WO2021195820A1 - Composition à deux constituants pour le soin de matières kératiniques - Google Patents

Composition à deux constituants pour le soin de matières kératiniques Download PDF

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Publication number
WO2021195820A1
WO2021195820A1 PCT/CN2020/081977 CN2020081977W WO2021195820A1 WO 2021195820 A1 WO2021195820 A1 WO 2021195820A1 CN 2020081977 W CN2020081977 W CN 2020081977W WO 2021195820 A1 WO2021195820 A1 WO 2021195820A1
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WO
WIPO (PCT)
Prior art keywords
part composition
weight
gums
hydrous
composition according
Prior art date
Application number
PCT/CN2020/081977
Other languages
English (en)
Inventor
Yangdong CHEN
Yirui ZHU
Original Assignee
L'oreal
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by L'oreal filed Critical L'oreal
Priority to PCT/CN2020/081977 priority Critical patent/WO2021195820A1/fr
Priority to CN202080099376.6A priority patent/CN115297830A/zh
Priority to FR2006363A priority patent/FR3108506B1/fr
Publication of WO2021195820A1 publication Critical patent/WO2021195820A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0216—Solid or semisolid forms
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/042—Gels
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/735—Mucopolysaccharides, e.g. hyaluronic acid; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/30—Characterized by the absence of a particular group of ingredients
    • A61K2800/31—Anhydrous
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/52—Stabilizers
    • A61K2800/522—Antioxidants; Radical scavengers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
    • A61K2800/84—Products or compounds obtained by lyophilisation, freeze-drying

