousers, is made from the knitted fabric treated on one side or both sides; layer orientation with respect to the body must be followed - i.e., hydrophilic surface finish on the reverse side of the knitted fabric as well as the clothing comes into contact with the skin.
  • the outer right side of the knitted fabric and clothing is hydrophobic.
  • the hydrophobic surface finish on the right side of the knitted fabric has a water-repellent function.
  • the clothing masking traces of body moisture, intended for contact with the skin comprises at least one layer of the knitted fabric containing at least 90% wt. of cotton, weighing 150 g/m 2 , which is treated only with preparations without cationic substances,
  • the knitted fabric is provided with a hydrophobic, moisture-masking and locking surface finish of the knitted fabric situated to a depth of 30 to 70% of the knitted fabric from the right side of the knitted fabric, and a hydrophilic, moisture-distributing and retaining surface finish of the knitted fabric situated to a depth of 30 to 70% of the knitted fabric from the reverse side of the knitted fabric.
  • the hydrophobic surface finish of the knitted fabric consists of a hydrophobic mixture which constitutes 4 to 10% wt. of the clothing, and the hydrophilic surface finish of the knitted fabric has a drop test absorbency of at most 5 seconds, preferably 3 seconds; the hydrophobic surface finish of the knitted fabric masks at least 2 times of weight of water retained in the hydrophilic surface finish of the knitted fabric, regarding the weight thereof.
  • Drop test absorbency is a method designed to measure the water absorbency of fabric by measuring the time it takes a drop of water placed on the fabric surface to be completely absorbed by the fabric. Sample is placed over the top of the beaker so that the centre is unsupported. A measured drop of water is placed on the fabric from 1 cm off the surface, time is recorded until the water drop gets absorbed completely. The less seconds, the better absorbency.
  • the hydrophilic surface finish of the knitted fabric leads to the reverse inner side of the clothing and the hydrophobic surface finish of the knitted fabric leads to the right outer side of the clothing and the interface of the hydrophobic and hydrophilic surface finishes of the knitted fabric is situated inside the layer of the knitted fabric.
  • the hydrophobic mixture preferably contains at least 10% wt. of fluorocarbon and at least 50% wt. of a polymeric carrier, wherein the polymeric carrier is acrylate and the derivatives thereof or polyurethane and the derivatives thereof, or acrylate-polyurethane and the derivatives thereof.
  • the hydrophobic mixture preferably contains 70 to 99% wt. of a copolymer of fluorocarbon and acrylate and 1 to 30% wt. of polyurethane.
  • the fluorocarbon used consists of a carbon chain with a length of 4, 6.
  • the hydrophobic mixture preferably contains 60 to 100% wt. of resins or paraffins.
  • the knitted fabric preferably contains at least 95% wt. of cotton and at least 2% wt. of Lycra. General procedure for the manufacture of clothing capable of masking traces of body moisture
  • the carrier fabric is a flat textile structure - a knitted fabric.
  • a single or double knitted fabric is used.
  • the knitted fabric is made of at least 90% wt. of cotton, preferably 95% wt. of cotton and the weight per square metre thereof is 150 to 300 g/m 2 , preferably 160 g/m 2 .
  • Lycra, viscose, or synthetic fibres are preferably used as an additive.
  • the knitted fabric must always meet the condition of absorbency -drop test - maximum 5 seconds, preferably 3 seconds. This absorbency condition precludes the use of more than 10% wt. of the content of synthetic fibres in the knitted fabric.
  • the pre-treatment of the knitted fabric is carried out according to state of the art, complying with the given conditions.
  • the pre-treatment is preferably carried out using a continuous or pull-out method and consists of treating the fabric with a stabilizer and a wetting agent.
  • a stabilizer and a wetting agent Preferably, hydrogen peroxide and lye, preferably NaOH, are added during the pre-treatment.
  • Peroxide and lye are added to treat raw cotton, wherein it is bleached and unwanted particles adhering to the fibres are removed.
  • the knitted fabric When using peroxide and lye, the knitted fabric must be washed at least at 70 °C for at least 25 minutes at the end of the pre-treatment. No cationic substances must be applied in the pre-treatment step and any treatment agents used must remain stable in all subsequent steps, especially when exposed to temperatures of about 160 °C.
  • the dyeing of the knitted fabric is carried out according to state of the art, complying with the given conditions.
  • the dyeing is preferably carried out using a continuous or pull-out method and consists of dyeing the fabric with a textile dye.
  • a textile dye Preferably, an environmental-friendly non-sulfone textile dye having low water consumption and low carbon footprint is used.
  • an antifoaming agent, levelling and anti -refraction agents, salt, and alkali are preferably used. No cationic substances, in particular silicone or hydrophobic agents impairing the natural absorbency of the cotton, must be applied in the dyeing step and any treatment agents used must remain stable in all subsequent steps, especially when exposed to temperatures of about 160 °C.
  • the dyed knitted fabric is preferably fixed on a frame and dried.
  • the hydrophobic paste contains up to 10% wt. of the hydrophobic mixture, wherein the hydrophobic mixture contains 70 to 99% wt. of a copolymer of fluorocarbon and acrylate and 1 to 30% wt. of polyurethane. Or the hydrophobic mixture contains at least 10% wt. of fluorocarbon and at least 50% wt. of a polymeric carrier, wherein the polymeric carrier is acrylate and the derivatives thereof or polyurethane and the derivatives thereof, or acrylate- polyurethane and the derivatives thereof.
