WO2021142962A1 - High-contrast grating vertical-cavity surface-emitting laser and manufacturing method therefor - Google Patents

High-contrast grating vertical-cavity surface-emitting laser and manufacturing method therefor Download PDF

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Publication number
WO2021142962A1
WO2021142962A1 PCT/CN2020/085164 CN2020085164W WO2021142962A1 WO 2021142962 A1 WO2021142962 A1 WO 2021142962A1 CN 2020085164 W CN2020085164 W CN 2020085164W WO 2021142962 A1 WO2021142962 A1 WO 2021142962A1
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layer
grating
region
oxide
reflector
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PCT/CN2020/085164
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French (fr)
Chinese (zh)
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沈志强
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浙江博升光电科技有限公司
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01SDEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S5/00Semiconductor lasers
    • H01S5/10Construction or shape of the optical resonator, e.g. extended or external cavity, coupled cavities, bent-guide, varying width, thickness or composition of the active region
    • H01S5/18Surface-emitting [SE] lasers, e.g. having both horizontal and vertical cavities
    • H01S5/183Surface-emitting [SE] lasers, e.g. having both horizontal and vertical cavities having only vertical cavities, e.g. vertical cavity surface-emitting lasers [VCSEL]
    • H01S5/18386Details of the emission surface for influencing the near- or far-field, e.g. a grating on the surface
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01SDEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S5/00Semiconductor lasers
    • H01S5/10Construction or shape of the optical resonator, e.g. extended or external cavity, coupled cavities, bent-guide, varying width, thickness or composition of the active region
    • H01S5/18Surface-emitting [SE] lasers, e.g. having both horizontal and vertical cavities
    • H01S5/183Surface-emitting [SE] lasers, e.g. having both horizontal and vertical cavities having only vertical cavities, e.g. vertical cavity surface-emitting lasers [VCSEL]
    • H01S5/18361Structure of the reflectors, e.g. hybrid mirrors
    • H01S5/18377Structure of the reflectors, e.g. hybrid mirrors comprising layers of different kind of materials, e.g. combinations of semiconducting with dielectric or metallic layers

Definitions

  • the present invention generally relates to the technical field of lasers, in particular to a high-contrast grating vertical cavity surface emitting laser and a manufacturing method.
  • a high-contrast grating (High Contrast Grating; HCG) can be used instead of a Bragg reflector (Distributed Bragg Reflector; DBR).
  • the HCG includes a spacer layer, a groove is formed on the spacer layer, and a grating is suspended above the groove. Since the grating is suspended above the groove, it is susceptible to mechanical damage.
  • a 2-dimensional (Dimensions; D) grating is used, it can only adopt a gridded shape.
  • the present application intends to provide a high-contrast grating vertical cavity surface emitting laser and a manufacturing method to solve the problem that the 2D structure adopting the air-suspended grating in the prior art can only adopt a mesh structure, cannot form a columnar structure, and is easy to be damaged.
  • the present invention provides a high-contrast grating vertical cavity surface emitting laser, including:
  • the second reflector layer includes an oxide isolation layer and a grating layer, the oxide isolation layer is located between the grating layer and the active layer, at least a part of the grating layer is provided with a grating, and the grating
  • the gate trenches of the second oxide layer extend to the oxide isolation layer, the oxide isolation layer is provided with a first oxide region, the first oxide region supports the grating, and the refractive index of the first oxide region is smaller than that of the grating Refractive index.
  • the first reflector layer, the active layer, and the second reflector layer form a three-stage stepped structure
  • a current spreading layer is formed on the active layer, a first electrode is formed on the current spreading layer, and the first electrode is located at a step position.
  • the first reflector layer, the active layer, and the second reflector layer form a two-stage stepped structure, wherein the first reflector layer forms a first step, at least The active layer and the second reflector layer form a second step;
  • a first electrode is provided on the grating layer in an area outside the grating.
  • an oxide layer is formed on at least one side of the active layer, the oxide layer includes a second oxidized region and an unoxidized region, the second oxidized region surrounds the unoxidized region, and the unoxidized region The oxidized area is used to define the laser exit window.
  • the first reflector layer, the active layer, and the second reflector layer form a platform structure
  • the active layer includes a proton or ion implantation region and a first non-implantation region, the proton or ion implantation region surrounds the first non-implantation region, and the first non-implantation region is used to define a laser exit window.
  • the laser exit window is less than or equal to the first oxide region
  • the active layer further includes a second unimplanted region, and the second unimplanted region is located between the oxide isolation layer and the Proton or ion implantation between regions.
  • the thickness of the oxide isolation layer is less than ⁇ /6, where ⁇ is the wavelength of the laser light emitted by the high-contrast grating vertical cavity surface emitting laser.
  • the present invention provides a method for manufacturing the above-mentioned high-contrast grating vertical cavity surface emitting laser, including:
  • the method for forming the second reflector layer includes:
  • a wet oxidation process is performed on the oxide isolation layer through the gate groove to form a first oxidation region facing the grating, and the refractive index of the first oxidation region is smaller than the refractive index of the grating.
  • an electrode contact layer is formed on the side of the first reflector layer facing the active layer
  • An electrode is formed on the electrode contact layer and the current spreading layer.
  • an electrode contact layer is formed on the side of the first reflector layer facing the active layer
  • An electrode is formed on the electrode contact layer and the grating layer.
  • a proton or ion implantation region and a first non-implanted region are formed in the active layer through a proton or ion implantation process, and the proton or ion implantation region surrounds the first non-implanted region, and The first uninjected area is used to define the laser exit window.
  • the first oxidized region supports the grating instead of floating on the groove as the grating in the prior art, so the grating is not easily damaged, which greatly improves the reliability of the high-contrast grating vertical cavity surface emitting laser
  • the grating can adopt a structure such as a stripe, a mesh, or a column.
  • the refractive index of the first oxidized region is smaller than that of the grating, forming a high-contrast grating.
  • FIG. 1 is a schematic diagram of a vertical high-contrast grating vertical cavity surface emitting laser provided by an embodiment of the present invention
  • 2-7 are schematic diagrams of the manufacturing process of one of the vertical high-contrast grating vertical cavity surface emitting lasers provided by the embodiments of the invention.
  • Fig. 8 is a schematic diagram of one structure of a vertical high contrast grating vertical cavity surface emitting laser provided by an embodiment of the invention.
  • 9-13 are schematic diagrams of the manufacturing process of another vertical high-contrast grating vertical cavity surface emitting laser according to an embodiment of the invention.
  • Fig. 14 is another structural schematic diagram of a vertical high-contrast grating vertical cavity surface emitting laser provided by an embodiment of the invention.
  • an embodiment of the present invention provides a vertical high-contrast grating vertical cavity surface emitting laser, including:
  • the first reflector layer 1, the active layer 8 and the second reflector layer 3 are stacked; the second reflector layer 3 includes an oxide isolation layer 31 and a grating layer 32.
  • the oxide isolation layer 31 is located on the grating layer 32 and there are Between the source layers 8, at least a part of the grating layer 32 is provided with a grating 4, and the grating groove 5 of the grating 4 extends to the oxide isolation layer 31.
  • the oxide isolation layer 31 is provided with a first oxidized region 6, and the first oxidized region 6 supports For the grating, the refractive index of the first oxidized region 6 is smaller than the refractive index of the grating.
  • the material of the oxide isolation layer 31 is, for example, but not limited to, AlGaAs. Specifically, the ratio may be Al x Ga 1-x As (0.8 ⁇ x ⁇ 1).
  • the grating is, for example, but not limited to, a sub-wavelength grating.
  • the first oxidized region 6 supports the grating instead of suspending the grating on the groove as in the prior art, so the grating is not easily damaged, which greatly improves the reliability of the high-contrast grating vertical cavity surface emitting laser.
  • the grating can adopt a structure such as a stripe, a mesh, or a column.
  • more complex optical structures can be integrated into the grating, such as but not limited to lenses or phase plates used to generate orbital angular momentum beams.
  • the refractive index of the first oxidized region 6 is smaller than the refractive index of the grating, forming a high-contrast grating.
  • the vertical high contrast grating vertical cavity surface emitting laser can also include an oxide layer 2, a current spreading layer 9 and other functions according to actual needs.
  • sexual layer the following will describe one by one.
  • the first reflector layer 1, the active layer 8 and the second reflector layer 3 form a three-stage stepped structure; the first reflector layer 1 forms a first
  • the active layer 8 forms the second step, and the second reflector layer 3 forms the third step.
  • the dimensions of the first reflector layer 1, the active layer 8 and the second reflector layer 3 are reduced in order. Small.
  • the sizes of the first reflector layer 1, the active layer 8 and the second reflector layer 3 may also be increased sequentially.
  • a current spreading layer 9 is formed on the active layer 8, a first electrode 13 is formed on the current spreading layer 9, and the first electrode 13 is located at a step position.
  • the first electrode 13 may be formed on the current spreading layer 9 by a deposition method, for example, chemical vapor deposition, electroplating, sputtering, evaporation, or the like.
  • the material of the current spreading layer 9 is, for example, but not limited to, GaAs.
  • an oxide layer 2 is formed on at least one side of the active layer 8.
  • the oxide layer 2 includes a second oxidized region 12 and an unoxidized region 11
  • the second oxidized region 12 surrounds the non-oxidized region 11, and the non-oxidized region 11 is used to define the laser exit window.
  • the oxide layer 2 is provided to make the current flowing through each light emitting region uniform, so the brightness uniformity of the light emitting region is high, and the vertical cavity surface emitting laser is improved Quality.
  • the second oxidation region 12 can be formed in the same oxidation process as the first oxidation region 6, of course, it can also be formed in two oxidation processes separately.
  • a substrate is provided; the substrate can be a GaAs substrate.
  • a first reflector layer 1 is formed on the substrate; the first reflector layer 1 may be DBR.
  • the first reflector layer 1 may include two layers of materials with different refractive indices, AlGaAs and GaAs; the substrate and the first reflector layer 1 may be both N-type or P-type. The N-type is used in this embodiment.
  • An N-type electrode contact layer 7 is formed on the first reflector layer 1.
  • An active layer 8 is formed on the N-type electrode contact layer 7, and an oxide layer 2 is formed on the active layer 8.
