Classifications

• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
  • C10M169/04—Mixtures of base-materials and additives
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M131/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing halogen
  • C10M131/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing halogen containing carbon, hydrogen and halogen only
  • C10M131/04—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing halogen containing carbon, hydrogen and halogen only aliphatic
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  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M101/00—Lubricating compositions characterised by the base-material being a mineral or fatty oil
  • C10M101/02—Petroleum fractions
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
  • C10M2203/003—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions used as base material
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
  • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
  • C10M2203/1006—Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
  • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
  • C10M2203/106—Naphthenic fractions
  • C10M2203/1065—Naphthenic fractions used as base material
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
  • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
  • C10M2205/0206—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers used as base material
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
  • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
  • C10M2205/028—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms
  • C10M2205/0285—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms used as base material
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
  • C10M2207/02—Hydroxy compounds
  • C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
  • C10M2207/022—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
  • C10M2207/0225—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups used as base material
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
  • C10M2207/28—Esters
  • C10M2207/2805—Esters used as base material
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
  • C10M2211/02—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen and halogen only
  • C10M2211/022—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen and halogen only aliphatic
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
  • C10M2211/04—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen, halogen, and oxygen
  • C10M2211/042—Alcohols; Ethers; Aldehydes; Ketones
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
  • C10M2229/02—Unspecified siloxanes; Silicones
  • C10M2229/025—Unspecified siloxanes; Silicones used as base material
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
  • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
  • C10N2020/01—Physico-chemical properties
  • C10N2020/015—Distillation range
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
  • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
  • C10N2020/01—Physico-chemical properties
  • C10N2020/017—Specific gravity or density
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
  • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
  • C10N2020/01—Physico-chemical properties
  • C10N2020/02—Viscosity; Viscosity index
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
  • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
  • C10N2030/04—Detergent property or dispersant property
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
  • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
  • C10N2030/70—Soluble oils
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
  • C10N2040/00—Specified use or application for which the lubricating composition is intended
  • C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
  • C10N2040/042—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for automatic transmissions
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
  • C10N2040/00—Specified use or application for which the lubricating composition is intended
  • C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
  • C10N2040/045—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for continuous variable transmission [CVT]
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
  • C10N2040/00—Specified use or application for which the lubricating composition is intended
  • C10N2040/14—Electric or magnetic purposes
  • C10N2040/16—Dielectric; Insulating oil or insulators
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
  • C10N2040/00—Specified use or application for which the lubricating composition is intended
  • C10N2040/25—Internal-combustion engines

Definitions

• the present invention relates to a lubricating oil composition, for example, a lubricating oil composition used for cooling equipment for electric vehicles.
• Hybrid vehicles and electric vehicles which are vehicles with excellent fuel efficiency and environmental performance, are being promoted.
• Hybrid vehicles and electric vehicles are equipped with electric motors, generators, inverters, storage batteries, etc., and run using the power of the electric motors.
• Such electric vehicle equipment such as electric motors and batteries needs to be cooled because the efficiency is lowered and the equipment is damaged when the temperature becomes high.
• Lubricants such as existing automatic transmission fluid (hereinafter, ATF) and continuously variable transmission fluid (hereinafter, CVTF) are mainly used for cooling electric motors and generators in hybrid vehicles and electric vehicles. Further, since some hybrid vehicles and electric vehicles have a gear reducer, the lubricating oil composition used for these needs to have cooling property in addition to lubricity.
• Cooling performance of the lubricating oil composition includes high density and low viscosity for cooling that lowers the temperature of various devices, and a high flash point for preventing ignition of various devices during cooling.
• low viscosity and high flash point are generally in a trade-off relationship, so it is difficult to achieve both, and studies are being conducted to achieve both.
• Patent Document 1 proposes a lubricating oil composition obtained by blending a synthetic oil with a fluorine compound as a lubricating oil composition having cooling property and lubricity.
• the present invention relates to a lubricating oil composition containing a base oil and a fluorine compound, and a cooling device including the same.
• One embodiment of the present invention is a lubricating oil composition containing a base oil and a fluorine compound, wherein the base oil contains a mineral oil and the kinematic viscosity of the base oil at 40 ° C. is 1 to 25 mm 2 / s.
• the content of the fluorine compound is 3 to 30% by weight based on the total amount of the composition.