Definitions

  • the present invention relates to a cosmetic composition for caring for keratin materials such as the skin, in particular the face.
  • the present invention relates to a two-part composition for caring for keratin materials such as the skin, in particular the face.
  • the present invention also relates to a process for caring for keratin materials such as the skin, in particular the face.
  • compositions consisting of two separate parts are generally referred to as "two-part compositions" .
  • Two-part products have been proposed when the active agent is not suitable for presenting in the carrier system for long time, one part of which comprises the active agent and the other part of which comprises a carrier system.
  • the use of two-part compositions necessitates prior shaking in order to form a homogeneous composition.
  • WO 2008/045174 proposes a two-part product comprising a composition A containing a foaming amphoteric surfactant and a composition B containing hydrogen peroxide, said compositions being mixed before application to the skin.
  • Ferulic acid is a robust antioxidant active agent which could provide whitening/lightening, anti-finelines, anti-inflammation and UV protection benefits.
  • ferulic acid has odor issue when contacting with aqua/water after several days, for example 7 days when the content of ferulic acid is no less than 1.9%by weight, 15 days when the content of ferulic acid is no less than 1.5%by weight, and 30 days when the content of ferulic acid is no less than 1.0%by weight, relative to the composition containing it.
  • Dry-mix format is another solution to prolong the shelf life of ferulic acid-containing products and could cue robust efficacy, intensive treatment, fresh and safe formulation. But ferulic acid isn’t soluble to water at room temperature.
  • one object of the present is thus to provide a two-part composition for caring for keratin materials such as the skin, in particular the face, which based on ferulic acid, which has whitening/lightening, anti-finelines, anti-inflammation and UV protection benefits, and has no discomfort feeling such as greasy and sticky, meanwhile the ferulic acid can quickly dissolve into the carrier system.
  • Still another object of the present invention is to provide a process for caring for keratin materials such as the skin, in particular the face.
  • the present invention provides a two-part composition for caring for keratin materials comprising:
  • the present invention provides is a process for caring for keratin materials, comprising mixing the anhydrous part and the hydrous part of the two-part composition as described above together to form a solution and applying the solution to the keratin materials.
  • ferulic acid can quickly dissolve in the hydrous part comprising at least one non-ionic guar gum and at least one anionic polysaccharide, i.e. a homogeneous solution can be formed after the anhydrous part and the hydrous part are mixed by grinding gently with fingers for less than 5 seconds, even within 4 seconds.
  • the freshly mixed two-part composition delivers good skin feeling and presents a good texture.
  • the two-part composition for caring for keratin materials according to the present invention comprises:
  • the anhydrous part means that no water is added on purpose and the water content is less than 0.1%by weight of the anhydrous part, in particular, there is no water in the anhydrous part.
  • the two-part composition can be used to care for keratin materials such as the skin, in particular the face after being shaken to form a homogeneous solution.
  • the two-part composition of the present invention comprises an anhydrous part comprising ferulic acid.
  • the anhydrous part merely contains ferulic acid.
  • the anhydrous part may also comprise a disintegrating agent.
  • Ferulic acid CAS number of which is 1135-24-6, is also called 4-Hydroxy-3-methoxycinnamic acid, which has the following formula:
  • Ferulic acid can be broadly found in giant fennel, the seeds of coffee, apple, artichoke, peanut, and orange, as well as in both seeds and cell walls of commelinidae plants (such as rice, wheat, oats, and pineapple) . Like many natural phenols, it is a strong antioxidant that is very reactive toward free radicals and reduces oxidative stress. Many studies suggest that ferulic acid may have antitumor activity.
  • the term "disintegrating agent” is intended to mean a substance capable of accelerating the rate of separation of the anhydrous part, for example in contact with the hydrous part during the use of the composition of the present invention.
  • a disintegrating agent can be included in the anhydrous part, for the purpose of facilitating the disintegration of the anhydrous part when it is dissolved in the hydrous part. Accordingly, the disintegrating agent is preferably mixed homogeneously with ferulic acid.
  • the disintegrating agent is itself a binder for ferulic acid, or an additional binder is added, such that the disintegrating agent and ferulic acid are together formed into an integrated solid state, e.g., tablets, particles, granules, spheres, beads, balls, bars, strips or the like, in either hollow or solid form.
  • the disintegrating agent is preferably selected from the group consisting of starches, e.g., corn starch, tomato starch, or wheat starch; a derivative of starch, e.g., pregelatinized starch, alpha starch, acrylic grafted starch or carboxymethyl starch sodium; saccharide or saccharide alcohol, or mixtures thereof.
  • Saccharide or saccharide alcohol is preferably used as disintegrating agent according to the present invention. More preferably, saccharide or saccharide alcohol serves itself as a binder. Useful saccharides comprise monosaccharide, disaccharide and polysaccharide. The corresponding alcohol of the saccharide may also be useful.
  • the monosaccharide preference may be made to glucose and fructose.
  • the anhydrous part is in the form of a tablet, preferably a freeze-dry tablet.