  • the hydrophobic mixture is preferably in the form of an aqueous dispersion of a hydrophobic mixture with a dry matter content of 40 to 50% wt., preferably an aqueous dispersion of a copolymer of fluorocarbon and acrylate in a polyurethane carrier.
  • the finished knitted fabric features repellent characteristics not only for water or wine but also for oils and paste mixtures, such as ketchup or honey.
  • the hydrophobic paste contains water and is thickened using textile thickening agent to the desired viscosity.
  • the thickening agent is preferably made of polysaccharides, in particular starches, seaweed, or acrylic or maleic acid derivatives.
  • the thickening agent is a polymer dispersion of 3 to 10% wt. of ethoxylated branched tridecanol, 1 to 10% wt. of C11-C15 alkanes and water.
  • the hydrophobic paste additionally contains less than 5% wt. of an effective ingredient, which may be a dye or an antibacterial agent.
  • the hydrophobic paste is first mixed without thickening agent, usually to a viscosity of about 55 to 75 dPa s, preferably 60 to 65 dPa s, and mixed for at least 15 minutes. After 15 minutes, the paste is thickened to a viscosity of 80 to 90 dPa s, preferably 83 to 85 dPa s using the thickening agent.
  • the hydrophobic, visible moisture-masking surface finish of the knitted fabric is applied/coated on the right side of the knitted fabric by means of a rotary template having perforation/porosity of 100 to 200 mesh, preferably 125 to 195 mesh, in a dose of 110 to 200 g/m 2 of the knitted fabric, preferably in a dose of 110 to 130 g/m 2 of the knitted fabric weighing 150 to 180 g/m 2 , and in a dose of 130 to 200 g/m 2 of the knitted fabric weighing 180 to 300 g/m 2 .
  • the rotary template is a rotating hollow cylinder, which preferably has a diameter of 15 to 40 cm, and shell of which is perforated/porous.
  • the template is mounted on a dosing device dosing the hydrophobic paste into the rotary template.
  • the rotary template is fitted with a squeegee used to gather the hydrophobic paste and push it through the rotary template pores, wherein the hydrophobic paste is coated into the knitted fabric.
  • the rotating rotary template is placed loosely on the fabric without pressure or with a maximum pressure of 0.5 bar and rotates together with the knitted fabric being unwound.
  • the rotary template is shown in Figure 3. After coating the hydrophobic paste with the rotary template into the knitted fabric, the applied paste is preferably smoothed with a smoothing squeegee or knife without pressure or with a maximum pressure of 0.5 bar over the entire width thereof.
  • the hydrophobic paste applied to the knitted fabric and smoothed is first dried at 110 to 130 °C for 30 to 90 seconds to ensure each piece of the knitted fabric is dry. Only then, the dried hydrophobic paste applied to the knitted fabric is exposed to temperatures of 150 to 170 °C for 60 to 120 seconds, depending on the form of carrier used in the hydrophobic paste.
  • the hydrophobic, visible moisture-masking surface finish of the knitted fabric is dried at 120 °C for 60 seconds and condensed at 160 °C for 90 seconds. Drying and condensation may be performed in two steps or a single step, but it is always necessary to ensure the knitted fabric exposed to condensation temperatures is completely dry. After finishing the condensation, the knitted fabric becomes hydrophobic on one side, namely on the right side thereof. The reverse side keeps the properties of the knitted fabric before the one-side application of the hydrophobic paste, i.e., it remains hydrophilic.
  • the final manufacture step includes spatial stabilization of the knitted fabric called sanforising, wherein the sanforising is performed according to the state of the art.
  • sanforising spatial stabilization of the knitted fabric
  • the whole knitted fabric in particular, the reverse side thereof, is very preferably treated with a softening solution, supporting the knitted fabric hydrophilicity and the user comfort when wearing clothing made of such a knitted fabric.
  • the knitted fabric with the condensed hydrophilic surface finish is treated with cationic substances to increase the hydrophilicity and soften the fabric for feeling tone.
  • the knitted fabric having the condensed hydrophilic surface finish is preferably treated with a softening solution, which contains surfactants and/or silicones, contains preferably a silicone microemulsion in the form of polydimethylsiloxane in a concentration of at least 10 g/kg of the softening solution, using a pull-out or continuous method.
  • the softening solution contains ethoxylated isotridecanol at a concentration of 1 to 5 g/kg of the softening solution and sodium toluenesulfonate at a concentration of 0.2 to 0.8 g/kg of the softening solution.
  • the pH value of the softening hydrophilic solution ranges preferably between 5 and 6, which is achieved by the addition of acetic acid.
  • an effect treatment is applied to the double-sided treated knitted fabric with different properties, which may be an application of an antibacterial solution, preferably containing silver, zinc, copper, or cobalt.
  • Zinc is preferably applied in the form of pyrithione zinc.
  • the application of the antibacterial solution is performed instead of the hydrophilic treatment of the knitted fabric.
  • the treated knitted fabric is cut according to the patterns and sewn, preferably with cotton threads, into shapes of the desired piece of clothing.
  • socks, underwear, singlets, vests, petticoats, T-shirts, shirts, polo shirts, or caps are made.