• a lubricating oil composition having excellent cooling performance it is possible to provide a lubricating oil composition having excellent cooling performance.
• the lubricating oil composition of the present invention has excellent compatibility between the base oil and the fluorine compound, and separation is suppressed.
• a lubricating oil composition having a high density, low viscosity, and high flash point can be provided.
• composition a lubricating oil composition (hereinafter, also referred to as “composition”) containing the following components: (A) base oil and (B) fluorine compound, wherein the base oil contains mineral oil and fluorine.
• the compound has a boiling point in the range of 40 to 150 ° C.
• the composition according to this embodiment further contains (C) other additives, if necessary.
• each component contained in the composition according to the present embodiment will be described in order.
• Base oils include mineral oils.
• the mineral oil any one can be appropriately selected and used from the mineral oils conventionally used as the base oil of the lubricating oil.
• the lubricating oil distillate obtained by distilling the atmospheric residual oil obtained by atmospheric distillation of crude oil under reduced pressure is subjected to solvent desorption, solvent extraction, hydrocracking, solvent dewaxing, contact dewaxing, and hydrogenation.
• mineral oils and waxes refined by performing one or more kinds of treatments such as refining, and mineral oils produced by isomerizing GTL WAX (gast liquid wax).
• the mineral oil may be used alone or in combination of two or more.
• the base oil may be composed of only mineral oil, or may be a combination of mineral oil and synthetic oil. From the viewpoint of increasing the density of the lubricating oil composition, it is preferable to contain 60% by weight or more of the mineral oil in the base oil (100% by weight), more preferably 65% by weight or more, and particularly preferably 70% by weight or more. Is what you do.
• the synthetic oil used in combination with the mineral oil is not particularly limited, and any synthetic oil conventionally used as a base oil for lubricating oil can be appropriately selected and used.
• the synthetic oil is at least one selected from naphthen compounds, polyolefin compounds, aromatic compounds, ether compounds, ester compounds, and glycol compounds. Is preferable.
• the synthetic oil may be used alone or in combination of two or more. Above all, it is more preferable to use an ester compound from the viewpoint of obtaining a composition having a low viscosity and a high flash point.
• a compound having a ring selected from a cyclohexane ring, a bicycloheptane ring and a bicyclooctane ring is preferably mentioned.
• Preferred examples of the polyolefin compound include ⁇ -olefin homopolymers and copolymers (for example, ethylene- ⁇ -olefin copolymers) and hydrides thereof.
• the constituent alcohols include methanol, ethanol, n-propanol, n-butanol, n-pentanol, n-hexanol, n-heptanol, n-octanol, n-nonanol, and n-decanol.
• carboxylic acid (unit) constituting the ester nbutanoic acid, npentanoic acid, nhexanoic acid, nheptanoic acid, noctanoic acid, nnonanoic acid, ndecanoic acid, nundecanoic acid, ndodecanoic acid, ntridecanoic acid , N tetradecanoic acid, ethylhexanoic acid, butyloctanoic acid, pentylnonanoic acid, hexyldecanoic acid, heptylundecanoic acid, octyldodecanoic acid, methylheptadecanoic acid, oleic acid, benzoic acid, toluic acid, phenylacetic acid, and phenoxyacetic acid.
• dicarboxylic acids such as carboxylic acid, adipic acid, azelaic acid, sebacic acid, 1,10-decamethylene dicarboxylic acid, phthalic acid, isophthalic acid and terephthalic acid.
• Carboxylic acids (units) may be used alone or in combination.
• ester composed of alcohol and carboxylic acid examples include polyglycolbenzoic acid esters such as polyethylene glycol dibenzoate and polypropylene glycol dibenzoate, n-octanoic acid tetraester of pentaerythritol, and n-octanoic acid triester of trimethylolpropane.
• Chain carboxylic acid hindered esters diesters such as dinoctyl azelaic acid and ethylhexyl 1,10-decamethylene dicarboxylic acid, monoesters such as dodecyl 16-methylheptadecanoate and ndodecyl 2-heptylundecanoate, oleyl oleate and Oleyl esters such as 16-methylheptadecyl oleic acid are suitable.
• Examples of the aromatic compound include alkyl aromatic compounds such as alkylbenzene and alkylnaphthalene.
• examples of the ether compound include polyphenyl ether and the like.
• examples of glycol-based compounds include polyglycol oils such as polyoxyalkylene glycol.