  • the oxide layer 2 can also be formed on the N-type electrode contact layer 7 and the active layer 8 can be formed on the oxide layer 2. It is also possible to form an oxide layer 2 on the N-type electrode contact layer 7, form an active layer 8 on the oxide layer 2, and form an oxide layer 2 on the active layer 8.
  • the active layer 8 includes at least a stacked multi-quantum well layer.
  • the multi-quantum well layer is composed of GaAs, AlGaAs, GaAsP and InGaAs materials stacked and arranged, and the active layer 8 is used to convert electrical energy into light energy.
  • a single quantum well layer can also be used instead of a multiple quantum well layer.
  • the current spreading layer 9 is formed on the active layer 8 or the oxide layer 2, and the second reflector layer 3 is formed on the current spreading layer 9;
  • the isolation layer 31 is formed, and then a grating layer 32 is formed on the oxide isolation layer 31.
  • the material of the oxide isolation layer 31 may be Al x Ga 1-x As (x>0.9), and the material of the grating layer 32 may be Al y Ga 1-y As (y ⁇ 0.4).
  • a part of the grating layer 32 is etched to form a gate trench 5 by etching, and the gate trench 5 extends to the oxide isolation layer 31.
  • the above-mentioned gate trench 5 can be etched by laser etching or chemical etching.
  • the grating layer 32 and the oxide isolation layer 31 outside the grating region are etched away, and the current spreading layer 9 is exposed.
  • the oxidation trench 10 is etched, and the oxidation trench 10 extends to the N-type electrode contact layer 7;
  • the first oxidized region 6 is formed at the position of the oxide isolation layer 31 corresponding to the grating by a wet oxidation process. As an implementation manner, the first oxidized region 6 is the part remaining after the oxide isolation layer 31 is etched.
  • the second oxidized region 12 surrounding the unoxidized region 11 is formed inwardly from the oxidized trench 10 formed in the layer 2.
  • the wet oxidation process for example, at a temperature of 430°C, 2L/min of nitrogen carries a certain temperature of water vapor for selective wet oxidation.
  • the oxidation depth that is, the extension depth in the left and right directions in the figure, is controlled by time, so that the oxide layer 2 A second oxidized region 12 is formed, the second oxidized region 12 surrounds the unoxidized region 11 in the oxide layer 2, and the first oxidized region 6 is formed at a position of the oxide isolation layer 31 corresponding to the grating.
  • Electrodes are formed on the current spreading layer 9 and the N-type electrode contact layer 7 by chemical vapor deposition, electroplating, sputtering, evaporation, etc., wherein the electrode on the current spreading layer 9 is the first electrode 13, and the N-type electrode contact layer The electrode on 7 is the second electrode 14.
  • the second electrode 14 can also be formed on the side of the first reflector layer 1 away from the active layer 8.
  • the second electrode 14 can be a planar electrode, which can be The surface of the first reflector layer away from the active layer 8 is completely covered to provide a large enough electrode to reduce resistance.
  • the first reflector layer 1, the active layer 8 and the second reflector layer 3 form a two-stage stepped structure, wherein the first reflector layer 1 forms the first
  • the active layer 8 and the second reflector layer 3 form a second step; it can be understood that the size of the first reflector layer 1 is larger than the size of the active layer 8 and the second reflector layer 3, and, The active layer 8 and the second reflector layer 3 have the same size.
  • the size of the first reflector layer 1 is smaller than the sizes of the active layer 8 and the second reflector layer 3, and the sizes of the active layer 8 and the second reflector layer 3 are the same.
  • a current spreading layer 9 is formed between the active layer 8 and the second emitter layer.
  • the material of the current spreading layer 9 is, for example, but not limited to, GaAs. .
  • the grating layer 32 is provided with a first electrode 13 in an area outside the grating.
  • the first electrode 13 can be formed on the grating layer 32 by a deposition method, for example, chemical vapor deposition, electroplating, sputtering, evaporation, or the like.
  • an oxide layer 2 is formed on at least one side of the active layer 8.
  • the oxide layer 2 includes a second oxidized region 12 and an unoxidized region 11
  • the second oxidized region 12 surrounds the non-oxidized region 11, and the non-oxidized region 11 is used to define the laser exit window.
  • the oxide layer 2 is provided to make the current flowing through each light emitting region uniform, so the brightness uniformity of the light emitting region is high, and the vertical cavity surface emitting laser is improved Quality.
  • the second oxidation region 12 can be formed in the same oxidation process as the first oxidation region 6, of course, it can also be formed in two oxidation processes separately.
  • a substrate is provided; the substrate can be a GaAs substrate.
  • a first reflector layer 1 is formed on the substrate; the first reflector layer 1 may be DBR.
  • the first reflector layer 1 may include two layers of materials with different refractive indices, AlGaAs and GaAs; the substrate and the first reflector layer 1 may be both N-type or P-type. The N-type is used in this embodiment.
  • An N-type electrode contact layer 7 is formed on the first reflector layer 1.
  • An active layer 8 is formed on the N-type electrode contact layer 7, and an oxide layer 2 is formed on the active layer 8.
  • the oxide layer 2 can also be formed on the N-type electrode contact layer 7 and the active layer 8 can be formed on the oxide layer 2. It is also possible to form an oxide layer 2 on the N-type electrode contact layer 7, form an active layer 8 on the oxide layer 2, and form an oxide layer 2 on the active layer 8.
  • the active layer 8 includes at least a stacked multi-quantum well layer.
  • the multi-quantum well layer is composed of GaAs, AlGaAs, GaAsP and InGaAs materials stacked and arranged, and the active layer 8 is used to convert electrical energy into light energy.
  • a single quantum well layer can also be used instead of a multiple quantum well layer.
  • the current spreading layer 9 is formed on the active layer 8 or the oxide layer 2, and the second reflector layer 3 is formed on the current spreading layer 9;
  • the isolation layer 31 is formed, and then a grating layer 32 is formed on the oxide isolation layer 31.
  • the material of the oxide isolation layer 31 may be Al x Ga 1-x As (x>0.9), and the material of the grating layer 32 may be Al y Ga 1-y As (y ⁇ 0.4).
  • a part of the grating layer 32 is etched to form a gate trench 5 by etching, and the gate trench 5 extends to the oxide isolation layer 31.
  • the above-mentioned gate trench 5 can be etched by laser etching or chemical etching.
  • the oxidation trench 10 is etched, and the oxidation trench 10 extends to the N-type electrode contact layer 7;
  • a first oxidation region 6 is formed at the position of the oxide isolation layer 31 corresponding to the grating by a wet oxidation process, and a self-oxidation trench 10 is formed in the oxidation layer 2 to form a second oxidation region 12 surrounding the unoxidized region 11 inward;
  • Electrodes are formed on the grating layer 32 and the N-type electrode contact layer 7 by chemical vapor deposition, electroplating, sputtering, evaporation, etc., wherein the electrode on the grating layer 32 is the first electrode 13, and the N-type electrode contact layer 7 The electrode is the second electrode 14.
  • the second electrode 14 can also be formed on the side of the first reflector layer 1 away from the active layer 8.
  • the second electrode 14 can be a planar electrode, which can be The surface of the first reflector layer away from the active layer 8 is completely covered to provide a large enough electrode to reduce resistance.
  • the first reflector layer 1, the active layer 8 and the second reflector layer 3 form a platform structure. It can be understood that the three of them can be of equal size.
  • the active layer 8 includes a proton or ion implantation region 17 and a first non-implanted region 18, the proton or ion implantation region 17 surrounds the first non-implanted region 18, the first non-implanted region 18 is used to define the laser emission window.
  • the oxide layer 2 is not required, and the etching of the oxide trench 10 is not required, which simplifies the manufacturing process and reduces the complexity of processing.
  • a substrate is provided; the substrate can be a GaAs substrate.
  • a first reflector layer 1 is formed on the substrate; the first reflector layer 1 may be DBR.
  • the first reflector layer 1 may include two layers of materials with different refractive indices, AlGaAs and GaAs; the substrate and the first reflector layer 1 may be both N-type or P-type. The N-type is used in this embodiment.
  • An N-type electrode contact layer 7 is formed on the first reflector layer 1.
  • An active layer 8 is formed on the N-type electrode contact layer 7.
  • the active layer 8 includes at least a stacked multi-quantum well layer composed of GaAs, AlGaAs, GaAsP and InGaAs materials stacked and arranged, and the active layer 8 is used to convert electrical energy into light energy.
  • a single quantum well layer can also be used instead of a multiple quantum well layer.
  • a current spreading layer 9 is formed on the active layer 8, and a second reflector layer 3 is formed on the current spreading layer 9; the second reflector layer 3 is formed by first forming an oxide isolation layer 31 on the current spreading layer 9 and then A grating layer 32 is formed on the oxide isolation layer 31.
  • the material of the oxide isolation layer 31 may be Al x Ga 1-x As (x>0.9), and the material of the grating layer 32 may be Al y Ga 1-y As (y ⁇ 0.4).
  • a part of the grating layer 32 is etched to form a gate trench 5 by etching, and the gate trench 5 extends to the oxide isolation layer 31.
  • the above-mentioned gate trench 5 can be etched by laser etching or chemical etching.
  • a photoresist 15 and other proton or ion implantation process protection structure is provided on the grating layer 32, and the proton or ion implantation process is used to form the proton or ion implantation region 17 and the first non-implantation region 18 in the active layer 8.
  • Proton or ion implantation The area 17 surrounds the first non-injected area 18, and the first non-injected area 18 is used to define the laser exit window.
  • the first non-implanted region 18 is a region covered by the protective structure of the proton or ion implantation process.
  • the main function of the area covered by the protective structure of the proton or ion implantation process is to protect the underlying layers during proton or ion isolation implantation, and prevent the underlying layers from being insulated during the proton or ion isolation implantation.
  • the protective structure of the proton or ion implantation process is removed.
  • a first electrode 13 is formed on the grating layer 32 by chemical vapor deposition, electroplating, sputtering, evaporation, etc., and a second electrode 14 is formed on the side of the first reflector layer 1 facing away from the active layer 8.
  • 14 can be a planar electrode, which can completely cover the surface of the first reflector layer 1 away from the active layer 8 to provide a sufficiently large electrode and reduce resistance.
