Classifications

• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B28—WORKING CEMENT, CLAY, OR STONE
  • B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
  • B28B1/00—Producing shaped prefabricated articles from the material
  • B28B1/30—Producing shaped prefabricated articles from the material by applying the material on to a core or other moulding surface to form a layer thereon
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B27/00—Layered products comprising a layer of synthetic resin
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
  • C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
  • C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
  • C08L61/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
  • C08L61/28—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds with melamine
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
  • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
  • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
  • C08L83/04—Polysiloxanes

Definitions

• the present invention relates to a release film used in the process of manufacturing a ceramic green sheet.
• a ceramic green sheet is molded, and a plurality of obtained ceramic green sheets are laminated and fired.
• the ceramic green sheet is formed by applying a ceramic slurry containing a ceramic material such as barium titanate or titanium oxide onto a release film.
• the release film is required to have a release property that allows the release film to be released from a thin ceramic green sheet formed on the release film with an appropriate release force without causing cracks, breakage, or the like.
• Patent Document 1 includes a base material and a release agent layer provided on one side of the base material, and the release agent layer contains a melamine resin and polyorganosiloxane.
• a release film obtained by curing the release agent composition contained therein is disclosed.
• An object of the present invention is to provide a release film for a ceramic green sheet manufacturing process capable of manufacturing a ceramic green sheet having a high adhesive force between the ceramic green sheets during the ceramic green sheet laminating process.
• the present invention is a release film for a ceramic green sheet manufacturing process including a base material and a release agent layer provided on one side of the base material, and the release is described.
• a release film for a ceramic green sheet manufacturing process wherein the agent layer is formed of a release agent composition containing a melamine resin, an epoxy resin, and a polyorganosiloxane (Invention 1).
• a ceramic produced by using the release film by forming the release agent layer from a release agent composition containing a melamine resin, an epoxy resin, and a polyorganosiloxane It is possible to increase the adhesive force between the ceramic green sheets during the process of laminating the green sheets.
• the mass ratio of the content of the melamine resin to the content of the epoxy resin in the release agent composition is preferably 99: 1 to 30:70 (Invention 2).
• the polyorganosiloxane has at least one hydroxyl group in one molecule (Invention 3).
• the weight average molecular weight of the polyorganosiloxane is preferably 500 or more and 10000 or less (Invention 4).
• the content of the polyorganosiloxane in the release agent composition is 100 parts by mass, which is the total value of the content of the melamine resin and the content of the epoxy resin. It is preferably 1 part by mass or more and 50 parts by mass or less (Invention 5).
• the melamine resin is the following general formula (a).
• X represents -H, -CH 2- OH, or -CH 2 -OR, which may be the same or different.
• R has 1 to 8 carbon atoms. It represents an alkyl group, which may be the same or different; at least one X is -CH 2- OH, or -CH 2 -OR.
• the weight average molecular weight of the melamine resin is preferably 100 or more and 1000 or less (Invention 7).
• the release agent composition contains a catalyst (Invention 8).
• the release film for the ceramic green sheet manufacturing process it is possible to manufacture a ceramic green sheet having a high adhesive force between the ceramic green sheets during the laminating process of the ceramic green sheets.
• the release film for the ceramic green sheet manufacturing process according to the present embodiment (hereinafter, may be simply referred to as “release film”) includes a base material and a release agent layer provided on one side of the base material. Will be done.
• the release agent layer may be laminated directly on one side of the base material, or may be laminated on one side of the base material via another layer.
• Base material The base material in the present embodiment is not particularly limited as long as the release agent layer can be laminated.
• Examples of such a base material include a film made of polyester such as polyethylene terephthalate and polyethylene naphthalate, polyolefin such as polypropylene and polymethylpentene, and plastic such as polycarbonate and polyvinyl acetate, and may be a single layer. , Two or more layers of the same type or different types may be used.
• a polyester film is preferable, a polyethylene terephthalate film is particularly preferable, and a biaxially stretched polyethylene terephthalate film is further preferable.
• the polyethylene terephthalate film Since the polyethylene terephthalate film has high mechanical strength and excellent solvent resistance, stable productivity can be achieved regardless of the scale during processing, use, and the like. Further, by applying an antistatic treatment to the polyethylene terephthalate film, it is possible to prevent ignition due to static electricity when coating a ceramic slurry using an organic solvent, and to enhance the effect of preventing poor coating.