  • the anhydrous part is a freeze-dry tablet comprising ferulic acid and a disaccharide as an integrating agent.
  • the anhydrous part is a freeze-dry tablet comprising 1%to 40%by weight of ferulic acid and 60%to 99%by weight of integrating agent selected from sucrose, trehalose, lactose, cellobiose, and maltose.
  • the two-part composition of the present invention comprises from 0.05%to 3.0%by weight, preferably from 0.1%to 2.0%by weight of ferulic acid, relative to the total weight of the two-part composition.
  • the two-part composition of the present invention comprises a hydrous part containing at least one non-ionic guar gum and at least one anionic polysaccharide in an aqueous phase.
  • non-ionic guar gum is intended to mean modified non-ionic guar gums and unmodified non-ionic guar gums.
  • the unmodified non-ionic guar gums are, for example, the products sold under the name Vidogum GH 175 by the company Unipectine and under the names Meypro-Guar 50 and Jaguar C by the company Rhodia Chimie.
  • modified non-ionic guar gums are in particular modified with a C 1 -C 6 hydroxyalkyl group.
  • hydroxyalkyl groups that may be mentioned, for example, are hydroxymethyl, hydroxyethyl, hydroxypropyl and hydroxybutyl groups.
  • hydroxyalkylated guar gums are well known in the prior art and can be prepared, for example, by reacting corresponding alkene oxides such as, for example, propylene oxides, with the guar gum so as to obtain a guar gum modified with hydroxyalkyl groups, for example, hydroxypropyl groups.
  • the degree of hydroxyalkylation which corresponds to the number of alkylene oxide molecules consumed by the number of free hydroxyl functions present on the guar gum, preferably ranges from 0.4 to 1.2.
  • non-ionic guar gums optionally modified with hydroxyalkyl groups are sold, for example, under the trade names Jaguar HP8, Jaguar HP60 and Jaguar HP120, Jaguar DC 293 and Jaguar HP 105 by the company Rhodia Chimie or under the name Galactasol 4H4FD2 by the company Aqualon.
  • the two-part composition of the present invention comprises from 0.05%to 2.0%by weight, preferably from 0.1%to 1.0%by weight of non-ionic guar gum, relative to the total weight of the two-part composition.
  • microbial gums is understood to mean substances synthesized by fermentation of sugars by microorganisms.
  • the microbial gums can be chosen from scleroglucan gums, gellan gums, pullulan gums, curdlan gums, xanthan gums, grifolan gums, lentinan gums, schizophyllan gums, spirulinan gums and krestin gums.
  • Mention may also, in particular, be made of the xanthan gums produced by the bacterium Xanthomonas campestri and the mutants and variants o fthe latter. These xanthan gums generally have a mo lecular weight of between 1 000 000 and 50 000 000.
  • use is made, as anionic polysaccharides, of xanthan and scleroglucan gums. More preferably still, use is made of xanthan gums.
  • Xanthan gums are represented, for example, by the products sold under the names Rhodicare by the company Rhodia Chimie, under the name Satiaxane TM by the company Cargill Texturizing Solutions (for the food, cosmetic and pharmaceutical industries) , under the name Novaxan TM by the company ADM, and under the names by the company CP-Kelco.
  • the two-part composition of the present invention comprises from 0.05%to 1.0%by weight, preferably from 0.1%to 0.5%by weight of anionic polysaccharide, relative to the total weight of the two-part composition.
  • the aqueous part of the two-part composition according to the present invention also comprises water.
  • the water used may be sterile demineralized water and/or a floral water such as rose water, cornflower water, camomile water or lime blossom water, and/or a natural spring water or mineral water, for instance: Vittel water, Vichy basin water, Uriage water, Roche Posay water, Bourboule water, Enghien-les-Bains water, Saint Gervais-les-Bains water, Néris-les-Bains water, Allevar-les-Bains water, Digne water, Maizines water, Neyrac-les-Bains water, Lons-le-Saunier water, Eaux Bonnes water, Rochefort water, Saint Christau water, Fumades water, Tercis-les-bains water and Avene water.
  • the aqueous phase may also comprise reconstituted spring water, i.e. a water containing trace elements such as zinc, copper, magnesium, etc., reconstituting the characteristics of a spring water.
  • the aqueous part may also comprise water-miscible organic solvents (at room temperature: 25°C) , for instance monoalcohols containing from 2 to 6 carbon atoms, such as ethanol or isopropanol, glycerin, and mixtures thereof.
  • water-miscible organic solvents at room temperature: 25°C
  • monoalcohols containing from 2 to 6 carbon atoms such as ethanol or isopropanol, glycerin, and mixtures thereof.
  • the two-part composition according to the present invention may comprise an hydrous part in an amount ranging from 45%to 99.9%by weight, preferably from 80%to 99%by weight, even more preferably 95%to 99%by weight, relative to the total weight of the two-part composition.
  • the two-part composition can comprise an additional cosmetic active agent (s) in the anhydrous part and/or the hydrous part depending on their nature.
  • additional cosmetic active agents that may be used in the two-part composition of the present invention, examples that may be mentioned include enzymes; flavonoids; moisturizers; anti-inflammatory agents; vitamins; depigmenting agents and whitening agents; ⁇ -hydroxy acids; retinoids; tensioning agents; ceramides; essential oils; agents for improving skin feeling (for example, sodium hyaluronate) , UV-screening agents (or sunscreens) , anti-aging agents (for example, hydroxyethylpiperazine ethane sulfonic acid, dipeptide diaminobutyroyl benzylamide diacetate) , and mixtures thereof; and any other active agent that is suitable for the final purpose of the two-part composition.
  • enzymes for example, sodium hyaluronate
  • UV-screening agents or sunscreens