  • the active layer 8 also includes a second non-implanted region 16, which is located in the oxide isolation layer 31 and proton or ion implantation. Between area 17.
  • the second uninjected region 16 may serve as a current spreading layer.
  • annealing is performed after the proton or ion implantation, so that the layers on the proton or ion implantation path and above the proton or ion implantation region 17 restore better conductivity.
  • the thickness of the oxide isolation layer 31 is less than ⁇ /6, so as to reduce the amount of material used and the difficulty of manufacturing.
  • is the wavelength of the laser light emitted by the high-contrast grating vertical cavity surface emitting laser.
  • the embodiment of the present invention also provides a method for manufacturing the above-mentioned high-contrast grating vertical cavity surface emitting laser, which includes:
  • the first reflector layer 1, the active layer 8 and the second reflector layer 3 are formed in sequence;
  • the method for forming the second reflector layer 3 includes:
  • An oxide isolation layer 31 and a grating layer 32 are sequentially formed, and the oxide isolation layer 31 is located between the grating layer 32 and the active layer 8;
  • the oxide isolation layer 31 is subjected to a wet oxidation process through the gate groove 5 to form a first oxide region 6 facing the grating.
  • the refractive index of the first oxide region 6 is smaller than that of the grating. Rate.
  • This method is a manufacturing method corresponding to the above-mentioned high-contrast grating vertical cavity surface emitting laser.
  • This method is a manufacturing method corresponding to the above-mentioned high-contrast grating vertical cavity surface emitting laser.
  • an electrode contact layer is formed on the side of the first reflector layer 1 facing the active layer 8;
  • the oxide layer 2 forms the second oxidation region 12 surrounding the unoxidized region 11 from the oxidation trench 10 inward;
  • Electrodes are formed on the electrode contact layer and the current spreading layer 9.
  • an electrode contact layer is formed on the side of the first reflector layer 1 facing the active layer 8;
  • the oxide layer 2 forms the second oxide region 12 surrounding the unoxidized region 11 from the oxide trench 10 inward;
  • Electrodes are formed on the electrode contact layer and the grating layer 32.
  • a proton or ion implantation region 17 and a first non-implanted region 18 are formed in the active layer 8 through a proton or ion implantation process, and the proton or ion implantation region 17 surrounds the first non-implanted region 18, The first non-injected region 18 is used to define a laser exit window.
  • first and second are only used for descriptive purposes, and cannot be understood as indicating or implying relative importance or implicitly indicating the number of indicated technical features. Thus, the features defined with “first” and “second” may explicitly or implicitly include one or more of these features. In the description of the present invention, unless otherwise specified, “multiple” means two or more.

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Abstract

Disclosed are a high-contrast grating vertical-cavity surface-emitting laser and a manufacturing method therefor. The high-contrast grating vertical-cavity surface-emitting laser comprises: a first reflector layer, an active layer, and a second reflector layer that are stacked. The second reflector layer comprises an oxide isolation layer and a grating layer; the oxide isolation layer is located between the grating layer and the active layer; at least a part of the grating layer is provided with a grating; grating grooves of the grating extend to the oxide isolation layer; the oxide isolation layer is provided with a first oxidation region; and the first oxidation region supports the grating, and has a refractive index smaller than the refractive index of the grating. In the solution, the first oxidation region supports the grating, while in the prior art, the grating floats on the grooves, and therefore, the grating is not easily damaged; in addition, due to the supporting effect of the first oxidation region, the grating may use strip, mesh, columnar and other structures.

Description

高对比度光栅垂直腔面发射激光器及制造方法High-contrast grating vertical cavity surface emitting laser and manufacturing method 技术领域Technical field
本发明一般涉及激光器技术领域,具体涉及一种高对比度光栅垂直腔面发射激光器及制造方法。The present invention generally relates to the technical field of lasers, in particular to a high-contrast grating vertical cavity surface emitting laser and a manufacturing method.
背景技术Background technique
在垂直腔面发射激光(Vertical-Cavity Surface-Emitting Laser;VCSEL)器中,可以采用高对比度光栅(High Contrast Grating;HCG)来代替布拉格反射器(Distributed Bragg Reflector;DBR)。该HCG包括间隔层,间隔层上形成有凹槽,在该凹槽的上方悬浮光栅。由于光栅是悬浮于凹槽上方,则其易受到机械损伤,另外在采用2维(Dimensions;D)光栅时,其只能采用网格化的形状。In a vertical cavity surface emitting laser (Vertical-Cavity Surface-Emitting Laser; VCSEL) device, a high-contrast grating (High Contrast Grating; HCG) can be used instead of a Bragg reflector (Distributed Bragg Reflector; DBR). The HCG includes a spacer layer, a groove is formed on the spacer layer, and a grating is suspended above the groove. Since the grating is suspended above the groove, it is susceptible to mechanical damage. In addition, when a 2-dimensional (Dimensions; D) grating is used, it can only adopt a gridded shape.
发明内容Summary of the invention
本申请期望提供一种高对比度光栅垂直腔面发射激光器及制造方法,用于解决现有技术中采用空气悬浮光栅的2D结构仅能采用网状结构,不能形成柱状结构,且易于损坏的问题。The present application intends to provide a high-contrast grating vertical cavity surface emitting laser and a manufacturing method to solve the problem that the 2D structure adopting the air-suspended grating in the prior art can only adopt a mesh structure, cannot form a columnar structure, and is easy to be damaged.
第一方面,本发明提供一种高对比度光栅垂直腔面发射激光器,包括:In the first aspect, the present invention provides a high-contrast grating vertical cavity surface emitting laser, including:
层叠设置的第一反射器层、有源层及第二反射器层;A first reflector layer, an active layer, and a second reflector layer that are stacked;
所述第二反射器层包括氧化物隔离层和光栅层,所述氧化物隔离层位于所述光栅层和所述有源层之间,所述光栅层至少部分区域设置有光栅,所述光栅的栅槽延伸至所述氧化物隔离层,所述氧化物隔离层设置有第一氧化区域,所述第一氧化区域支撑所述光栅,所述第一氧化区域的折射率小于所述光栅的折射率。The second reflector layer includes an oxide isolation layer and a grating layer, the oxide isolation layer is located between the grating layer and the active layer, at least a part of the grating layer is provided with a grating, and the grating The gate trenches of the second oxide layer extend to the oxide isolation layer, the oxide isolation layer is provided with a first oxide region, the first oxide region supports the grating, and the refractive index of the first oxide region is smaller than that of the grating Refractive index.
作为可实现的方式,所述第一反射器层、所述有源层和所述第二反射器层形成三阶台阶结构;As an achievable manner, the first reflector layer, the active layer, and the second reflector layer form a three-stage stepped structure;
所述有源层上形成有电流扩展层,所述电流扩展层上形成有第一电极,所述第一电极位于台阶位置处。A current spreading layer is formed on the active layer, a first electrode is formed on the current spreading layer, and the first electrode is located at a step position.
作为可实现的方式,所述第一反射器层、所述有源层和所述第二反射器层形成两阶台阶结构,其中,所述第一反射器层形成第一个台阶,至少所述有源层和所述第二反射器层形成第二个台阶;As an achievable manner, the first reflector layer, the active layer, and the second reflector layer form a two-stage stepped structure, wherein the first reflector layer forms a first step, at least The active layer and the second reflector layer form a second step;
所述光栅层上位于所述光栅外侧的区域设置有第一电极。A first electrode is provided on the grating layer in an area outside the grating.
作为可实现的方式,所述有源层的至少一侧形成有氧化层,所述氧化层包括第二氧化区域和未氧化区域,所述第二氧化区域环绕所述未氧化区域,所述未氧化区域用于界定激光出射窗。As an achievable way, an oxide layer is formed on at least one side of the active layer, the oxide layer includes a second oxidized region and an unoxidized region, the second oxidized region surrounds the unoxidized region, and the unoxidized region The oxidized area is used to define the laser exit window.
作为可实现的方式,所述第一反射器层、所述有源层和所述第二反射器层形成平台结构;As an achievable manner, the first reflector layer, the active layer, and the second reflector layer form a platform structure;
所述有源层包括质子或离子注入区域和第一未注入区域,所述质子或离子注入区域环绕所述第一未注入区域,所述第一未注入区域用于界定激光出射窗。The active layer includes a proton or ion implantation region and a first non-implantation region, the proton or ion implantation region surrounds the first non-implantation region, and the first non-implantation region is used to define a laser exit window.
作为可实现的方式,所述激光出射窗小于等于所述第一氧化区域,所述有源层还包括第二未注入区域,所述第二未注入区域位于所述氧化物隔离层与所述质子或离子注入区域之间。As an achievable manner, the laser exit window is less than or equal to the first oxide region, the active layer further includes a second unimplanted region, and the second unimplanted region is located between the oxide isolation layer and the Proton or ion implantation between regions.
作为可实现的方式,所述氧化物隔离层的厚度小于λ/6,其中,λ为所述高对比度光栅垂直腔面发射激光器所发射激光的波长。As an achievable manner, the thickness of the oxide isolation layer is less than λ/6, where λ is the wavelength of the laser light emitted by the high-contrast grating vertical cavity surface emitting laser.
第二方面,本发明提供一种上述高对比度光栅垂直腔面发射激光器的制造方法,包括:In a second aspect, the present invention provides a method for manufacturing the above-mentioned high-contrast grating vertical cavity surface emitting laser, including:
依次形成层叠设置的第一反射器层、有源层及第二反射器层;Sequentially forming a first reflector layer, an active layer, and a second reflector layer that are stacked;
所述第二反射器层的形成方法包括:The method for forming the second reflector layer includes:
依次形成氧化物隔离层和光栅层,所述氧化物隔离层位于所述光栅层和所述有源层之间;Sequentially forming an oxide isolation layer and a grating layer, the oxide isolation layer being located between the grating layer and the active layer;
对所述光栅层的至少部分区域进行栅槽的刻蚀,以形成所述光栅,所述栅槽延伸至所述氧化物隔离层;Etching at least a part of the grating layer to form a grating groove, and the grating groove extends to the oxide isolation layer;
透过所述栅槽对所述氧化物隔离层进行湿法氧化工艺,形成正对所述光栅的第一氧化区域,所述第一氧化区域的折射率小于所述光栅的折射率。A wet oxidation process is performed on the oxide isolation layer through the gate groove to form a first oxidation region facing the grating, and the refractive index of the first oxidation region is smaller than the refractive index of the grating.