• the above base material may contain a filler. Further, when the base material is multi-layered, the filler may be contained in at least one surface side layer.
• one side or both sides thereof may be subjected to surface treatment or primer treatment by an oxidation method, an unevenness method or the like, if desired.
• the oxidation method include corona discharge treatment, plasma discharge treatment, chromium oxidation treatment (wet), flame treatment, hot air treatment, ozone, and ultraviolet irradiation treatment
• the unevenness method include sandblasting and sandblasting.
• Examples include a thermal spraying method.
• the thickness of the base material is preferably 10 ⁇ m or more, particularly preferably 15 ⁇ m or more, and further preferably 20 ⁇ m or more.
• the thickness of the base material is preferably 300 ⁇ m or less, particularly preferably 200 ⁇ m or less, and further preferably 125 ⁇ m or less.
• the release agent layer in the present embodiment is formed from a release agent composition containing a melamine resin, an epoxy resin, and a polyorganosiloxane.
• the release agent layer is formed from a release agent composition containing a melamine resin, an epoxy resin, and a polyorganosiloxane, and is produced by using the release agent composition. It is possible to enhance the adhesive force between the ceramic green sheets in the laminating process of the ceramic green sheets.
• the release agent composition for forming the release agent layer contains polyorganosiloxane, the surface free energy on the release surface of the release agent layer is appropriately reduced. Furthermore, since the release agent composition contains a melamine resin and an epoxy resin, the release agent composition can be sufficiently cured by heating (and the presence of a catalyst), and the release agent layer formed has sufficient elasticity. It becomes a thing. As a result, the peeling force when the peeling film is peeled from the ceramic green sheet formed on the peeling surface of the peeling film is appropriately reduced, and good peelability is achieved.
• the "melamine resin” means a mixture containing a plurality of types of melamine compounds and / or a polynuclear compound formed by condensing the melamine compounds.
• the phrase “melamine resin” is meant to mean the above mixture or an aggregate of one melamine compound.
• a cured product of the melamine resin is referred to as a "cured melamine product”.
• epoxy resin in the present specification means a compound having one or more epoxy groups in the molecule, and includes those which are polymers and those which are not polymers.
• the melamine resin is not particularly limited as long as it can form a cured melamine product.
• the melamine resin preferably contains a compound represented by the following general formula (a).
• X represents -H, -CH 2- OH, or -CH 2 -OR.
• These groups constitute reactive groups in the condensation reaction between melamine compounds and the hydroxyl group of polyorganosiloxane or the hydroxyl group generated by opening the epoxy group of the epoxy resin.
• the -NH group formed when X becomes H can carry out a condensation reaction with the -N-CH 2- OH group and the -N-CH 2-R group.
• both the -N-CH 2- OH group formed when X becomes -CH 2- OH and the -N-CH 2- R group formed when X becomes -CH 2- R are both.
• -NH group, -N-CH 2- OH group and -N-CH 2- R group can be subjected to a condensation reaction.
• the groups represented by -CH 2- OH and -CH 2 -OR are condensation reactions between the hydroxyl group of the polyorganosiloxane or the hydroxyl group generated by the opening of the epoxy group of the epoxy resin and the melamine compound. Consists of a reactive group that contributes to. In the formula (a), it is preferable that not all X's are -H, and specifically, at least one X is preferably -CH 2- OH or -CH 2 -OR.
• R represents a C 1-8 alkyl group having a carbon.
• the number of carbon atoms is preferably 1 to 4, and particularly preferably 1 to 2.
• Examples of the alkyl group having 1 to 8 carbon atoms include a methyl group, an ethyl group, a propyl group, a butyl group, a pentyl group, a hexyl group, an octyl group and the like, and a methyl group is particularly preferable.
• the above Xs may be the same or different. Further, the above Rs may be the same or different.
• the number of Xs having ⁇ H in the formula (a) is preferably 2 or less, particularly preferably 1 or less, and further 0. Is preferable.
• the melamine resin may contain a polynuclear body formed by condensing 2 to 10 compounds represented by the above formula (a), may contain a polynuclear body formed by condensing 2 to 8 compounds, and further may contain 2 It may contain a polynuclear body formed by condensing up to 5 pieces.