  • a knitted fabric comprising cotton for manufacturing of clothing masking traces of body moisture, capable of absorbing and masking of absorbated at least the same weight of body moisture as it weighs itself, characterized in that the knitted fabric contains at least 90% wt. of cotton, weighing 150 g/m 2 to 300 g/m 2 and is treated only with preparations without cationic substances, wherein the knitted fabric is provided with a hydrophilic, moisture-distributing and retaining surface finish, on its side intended for contact with a skin of user, situated to a depth of 30 to 70%, and on the other side of the knitted fabric is the knitted fabric provided with a hydrophobic, moisture-masking and locking surface finish, situated to a depth of 30 to 70%, wherein the hydrophobic surface finish of the knitted fabric consists of a hydrophobic mixture which constitutes 4 to 10% wt.
  • the side of the knitted fabric intended for contact with a skin of user is a reverse inner side of the intended clothing and the other side of the knitted fabric is right outer side of the intended clothing.
  • the hydrophobic mixture contains at least 10% wt. of fluorocarbon and at least 50% wt. polymeric carrier.
  • the polymeric carrier is acrylate and the derivatives thereof or polyurethane and the derivatives thereof or acrylate-polyurethane and the derivatives thereof.
  • the hydrophobic mixture contains 70 to 99 % wt. of a copolymer of fluorocarbon and acrylate and 1 to 30 % wt. of polyurethane.
  • the fluorocarbon is formed by a carbon chain with a length of 4 or 6 carbons.
  • the knitted fabric (1) contains at least 95% wt. of cotton and at least 2% wt. of Lycra.
  • the hydrophilic surface finish (3) of the knitted fabric (1) has a Drop test absorbency of at most 3 seconds.
  • a clothing masking traces of body moisture, capable of absorbing and masking of absorbated at least the same weight of water as it weighs itself, manufactured from a knitted is characterized in that the clothing is manufartured from at least one layer of knitted fabric containing at least 90% wt.
  • the knitted fabric is provided with a hydrophilic, moisture-distributing and retaining surface finish, on its side for contact with a skin of user, situated to a depth of 30 to 70%, and the other side of the knitted fabric is provided with a hydrophobic, moisture-masking and locking surface finish situated to a depth of 30 to 70%, and wherein the hydrophobic surface finish consists of a hydrophobic mixture which constitutes 4 to 10% wt.
  • the hydrophilic surface finish features a maximum Drop test absorbency of 5 seconds, wherein the hydrophilic surface finish leads to the reverse inner side of the clothing and the hydrophobic surface finish leads to the right outer side of the clothing and the interface of the hydrophobic surface finish and hydrophilic surface finish is situated inside the layer of the knitted fabric.
  • the hydrophobic mixture contains at least 10% wt. of fluorocarbon and at least 50% wt. polymeric carrier.
  • the polymeric carrier is acrylate and the derivatives thereof or polyurethane and the derivatives thereof or acrylate-polyurethane and the derivatives thereof.
  • the hydrophobic mixture contains 70 to 99 % wt. of a copolymer of fluorocarbon and acrylate and 1 to 30 % wt. of polyurethane.
  • the fluorocarbon is formed by a carbon chain with a length of 4 or 6 carbons.
  • the knitted fabric contains at least 95% wt. of cotton and at least 2% wt. of Lycra.
  • the hydrophilic surface finish of the knitted fabric has a Drop test absorbency of at most 3 seconds.
  • a manufacturing method for knited fabric capable of absorbing and masking absorbated body moisture is characterized in that the knitted fabric weighing 150 to 300 g/m 2 is wound on the unwinding calender of the textile line comprising the unwinding calender, rotary template for coating the hydrophobic paste, with shell porosity of 100 to 200 mesh, squeegee for smoothing the hydrophobic paste, at least one dryer, and winding calender, wherein the knitted fabric is unwound from the unwinding calender and wound on the winding calender, wherein the knitted fabric passes through the textile line, into the rotary template; dosing of a hydrophobic paste containing 4 to 10% wt.
  • the hydrophobic paste is thickened to a dynamic viscosity of 80 to 90 dPa s with the thickening agent;
  • the winding of the knitted fabric on the winding calender is started, wherein the knitted fabric passes through the textile line at a maximum speed of 25 m/min and the hydrophobic paste is applied to the passing knitted fabric in a dose of 110 to 200 g/m 2 of the knitted fabric through the rotary template, which fits on the knitted fabric tightly with a maximum pressure of 0.5 bar, and the rotary template shell rotates at a speed corresponding to the unwinding speed of the knitted fabric, wherein, after applying the hydrophobic paste to the knitted fabric, the hydrophobic paste applied on the knitted fabric is smoothed with a squeegee, which fits on the knitted fabric tightly without pressure, wherein the knitted fabric with applied and smoothed the hydrophobic paste is introduced into the dryer at 110 to 130 °
  • the hydrophobic paste contains 12 to 18% wt. of aqueous dispersion of the hydrophobic mixture with a dry matter content of 40 to 50% wt. in the aqueous dispersion.
  • the hydrophobic mixture contains at least 10% wt. of fluorocarbon and at least 50% wt. polymeric carrier.
  • the polymeric carrier is acrylate and the derivatives thereof or polyurethane and the derivatives thereof or acrylate-polyurethane and the derivatives thereof.
  • the hydrophobic mixture contains 70 to 99 % wt. of a copolymer of fluorocarbon and acrylate and 1 to 30 % wt. of polyurethane.
  • the textile is knitted fabric containing at least 95% wt. of cotton and at least 2% wt. of Lycra.
  • the rotary template has a shell with a porosity of 125 to 195 mesh.
  • the fluorocarbon is formed by a carbon chain with a length of 4 or 6 carbons.
  • the textile thickening agent is made of polysaccharides or of acrylic or maleic acid derivatives.