• the base oil is the main component of the lubricating oil composition, and the content of the base oil is usually 60 to 97% by weight, more preferably 65 to 97% by weight, still more preferably 70 to 70% based on the total amount of the composition. It is 95% by weight.
• the kinematic viscosity of the base oil at 40 ° C. is 1 to 25 mm 2 / s. When it is 1 mm 2 / s or more, the efficiency of the oil pump is improved. When it is 25 mm 2 / s or less, a composition having excellent cooling performance can be obtained.
• the kinematic viscosity of the base oil at 40 ° C. is more preferably 1 to 20 mm 2 / s from the viewpoint of cooling performance.
• the kinematic viscosity of the base oil at 40 ° C. may be, for example, in the range of 1 to 15 mm 2 / s, or in the range of 1 to 10 mm 2 / s, or 1 to 5 mm 2 / s.
• the kinematic viscosity at a predetermined temperature means a value measured according to JIS K2283: 2000.
• the flash point of the base oil is not particularly limited, but is preferably 60 ° C. or higher from the viewpoint of imparting excellent cooling property to the lubricating oil composition.
• the flash point of the base oil is more preferably 65 ° C. or higher, still more preferably 70 ° C. or higher.
• the flash point (PM) of the base oil is measured by the Penske Maltens Sealing Method (PM method) in accordance with JIS K 2265-3: 2007.
• Component (B): Fluorine compound As the fluorocarbon compound, a compound known as a so-called fluorocarbon refrigerant is preferable, and examples thereof include hydrochlorofluorocarbon (HCFC), hydrofluorocarbon (HFC), and hydrofluoroether (HFE). However, it is preferable that the boiling point is in the range of 40 to 150 ° C. When the boiling point is 150 ° C. or lower, the cooling performance of the lubricating oil composition is improved. When the boiling point is 40 ° C. or higher, vaporization at room temperature is prevented, so that handleability and odor are improved. From the viewpoint of improving the cooling performance of the lubricating oil composition, the boiling point of the fluorine compound is preferably 150 ° C.
• the boiling point of the fluorine compound is preferably 40 ° C. or higher, more preferably 50 ° C. or higher.
• the boiling point of the fluorine compound is preferably in the range of 40 to 150 ° C, more preferably in the range of 50 to 140 ° C.
• the boiling point of the fluorine compound can be more than 100 ° C. and 150 ° C. or lower, or 105 ° C. or higher and 150 ° C. or lower.
• HCFC examples include 3,3-dichloro-1,1,1,1,2,2-pentafluoropropane and 1,3-dichloro-1,1,1,2,2,3-pentafluoropropane.
• Asahi Clean AK-225 manufactured by Asahi Glass Co., Ltd. is a mixture thereof and has a boiling point of 54 ° C.
• a fluoride of an alkane having 4 to 12 carbon atoms is preferable.
• CF 3 CHFCHFCF 2 CF 3 (boiling point 55 ° C.) (Bertrel XF manufactured by Mitsui-Dupont Fluorochemical Co., Ltd.), CF 3 CH 2 CF 2 CH 3 (boiling point 40 ° C) ( Solbeisolexis solcan 365 mfc), C 5 H 3 F 7 (boiling point 82 ° C) (Zeorolla HTA manufactured by Nippon Zeon Co., Ltd.), 1,1,1,2,2,3 , 3,4,4,5,5,6,6-tridecafluorooctane (CF 3 CF 2 CF 2 CF 2 CF 2 CH 2 CH 3 ) (boiling point 114 ° C) (ASC Co., Ltd.
• HFE examples include C 4 F 9 OCH 3 (boiling point 61 ° C) (3M Novec 7100), C 4 F 9 OC 2 H 5 (boiling point 76 ° C) (3M Novec 7200), C 2 F 5 CF (3M Novec 7200).
• the kinematic viscosity of the fluorine compound is not particularly limited, but the kinematic viscosity of the fluorine compound at 25 ° C. is preferably 0.1 to 5 mm 2 / s, more preferably 0.1 to 4 mm, from the viewpoint of cooling performance. It is 2 / s, more preferably 0.1 to 3 mm 2 / s.
• the content of the fluorine compound is 3 to 30% by weight based on the total amount of the composition. If it is less than 3% by weight, the cooling property that can be imparted to the lubricating oil composition is not sufficient. If it exceeds 30% by weight, the compatibility between the fluorine compound and the base oil may deteriorate. When the compatibility between the fluorine compound and the base oil is poor, the fluorine compound tends to settle in the lower part of the lubricating oil composition due to its high density.