• the weight average molecular weight of the melamine resin is preferably 1000 or less, particularly preferably 900 or less, and further preferably 800 or less.
• the weight average molecular weight of the melamine resin is 1000 or less, the curability of the release agent composition becomes more excellent, and it becomes easy to form a release agent layer having sufficient coating film strength. As a result, it becomes possible to achieve better peelability.
• the weight average molecular weight of the melamine resin is preferably 100 or more, particularly preferably 200 or more, and further preferably 300 or more. When the weight average molecular weight of the melamine resin is 100 or more, the reaction rate of the condensation reaction described above is stable, and it becomes easy to form a peeled surface having an excellent surface condition.
• the weight average molecular weight in the present specification is a standard polystyrene-equivalent value measured by a gel permeation chromatography (GPC) method.
• epoxy resin in the epoxy resin, the epoxy group is opened in the presence of a catalyst, particularly an acid catalyst, the epoxy compounds are polymerized with each other, or the epoxy group of the epoxy resin is opened.
• the hydroxyl group produced in the above process and the melamine compound undergo a condensation reaction to bond with each other.
• the epoxy resin in the present embodiment is a compound having one or more epoxy groups in the molecule, but is preferably a compound having two or more epoxy groups in the molecule.
• an epoxy resin various known epoxy resins can be used and are not particularly limited.
• the epoxy resin include bisphenol A type epoxy resin, bisphenol F type epoxy resin, brominated bisphenol A type epoxy resin, hydrogenated bisphenol A type epoxy resin, bisphenol S type epoxy resin, bisphenol AF type epoxy resin, and biphenyl type epoxy.
• Bifunctional such as an epoxy resin having a biphenyl group such as a resin, a urethane-modified epoxy resin, a rubber-modified epoxy resin, an alkylene glycol-type epoxy resin such as a polyalkylene glycol type, an epoxy resin having a naphthalene ring, and an epoxy resin having a fluorene group.
• Type glycidyl ether type epoxy resin polyfunctional glycidyl ether type epoxy resin such as phenol novolac type epoxy resin, orthocresol novolac type epoxy resin, trishydroxyphenylmethane type epoxy resin, tetraphenylol ethane type epoxy resin; dimer acid Glycidyl ester type epoxy resin of synthetic fatty acids such as N, N, N', N'-tetraglycidyldiaminodiphenylmethane (TGDDM), tetraglycidyl-m-xylylene diamine, triglycidyl-p-aminophenol, N, N- Aromatic epoxy resins having a glycidyl amino group such as diglycidyl aniline; epoxy resins having a tricyclodecane ring and the like can be mentioned.
• the epoxy resin one type may be used alone, or two or more types may be used in combination.
• the rubber-modified epoxy resin can be produced by reacting a rubber component with an epoxy group in the epoxy resin.
• the rubber component is not particularly limited, and examples thereof include butadiene rubber, acrylic rubber, silicone rubber, butyl rubber, olefin rubber, styrene rubber, isoprene rubber, nitrile rubber, styrene / butadiene rubber, and ethylene / propylene rubber.
• Examples of the functional group of the rubber component include amino-modified, hydroxy-modified, and carboxyl-modified.
• the epoxy resin used in producing the rubber-modified epoxy resin is not particularly limited, and conventionally known epoxy resins can be used.
• the epoxy equivalent of the epoxy resin is preferably 50 g / eq or more, particularly preferably 80 g / eq or more, and further preferably 100 g / eq or more.
• the epoxy equivalent is preferably 5000 g / eq or less, particularly preferably 2000 g / eq or less, and more preferably 1000 g / eq or less.
• the epoxy equivalent in the present specification is a value measured according to JIS K7236.
• the weight average molecular weight (Mw) of the epoxy resin is preferably 100 or more, particularly preferably 200 or more, and further preferably 300 or more.
• the weight average molecular weight is preferably 50,000 or less, particularly preferably 30,000 or less, and further preferably 20,000 or less.
• the mass ratio of the melamine resin content and the epoxy resin content is preferably 99: 1 to 30:70, particularly 98: 2 to 40:60. It is preferably 95: 5 to 50:50.
• the mass ratio of the content of the melamine resin and the content of the epoxy resin is in the above range, the adhesive force between the ceramic green sheets becomes higher. Further, the ceramic green sheet formed on the peeling surface of the release film has excellent peelability when peeled from the release film.