作为可实现的方式,在所述第一反射器层朝向所述有源层的一侧形成电极接触层;As an achievable manner, an electrode contact layer is formed on the side of the first reflector layer facing the active layer;
至少在所述有源层的一侧形成氧化层;Forming an oxide layer on at least one side of the active layer;
在所述氧化物隔离层背离所述光栅层的一侧形成电流扩展层;Forming a current spreading layer on the side of the oxide isolation layer away from the grating layer;
去除所述光栅所对区域以外的所述光栅层及所述光栅所对区域以外的所述氧化物隔离层;Removing the grating layer other than the region opposed by the grating and the oxide isolation layer other than the region opposed by the grating;
形成氧化沟槽,所述氧化沟槽至少自所述第二反射器层延伸至所述电极接触层;Forming an oxidation trench, the oxidation trench at least extending from the second reflector layer to the electrode contact layer;
在所述氧化沟槽内通过所述湿法氧化工艺,使所述氧化层自所述氧化沟槽向内形成环绕所述未氧化区域的所述第二氧化区域;Using the wet oxidation process in the oxidation trench to make the oxide layer form the second oxidation region surrounding the non-oxidized region inwardly from the oxidation trench;
在电极接触层及电流扩展层形成电极。An electrode is formed on the electrode contact layer and the current spreading layer.
作为可实现的方式,在所述第一反射器层朝向所述有源层的一侧形成电极接触层;As an achievable manner, an electrode contact layer is formed on the side of the first reflector layer facing the active layer;
至少在所述有源层的一侧形成氧化层;Forming an oxide layer on at least one side of the active layer;
在所述氧化物隔离层背离所述光栅层的一侧形成电流扩展层;Forming a current spreading layer on the side of the oxide isolation layer away from the grating layer;
形成氧化沟槽,所述氧化沟槽至少自所述第二反射器层延伸至所述电极接触层;Forming an oxidation trench, the oxidation trench at least extending from the second reflector layer to the electrode contact layer;
在所述氧化沟槽内通过所述湿法氧化工艺,使所述氧化层自所述氧化沟槽向内形成环绕所述未氧化区域的所述第二氧化区域;Using the wet oxidation process in the oxidation trench to make the oxide layer form the second oxidation region surrounding the non-oxidized region inwardly from the oxidation trench;
在电极接触层及光栅层形成电极。An electrode is formed on the electrode contact layer and the grating layer.
作为可实现的方式,通过质子或离子注入工艺,在所述有源层形成质子或离子注入区域和第一未注入区域,所述质子或离子注入区域环绕所述第一未注入区域,所述第一未注入区域用于界定激光出射窗。As an achievable way, a proton or ion implantation region and a first non-implanted region are formed in the active layer through a proton or ion implantation process, and the proton or ion implantation region surrounds the first non-implanted region, and The first uninjected area is used to define the laser exit window.
上述方案,第一氧化区域对光栅进行支撑,而并非如现有技术中的光栅悬浮于凹槽上,因此光栅不易于被损坏,极大地提高了该高对比度光栅垂直腔面发射激光器的可靠性,另外,由于第一氧化区域的支撑作用,光栅可以采用条状、网状、柱状等结构。第一氧化区域的折射率小于光栅的折射率,形成了高对比度光栅。In the above solution, the first oxidized region supports the grating instead of floating on the groove as the grating in the prior art, so the grating is not easily damaged, which greatly improves the reliability of the high-contrast grating vertical cavity surface emitting laser In addition, due to the supporting effect of the first oxidation region, the grating can adopt a structure such as a stripe, a mesh, or a column. The refractive index of the first oxidized region is smaller than that of the grating, forming a high-contrast grating.
附图说明Description of the drawings
通过阅读参照以下附图所作的对非限制性实施例所作的详细描述,本申请的其它特征、目的和优点将会变得更明显:By reading the detailed description of the non-limiting embodiments with reference to the following drawings, other features, purposes and advantages of the present application will become more apparent:
图1为本发明实施例提供的垂高对比度光栅垂直腔面发射激光器的示意图;FIG. 1 is a schematic diagram of a vertical high-contrast grating vertical cavity surface emitting laser provided by an embodiment of the present invention;
图2-图7为发明实施例提供的其中一种垂高对比度光栅垂直腔面发射激光器的制作过程示意图,2-7 are schematic diagrams of the manufacturing process of one of the vertical high-contrast grating vertical cavity surface emitting lasers provided by the embodiments of the invention.
图8发明实施例提供的垂高对比度光栅垂直腔面发射激光器的其中一种结构示意图;Fig. 8 is a schematic diagram of one structure of a vertical high contrast grating vertical cavity surface emitting laser provided by an embodiment of the invention;
图9-图13为发明实施例提供的另一种垂高对比度光栅垂直腔面发射激光器的制作过程示意图;9-13 are schematic diagrams of the manufacturing process of another vertical high-contrast grating vertical cavity surface emitting laser according to an embodiment of the invention;
图14发明实施例提供的垂高对比度光栅垂直腔面发射激光器的另外一种结构示意图;Fig. 14 is another structural schematic diagram of a vertical high-contrast grating vertical cavity surface emitting laser provided by an embodiment of the invention;
图15-图20为发明实施例提供的又一种垂高对比度光栅垂直腔面发射激光器的制作过程示意图。15-20 are schematic diagrams of the manufacturing process of yet another vertical high-contrast grating vertical cavity surface emitting laser provided by an embodiment of the invention.
具体实施方式Detailed ways
下面结合附图和实施例对本申请作进一步的详细说明。可以理解的是,此处所描述的具体实施例仅仅用于解释相关发明,而非对该发明的限定。另外还需要说明的是,为了便于描述,附图中仅示出了与发明相关的部分。The application will be further described in detail below with reference to the drawings and embodiments. It can be understood that the specific embodiments described here are only used to explain the related invention, but not to limit the invention. In addition, it should be noted that, for ease of description, only the parts related to the invention are shown in the drawings.
需要说明的是,在不冲突的情况下,本申请中的实施例及实施例中的特征可以相互组合。下面将参考附图并结合实施例来详细说明本申请。It should be noted that the embodiments in the application and the features in the embodiments can be combined with each other if there is no conflict. Hereinafter, the application will be described in detail with reference to the drawings and in conjunction with the embodiments.
如图1所示,本发明实施例提供一种垂高对比度光栅垂直腔面发射激光器,包括:As shown in FIG. 1, an embodiment of the present invention provides a vertical high-contrast grating vertical cavity surface emitting laser, including:
层叠设置的第一反射器层1、有源层8及第二反射器层3;第二反射器层3包括氧化物隔离层31和光栅层32,氧化物隔离层31位于光栅层32和有源层8之间,光栅层32至少部分区域设置有光栅4,光栅4的栅槽5延伸至氧化物隔离层31,氧化物隔离层31设置有第一氧化区域6,第一氧化区域6支撑光栅,第一氧化区域6的折射率小 于光栅的折射率。The first reflector layer 1, the active layer 8 and the second reflector layer 3 are stacked; the second reflector layer 3 includes an oxide isolation layer 31 and a grating layer 32. The oxide isolation layer 31 is located on the grating layer 32 and there are Between the source layers 8, at least a part of the grating layer 32 is provided with a grating 4, and the grating groove 5 of the grating 4 extends to the oxide isolation layer 31. The oxide isolation layer 31 is provided with a first oxidized region 6, and the first oxidized region 6 supports For the grating, the refractive index of the first oxidized region 6 is smaller than the refractive index of the grating.
氧化物隔离层31的材料例如但不限于选用AlGaAs,具体地,其配比可以为Al xGa 1-xAs(0.8<x≤1)。 The material of the oxide isolation layer 31 is, for example, but not limited to, AlGaAs. Specifically, the ratio may be Al x Ga 1-x As (0.8<x≦1).
光栅例如但不限于为亚波长光栅。The grating is, for example, but not limited to, a sub-wavelength grating.
上述方案,第一氧化区域6对光栅进行支撑,而并非如现有技术中的光栅悬浮于凹槽上,因此光栅不易于被损坏,极大地提高了该高对比度光栅垂直腔面发射激光器的可靠性,另外,由于第一氧化区域6的支撑作用,光栅可以采用条状、网状、柱状等结构。此外还可以使更复杂的光学结构集成到光栅上,例如但不限于用于生成轨道角动量束的透镜或相位板等。第一氧化区域6的折射率小于光栅的折射率,形成了高对比度光栅。In the above solution, the first oxidized region 6 supports the grating instead of suspending the grating on the groove as in the prior art, so the grating is not easily damaged, which greatly improves the reliability of the high-contrast grating vertical cavity surface emitting laser. In addition, due to the supporting effect of the first oxidation region 6, the grating can adopt a structure such as a stripe, a mesh, or a column. In addition, more complex optical structures can be integrated into the grating, such as but not limited to lenses or phase plates used to generate orbital angular momentum beams. The refractive index of the first oxidized region 6 is smaller than the refractive index of the grating, forming a high-contrast grating.
该垂高对比度光栅垂直腔面发射激光器,除了包括第一反射器层1、有源层8及第二反射器层3之外,还可以根据实际需要包括氧化层2、电流扩展层9等功能性层,下文将逐一进行叙述。In addition to the first reflector layer 1, the active layer 8 and the second reflector layer 3, the vertical high contrast grating vertical cavity surface emitting laser can also include an oxide layer 2, a current spreading layer 9 and other functions according to actual needs. Sexual layer, the following will describe one by one.
如图2-图7所示,作为其中一种可实现方式,第一反射器层1、有源层8和第二反射器层3形成三阶台阶结构;第一反射器层1形成第一个台阶、有源层8形成第二个台阶、第二反射器层3形成第三个台阶,可以理解为第一反射器层1、有源层8和第二反射器层3的尺寸依次减小。当然,在其他实施例中,第一反射器层1、有源层8和第二反射器层3的尺寸还可以依次增大。As shown in Figures 2-7, as one of the possible implementations, the first reflector layer 1, the active layer 8 and the second reflector layer 3 form a three-stage stepped structure; the first reflector layer 1 forms a first The active layer 8 forms the second step, and the second reflector layer 3 forms the third step. It can be understood that the dimensions of the first reflector layer 1, the active layer 8 and the second reflector layer 3 are reduced in order. Small. Of course, in other embodiments, the sizes of the first reflector layer 1, the active layer 8 and the second reflector layer 3 may also be increased sequentially.