• the fluorine compound stays in the lower part of the lubricating oil composition, so that the amount of the fluorine compound supplied to the cooling portion is reduced, causing a decrease in cooling performance, or a gear of the fluorine compound.
• the lubrication performance wear resistance
• the content of the fluorine compound is more preferably 20% by weight or less, still more preferably 15% by weight or less.
• the content of the fluorine compound is more preferably 4% by weight or more, still more preferably 5% by weight or more.
• the content of the fluorine compound is more preferably 4 to 20% by weight, further preferably 5 to 15% by weight.
• the lubricating oil composition is, if necessary, an anti-wear agent, an antioxidant, a viscosity index improver, a rust preventive, a metal inactivating agent, a defoaming agent, and a cleaning dispersion, as long as the effect of the present invention is not impaired.
• Additives such as agents can be added.
• the total content of these other components is not particularly limited, but is, for example, about 0 to 20% by weight based on the total amount of the composition.
• the anti-wear agent is not particularly limited, and any anti-wear agent conventionally used for lubricating oil can be appropriately selected and used.
• any anti-wear agent conventionally used for lubricating oil can be appropriately selected and used.
• a neutral phosphorus compound, an acidic phosphite ester or an amine salt thereof so as not to impair the electrical insulation as much as possible.
• a sulfur compound or the like it is preferable to use a sulfur compound or the like.
• the content of the anti-wear agent is not particularly limited, but is, for example, about 0.01 to 5% by weight based on the total amount of the composition.
• neutral phosphorus compound examples include aromatic neutral phosphates such as tricresyl phosphate, triphenyl phosphate, trixylenyl phosphate, tricresylphenyl phosphate, tricresyl thiosphate, and triphenyl thiophosphate, and tributyl phosphate.
• aromatic neutral phosphates such as tricresyl phosphate, triphenyl phosphate, trixylenyl phosphate, tricresylphenyl phosphate, tricresyl thiosphate, and triphenyl thiophosphate, and tributyl phosphate.
• Tri-2-ethylhexyl phosphate, tributoxy phosphate, tributylthiophosphate and other aliphatic neutral phosphates triphenyl phosphate, tricresyl phosphate, trisnonylphenyl phosphate, diphenylmono-2-ethylhexyl phosphate , Aromatic neutral phosphite such as diphenylmonotridecylphosphite, torqueregylthiophosphite, triphenylthiophosphite, tributylphosphite, trioctylphosphite, trisdecylphosphite, tristridecylphosphite, Examples thereof include aliphatic neutral phosphites such as trioleyl phosphite, tolbutylthiophosphite, and trioctylthiophosphite. These may be used alone
• acidic subphosphate examples include aliphatic acidic phosphate ester amine salts such as di-2-ethylhexyl acid phosphate amine salt, dilauryl acid phosphate amine salt, and diolayl acid phosphate amine salt, and di-2-ethylhexyl hydrogen phosphite.
• Dilauryl hydrogen phosphite aliphatic acidic phosphite such as diolayl hydrogen phosphite and aromatic acidic phosphate amine salts such as amine salts thereof, diphenyl acid phosphate amine salt, dicresyl acid phosphate amine salt, Aromatic acidic acid phosphite such as diphenylhydrogen phosphite and dicredyl hydrogen phosphite and their amine salts, sulfur-containing acidic phosphorus such as S-octylthioethyl acid phosphate amine salt and S-dodecylthioethyl acid phosphate amine salt.
• Examples thereof include acid ester amine salts, sulfur-containing acidic hypophosphates such as S-octylthioethylhydrogen phosphite and S-dodecylthioethylhydrogen phosphite, and amine salts thereof. These may be used alone or in combination of two or more.
• sulfur-based compounds can be used, and specific examples thereof include thiadiazole-based compounds, polysulfide-based compounds, dithiocarbamate-based compounds, sulfide oil-fat-based compounds, and olefin sulfide-based compounds.
• antioxidant any known antioxidant that has been conventionally used as an antioxidant for lubricating oil can be appropriately selected and used.
• amine-based antioxidants diphenylamines, naphthylamines
• phenol-based antioxidants phenol-based antioxidants
• molybdenum-based antioxidants sulfur-based antioxidants
• phosphorus-based antioxidants and the like can be mentioned.
