WO2021143435A8 - 一种丁烯二醇基聚酯弹性体及制备方法 - Google Patents

一种丁烯二醇基聚酯弹性体及制备方法 Download PDF

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Publication number
WO2021143435A8
WO2021143435A8 PCT/CN2020/137013 CN2020137013W WO2021143435A8 WO 2021143435 A8 WO2021143435 A8 WO 2021143435A8 CN 2020137013 W CN2020137013 W CN 2020137013W WO 2021143435 A8 WO2021143435 A8 WO 2021143435A8
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WO
WIPO (PCT)
Prior art keywords
butenediol
polyester elastomer
based polyester
preparation
narrow
Prior art date
Application number
PCT/CN2020/137013
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English (en)
French (fr)
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WO2021143435A1 (zh
Inventor
王朝
张奇男
张立群
王文才
张宁
赵燕超
Original Assignee
北京化工大学
彤程新材料集团股份有限公司
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Application filed by 北京化工大学, 彤程新材料集团股份有限公司 filed Critical 北京化工大学
Priority to EP20913497.2A priority Critical patent/EP4092066A4/en
Priority to AU2020422756A priority patent/AU2020422756A1/en
Priority to JP2022543480A priority patent/JP2023510414A/ja
Priority to MYPI2022003698A priority patent/MY198080A/en
Priority to CA3167881A priority patent/CA3167881A1/en
Publication of WO2021143435A1 publication Critical patent/WO2021143435A1/zh
Priority to US17/866,424 priority patent/US20220363821A1/en
Publication of WO2021143435A8 publication Critical patent/WO2021143435A8/zh

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/66Polyesters containing oxygen in the form of ether groups
    • C08G63/668Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/672Dicarboxylic acids and dihydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/52Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/60Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from the reaction of a mixture of hydroxy carboxylic acids, polycarboxylic acids and polyhydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/66Polyesters containing oxygen in the form of ether groups
    • C08G63/668Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/676Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78Preparation processes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78Preparation processes
    • C08G63/82Preparation processes characterised by the catalyst used
    • C08G63/85Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78Preparation processes
    • C08G63/82Preparation processes characterised by the catalyst used
    • C08G63/87Non-metals or inter-compounds thereof

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

本发明公开了一种丁烯二醇基聚酯弹性体及制备方法。所述丁烯二醇基聚酯弹性体的结构如(I)所示。本发明选用含有高稳定性双键的1,4-丁烯二醇替代衣康酸,合成了一系列高分子量窄分布的丁烯二醇基聚酯弹性体,具有高的相对分子质量和窄的相对分子质量分布,后续加工过程中交联更可控,其硫化剂用量与传统橡胶相当。
PCT/CN2020/137013 2020-01-16 2020-12-17 一种丁烯二醇基聚酯弹性体及制备方法 WO2021143435A1 (zh)

Priority Applications (6)

Application Number Priority Date Filing Date Title
EP20913497.2A EP4092066A4 (en) 2020-01-16 2020-12-17 BUTENEDIOL-BASED POLYESTER ELASTOMER AND PREPARATION METHOD THEREFOR
AU2020422756A AU2020422756A1 (en) 2020-01-16 2020-12-17 Butenediol-based polyester elastomer and preparation method
JP2022543480A JP2023510414A (ja) 2020-01-16 2020-12-17 ブテンジオール系ポリエステルエラストマー及び製造方法
MYPI2022003698A MY198080A (en) 2020-01-16 2020-12-17 Butenediol-based polyester elastomer and method for preparing same
CA3167881A CA3167881A1 (en) 2020-01-16 2020-12-17 Butenediol-based polyester elastomer and method for preparing same
US17/866,424 US20220363821A1 (en) 2020-01-16 2022-07-15 Butenediol-based Polyester Elastomer and Method for Preparing Same

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN202010045414.1A CN113136027B (zh) 2020-01-16 2020-01-16 一种丁烯二醇基聚酯弹性体及制备方法
CN202010045414.1 2020-01-16

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US17/866,424 Continuation US20220363821A1 (en) 2020-01-16 2022-07-15 Butenediol-based Polyester Elastomer and Method for Preparing Same

Publications (2)

Publication Number Publication Date
WO2021143435A1 WO2021143435A1 (zh) 2021-07-22
WO2021143435A8 true WO2021143435A8 (zh) 2022-08-04

Family

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PCT/CN2020/137013 WO2021143435A1 (zh) 2020-01-16 2020-12-17 一种丁烯二醇基聚酯弹性体及制备方法

Country Status (8)

Country Link
US (1) US20220363821A1 (zh)
EP (1) EP4092066A4 (zh)
JP (1) JP2023510414A (zh)
CN (1) CN113136027B (zh)
AU (1) AU2020422756A1 (zh)
CA (1) CA3167881A1 (zh)
MY (1) MY198080A (zh)
WO (1) WO2021143435A1 (zh)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115073716B (zh) * 2021-03-16 2023-05-26 北京化工大学 一种丁烯二醇基脂肪族-芳香族共聚酯弹性体及制备方法
CN115109399B (zh) * 2021-03-17 2024-04-26 北京化工大学 一种可降解鞋底和鞋边条的胶料及其制备方法和应用
CN115109400A (zh) * 2021-03-18 2022-09-27 北京化工大学 一种可生物降解的丁烯二醇基聚酯弹性体胎面胶及制备方法
CN115109401A (zh) * 2021-03-19 2022-09-27 北京化工大学 一种胎面可生物降解的聚酯橡胶复合轮胎及制备方法
CN115594830B (zh) * 2022-10-20 2024-03-26 北京化工大学 一种生物基聚酯弹性体、制备方法及形变诱导结晶的聚酯弹性体

Family Cites Families (17)

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US4240947A (en) * 1979-05-29 1980-12-23 Borg-Warner Corporation Cross-linked elastomeric polyester laticies
US4225684A (en) * 1979-05-29 1980-09-30 Borg-Warner Corporation High impact PVC compositions with cross-linked polyester modifiers
US4224207A (en) * 1979-06-04 1980-09-23 Borg-Warner Corporation High impact blends of SAN and cross-linked polyester elastomers
JPS5958026A (ja) * 1982-09-27 1984-04-03 Nippon Synthetic Chem Ind Co Ltd:The スルホン酸塩基を含有するポリエステルの製造法
US4520148A (en) * 1983-12-01 1985-05-28 Gaf Corporation Thermoplastic elastomer compositions
JPS63317546A (ja) * 1987-06-02 1988-12-26 ヘキスト・セラニーズ・コーポレーション コポリエステルエラストマーとカルボジイミドとの混合物
DE4226520A1 (de) * 1992-08-11 1994-02-17 Bayer Ag Radikalisch härtbare Kompositionen und ihre Verwendung
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JP3882639B2 (ja) * 2002-02-27 2007-02-21 東レ株式会社 生分解性ポリエステル樹脂架橋発泡体及びその製造方法
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Also Published As

Publication number Publication date
JP2023510414A (ja) 2023-03-13
AU2020422756A1 (en) 2022-08-25
EP4092066A1 (en) 2022-11-23
EP4092066A4 (en) 2024-02-07
US20220363821A1 (en) 2022-11-17
CN113136027B (zh) 2023-03-10
CA3167881A1 (en) 2021-07-22
WO2021143435A1 (zh) 2021-07-22
MY198080A (en) 2023-07-31
CN113136027A (zh) 2021-07-20

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