在有源层8上形成有电流扩展层9,电流扩展层9上形成有第一电极13,第一电极13位于台阶位置处。可以通过沉积的方式,例如可以通过化学气相沉积、电镀、溅射、蒸镀等方式在电流扩展层9上形成第一电极13。A current spreading layer 9 is formed on the active layer 8, a first electrode 13 is formed on the current spreading layer 9, and the first electrode 13 is located at a step position. The first electrode 13 may be formed on the current spreading layer 9 by a deposition method, for example, chemical vapor deposition, electroplating, sputtering, evaporation, or the like.
电流扩展层9的材料例如但不限于为GaAs。The material of the current spreading layer 9 is, for example, but not limited to, GaAs.
为了对电流进行局限,以提高该高对比度光栅垂直腔面发射激光器的出光效率,在有源层8的至少一侧形成有氧化层2,氧化层2包括第二氧化区域12和未氧化区域11,第二氧化区域12环绕所述未氧化区域11,未氧化区域11用于界定激光出射窗。该高对比度光栅垂直腔面发射激光器设置多个发光区域的情况下,通过设置氧化层2使 得各发光区所流经的电流均匀,因此发光区的亮度一致性高,提高了垂直腔面发射激光器的品质。该第二氧化区域12可以与第一氧化区域6在同一氧化工艺中形成,当然,也可在两个氧化工艺中分别形成。In order to limit the current and improve the light extraction efficiency of the high-contrast grating vertical cavity surface emitting laser, an oxide layer 2 is formed on at least one side of the active layer 8. The oxide layer 2 includes a second oxidized region 12 and an unoxidized region 11 The second oxidized region 12 surrounds the non-oxidized region 11, and the non-oxidized region 11 is used to define the laser exit window. When the high-contrast grating vertical cavity surface emitting laser is provided with multiple light emitting regions, the oxide layer 2 is provided to make the current flowing through each light emitting region uniform, so the brightness uniformity of the light emitting region is high, and the vertical cavity surface emitting laser is improved Quality. The second oxidation region 12 can be formed in the same oxidation process as the first oxidation region 6, of course, it can also be formed in two oxidation processes separately.
该实施例的高对比度光栅垂直腔面发射激光器可以采用以下步骤形成:The high-contrast grating vertical cavity surface emitting laser of this embodiment can be formed by the following steps:
提供一基底;该基底可为GaAs基底。A substrate is provided; the substrate can be a GaAs substrate.
在基底上形成第一反射器层1;第一反射器层1可以为DBR。第一反射器层1可包括由AlGaAs和GaAs两种不同折射率的材料层叠构成;基底及第一反射器层1可均为N型或均为P型。该实施例中采用N型。A first reflector layer 1 is formed on the substrate; the first reflector layer 1 may be DBR. The first reflector layer 1 may include two layers of materials with different refractive indices, AlGaAs and GaAs; the substrate and the first reflector layer 1 may be both N-type or P-type. The N-type is used in this embodiment.
在第一反射器层1上形成N型电极接触层7。An N-type electrode contact layer 7 is formed on the first reflector layer 1.
在N型电极接触层7上形成有源层8,在有源层8上形成氧化层2。当然,还可以在N型电极接触层7上形成氧化层2,在氧化层2上形成有源层8。还可以在N型电极接触层7上形成氧化层2,在氧化层2上形成有源层8,在有源层8上再形成一层氧化层2。An active layer 8 is formed on the N-type electrode contact layer 7, and an oxide layer 2 is formed on the active layer 8. Of course, the oxide layer 2 can also be formed on the N-type electrode contact layer 7 and the active layer 8 can be formed on the oxide layer 2. It is also possible to form an oxide layer 2 on the N-type electrode contact layer 7, form an active layer 8 on the oxide layer 2, and form an oxide layer 2 on the active layer 8.
有源层8至少包括层叠设置的多量子阱层,多量子阱层由GaAs、AlGaAs、GaAsP及InGaAs材料层叠排列构成,有源层8用以将电能转换为光能。当然,在某些示例中还可以采用单量子阱层代替多量子阱层。The active layer 8 includes at least a stacked multi-quantum well layer. The multi-quantum well layer is composed of GaAs, AlGaAs, GaAsP and InGaAs materials stacked and arranged, and the active layer 8 is used to convert electrical energy into light energy. Of course, in some examples, a single quantum well layer can also be used instead of a multiple quantum well layer.
相应地,在有源层8或氧化层2上形成电流扩展层9,在电流扩展层9上形成第二反射器层3;形成第二反射器层3是先在电流扩展层9上形成氧化物隔离层31,然后在氧化物隔离层31上形成光栅层32。氧化物隔离层31的材料可以为Al xGa 1-xAs(x>0.9),光栅层32的材料可以为Al yGa 1-yAs(y<0.4)。 Correspondingly, the current spreading layer 9 is formed on the active layer 8 or the oxide layer 2, and the second reflector layer 3 is formed on the current spreading layer 9; The isolation layer 31 is formed, and then a grating layer 32 is formed on the oxide isolation layer 31. The material of the oxide isolation layer 31 may be Al x Ga 1-x As (x>0.9), and the material of the grating layer 32 may be Al y Ga 1-y As (y<0.4).
然后通过刻蚀的方式在光栅层32的部分区域上刻蚀形成栅槽5,栅槽5延伸至氧化物隔离层31。可以通过激光刻蚀或化学刻蚀的方式来刻蚀上述栅槽5。Then, a part of the grating layer 32 is etched to form a gate trench 5 by etching, and the gate trench 5 extends to the oxide isolation layer 31. The above-mentioned gate trench 5 can be etched by laser etching or chemical etching.
随后再刻蚀掉光栅区域之外的光栅层32及氧化物隔离层31,并暴露出电流扩展层9。Then, the grating layer 32 and the oxide isolation layer 31 outside the grating region are etched away, and the current spreading layer 9 is exposed.
之后再进行氧化沟槽10的刻蚀,氧化沟槽10延伸至N型电极接 触层7;Then, the oxidation trench 10 is etched, and the oxidation trench 10 extends to the N-type electrode contact layer 7;
通过湿法氧化工艺在氧化物隔离层31对应于光栅的位置形成第一氧化区域6,作为一种实现方式,第一氧化区域6为上述刻蚀氧化物隔离层31后剩余的部分,在氧化层2内形成自氧化沟槽10向内形成环绕未氧化区域11的第二氧化区域12。The first oxidized region 6 is formed at the position of the oxide isolation layer 31 corresponding to the grating by a wet oxidation process. As an implementation manner, the first oxidized region 6 is the part remaining after the oxide isolation layer 31 is etched. The second oxidized region 12 surrounding the unoxidized region 11 is formed inwardly from the oxidized trench 10 formed in the layer 2.
通过湿法氧化工艺,例如在温度430℃下,2L/min的氮气携带一定温度的水蒸气进行选择性湿法氧化,氧化深度即图中左右方向的延伸深度由时间控制,以在氧化层2形成第二氧化区域12,第二氧化区域12围绕氧化层2中的未氧化区域11,以及在氧化物隔离层31对应于光栅的位置形成第一氧化区域6。Through the wet oxidation process, for example, at a temperature of 430°C, 2L/min of nitrogen carries a certain temperature of water vapor for selective wet oxidation. The oxidation depth, that is, the extension depth in the left and right directions in the figure, is controlled by time, so that the oxide layer 2 A second oxidized region 12 is formed, the second oxidized region 12 surrounds the unoxidized region 11 in the oxide layer 2, and the first oxidized region 6 is formed at a position of the oxide isolation layer 31 corresponding to the grating.
通过化学气相沉积、电镀、溅射、蒸镀等方式在电流扩展层9及N型电极接触层7上形成电极,其中,电流扩展层9上的电极为第一电极13,N型电极接触层7上的电极为第二电极14。Electrodes are formed on the current spreading layer 9 and the N-type electrode contact layer 7 by chemical vapor deposition, electroplating, sputtering, evaporation, etc., wherein the electrode on the current spreading layer 9 is the first electrode 13, and the N-type electrode contact layer The electrode on 7 is the second electrode 14.
如图8所示,作为其中的一种优选方式,第二电极14还可以形成在第一反射器层1背离有源层8的一侧,该第二电极14可以是面状电极,其可以完全覆盖第一反射器层背离有源层8的表面,以提供足够大的电极,降低电阻。As shown in FIG. 8, as a preferred way, the second electrode 14 can also be formed on the side of the first reflector layer 1 away from the active layer 8. The second electrode 14 can be a planar electrode, which can be The surface of the first reflector layer away from the active layer 8 is completely covered to provide a large enough electrode to reduce resistance.
如图9-13所示,作为其中一种可实现方式,第一反射器层1、有源层8和第二反射器层3形成两阶台阶结构,其中,第一反射器层1形成第一个台阶,至少有源层8和第二反射器层3形成第二个台阶;可以理解为第一反射器层1的尺寸大于有源层8和第二反射器层3的尺寸,并且,有源层8和第二反射器层3的尺寸相同。当然,在其他实施例中,第一反射器层1的尺寸小于有源层8和第二反射器层3的尺寸,并且,有源层8和第二反射器层3的尺寸相同。在有源层8上和第二发射器层之间形成有电流扩展层9,电流扩展层9的材料例如但不限于为GaAs。。光栅层32上位于光栅外侧的区域设置有第一电极13。可以通过沉积的方式,例如可以通过化学气相沉积、电镀、溅射、蒸镀等方式在光栅层32上形成第一电极13。As shown in FIGS. 9-13, as one of the achievable ways, the first reflector layer 1, the active layer 8 and the second reflector layer 3 form a two-stage stepped structure, wherein the first reflector layer 1 forms the first For one step, at least the active layer 8 and the second reflector layer 3 form a second step; it can be understood that the size of the first reflector layer 1 is larger than the size of the active layer 8 and the second reflector layer 3, and, The active layer 8 and the second reflector layer 3 have the same size. Of course, in other embodiments, the size of the first reflector layer 1 is smaller than the sizes of the active layer 8 and the second reflector layer 3, and the sizes of the active layer 8 and the second reflector layer 3 are the same. A current spreading layer 9 is formed between the active layer 8 and the second emitter layer. The material of the current spreading layer 9 is, for example, but not limited to, GaAs. . The grating layer 32 is provided with a first electrode 13 in an area outside the grating. The first electrode 13 can be formed on the grating layer 32 by a deposition method, for example, chemical vapor deposition, electroplating, sputtering, evaporation, or the like.