• the antioxidant may be used alone or in combination of two or more.
• the content of the antioxidant is not particularly limited, but is, for example, about 0.05 to 7% by weight based on the total amount of the composition.
• Viscosity index improver examples include polymethacrylate, dispersed polymethacrylate, olefin-based copolymer (for example, ethylene-propylene copolymer, etc.), dispersed olefin-based copolymer, and styrene-based copolymer (for example, styrene-based copolymer). Styrene-diene copolymer, styrene-isoprene copolymer, etc.) and the like.
• the viscosity index improver may be used alone or in combination of two or more.
• the blending amount of the viscosity index improver is not particularly limited, but is, for example, about 0.5% by weight or more and 15% by weight or less based on the total amount of the composition from the viewpoint of the blending effect.
• rust preventive agent examples include fatty acids, alkenyl succinic acid half esters, fatty acid sequels, alkyl sulfonates, polyhydric alcohol fatty acid esters, fatty acid amides, oxidized paraffins, alkyl polyoxyethylene ethers and the like.
• the rust preventive may be used alone or in combination of two or more.
• the preferable blending amount of the rust preventive is not particularly limited, but is about 0.01% by weight or more and 3% by weight or less based on the total amount of the composition.
• Metal inactivating agent examples include benzotriazole, triazole derivative, benzotriazole derivative, and thiadiazole derivative.
• the metal inactivating agent may be used alone or in combination of two or more.
• the content of the metal inactivating agent is not particularly limited, but is preferably 0.01 to 5% by weight based on the total amount of the composition.
• Examples of the defoaming agent include silicone compounds such as dimethylpolysiloxane and polyacrylates.
• the defoaming agent may be used alone or in combination of two or more.
• the content of the defoaming agent is not particularly limited, but is about 0.01% by weight or more and 5% by weight or less based on the total amount of the composition.
• cleaning dispersant examples include succinimide compounds, boron-based imide compounds, and acid amide-based compounds.
• the cleaning dispersant may be used alone or in combination of two or more.
• the content of the cleaning dispersant is not particularly limited, but is preferably 0.1 to 20% by weight based on the total amount of the composition.
• the lubricating oil composition preferably satisfies the three performances of low viscosity, high density, and high flash point (or no flash point) as cooling performance.
• the kinematic viscosity at 40 ° C. of the lubricating oil composition from the viewpoint of cooling performance, preferably 0.5 ⁇ 40mm 2 / s, more preferably from 1 ⁇ 35mm 2 / s, more preferably 1 ⁇ 30mm 2 / s.
• the kinematic viscosity at 100 ° C. of the lubricating oil composition, from the viewpoint of cooling performance preferably 0.1 ⁇ 20mm 2 / s, more preferably 0.5 ⁇ 15mm 2 / s, 0.5 ⁇ 10mm 2 / s Is even more preferable.
• the density of the lubricating oil composition from the viewpoint of cooling performance, said seal degree, preferably 0.75 g / cm 3 or more, more preferably 0.80 g / cm 3 or more, more preferably 0.84 g / cm 3 or more be.
• the density is high, the heat transfer coefficient is improved, so that the cooling property is improved.
• the density of the lubricating oil composition preferably 1.25 g / cm 3 or less, more preferably 1.20 g / cm 3 or less, further preferably 1.15 g / cm 3 or less.
• the density of the lubricating oil composition is in the range of 0.85 ⁇ 1.25g / cm 3, more preferably in the range of 0.855 ⁇ 1.20g / cm 3, more preferably 0 It is in the range of .86 to 1.15 g / cm 3.
• the density of the lubricating oil composition is measured by the method of JIS K 2249-1: 2011 in an environment of 15 ° C.
• the flash point of the lubricating oil composition is preferably 60 ° C. or higher, more preferably 65 ° C. or higher, and even more preferably 70 ° C. or higher. If the flash point is less than 60 ° C., it is not preferable from the viewpoint of handling safety, and the problem of odor is likely to occur. From the viewpoint of handling safety, a higher flash point is preferable, and one having no flash point is particularly preferable. In particular, in electric vehicles and the like, it is more desirable that there is no flash point in terms of safety.
• the flash point (PM) of the lubricating oil composition was measured by the Penske Maltens sealing method (PM method) in accordance with JIS K 2265-3: 2007.