  • the textile thickening agent contains 3 to 10% wt. of ethoxylated branched tridecanol and 1 to 10% wt. of Cl 1-C15 alkanes.
  • the hydrophobic paste is applied in a dose of 110 to 150 g/m 2 of the knitted fabric being unwound, weighing 150 to 180 g/m 2 .
  • the hydrophobic paste is applied in a dose of 130 to 200 g/m 2 of the knitted fabric being unwound, weighing 180 to 300 g/m 2 .
  • the knitted fabric with hydrophobic surface finish of the knitted fabric is treated by immersion into the water bath of a softening solution containing surfactants and/or silicones for at least 4 seconds and dried at 120 to 140 °C for 30 to 90 seconds before sanforising.
  • the softening solution contains a substance selected from the group or a mixture thereof: polydimethylsiloxane or salts thereof, ethoxylated isotridecanol, sodium toluenesulfonate.
  • the textile with hydrophobic surface finish of the knitted fabric is treated by immersion into the water bath of an antibacterial solution containing silver, zinc, copper, or cobalt for at least 4 seconds and dried at 120 to 140 °C for 30 to 90 seconds before sanforising.
  • the antibacterial solution comprises pyrithione zinc.
  • a manufacturing method of clothing is characterised in that the stabilized treated knitted fabric is cut and sew into the form of clothing, wherein the hydrophobic surface finish of the knitted fabric is oriented on the right side of the clothing and the hydrophilic surface finish of the knitted fabric is oriented on the reverse side of the clothing.
  • Fig. 1A State of the art, drawing of the treated fabric according to CN 100414 036
  • Fig. IB State of the art, drawing of the treated fabric according to CN 101 845 702.
  • Fig. 2 Drawing of a treated knitted fabric according to this invention
  • Fig. 3 Rotary template for coating the hydrophobic paste
  • Fig. 4A Hydrophobicity of the treated knitted fabric according to Example 1
  • Fig. 4B Hydrophobicity of the treated knitted fabric according to Example 1
  • Fig. 4C The stain-resistance of T-shirt made of the treated knitted fabric of the present invention
  • Fig. 4D The stain-resistance of the treated knitted fabric of the present invention
  • Fig. 5A Speed of liquid penetration into the hydrophilic surface finish of the knitted fabric - time 0 s
  • Fig. 5B Speed of liquid penetration into the hydrophilic surface finish of the knitted fabric - time 2 s
  • Fig. 5C Speed of liquid penetration into the hydrophilic surface finish of the knitted fabric - time 6 s
  • Example 1 Preparation of hydrophobic paste, dispersion, application to knitted fabric, softening of knitted fabric, and manufacture of clothing
  • a hydrophobic paste was prepared, which contained:
  • the rest of the hydrophobic paste was water. After mixing all the ingredients of the hydrophobic paste, the mixture was stirred for 15 minutes, then the viscosity of the hydrophobic paste was measured to be 85 dPa s.
  • the knitted fabric 1 was unwound from the unwinding calender and wound on the winding calender so that the knitted fabric 1 passed through the entire textile line.
  • the rotating template was filled with hydrophobic paste to a maximum of 1/6 of the free internal space, i.e., a maximum of 12 kg of hydrophobic paste. Then, continuous dosing of the hydrophobic paste into the rotary template was started at a rate of 2.8 kg/min.
  • the rotary template is fitted with a rubber squeegee, which is used to gather the hydrophobic paste and push it actively through the rotary template pores to coat the hydrophobic paste into the knitted fabric T
  • the winding of the knitted fabric l on the winding calender was started.
  • the knitted fabric l first passed through the textile line at a speed of 5 m/s to ensure the correct adjustment of all parts of the textile line. Then, the winding speed of the knitted fabric I was increased to 17 m/min, and the hydrophobic paste was applied to the passing knitted fabric I through the rotary template at a dose of 110 g/m 2 of the knitted fabric T
  • the rotary template fit on the knitted fabric l tightly, with a pressure of 0.5 bar, and the shell of the rotary template also rotated at a speed of 17 m/min, i.e., together with the unwinding knitted fabric T
  • the hydrophobic paste applied onto the knitted fabric l was smoothed using the squeegee that fits closely on the knitted fabric l without pressure, wherein the knitted fabric l with the hydrophobic paste applied and smoothed was introduced into the first dryer at 120 °C for 60 seconds.
  • the knitted fabric l with the hydrophobic paste applied, smoothed, and dried was introduced into the second dryer at 160 °C for 90 seconds to condense the applied and dried hydrophobic paste.
  • a single side hydrophobic knitted fabric l was formed with a hydrophobic, visible moisture-masking surface finish 2 of the knitted fabric l placed on the right side 6 and soaked to half the thickness of the knitted fabric T
  • the reverse side 5 of the knitted fabric l keeps the properties of the knitted fabric l before the one-side application of the hydrophobic paste, i.e., it remains hydrophilic with a Drop test absorbency of 3 seconds.
  • the knitted fabric! with hydrophobic surface finish 2 of the knitted fabric 1 was subsequently immersed in a silicone softening solution in the form of polydimethylsiloxane at a concentration of 15 g/1 for 10 seconds.
  • the pH value of the softening solution was between 5 and 6, which was achieved by the addition of acetic acid.
  • the knitted fabric 1 was dried at 130 °C for 60 seconds.