为了对电流进行局限,以提高该高对比度光栅垂直腔面发射激光器的出光效率,在有源层8的至少一侧形成有氧化层2,氧化层2包 括第二氧化区域12和未氧化区域11,第二氧化区域12环绕所述未氧化区域11,未氧化区域11用于界定激光出射窗。该高对比度光栅垂直腔面发射激光器设置多个发光区域的情况下,通过设置氧化层2使得各发光区所流经的电流均匀,因此发光区的亮度一致性高,提高了垂直腔面发射激光器的品质。该第二氧化区域12可以与第一氧化区域6在同一氧化工艺中形成,当然,也可在两个氧化工艺中分别形成。In order to limit the current and improve the light extraction efficiency of the high-contrast grating vertical cavity surface emitting laser, an oxide layer 2 is formed on at least one side of the active layer 8. The oxide layer 2 includes a second oxidized region 12 and an unoxidized region 11 The second oxidized region 12 surrounds the non-oxidized region 11, and the non-oxidized region 11 is used to define the laser exit window. When the high-contrast grating vertical cavity surface emitting laser is provided with multiple light emitting regions, the oxide layer 2 is provided to make the current flowing through each light emitting region uniform, so the brightness uniformity of the light emitting region is high, and the vertical cavity surface emitting laser is improved Quality. The second oxidation region 12 can be formed in the same oxidation process as the first oxidation region 6, of course, it can also be formed in two oxidation processes separately.
该实施例的高对比度光栅垂直腔面发射激光器可以采用以下步骤形成:The high-contrast grating vertical cavity surface emitting laser of this embodiment can be formed by the following steps:
提供一基底;该基底可为GaAs基底。A substrate is provided; the substrate can be a GaAs substrate.
在基底上形成第一反射器层1;第一反射器层1可以为DBR。第一反射器层1可包括由AlGaAs和GaAs两种不同折射率的材料层叠构成;基底及第一反射器层1可均为N型或均为P型。该实施例中采用N型。A first reflector layer 1 is formed on the substrate; the first reflector layer 1 may be DBR. The first reflector layer 1 may include two layers of materials with different refractive indices, AlGaAs and GaAs; the substrate and the first reflector layer 1 may be both N-type or P-type. The N-type is used in this embodiment.
在第一反射器层1上形成N型电极接触层7。An N-type electrode contact layer 7 is formed on the first reflector layer 1.
在N型电极接触层7上形成有源层8,在有源层8上形成氧化层2。当然,还可以在N型电极接触层7上形成氧化层2,在氧化层2上形成有源层8。还可以在N型电极接触层7上形成氧化层2,在氧化层2上形成有源层8,在有源层8上再形成一层氧化层2。An active layer 8 is formed on the N-type electrode contact layer 7, and an oxide layer 2 is formed on the active layer 8. Of course, the oxide layer 2 can also be formed on the N-type electrode contact layer 7 and the active layer 8 can be formed on the oxide layer 2. It is also possible to form an oxide layer 2 on the N-type electrode contact layer 7, form an active layer 8 on the oxide layer 2, and form an oxide layer 2 on the active layer 8.
有源层8至少包括层叠设置的多量子阱层,多量子阱层由GaAs、AlGaAs、GaAsP及InGaAs材料层叠排列构成,有源层8用以将电能转换为光能。当然,在某些示例中还可以采用单量子阱层代替多量子阱层。The active layer 8 includes at least a stacked multi-quantum well layer. The multi-quantum well layer is composed of GaAs, AlGaAs, GaAsP and InGaAs materials stacked and arranged, and the active layer 8 is used to convert electrical energy into light energy. Of course, in some examples, a single quantum well layer can also be used instead of a multiple quantum well layer.
相应地,在有源层8或氧化层2上形成电流扩展层9,在电流扩展层9上形成第二反射器层3;形成第二反射器层3是先在电流扩展层9上形成氧化物隔离层31,然后在氧化物隔离层31上形成光栅层32。氧化物隔离层31的材料可以为Al xGa 1-xAs(x>0.9),光栅层32的材料可以为Al yGa 1-yAs(y<0.4)。 Correspondingly, the current spreading layer 9 is formed on the active layer 8 or the oxide layer 2, and the second reflector layer 3 is formed on the current spreading layer 9; The isolation layer 31 is formed, and then a grating layer 32 is formed on the oxide isolation layer 31. The material of the oxide isolation layer 31 may be Al x Ga 1-x As (x>0.9), and the material of the grating layer 32 may be Al y Ga 1-y As (y<0.4).
然后通过刻蚀的方式在光栅层32的部分区域上刻蚀形成栅槽5,栅槽5延伸至氧化物隔离层31。可以通过激光刻蚀或化学刻蚀的方式来刻蚀上述栅槽5。Then, a part of the grating layer 32 is etched to form a gate trench 5 by etching, and the gate trench 5 extends to the oxide isolation layer 31. The above-mentioned gate trench 5 can be etched by laser etching or chemical etching.
之后进行氧化沟槽10的刻蚀,氧化沟槽10延伸至N型电极接触层7;Afterwards, the oxidation trench 10 is etched, and the oxidation trench 10 extends to the N-type electrode contact layer 7;
通过湿法氧化工艺在氧化物隔离层31对应于光栅的位置形成第一氧化区域6,在氧化层2内形成自氧化沟槽10向内形成环绕未氧化区域11的第二氧化区域12;A first oxidation region 6 is formed at the position of the oxide isolation layer 31 corresponding to the grating by a wet oxidation process, and a self-oxidation trench 10 is formed in the oxidation layer 2 to form a second oxidation region 12 surrounding the unoxidized region 11 inward;
通过化学气相沉积、电镀、溅射、蒸镀等方式在光栅层32及N型电极接触层7上形成电极,其中,光栅层32上的电极为第一电极13,N型电极接触层7上的电极为第二电极14。Electrodes are formed on the grating layer 32 and the N-type electrode contact layer 7 by chemical vapor deposition, electroplating, sputtering, evaporation, etc., wherein the electrode on the grating layer 32 is the first electrode 13, and the N-type electrode contact layer 7 The electrode is the second electrode 14.
如图14所示,作为其中的一种优选方式,第二电极14还可以形成在第一反射器层1背离有源层8的一侧,该第二电极14可以是面状电极,其可以完全覆盖第一反射器层背离有源层8的表面,以提供足够大的电极,降低电阻。As shown in FIG. 14, as a preferred way, the second electrode 14 can also be formed on the side of the first reflector layer 1 away from the active layer 8. The second electrode 14 can be a planar electrode, which can be The surface of the first reflector layer away from the active layer 8 is completely covered to provide a large enough electrode to reduce resistance.
如图15-20所示,作为其中一种可实现方式,第一反射器层1、有源层8和第二反射器层3形成平台结构,可以理解他们三者之间可以是尺寸相等的,不存在台阶结构;有源层8包括质子或离子注入区域17和第一未注入区域18,质子或离子注入区域17环绕第一未注入区域18,第一未注入区域18用于界定激光出射窗。采用此种结构可以不用设置氧化层2,亦不需要进行氧化沟槽10的刻蚀,简化制程工艺,降低加工的复杂程度。As shown in Figures 15-20, as one of the achievable ways, the first reflector layer 1, the active layer 8 and the second reflector layer 3 form a platform structure. It can be understood that the three of them can be of equal size. , There is no step structure; the active layer 8 includes a proton or ion implantation region 17 and a first non-implanted region 18, the proton or ion implantation region 17 surrounds the first non-implanted region 18, the first non-implanted region 18 is used to define the laser emission window. With this structure, the oxide layer 2 is not required, and the etching of the oxide trench 10 is not required, which simplifies the manufacturing process and reduces the complexity of processing.
该实施例的高对比度光栅垂直腔面发射激光器可以采用以下步骤形成:The high-contrast grating vertical cavity surface emitting laser of this embodiment can be formed by the following steps:
提供一基底;该基底可为GaAs基底。A substrate is provided; the substrate can be a GaAs substrate.
在基底上形成第一反射器层1;第一反射器层1可以为DBR。第一反射器层1可包括由AlGaAs和GaAs两种不同折射率的材料层叠构成;基底及第一反射器层1可均为N型或均为P型。该实施例中采用N型。A first reflector layer 1 is formed on the substrate; the first reflector layer 1 may be DBR. The first reflector layer 1 may include two layers of materials with different refractive indices, AlGaAs and GaAs; the substrate and the first reflector layer 1 may be both N-type or P-type. The N-type is used in this embodiment.
在第一反射器层1上形成N型电极接触层7。An N-type electrode contact layer 7 is formed on the first reflector layer 1.
在N型电极接触层7上形成有源层8。An active layer 8 is formed on the N-type electrode contact layer 7.
有源层8至少包括层叠设置的多量子阱层,多量子阱层由GaAs、AlGaAs、GaAsP及InGaAs材料层叠排列构成,有源层8用以将电能 转换为光能。当然,在某些示例中还可以采用单量子阱层代替多量子阱层。The active layer 8 includes at least a stacked multi-quantum well layer composed of GaAs, AlGaAs, GaAsP and InGaAs materials stacked and arranged, and the active layer 8 is used to convert electrical energy into light energy. Of course, in some examples, a single quantum well layer can also be used instead of a multiple quantum well layer.