• the lubricating oil composition preferably has excellent compatibility between the base oil and the fluorine compound.
• "Excellent compatibility” means that precipitation of the fluorine compound does not occur in the present composition obtained by mixing the two in a predetermined ratio. More specifically, it is preferable that the fluorine compound does not precipitate at a temperature of 30 ° C., and it is more preferable that the fluorine compound does not precipitate at both the room temperature (25 ° C.) temperature and the temperature of 30 ° C.
• the fluorine compound When the fluorine compound is precipitated, the fluorine compound stays in the lower part of the lubricating oil composition, so that the amount of the fluorine compound supplied to the cooling part is reduced and the cooling performance is lowered, or the fluorine compound is supplied to the lubricating part such as gears. If the amount is excessive, the lubrication performance (wear resistance) may deteriorate.
• a lubricating oil composition having excellent compatibility the fluorine compound and the base oil can be uniformly supplied to the lubricating portion such as the cooling portion and the gear, and sufficient cooling performance and lubricating performance can be imparted.
• the lubricating oil composition is homogeneous without phase separation.
• the lubricating oil composition of the present invention described above has lubricity and excellent cooling performance (for example, high density, low viscosity, and high flash point). Therefore, it can be suitably used for cooling various devices.
• it is preferably used for cooling equipment for electric vehicles such as electric vehicles and hybrid vehicles.
• it is suitable as an oil for cooling at least one electric vehicle equipment selected from motors, batteries, inverters, engines, and transmissions.
• the lubricating oil composition imparts lubricity and cooling effect in various devices.
• the lubricating oil composition cools the equipment while lubricating the equipment by circulating various equipment such as equipment for electric vehicles.
• One embodiment provides a cooling device for cooling an electric vehicle device, which comprises the above-described lubricating oil composition of the present invention.
• the lubricating oil composition is used in a cooling device for cooling at least one electric vehicle equipment selected from motors, batteries, inverters, engines, and transmissions.
• the lubricating oil composition can be used in a hydraulic system, a stationary transmission, an automobile transmission, a motor or a battery cooling device.
• the method for producing the lubricating oil composition of the present embodiment is not particularly limited.
• the method for producing a lubricating oil composition of one embodiment includes mixing the component (A), the component (B), and if necessary, the component (C).
• the component (A), the component (B), and if necessary, the component (C) may be blended in any way, and the order of blending and the method thereof are not limited.
• the flash point of the base oil was measured by two methods.
• the flash point (PM) was measured by the Penske Altense Sealing Method (PM method) in accordance with JIS K 2265-3: 2007.
• the flash point of the fluorine compound was measured by the PM method.
• the flash point of silicone oil was measured by the PM method.
• the flash point of the lubricating oil composition was measured by the PM method.
• Mineral oil 1 Mineral oil (40 ° C kinematic viscosity: 2.10 mm 2 / s, flash point (PM): 100 ° C)
• Mineral oil 2 Mineral oil (40 ° C kinematic viscosity: 1.64 mm 2 / s, flash point (PM): 80 ° C)
• Synthetic oil 1 Poly- ⁇ -olefin (40 ° C.
• the lubricating oil compositions of Examples 1 to 5 containing a mineral oil and a specific amount of a fluorine compound have a low kinematic viscosity and a high density, have no ignition point, and are miscible. It was confirmed that it was excellent in (compatibility between fluorine compound and base oil).
• the lubricating oil compositions of Comparative Example 1, Comparative Example 2, Comparative Example 4, and Comparative Example 5 containing no fluorine compound had low flash points and densities, and sufficient cooling performance could not be obtained.
• the density value was low and sufficient cooling performance could not be obtained.
• the miscibility was deteriorated and the fluorine compound was precipitated.
• the lubricating oil composition of the present invention has lubricity and excellent cooling performance, and can be used for cooling equipment for electric vehicles such as electric vehicles and hybrid vehicles.
• it is suitable as a lubricating oil for cooling at least one electric vehicle equipment selected from motors, batteries, inverters, engines, and transmissions.

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• General Chemical & Material Sciences (AREA)
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• Engineering & Computer Science (AREA)
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• 2021
  • 2021-01-15 JP JP2021571244A patent/JP7596312B2/ja active Active
  • 2021-01-15 US US17/792,362 patent/US11946013B2/en active Active
  • 2021-01-15 CN CN202180007950.5A patent/CN114901788B/zh active Active
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