  • the double-sided treated knitted fabric 1 was formed having hydrophobic surface finish 2 on the right side of the knitted fabric 1 and hydrophilic surface finish 3 on the reverse side of the knitted fabric T
  • the knitted fabric 1 with the hydrophobic surface finish 2 was subsequently spatially stabilized by sanforising, i.e., spatial stabilization where the knitted fabric 1 is stretched on three rollers, wherein the knitted fabric 1 passes in an infinite length through a hot bath at a temperature of at least 70°C in cycles.
  • an urban T-shirt intended for direct contact with the wearer’s skin able to effectively distribute moisture in the hydrophilic surface finish 3 on the reverse side of the knitted fabric 1 and then evaporate this moisture through the hydrophobic surface finish 2 on the right side of the knitted fabric _L was made while keeping the reverse and right orientation.
  • this urban T-shirt is resistant to stains from common liquids and food thanks to the hydrophobic surface finish 2 on the right side of the knitted fabric 1, which repels not only liquids but also oils and pastes, such as ketchup.
  • Example 2 Preparation of hydrophobic paste, dispersion, application to knitted fabric, softening of knitted fabric, and manufacture of clothing
  • a hydrophobic paste was prepared, which contained:
  • the rest of the hydrophobic paste was water. After mixing all the ingredients of the hydrophobic paste, the mixture was heated to 40 °C and stirred for 15 minutes, then the viscosity of the hydrophobic paste was measured to be 80 dPa s.
  • Dry double cotton knitted fabric 1 having cotton content of 95% wt. Lycra content of 5% wt., weighing 300 g/m 2 , winding width of 150 cm, and Drop test absorbency of 5 seconds, dyed according to the state of the art without cationic substances was wound on an unwinding calender of a textile line, comprising, in addition to the unwinding calender, also a rotating template for coating the hydrophobic paste with a diameter of 40 cm, length of 150 cm and a shell porosity of 195 mesh, a squeegee for smoothing the hydrophobic paste, one dryer and a winding calender.
  • the knitted fabric 1 was unwound from the unwinding calender and wound on the winding calender so that the knitted fabric l passed through the entire textile line.
  • the rotating template was filled with hydrophobic paste to a maximum of 1/5 of the free internal space, i.e., a maximum of 37 kg of hydrophobic paste. Then, continuous dosing of the hydrophobic paste into the rotary template was started at a rate of 7.5 kg/min.
  • the rotary template is fitted with a rubber squeegee, which is used to gather the hydrophobic paste and push it actively through the rotary template pores to coat the hydrophobic paste into the knitted fabric T
  • the winding of the knitted fabric l on the winding calender was started.
  • the knitted fabric l first passed through the textile line at a speed of 5 m/s to ensure the correct adjustment of all parts of the textile line. Then, the winding speed of the knitted fabric l was increased to 25 m/min, and the hydrophobic paste was applied to the passing knitted fabric I through the rotary template at a dose of 200 g/m 2 of the knitted fabric T
  • the rotary template fit on the knitted fabric 1 tightly, with a pressure of 0.5 bar, and the shell of the rotary template also rotated at a speed of 25 m/min, i.e., together with the unwinding knitted fabric L
  • the hydrophobic paste applied onto the knitted fabric l was smoothed using the squeegee that fits closely on the knitted fabric l without pressure, wherein the knitted fabric l with the hydrophobic paste applied and smoothed was introduced into the first dryer at 110 °C for 90 seconds.
  • the knitted fabric l with the hydrophobic paste applied, smoothed, and dried was introduced into the second dryer at 150 °C for 60 seconds to condense the applied and dried hydrophobic paste.
  • a single side hydrophobic knitted fabric l was formed with a hydrophobic, visible moisture-masking surface finish 2 of the knitted fabric 1 placed on the right side 6 and soaked to 30% of the thickness of the knitted fabric T
  • the reverse side 5 of the knitted fabric l keeps the properties of the knitted fabric l before the one-side application of the hydrophobic paste, i.e., it remains hydrophilic with a Drop test absorbency of 3 seconds.
  • the knitted fabric! with hydrophobic surface finish 2 of the knitted fabric 1 was subsequently immersed in a softening solution of polydimethylsiloxane at a concentration of 10 g/1, ethoxylated isotridecanol at a concentration of 3 g/1, sodium toluenesulfonate at a concentration of 0.5 g/kg and a surfactant in the form of cetylmethylammonium bromide at a concentration of 0.5 g/kg.
  • the pH value of the softening solution was between 5 and 6, which was achieved by the addition of acetic acid.
  • the knitted fabric 1 was dried at 140 °C for 30 seconds.
  • the double-sided treated knitted fabric 1 was formed having hydrophobic surface finish 2 on the right side of the knitted fabric 1 and hydrophilic surface finish 3 on the reverse side of the knitted fabric 1.
  • the knitted fabric 1 with the hydrophobic surface finish 2 was subsequently spatially stabilized by sanforising, i.e., spatial stabilization where the knitted fabric 1 is stretched on three rollers, wherein the knitted fabric 1 passes in an infinite length through a hot bath at a temperature of at least 70°C in cycles.
  • an urban T-shirt intended for direct contact with the wearer’s skin able to effectively distribute moisture in the hydrophilic surface finish 3 on the reverse side of the knitted fabric 1 and then evaporate this moisture through the hydrophobic surface finish 2 on the right side of the knitted fabric _L was made while keeping the reverse and right orientation.
  • this urban T-shirt is resistant to stains from common liquids and food thanks to the hydrophobic surface finish 2 on the right side of the knitted fabric 1, which repels not only liquids but also oils and pastes, such as ketchup.