在有源层8上形成电流扩展层9,在电流扩展层9上形成第二反射器层3;形成第二反射器层3是先在电流扩展层9上形成氧化物隔离层31,然后在氧化物隔离层31上形成光栅层32。氧化物隔离层31的材料可以为Al xGa 1-xAs(x>0.9),光栅层32的材料可以为Al yGa 1-yAs(y<0.4)。 A current spreading layer 9 is formed on the active layer 8, and a second reflector layer 3 is formed on the current spreading layer 9; the second reflector layer 3 is formed by first forming an oxide isolation layer 31 on the current spreading layer 9 and then A grating layer 32 is formed on the oxide isolation layer 31. The material of the oxide isolation layer 31 may be Al x Ga 1-x As (x>0.9), and the material of the grating layer 32 may be Al y Ga 1-y As (y<0.4).
然后通过刻蚀的方式在光栅层32的部分区域上刻蚀形成栅槽5,栅槽5延伸至氧化物隔离层31。可以通过激光刻蚀或化学刻蚀的方式来刻蚀上述栅槽5。Then, a part of the grating layer 32 is etched to form a gate trench 5 by etching, and the gate trench 5 extends to the oxide isolation layer 31. The above-mentioned gate trench 5 can be etched by laser etching or chemical etching.
通过湿法氧化工艺在氧化物隔离层31对应于光栅的位置形成第一氧化区域6;Forming the first oxide region 6 at the position of the oxide isolation layer 31 corresponding to the grating by a wet oxidation process;
在光栅层32上设置光阻15等质子或离子注入工艺的保护结构,通过质子或离子注入工艺,在有源层8形成质子或离子注入区域17和第一未注入区域18,质子或离子注入区域17环绕第一未注入区域18,第一未注入区域18用于界定激光出射窗。第一未注入区域18是质子或离子注入工艺的保护结构覆盖的区域。质子或离子注入工艺的保护结构覆盖的区域主要作用是在质子或离子隔离注入时,对其下方的各层起到保护作用,防止其下的各层在质子或离子隔离注入时被绝缘化。在质子或离子注入工艺结束后去除质子或离子注入工艺的保护结构。A photoresist 15 and other proton or ion implantation process protection structure is provided on the grating layer 32, and the proton or ion implantation process is used to form the proton or ion implantation region 17 and the first non-implantation region 18 in the active layer 8. Proton or ion implantation The area 17 surrounds the first non-injected area 18, and the first non-injected area 18 is used to define the laser exit window. The first non-implanted region 18 is a region covered by the protective structure of the proton or ion implantation process. The main function of the area covered by the protective structure of the proton or ion implantation process is to protect the underlying layers during proton or ion isolation implantation, and prevent the underlying layers from being insulated during the proton or ion isolation implantation. After the proton or ion implantation process is completed, the protective structure of the proton or ion implantation process is removed.
通过化学气相沉积、电镀、溅射、蒸镀等方式在光栅层32上形成第一电极13,在第一反射器层1背离有源层8的一侧形成第二电极14,该第二电极14可以是面状电极,其可以完全覆盖第一反射器层1背离有源层8的表面,以提供足够大的电极,降低电阻。A first electrode 13 is formed on the grating layer 32 by chemical vapor deposition, electroplating, sputtering, evaporation, etc., and a second electrode 14 is formed on the side of the first reflector layer 1 facing away from the active layer 8. 14 can be a planar electrode, which can completely cover the surface of the first reflector layer 1 away from the active layer 8 to provide a sufficiently large electrode and reduce resistance.
进一步地,激光出射窗小于等于第一氧化区域6,以提高激光出射效率,有源层8还包括第二未注入区域16,第二未注入区域16位于氧化物隔离层31与质子或离子注入区域17之间。第二未注入区域16可以作为电流扩展层。为了降低电流扩展层的电阻,在质子或离子注入后,进行退火处理,使质子或离子注入路径上,位于质子或离子 注入区域17之上的各层恢复较好的导电性。Further, the laser exit window is less than or equal to the first oxidized region 6 to improve laser exit efficiency. The active layer 8 also includes a second non-implanted region 16, which is located in the oxide isolation layer 31 and proton or ion implantation. Between area 17. The second uninjected region 16 may serve as a current spreading layer. In order to reduce the resistance of the current spreading layer, annealing is performed after the proton or ion implantation, so that the layers on the proton or ion implantation path and above the proton or ion implantation region 17 restore better conductivity.
进一步地,氧化物隔离层31的厚度小于λ/6,以降低材料的使用量及制造难度。其中,λ为所述高对比度光栅垂直腔面发射激光器所发射激光的波长。Further, the thickness of the oxide isolation layer 31 is less than λ/6, so as to reduce the amount of material used and the difficulty of manufacturing. Wherein, λ is the wavelength of the laser light emitted by the high-contrast grating vertical cavity surface emitting laser.
本发明实施例还提供一种上述高对比度光栅垂直腔面发射激光器的制造方法,包括:The embodiment of the present invention also provides a method for manufacturing the above-mentioned high-contrast grating vertical cavity surface emitting laser, which includes:
依次形成层叠设置的第一反射器层1、有源层8及第二反射器层3;The first reflector layer 1, the active layer 8 and the second reflector layer 3 are formed in sequence;
所述第二反射器层3的形成方法包括:The method for forming the second reflector layer 3 includes:
依次形成氧化物隔离层31和光栅层32,所述氧化物隔离层31位于所述光栅层32和所述有源层8之间;An oxide isolation layer 31 and a grating layer 32 are sequentially formed, and the oxide isolation layer 31 is located between the grating layer 32 and the active layer 8;
对所述光栅层32的至少部分区域进行栅槽5的刻蚀,以形成所述光栅,所述栅槽5延伸至所述氧化物隔离层31;Etching at least a part of the grating layer 32 to the grating groove 5 to form the grating, and the grating groove 5 extends to the oxide isolation layer 31;
透过所述栅槽5对所述氧化物隔离层31进行湿法氧化工艺,形成正对所述光栅的第一氧化区域6,所述第一氧化区域6的折射率小于所述光栅的折射率。The oxide isolation layer 31 is subjected to a wet oxidation process through the gate groove 5 to form a first oxide region 6 facing the grating. The refractive index of the first oxide region 6 is smaller than that of the grating. Rate.
该方法是上述高对比度光栅垂直腔面发射激光器对应的制作方法,其原理及效果参见上述实施例的描述,这里不再赘述。This method is a manufacturing method corresponding to the above-mentioned high-contrast grating vertical cavity surface emitting laser. For its principle and effect, please refer to the description of the above-mentioned embodiment, which will not be repeated here.
进一步地,在所述第一反射器层1朝向所述有源层8的一侧形成电极接触层;Further, an electrode contact layer is formed on the side of the first reflector layer 1 facing the active layer 8;
至少在所述有源层8的一侧形成氧化层2;Forming an oxide layer 2 on at least one side of the active layer 8;
在所述氧化物隔离层31背离所述光栅层32的一侧形成电流扩展层9;Forming a current spreading layer 9 on the side of the oxide isolation layer 31 away from the grating layer 32;
去除所述光栅所对区域以外的所述光栅层32及所述光栅所对区域以外的所述氧化物隔离层31;Removing the grating layer 32 other than the region opposed by the grating and the oxide isolation layer 31 other than the region opposed by the grating;
形成氧化沟槽10,所述氧化沟槽10至少自所述第二反射器层3延伸至所述电极接触层;Forming an oxidation trench 10, which extends at least from the second reflector layer 3 to the electrode contact layer;
在所述氧化沟槽10内通过所述湿法氧化工艺,使所述氧化层2自所述氧化沟槽10向内形成环绕所述未氧化区域11的所述第二氧化区域12;In the oxidation trench 10 through the wet oxidation process, the oxide layer 2 forms the second oxidation region 12 surrounding the unoxidized region 11 from the oxidation trench 10 inward;
在电极接触层及电流扩展层9形成电极。Electrodes are formed on the electrode contact layer and the current spreading layer 9.
进一步地,在所述第一反射器层1朝向所述有源层8的一侧形成电极接触层;Further, an electrode contact layer is formed on the side of the first reflector layer 1 facing the active layer 8;
至少在所述有源层8的一侧形成氧化层2;Forming an oxide layer 2 on at least one side of the active layer 8;
在所述氧化物隔离层31背离所述光栅层32的一侧形成电流扩展层9;Forming a current spreading layer 9 on the side of the oxide isolation layer 31 away from the grating layer 32;
形成氧化沟槽10,所述氧化沟槽10至少自所述第二反射器层3延伸至所述电极接触层;Forming an oxidation trench 10, which extends at least from the second reflector layer 3 to the electrode contact layer;
在所述氧化沟槽10内通过所述湿法氧化工艺,使所述氧化层2自所述氧化沟槽10向内形成环绕所述未氧化区域11的所述第二氧化区域12;Through the wet oxidation process in the oxide trench 10, the oxide layer 2 forms the second oxide region 12 surrounding the unoxidized region 11 from the oxide trench 10 inward;
在电极接触层及光栅层32形成电极。Electrodes are formed on the electrode contact layer and the grating layer 32.
进一步地,通过质子或离子注入工艺,在所述有源层8形成质子或离子注入区域17和第一未注入区域18,所述质子或离子注入区域17环绕所述第一未注入区域18,所述第一未注入区域18用于界定激光出射窗。Further, a proton or ion implantation region 17 and a first non-implanted region 18 are formed in the active layer 8 through a proton or ion implantation process, and the proton or ion implantation region 17 surrounds the first non-implanted region 18, The first non-injected region 18 is used to define a laser exit window.
需要理解的是,上文如有涉及术语“中心”、“纵向”、“横向”、“上”、“下”、“前”、“后”、“左”、“右”、“竖直”、“水平”、“顶”、“底”、“内”、“外”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本实用新型和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本实用新型的限制。此外,术语“第一”、“第二”仅用于描述目的,而不能理解为指示或暗示相对重要性或者隐含指明所指示的技术特征的数量。由此,限定有“第一”、“第二”的特征可以明示或者隐含地包括一个或者更多个该特征。在本实用新型的描述中,除非另有说明,“多个”的含义是两个或两个以上。It should be understood that if the terms "center", "vertical", "horizontal", "upper", "lower", "front", "rear", "left", "right", "vertical" are involved in the above "," "horizontal", "top", "bottom", "inner", "outer" and other directions or positional relations are based on the directions or positional relations shown in the drawings, only for the convenience of describing the utility model and simplifying The description does not indicate or imply that the pointed device or element must have a specific orientation, be constructed and operated in a specific orientation, and therefore cannot be understood as a limitation of the present invention. In addition, the terms "first" and "second" are only used for descriptive purposes, and cannot be understood as indicating or implying relative importance or implicitly indicating the number of indicated technical features. Thus, the features defined with "first" and "second" may explicitly or implicitly include one or more of these features. In the description of the present invention, unless otherwise specified, "multiple" means two or more.