  • anti-aging agents for example, hydroxyethylpiperazine ethane sulfonic acid, dipeptide diaminobutyroyl benzylamide dia
  • the two-part composition according to the present invention may also contain conventional cosmetic adjuvants or additives, which will be in the anhydrous part and/or the hydrous part depending on their nature, for instance fragrances, preserving agents and bactericides, surfactants (for example, PEG-60 hydrogenated castor oil) , opacifiers, softeners, buffers, electrolytes such as sodium chloride, or a pH regulator (for example citric acid or potassium hydroxide) , and mixtures thereof.
  • fragrances for example, PEG-60 hydrogenated castor oil
  • opacifiers for example, PEG-60 hydrogenated castor oil
  • softeners for example, opacifiers, softeners, buffers, electrolytes such as sodium chloride, or a pH regulator (for example citric acid or potassium hydroxide) , and mixtures thereof.
  • a pH regulator for example citric acid or potassium hydroxide
  • Preserving agents that may be used include any preserving agent usually used in the fields under consideration, for instance p-anisic acid, parabens, chlorphenesin, phenoxyethanol, chlorhexidine gluconate and polyhexamethylene biguanide hydrochloride (CTFA name: Polyaminopropyl biguanide) .
  • CFA name Polyaminopropyl biguanide
  • the preserving agent when presents in the two-part composition, generally represent from 0.1%to 2%by weight, preferably from 0.5%to 1.0%by weight relative to the total weight of the two-part composition.
  • the two-part composition contains phenoxyethanol as preserving agent in the hydrous part.
  • the two-part composition for caring for keratin materials according to the present invention comprises, relative to the total weight of the two-part composition:
  • the anhydrous part and the hydrous part are kept separate from one another in two separate containers or preferably one container before the anhydrous part and the hydrous part are mixed.
  • the hydrous part may be packaged in the body of a container which is closed with a cap containing the anhydrous part, a portable and/or detachable separator being provided between the anhydrous part and the hydrous part.
  • packages include those described in FR- A-2, 476, 607, FA-A-2, 453, 793 or FR-A-2, 645, 740, all incorporated herein by reference.
  • the user may then mix the anhydrous part and the hydrous part to obtain a homogeneous solution.
  • Ferulic acid can quickly dissolve in the hydrous part upon mixing.
  • the mixing can be done by grinding gently with fingers.
  • the solution Upon mixing, the solution obtained a desirable texture, which can be evaluated by the viscosity of the solution.
  • the viscosity measurement is generally performed at 25°C, using a Rheomat RM180 viscometer equipped with a M3 spindle, the measurement being performed after 10 minutes of rotation of the spindle in the composition (after which time stabilization of the viscosity and of the spin speed of the spindle are observed) , at a shear rate of 200 rpm.
  • the viscosity ranges from 10 to 20 UD (M3) .
  • Another object of the present invention is to provide a process for caring for keratin materials.
  • the keratin materials include the skin, in particular the face.
  • the two-part composition according to the present invention may be used for caring for keratin materials.
  • the present invention provides is a process for caring for keratin materials, comprising mixing the anhydrous part and the hydrous part of the two-part composition as described above together to form a solution and applying the solution to the keratin materials.
  • the two-part composition according to the present invention provides a good skin feeling.
  • the hydrous part of the two-part composition of Comparative formula 1 does not comprise non-ionic guar gum.
  • the hydrous part of the two-part composition of Comparative formula 2 does not comprise anionic polysaccharide.
  • hydrous parts were prepared as follows:
  • the anhydrous part used was a freeze-dry tablet containing about 15 wt. %of ferulic acid and 85 wt. %of trehalose, relative to the total weight of the anhydrous part.
  • compositions according to invention formula (inv. ) and comparative formulas (comp. ) were consisted of 1.5 g hydrous part prepared above and 20 mg anhydrous part.
  • the hydrous part was dipped onto the anhydrous part 24 hours after formulation of the hydrous part and then a fresh-mixing process was conducted by grinding gently by fingers to observe the time needed for complete dissolution of ferulic acid in the hydrous part.
  • “Fast dissolution” is achieved ifthe grinding is not longer than 5 seconds, and the acceptable criterion of dissolution is achieved when there are no visible particles.
  • the skin feeling after application was evaluated for each of the two-part compositions of invention formula and compositions of comparative formulas freshly mixed after formulation of the hydrous part.
  • the freshly mixed compositions were transparent.
  • Test design Sequential monadic evaluation in blind, randomized design
  • Panel 5 women, all skin types
  • the panellists were asked to score for the skin feeling after application based on the following standards, wherein skin feeling includes watery, greasy, slippery and sticky feeling.
  • the texture was evaluated according to the viscosity of each of the two-part compositions of invention formula and compositions of comparative formulas freshly mixed after formulation of the hydrous part.
  • the viscosity measurement is generally performed at 25°C, using a Rheomat RM180 viscometer equipped with a M3 spindle, the measurement being performed after 10 minutes of rotation of the spindle in the composition (after which time stabilization of the viscosity and of the spin speed of the spindle are observed) , at a shear rate of 200 rpm.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dermatology (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Emergency Medicine (AREA)
  • Cosmetics (AREA)