  • Example 3 Preparation of hydrophobic paste, copolymer, application to knitted fabric, antibacterial treatment of knitted fabric, and manufacture of clothing
  • a hydrophobic paste was prepared, which contained:
  • alginate thickening agent being sodium alginate.
  • the rest of the hydrophobic paste was water. After mixing all the ingredients of the hydrophobic paste, the mixture was stirred for 15 minutes, then the viscosity of the hydrophobic paste was measured to be 75 dPa s. Thus, the thickening agent at a concentration of 2 g/kg was added to the hydrophobic paste, and the mixture was stirred again for 10 minutes; then, the viscosity of the hydrophobic paste was measured to be 83 dPa s.
  • the knitted fabric 1 was unwound from the unwinding calender and wound on the winding calender so that the knitted fabric 1 passed through the entire textile line.
  • the rotating template was filled with hydrophobic paste to a maximum of 1/6 of the free internal space, i.e., a maximum of 17.5 kg of hydrophobic paste. Then, continuous dosing of the hydrophobic paste into the rotary template was started at a rate of 1.9 kg/min.
  • the rotary template is fitted with a rubber squeegee, which is used to gather the hydrophobic paste and push it actively through the rotary template pores to coat the hydrophobic paste into the knitted fabric T
  • the winding of the knitted fabric l on the winding calender was started.
  • the knitted fabric l first passed through the textile line at a speed of 5 m/s to ensure the correct adjustment of all parts of the textile line.
  • the winding speed of the knitted fabric l was increased to 10 m/min, and the hydrophobic paste was applied to the passing knitted fabric 1 through the rotary template at a dose of 130 g/m 2 of the knitted fabric T
  • the rotary template fit on the knitted fabric 1 tightly, without pressure, and the shell of the rotary template also rotated at a speed of 10 m/min, i.e., together with the unwinding knitted fabric 1.
  • the hydrophobic paste applied onto the knitted fabric l was smoothed using the squeegee that fits closely on the knitted fabric l without pressure, with a pressure of 0.5 bar, wherein the knitted fabric 1 with the hydrophobic paste applied and smoothed was introduced into the dryer at 130 °C for 30 seconds. This dried the hydrophobic paste. Then, the dryer temperature was increased to 170 °C and the knitted fabric I with the hydrophobic paste applied, smoothed, and dried was introduced again into the dryer for 120 seconds to condense applied and dried hydrophobic paste.
  • a single-side hydrophobic knitted fabric 1 was formed with a hydrophobic, visible moisture-masking surface finish 2 of the knitted fabric 1 placed on the right side and soaked to 70% of the thickness of the knitted fabric T
  • the reverse side of the knitted fabric l keeps the properties of the fabric before the one-side application of the hydrophobic paste, i.e., it remains hydrophilic with a Drop test absorbency of 3 seconds.
  • the knitted fabric 1 with hydrophobic surface finish 2 of the knitted fabric l was subsequently treated with an antibacterial solution containing silver at a concentration of 2 g/kg, cobalt at a concentration of 0.5 g/kg, and copper at a concentration of 0.5 g/kg in the bath, into which the knitted fabric 1 was immersed for 4 seconds. After treatment with the antibacterial solution, the knitted fabric 1 was dried at 120 °C for 90 seconds. After finishing the antibacterial treatment of the knitted fabric I, the double-side treated knitted fabric 1 was formed having the hydrophobic surface finish 2 on the right side of the knitted fabric l and hydrophilic and antibacterial surface finish 3 on the reverse side of the knitted fabric 1.
  • the knitted fabric 1 with the hydrophobic surface finish 2 was subsequently spatially stabilized by sanforising, i.e., spatial stabilization where the knitted fabric 1 is stretched on three rollers, wherein the knitted fabric 1 passes in an infinite length through a hot bath at a temperature of at least 70°C in cycles.
  • an urban T-shirt intended for direct contact with the wearer’s skin able to effectively distribute moisture in the hydrophilic surface finish 3 on the reverse side of the knitted fabric l and then evaporate this moisture through the hydrophobic surface finish 2 on the right side of the knitted fabric _L was made while keeping the reverse and right orientation.
  • this urban T-shirt is resistant to stains from common liquids and food thanks to the hydrophobic surface finish 2 on the right side of the knitted fabric I, which repels not only liquids but also oils and pastes, such as ketchup.
  • Example 4 Preparation of hydrophobic paste, copolymer, application to knitted fabric, antibacterial treatment of knitted fabric, and manufacture of clothing
  • a hydrophobic paste was prepared, which contained:
  • the rest of the hydrophobic paste was water. After mixing all the ingredients of the hydrophobic paste, the mixture was stirred for 15 minutes, then the viscosity of the hydrophobic paste was measured to be 90 dPa s.
  • Dry double cotton knitted fabric 1 having cotton content of 98% wt., synthetic fibre content of 2% wt., weighing 160 g/m 2 , winding width of 150 cm, and Drop test absorbency of 3 seconds, dyed according to the state of the art without cationic substances was wound on an unwinding calender of a textile line, comprising, in addition to the unwinding calender, also a rotating template for coating the hydrophobic paste with a diameter of 30 cm, length of 150 cm and a shell porosity of 200 mesh, a squeegee for smoothing the hydrophobic paste, one dryer and a winding calender.
  • the knitted fabric 1 was unwound from the unwinding calender and wound on the winding calender so that the knitted fabric l passed through the entire textile line.