以上描述仅为本申请的较佳实施例以及对所运用技术原理的说明。本领域技术人员应当理解,本申请中所涉及的发明范围,并不限于上述技术特征的特定组合而成的技术方案,同时也应涵盖在不脱离发明构思的情况下,由上述技术特征或其等同特征进行任意组合而形成的 其它技术方案。例如上述特征与本申请中公开的(但不限于)具有类似功能的技术特征进行互相替换而形成的技术方案。The above description is only a preferred embodiment of the present application and an explanation of the applied technical principles. Those skilled in the art should understand that the scope of the invention involved in this application is not limited to the technical solutions formed by the specific combination of the above technical features, and should also cover the above technical features or their technical solutions without departing from the inventive concept. Other technical solutions formed by arbitrarily combining equivalent features. For example, the above-mentioned features and the technical features disclosed in this application (but not limited to) with similar functions are mutually replaced to form a technical solution.

Claims (11)

  1. 一种高对比度光栅垂直腔面发射激光器,其特征在于,包括:A high-contrast grating vertical cavity surface emitting laser, which is characterized in that it comprises:
    层叠设置的第一反射器层、有源层及第二反射器层;A first reflector layer, an active layer, and a second reflector layer that are stacked;
    所述第二反射器层包括氧化物隔离层和光栅层,所述氧化物隔离层位于所述光栅层和所述有源层之间,所述光栅层至少部分区域设置有光栅,所述光栅的栅槽延伸至所述氧化物隔离层,所述氧化物隔离层设置有第一氧化区域,所述第一氧化区域支撑所述光栅,所述第一氧化区域的折射率小于所述光栅的折射率。The second reflector layer includes an oxide isolation layer and a grating layer, the oxide isolation layer is located between the grating layer and the active layer, at least a part of the grating layer is provided with a grating, and the grating The gate trenches of the second oxide layer extend to the oxide isolation layer, the oxide isolation layer is provided with a first oxide region, the first oxide region supports the grating, and the refractive index of the first oxide region is smaller than that of the grating Refractive index.
  2. 根据权利要求1所述的高对比度光栅垂直腔面发射激光器,其特征在于,所述第一反射器层、所述有源层和所述第二反射器层形成三阶台阶结构;The high-contrast grating vertical cavity surface emitting laser according to claim 1, wherein the first reflector layer, the active layer, and the second reflector layer form a three-stage stepped structure;
    所述有源层上形成有电流扩展层,所述电流扩展层上形成有第一电极,所述第一电极位于台阶位置处。A current spreading layer is formed on the active layer, a first electrode is formed on the current spreading layer, and the first electrode is located at a step position.
  3. 根据权利要求1所述的高对比度光栅垂直腔面发射激光器,其特征在于,所述第一反射器层、所述有源层和所述第二反射器层形成两阶台阶结构,其中,所述第一反射器层形成第一个台阶,至少所述有源层和所述第二反射器层形成第二个台阶;The high-contrast grating vertical cavity surface emitting laser according to claim 1, wherein the first reflector layer, the active layer and the second reflector layer form a two-stage stepped structure, wherein the The first reflector layer forms a first step, and at least the active layer and the second reflector layer form a second step;
    所述光栅层上位于所述光栅外侧的区域设置有第一电极。A first electrode is provided on the grating layer in an area outside the grating.
  4. 根据权利要求2或3所述的高对比度光栅垂直腔面发射激光器,其特征在于,所述有源层的至少一侧形成有氧化层,所述氧化层包括第二氧化区域和未氧化区域,所述第二氧化区域环绕所述未氧化区域,所述未氧化区域用于界定激光出射窗。The high-contrast grating vertical cavity surface emitting laser according to claim 2 or 3, wherein an oxide layer is formed on at least one side of the active layer, and the oxide layer includes a second oxidized region and an unoxidized region, The second oxidized area surrounds the non-oxidized area, and the non-oxidized area is used to define a laser exit window.
  5. 根据权利要求1所述的高对比度光栅垂直腔面发射激光器,其特征在于,所述第一反射器层、所述有源层和所述第二反射器层形成平台结构;The high-contrast grating vertical cavity surface emitting laser according to claim 1, wherein the first reflector layer, the active layer and the second reflector layer form a platform structure;
    所述有源层包括质子或离子注入区域和第一未注入区域,所述质子或离子注入区域环绕所述第一未注入区域,所述第一未注入区域用于界定激光出射窗。The active layer includes a proton or ion implantation region and a first non-implantation region, the proton or ion implantation region surrounds the first non-implantation region, and the first non-implantation region is used to define a laser exit window.
  6. 根据权利要求5所述的高对比度光栅垂直腔面发射激光器,其特征在于,所述激光出射窗小于等于所述第一氧化区域,所述有源层还包括第二未注入区域,所述第二未注入区域位于所述氧化物隔离层与所述质子或离子注入区域之间。The high-contrast grating vertical cavity surface emitting laser of claim 5, wherein the laser exit window is less than or equal to the first oxidized region, the active layer further includes a second uninjected region, and the first Two non-implanted regions are located between the oxide isolation layer and the proton or ion implanted region.
  7. 根据权利要求1-3、5-6任一项所述的高对比度光栅垂直腔面发射激光器,其特征在于,所述氧化物隔离层的厚度小于λ/6,其中,λ为所述高对比度光栅垂直腔面发射激光器所发射激光的波长。The high-contrast grating vertical cavity surface emitting laser according to any one of claims 1-3 and 5-6, wherein the thickness of the oxide isolation layer is less than λ/6, where λ is the high contrast The wavelength of the laser light emitted by the grating vertical cavity surface emitting laser.
  8. 一种权利要求1-7任一项所述的高对比度光栅垂直腔面发射激光器的制造方法,其特征在于,包括:A method for manufacturing a high-contrast grating vertical cavity surface emitting laser according to any one of claims 1-7, characterized in that it comprises:
    依次形成层叠设置的第一反射器层、有源层及第二反射器层;Sequentially forming a first reflector layer, an active layer, and a second reflector layer that are stacked;
    所述第二反射器层的形成方法包括:The method for forming the second reflector layer includes:
    依次形成氧化物隔离层和光栅层,所述氧化物隔离层位于所述光栅层和所述有源层之间;Sequentially forming an oxide isolation layer and a grating layer, the oxide isolation layer being located between the grating layer and the active layer;
    对所述光栅层的至少部分区域进行栅槽的刻蚀,以形成所述光栅,所述栅槽延伸至所述氧化物隔离层;Etching at least a part of the grating layer to form a grating groove, and the grating groove extends to the oxide isolation layer;
    透过所述栅槽对所述氧化物隔离层进行湿法氧化工艺,形成正对所述光栅的第一氧化区域,所述第一氧化区域的折射率小于所述光栅的折射率。A wet oxidation process is performed on the oxide isolation layer through the gate groove to form a first oxidation region facing the grating, and the refractive index of the first oxidation region is smaller than the refractive index of the grating.
  9. 根据权利要求8所述的制造方法,其特征在于,在所述第一反射器层朝向所述有源层的一侧形成电极接触层;8. The manufacturing method according to claim 8, wherein an electrode contact layer is formed on the side of the first reflector layer facing the active layer;
    至少在所述有源层的一侧形成氧化层;Forming an oxide layer on at least one side of the active layer;
    在所述氧化物隔离层背离所述光栅层的一侧形成电流扩展层;Forming a current spreading layer on the side of the oxide isolation layer away from the grating layer;
    去除所述光栅所对区域以外的所述光栅层及所述光栅所对区域以 外的所述氧化物隔离层;Removing the grating layer outside of the region opposed by the grating and the oxide isolation layer outside the region opposed by the grating;
    形成氧化沟槽,所述氧化沟槽至少自所述第二反射器层延伸至所述电极接触层;Forming an oxidation trench, the oxidation trench at least extending from the second reflector layer to the electrode contact layer;
    在所述氧化沟槽内通过所述湿法氧化工艺,使所述氧化层自所述氧化沟槽向内形成环绕所述未氧化区域的所述第二氧化区域;Using the wet oxidation process in the oxidation trench to make the oxide layer form the second oxidation region surrounding the non-oxidized region inwardly from the oxidation trench;
    在电极接触层及电流扩展层形成电极。An electrode is formed on the electrode contact layer and the current spreading layer.
  10. 根据权利要求8所述的制造方法,其特征在于,在所述第一反射器层朝向所述有源层的一侧形成电极接触层;8. The manufacturing method according to claim 8, wherein an electrode contact layer is formed on the side of the first reflector layer facing the active layer;
    至少在所述有源层的一侧形成氧化层;Forming an oxide layer on at least one side of the active layer;
    在所述氧化物隔离层背离所述光栅层的一侧形成电流扩展层;Forming a current spreading layer on the side of the oxide isolation layer away from the grating layer;
    形成氧化沟槽,所述氧化沟槽至少自所述第二反射器层延伸至所述电极接触层;Forming an oxidation trench, the oxidation trench at least extending from the second reflector layer to the electrode contact layer;
    在所述氧化沟槽内通过所述湿法氧化工艺,使所述氧化层自所述氧化沟槽向内形成环绕所述未氧化区域的所述第二氧化区域;Using the wet oxidation process in the oxidation trench to make the oxide layer form the second oxidation region surrounding the non-oxidized region inwardly from the oxidation trench;
    在电极接触层及光栅层形成电极。An electrode is formed on the electrode contact layer and the grating layer.
  11. 根据权利要求8所述的制造方法,其特征在于,通过质子或离子注入工艺,在所述有源层形成质子或离子注入区域和第一未注入区域,所述质子或离子注入区域环绕所述第一未注入区域,所述第一未注入区域用于界定激光出射窗。The manufacturing method according to claim 8, wherein a proton or ion implantation region and a first non-implanted region are formed in the active layer by a proton or ion implantation process, and the proton or ion implantation region surrounds the The first non-injected region is used to define the laser exit window.
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