• the polyorganosiloxane is not particularly limited as long as it can impart desired release property to the release agent layer.
• the polyorganosiloxane preferably has at least one hydroxyl group in one molecule.
• the polyorganosiloxane having a hydroxyl group allows the polyorganosiloxane to be chemically immobilized in the cured product by a condensation reaction with the melamine resin, and as a result, the poly from the release agent layer to the ceramic green sheet. It becomes easy to suppress the migration of organosiloxane.
• the structure of the polyorganosiloxane other than the hydroxyl group is not particularly limited as long as it does not inhibit the above-mentioned peelability and the condensation reaction with the melamine resin.
• a polymer of a silicon-containing compound represented by the following general formula (b) can be used as the polyorganosiloxane.
• m is an integer of 1 or more.
• R 1 to R 8 independently mean a hydroxyl group, an organic group (including an organic group having a hydroxyl group), or a group other than these groups.
• at least one of R 1 to R 8 is a hydroxyl group or an organic group having a hydroxyl group
• it is preferable that at least one of R 3 to R 8 is these groups. That is, when the polyorganosiloxane has a hydroxyl group or an organic group having a hydroxyl group, the group is preferably present at the terminal of the polyorganosiloxane. The presence of the hydroxyl group at the terminal facilitates the condensation reaction of the polyorganosiloxane with the melamine resin, and the migration of the polyorganosiloxane is effectively suppressed.
• the organic group examples include a polyester group and a polyether group.
• the polyorganosiloxane in the present embodiment preferably has at least one polyester group and a polyether group.
• the polyorganosiloxane and the melamine resin are easily mixed well in the release agent composition, and these are extremely phase-separated during curing. Is suppressed.
• the condensation reaction between the polyorganosiloxane and the melamine resin and / or the epoxy resin as described above proceeds satisfactorily, and the migration of the polyorganosiloxane is also effectively suppressed.
• the "organic group” does not include an alkyl group described later.
• Examples of groups other than hydroxyl groups and organic groups include alkyl groups having 1 to 12 carbon atoms.
• alkyl groups having 1 to 12 carbon atoms include a methyl group, an ethyl group, a propyl group, a butyl group, a pentyl group, a hexyl group, an octyl group and the like, and a methyl group is particularly preferable.
• R 1 to R 8 may be the same or different. Further, when a plurality of R 1 and R 2 exist, R 1 and R 2 may be the same or different from each other.
• the weight average molecular weight of the polyorganosiloxane is preferably 10,000 or less, particularly preferably 8,000 or less, and further preferably 5,000 or less.
• the weight average molecular weight of the polyorganosiloxane is preferably 500 or more, particularly preferably 700 or more, and further preferably 1000 or more.
• the content of polyorganosiloxane in the release agent composition is preferably 1 part by mass or more, particularly 3 parts by mass or more, based on 100 parts by mass of the total value of the melamine resin content and the epoxy resin content. It is preferable that the amount is 5 parts by mass or more.
• the content of the polyorganosiloxane is preferably 50 parts by mass or less, particularly 40 parts by mass or less, based on 100 parts by mass of the total value of the melamine resin content and the epoxy resin content. It is preferable, and more preferably 30 parts by mass or less. When the content of the polyorganosiloxane is in the above range, appropriate peelability can be obtained from the formed ceramic green sheet.
• the release agent composition in the present embodiment preferably contains a catalyst from the viewpoint of efficiently proceeding the above-mentioned condensation reaction with the melamine resin and promoting the ring-opening reaction of the epoxy resin.
• a catalyst from the viewpoint of efficiently proceeding the above-mentioned condensation reaction with the melamine resin and promoting the ring-opening reaction of the epoxy resin.
• an acid catalyst is preferable, specifically, hydrochloric acid, sulfuric acid, nitrate, phosphoric acid, phosphite, p-toluenesulfonic acid and the like are preferable, and p-toluenesulfonic acid is particularly preferable.
• the content of the catalyst in the release agent composition is preferably 0.1 part by mass or more, particularly 0.5 part by mass, with respect to 100 parts by mass of the total value of the melamine resin content and the epoxy resin content.
• the amount is preferably 1 part or more, and more preferably 1 part by mass or more.
• the content is preferably 30 parts by mass or less, more preferably 20 parts by mass or less, particularly preferably 15 parts by mass or less, and further preferably 10 parts by mass or less. ..