  • the rotating template was filled with hydrophobic paste to a maximum of 1/6 of the free internal space, i.e., a maximum of 17.5 kg of hydrophobic paste. Then, continuous dosing of the hydrophobic paste into the rotary template was started at a rate of 3.3 kg/min.
  • the rotary template is fitted with a rubber squeegee, which is used to gather the hydrophobic paste and push it actively through the rotary template pores to coat the hydrophobic paste into the knitted fabric T
  • the winding of the knitted fabric l on the winding calender was started.
  • the knitted fabric l first passed through the textile line at a speed of 5 m/s to ensure the correct adjustment of all parts of the textile line. Then, the winding speed of the knitted fabric l was increased to 15 m/min, and the hydrophobic paste was applied to the passing knitted fabric ! through the rotary template at a dose of 150 g/m 2 of the knitted fabric.
  • the rotary template fit on the knitted fabric 1 tightly, without pressure, and the shell of the rotary template also rotated at a speed of 15 m/min, i.e., together with the unwinding knitted fabric 1.
  • the hydrophobic paste applied onto the knitted fabric l was smoothed using the squeegee that fits closely on the knitted fabric l without pressure, with a pressure of 0.5 bar, wherein the knitted fabric 1 with the hydrophobic paste applied and smoothed was introduced into the dryer at 120 °C for 60 seconds. This dried the hydrophobic paste. Then, the dryer temperature was increased to 160 °C and the knitted fabric l with the hydrophobic paste applied, smoothed, and dried was introduced again into the dryer for 90 seconds to condense applied and dried hydrophobic paste.
  • a single-side hydrophobic knitted fabric l was formed with a hydrophobic, visible moisture-masking surface finish 2 of the knitted fabric 1 placed on the right side and soaked to 40% of the thickness of the knitted fabric 1.
  • the reverse side of the knitted fabric l keeps the properties of the fabric before the one-side application of the hydrophobic paste, i.e., it remains hydrophilic with a Drop test absorbency of 3 seconds.
  • the knitted fabric l with hydrophobic surface finish 2 of the knitted fabric l was subsequently treated with an antibacterial solution containing zinc, specifically pyrithione zinc at a concentration of 5 g/kg in the bath, into which the knitted fabric 1 was immersed for 4 seconds. After treatment with the antibacterial solution, the knitted fabric 1 was dried at 140 °C for 30 seconds. After finishing the antibacterial treatment of the knitted fabric I, the double-side treated knitted fabric 1 was formed having the hydrophobic surface finish 2 on the right side of the knitted fabric 1 and hydrophilic and antibacterial surface finish 3 on the reverse side of the knitted fabric 1.
  • the knitted fabric 1 with the hydrophobic surface finish 2 was subsequently spatially stabilized by sanforising, i.e., spatial stabilization where the knitted fabric 1 is stretched on three rollers, wherein the knitted fabric 1 passes in an infinite length through a hot bath at a temperature of at least 70°C in cycles.
  • a hydrophobic paste was prepared, which contained:
  • the rest of the hydrophobic paste was water. After mixing all the ingredients of the hydrophobic paste, the mixture was stirred for 15 minutes, then the viscosity of the hydrophobic paste was measured to be 84 dPa s.
  • the knitted fabric 1 was unwound from the unwinding calender and wound on the winding calender so that the knitted fabric 1 passed through the entire textile line.
  • the rotating template was filled with hydrophobic paste to a maximum of 1/6 of the free internal space, i.e., a maximum of 12 kg of hydrophobic paste. Then, continuous dosing of the hydrophobic paste into the rotary template was started at a rate of 3.3 kg/min.
  • the rotary template is fitted with a rubber squeegee, which is used to gather the hydrophobic paste and push it actively through the rotary template pores to coat the hydrophobic paste into the knitted fabric T
  • the winding of the knitted fabric l on the winding calender was started.
  • the knitted fabric l first passed through the textile line at a speed of 5 m/s to ensure the correct adjustment of all parts of the textile line. Then, the winding speed of the knitted fabric l was increased to 17 m/min, and the hydrophobic paste was applied to the passing knitted fabric through the rotary template at a dose of 130 g/m 2 of the knitted fabric T
  • the rotary template fit on the knitted fabric 1 tightly, with a pressure of 0.5 bar, and the shell of the rotary template also rotated at a speed of 17 m/min, i.e., together with the unwinding knitted fabric 1.
  • the hydrophobic paste applied onto the knitted fabric l was smoothed using the squeegee that fits closely on the knitted fabric l without pressure, wherein the knitted fabric l with the hydrophobic paste applied and smoothed was introduced into the first dryer at 120 °C for 60 seconds. This dried the hydrophobic paste. Then, the knitted fabric l with the hydrophobic paste applied, smoothed, and dried was introduced into the second dryer at 160 °C for 90 seconds to condense the applied and dried hydrophobic paste.
  • a single side hydrophobic knitted fabric l was formed with a hydrophobic, visible moisture-masking surface finish 2 of the knitted fabric l placed on the right side 6 and soaked to half the thickness of the knitted fabric T
  • the reverse side 5 of the knitted fabric l keeps the properties of the knitted fabric l before the one-side application of the hydrophobic paste, i.e., it remains hydrophilic with a Drop test absorbency of 3 seconds.
  • the knitted fabric l with hydrophobic surface finish 2 of the knitted fabric l was subsequently immersed in a silicone softening solution in the form of polydimethylsiloxane at a concentration of 10 g/1.