Abstract

La présente invention concerne une composition à deux constituants pour le soin des matières kératiniques comprenant : a) un constituant anhydre comprenant de l'acide férulique ; et b) un constituant aqueux contenant au moins une gomme de guar non ionique et au moins un polysaccharide anionique ; le constituant anhydre et le constituant aqueux étant séparés. L'invention concerne également un procédé pour le soin de matières kératiniques, consistant à mélanger ensemble le constituant anhydre et le constituant aqueux de la composition à deux constituants telle que décrite ci-dessus pour former une solution et à appliquer la solution sur les matières kératiniques.
PCT/CN2020/081977 2020-03-30 2020-03-30 Composition à deux constituants pour le soin de matières kératiniques WO2021195820A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
PCT/CN2020/081977 WO2021195820A1 (fr) 2020-03-30 2020-03-30 Composition à deux constituants pour le soin de matières kératiniques
CN202080099376.6A CN115297830A (zh) 2020-03-30 2020-03-30 用于护理角蛋白材料的两部分组合物
FR2006363A FR3108506B1 (fr) 2020-03-30 2020-06-18 Composition en deux parties de soin de matieres keratineuses

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/CN2020/081977 WO2021195820A1 (fr) 2020-03-30 2020-03-30 Composition à deux constituants pour le soin de matières kératiniques

Publications (1)

Publication Number Publication Date
WO2021195820A1 true WO2021195820A1 (fr) 2021-10-07

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PCT/CN2020/081977 WO2021195820A1 (fr) 2020-03-30 2020-03-30 Composition à deux constituants pour le soin de matières kératiniques

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CN (1) CN115297830A (fr)
FR (1) FR3108506B1 (fr)
WO (1) WO2021195820A1 (fr)

Citations (4)

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Publication number Priority date Publication date Assignee Title
JP2015010070A (ja) * 2013-06-28 2015-01-19 富士フイルム株式会社 メラニン分解促進剤およびメラノソームタンパク質分解促進剤
WO2015176147A1 (fr) * 2014-05-21 2015-11-26 Chemyunion Química Ltda Agent actif éclaircissant contenant des extraits végétaux, utilisations de celui-ci et compositions le contenant
WO2017117099A1 (fr) * 2015-12-29 2017-07-06 L'oreal Compositions antioxydantes stables
CN109984950A (zh) * 2018-12-06 2019-07-09 上海益好纳米科技有限公司 一系列免洗全吸收型纳米纤维功能面膜及其制备方法

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US7741366B2 (en) 2006-10-11 2010-06-22 Leonard Mackles Low pH pharmacologically active products and methods for the production thereof
CN112334124A (zh) * 2018-06-28 2021-02-05 莱雅公司 用于护理皮肤的套盒
FR3088548B1 (fr) * 2018-11-15 2021-01-22 Oreal Composition comprenant un derive d’acide cinnamique et un polymere cellulosique non ionique non associatif

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JP2015010070A (ja) * 2013-06-28 2015-01-19 富士フイルム株式会社 メラニン分解促進剤およびメラノソームタンパク質分解促進剤
WO2015176147A1 (fr) * 2014-05-21 2015-11-26 Chemyunion Química Ltda Agent actif éclaircissant contenant des extraits végétaux, utilisations de celui-ci et compositions le contenant
WO2017117099A1 (fr) * 2015-12-29 2017-07-06 L'oreal Compositions antioxydantes stables
CN109984950A (zh) * 2018-12-06 2019-07-09 上海益好纳米科技有限公司 一系列免洗全吸收型纳米纤维功能面膜及其制备方法

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Title
SUZHOU SHANGMEI INTERNATIONAL COSMETICS CO: "L'Oreal replumping hyaluronic acid revitalize lift freeze dry ampoule essence，", 19 January 2020 (2020-01-19), pages 1 - 1, XP009532045, Retrieved from the Internet <URL:http://ftba.nmpa.gov.cn:8181/ftban/itownet/hzp_ba/fw/pz.jsp?processid=20191231134341hzrxw&nid=20191231134341hzrxw> *
ZHU HUI ET AL.: "Studies on Rheological Properties of Complex Gum Solution with Xanthan and Anionic Guar，", JOURNAL OF CHINESE INSTITUTE OF FOOD SCIENCE AND TECHNOLOGY, vol. 14, no. 5, 31 May 2014 (2014-05-31), CN, pages 55 - 62, XP009530814, ISSN: 1009-7848 *

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CN115297830A (zh) 2022-11-04
FR3108506A1 (fr) 2021-10-01
FR3108506B1 (fr) 2022-04-01

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