• the release agent composition may contain a cross-linking agent, a reaction inhibitor, an adhesion improver, a slip agent and the like.
• the thickness of the release agent layer is preferably 0.01 ⁇ m or more and 2 ⁇ m or less, more preferably 0.03 ⁇ m or more and 1 ⁇ m or less, and particularly 0.1 ⁇ m. As mentioned above, it is preferably 0.5 ⁇ m or less. As a result, good peelability can be obtained, and it is possible to effectively suppress the occurrence of blocking when the release film is wound into a roll.
• the release force required for peeling the release film from the ceramic green sheet formed on the release surface can be appropriately set.
• it is preferably 10 mN / 40 mm or more, particularly preferably 15 mN / 40 mm or more, and further preferably 20 mN / 40 mm or more.
• the peeling force is, for example, preferably 300 mN / 40 mm or less, particularly preferably 200 mN / 40 mm or less, and further preferably 100 mN / 40 mm or less.
• the release agent layer is formed of a release agent composition containing a melamine resin, an epoxy resin, and polyorganosiloxane, the release force as described above can be easily set. be able to.
• the details of the method for measuring the peeling force described above are as described in the test examples described later.
• the method for producing the release film in the present embodiment is not particularly limited as long as it includes forming a release agent layer from the above-mentioned release agent composition.
• the obtained coating film is dried and heated to cure the release agent composition. It is preferable to form a release agent layer, thereby obtaining a release film.
• Specific examples of the above-mentioned coating method include a gravure coating method, a bar coating method, a spray coating method, a spin coating method, a knife coating method, a roll coating method, and a die coating method.
• the organic solvent is not particularly limited, and various solvents can be used.
• hydrocarbon compounds such as toluene, hexane, and heptane, isopropyl alcohol, isobutyl alcohol, acetone, ethyl acetate, methyl ethyl ketone, methyl isobutyl ketone, and mixtures thereof are used.
• the release agent composition coated as described above is preferably thermoset.
• the heating temperature is preferably 80 ° C. or higher, and particularly preferably 100 ° C. or higher. Further, the heating temperature is preferably 170 ° C. or lower, and particularly preferably 160 ° C. or lower.
• the heating time for thermosetting is preferably 30 seconds or longer, and particularly preferably 50 seconds or longer. The heating time is preferably 120 seconds or less, and particularly preferably 90 seconds or less.
• the release film in this embodiment is preferably used for producing a ceramic green sheet.
• a ceramic slurry containing a ceramic material such as barium titanate or titanium oxide is applied to the peeled surface of the release agent layer.
• the coating can be performed by using, for example, a slot die coating method, a doctor blade method, or the like.
• binder component contained in the ceramic slurry examples include butyral resin, acrylic resin and the like.
• solvent contained in the ceramic slurry examples include an organic solvent, an aqueous solvent and the like.
• the ceramic green sheet can be molded by drying the coated ceramic slurry. After molding the ceramic green sheet, the ceramic green sheet is separated from the release film. At this time, in the release film of the present embodiment, the release agent layer is formed from the release agent composition containing the melamine resin, the epoxy resin and the polyorganosiloxane, so that the release film is formed against the ceramic green sheet. It has excellent peelability. Therefore, the ceramic green sheet can be peeled off with an appropriate peeling force without causing cracks, breakage, or the like.
• the release agent layer is formed from the release agent composition containing the melamine resin, the epoxy resin and the polyorganosiloxane, the release agent layer is said to be present during the step of laminating the ceramic green sheet.
• the adhesive strength between the ceramic green sheets is high, which suppresses the misalignment between the plurality of ceramic green sheets.
• another layer such as an antistatic layer may be provided on the surface of the base material opposite to the release agent layer, or between the base material and the release agent layer.
• Example 1 Methylated melamine resin as a melamine resin (manufactured by Sanwa Chemical Co., Ltd., product name "MW-30MLF", weight average molecular weight: 714) 95 parts by mass (solid content conversion value, the same applies hereinafter) and rubber-modified epoxy as an epoxy resin.
• the obtained coating liquid was uniformly coated on one side of a biaxially stretched polyethylene terephthalate film (thickness: 38 ⁇ m) as a base material with a bar coater. Next, the obtained coating film was dried by heating at 150 ° C. for 1 minute and cured to obtain a release film in which a release agent layer having a thickness of 0.1 ⁇ m was laminated on the substrate.