  • the pH value of the softening solution was between 5 and 6, which was achieved by the addition of acetic acid.
  • the knitted fabric 1 was dried at 130 °C for 60 seconds.
  • the double-sided treated knitted fabric 1 was formed having hydrophobic surface finish 2 on the right side of the knitted fabric l and hydrophilic surface finish 3 on the reverse side of the knitted fabric 1.
  • the knitted fabric 1 with the hydrophobic surface finish 2 was subsequently spatially stabilized by sanforising, i.e., spatial stabilization where the knitted fabric 1 is stretched on three rollers, wherein the knitted fabric 1 passes in an infinite length through a hot bath at a temperature of at least 70°C in cycles.
  • the ability of clothing to mask moisture was tested on the urban T-shirt made according to Example 5 according to the protocol for the water binding capacity of fabrics.
  • a T-shirt of size M with an area of 0.78 m 2 was weighed in the dry state.
  • the T-shirt was then completely immersed in mineral water simulating the composition of body sweat the best and allowed to soak for 5 minutes. Then the T-shirt was removed from the water and allowed to drip. As soon as the water stopped dripping from the T-shirt, or the interval between drops was longer than 1 min, the T-shirt was re-weighed. It was found that a T-shirt having an area of the knitted fabric 1 of 0.78 m 2 holds 196.5 ml of water. The T-shirt was then hung on a hanger and allowed to dry slowly.
  • the T-shirt was re-weighed every 15 minutes, and the shade of the right side of the test T-shirt and the one of a dry T-shirt were compared by image analysis. It was found that, despite the fact that the T-shirt still contains 139.2 g of soaked mineral water, the shade of the right side of the T-shirt corresponds to the shade of the dry T-shirt. Since the penetration of the hydrophobic paste in Example 5 was carried out to half the thickness of the knitted fabric 1, it was calculated that 63.6 g of the hydrophobic surface finish 2 of the knitted fabric 1 could mask 139.2 g of moisture, i.e., 2.19 times of its own weight. The test results are shown in Figure 7. The deviation of the T-shirt weight per square metre from the footage is caused by the presence of stitches and information appliques. List of marks for terms

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Abstract

L'invention concerne un tissu tricoté (1) pour vêtements pouvant absorber et masquer au moins le même poids d'humidité corporelle que son propre poids, caractérisé en ce que le tissu tricoté (1) contient au moins 90 % en poids de coton, pesant entre 150 g/m2 et 300 g/m2. Le tissu tricoté (1) est pourvu d'une finition de surface hydrophile, répartissant et retenant l'humidité (3), sur son côté destiné à être en contact avec la peau d'un utilisateur, située à une profondeur de 30 à 70 %, et de l'autre côté du tissu tricoté (1) se trouve le tissu tricoté (1) pourvu d'une finition de surface hydrophobe, masquant et bloquant l'humidité (2), située à une profondeur de 30 à 70 %, l'interface (4) entre la finition de surface hydrophobe (2) et la finition de surface hydrophile (3) du tissu tricoté (1) se trouvant à l'intérieur du tissu tricoté (1).
PCT/IB2021/054011 2020-05-12 2021-05-11 Vêtement pouvant masquer des traces d'humidité corporelle et procédé de fabrication correspondant WO2021229438A1 (fr)

Priority Applications (1)

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EP21732507.5A EP4288601A1 (fr) 2020-05-12 2021-05-11 Vêtement pouvant masquer des traces d'humidité corporelle et procédé de fabrication correspondant

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Citations (6)

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Publication number Priority date Publication date Assignee Title
WO2007059590A1 (fr) * 2005-11-25 2007-05-31 Commonwealth Scientific And Industrial Research Organisation Tissu a effet meche et procede de fabrication correspondant
JP2007182636A (ja) * 2005-12-29 2007-07-19 Osaka Senko Kk 汗滲み防止布帛の製造方法
CN100414036C (zh) 2006-04-18 2008-08-27 广东溢达纺织有限公司 一种舒适快干的内外层具有亲水、疏水性能差异的织物及其生产方法
CN101845702A (zh) 2010-05-10 2010-09-29 中国人民解放军总后勤部军需装备研究所 一种单向导湿织物的加工方法
JP2012007272A (ja) * 2010-06-28 2012-01-12 Komatsu Seiren Co Ltd 汗しみ抑制布帛及びその製造方法、並びにそれを用いた衣服
US20140352073A1 (en) * 2013-06-04 2014-12-04 Welspun India Limited Semi-absorbent, semi-resistant, breathable fabric

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007059590A1 (fr) * 2005-11-25 2007-05-31 Commonwealth Scientific And Industrial Research Organisation Tissu a effet meche et procede de fabrication correspondant
JP2007182636A (ja) * 2005-12-29 2007-07-19 Osaka Senko Kk 汗滲み防止布帛の製造方法
CN100414036C (zh) 2006-04-18 2008-08-27 广东溢达纺织有限公司 一种舒适快干的内外层具有亲水、疏水性能差异的织物及其生产方法
CN101845702A (zh) 2010-05-10 2010-09-29 中国人民解放军总后勤部军需装备研究所 一种单向导湿织物的加工方法
JP2012007272A (ja) * 2010-06-28 2012-01-12 Komatsu Seiren Co Ltd 汗しみ抑制布帛及びその製造方法、並びにそれを用いた衣服
US20140352073A1 (en) * 2013-06-04 2014-12-04 Welspun India Limited Semi-absorbent, semi-resistant, breathable fabric

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