• the thickness of the release agent layer was measured using a spectroscopic ellipsometer (manufactured by JA Woolam Japan, product name "M-2000").
• Examples 2 to 8 A release film was produced in the same manner as in Example 1 except that the type of epoxy resin was changed as shown in Table 1.
• Example 9 A release film was produced in the same manner as in Example 1 except that the content of the melamine resin and the type and content of the epoxy resin were changed as shown in Table 1.
• E1 Rubber-modified epoxy resin (manufactured by DIC Corporation, product name "TSR-601", epoxy equivalent: 450 to 500 g / eq, weight average molecular weight (Mw): 16,000)
• E4 Phenol novolac type epoxy resin (manufactured by Mitsubishi Chemical Corporation, product name
• the ceramic slurry was uniformly applied to the release surface of the release agent layer, and then dried in a dryer. As a result, a ceramic green sheet having a thickness of 3 ⁇ m was formed on the release film.
• the release film with a ceramic green sheet thus obtained was cut into a width of 40 mm, and this was used as a measurement sample.
• the base material side of the above measurement sample is fixed to a rigid plate, and a tensile tester (manufactured by Shimadzu Corporation, product name "AG-IS500N”) is used to make a ceramic with a peeling angle of 90 ° and a peeling speed of 0.3 m / min.
• the green sheet was peeled from the release film, and the force required for peeling (peeling force; mN / 40 mm) was measured. The results are shown in Table 1.
• Test Example 2 Evaluation of adhesive strength between green sheets
• a ceramic green sheet having a thickness of 3 ⁇ m was formed on the release film in the same manner as in Test Example 1.
• the release film with a ceramic green sheet thus obtained was cut into a length of 100 mm and a width of 100 mm.
• an adhesive tape whose base material is a polyethylene terephthalate film was attached to the surface of the release film with a ceramic green sheet on the side of the ceramic green sheet to support the ceramic green sheet so that it could withstand the release test.
• the surface on the ceramic green sheet side that was in contact with the release surface of the release film is placed on the surface on the ceramic green sheet side of another release film with ceramic green sheet.
• the two ceramic green sheets were thermocompression bonded (60 ° C., 10 MPa). Then, the release film of the release film with the ceramic green sheet was peeled off and cut into 10 mm squares, and this was used as a measurement sample.
• Test Example 4 (Amount of silicone transferred to the green sheet surface) A ceramic green sheet having a thickness of 3 ⁇ m was formed on the release film in the same manner as in Test Example 1. The ceramic green sheet thus obtained is peeled from the release film, and the silicon atom ratio (atomic%) measured by X-ray photoelectron spectroscopy (XPS) on the surface of the ceramic green sheet in contact with the release film. ) was obtained, and this was used as an index of the amount of silicone transfer. Regarding the calculation of the silicon atom ratio, the count numbers of each element of Si, C, O, Ti and Ba are obtained, the total amount is 100%, and the percentage of the count number of Si elements is the silicon atom ratio (atomic%). ). The results are shown in Table 1.
• the release film of Comparative Example 2 using a general-purpose silicone-based release agent did not provide any adhesive force between the ceramic green sheets. Further, even in the release film of Comparative Example 1 in which only the melamine resin was used as the main component of the release agent composition without containing the epoxy resin, the adhesive force between the ceramic green sheets was not sufficient. On the other hand, according to the release film of the example using the release agent composition containing the epoxy resin together with the melamine resin, the adhesive force between the ceramic green sheets was sufficiently high.
• the reason why the adhesive strength between the ceramic green sheets is insufficient is considered to be that the silicone-based component used in the release agent layer of the release film is transferred to the ceramic green sheet.
• Comparative Example 1 which showed a value similar to that of the example, was inferior in the adhesive strength between the green sheets. .. Therefore, the lack of adhesive strength between the ceramic green sheets cannot be explained only by the transfer of polyorganosiloxane.
• the release agent layer of the release film forming the ceramic green sheet is formed of a release agent composition containing a melamine resin, an epoxy resin, and a polyorganosiloxane. You can see that it was achieved by doing.
• the release film for the ceramic green sheet manufacturing process of the present invention is suitable for molding a ceramic green sheet for manufacturing a laminated ceramic product.

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• 2021
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