WO2021047424A1 - 玻璃盖板的制作方法、玻璃盖板及移动终端 - Google Patents

玻璃盖板的制作方法、玻璃盖板及移动终端 Download PDF

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Publication number
WO2021047424A1
WO2021047424A1 PCT/CN2020/112874 CN2020112874W WO2021047424A1 WO 2021047424 A1 WO2021047424 A1 WO 2021047424A1 CN 2020112874 W CN2020112874 W CN 2020112874W WO 2021047424 A1 WO2021047424 A1 WO 2021047424A1
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Prior art keywords
glass cover
cover plate
glass substrate
manufacturing
bent side
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PCT/CN2020/112874
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English (en)
French (fr)
Inventor
李�杰
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Oppo广东移动通信有限公司
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Publication of WO2021047424A1 publication Critical patent/WO2021047424A1/zh

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    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/0035Multiple processes, e.g. applying a further resist layer on an already in a previously step, processed pattern or textured surface
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/20Exposure; Apparatus therefor
    • G03F7/2051Exposure without an original mask, e.g. using a programmed deflection of a point source, by scanning, by drawing with a light beam, using an addressed light or corpuscular source
    • G03F7/2053Exposure without an original mask, e.g. using a programmed deflection of a point source, by scanning, by drawing with a light beam, using an addressed light or corpuscular source using a laser
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/70Microphotolithographic exposure; Apparatus therefor
    • G03F7/70383Direct write, i.e. pattern is written directly without the use of a mask by one or multiple beams

Definitions

  • This application relates to the technical field of electronic products, and in particular to a manufacturing method of a glass cover, a glass cover manufactured by the manufacturing method of the glass cover, and a mobile terminal using the glass cover.
  • the glass substrates used in the screens of mobile terminals have gradually transitioned from 2D and 2.5D to 3D.
  • they have developed to 3D glass substrates with large bending angles.
  • the related mask exposure and development process can no longer be fully adapted.
  • the straightness of the border edge is significantly reduced and the jaggedness is obvious. Enhancement, serious decline in product quality.
  • the main purpose of this application is to provide a method for manufacturing a glass cover plate, a glass cover plate manufactured by the method for manufacturing a glass cover plate, and a mobile terminal using the glass cover plate, aiming to reduce 3D glass with large bending angles
  • the serrations on the edge of the frame after the substrate is colored to improve the straightness of the edge, thereby improving the quality of the product.
  • An embodiment of the present application proposes a method for manufacturing a glass cover plate, which includes the following steps:
  • the glass substrate Preparing a glass substrate, the glass substrate including a main body and a bent side edge provided on the outer periphery of the main body;
  • Laser exposure processing is performed on the inner surface edge of the bent side of the pre-exposed glass substrate to obtain a pre-developed glass substrate;
  • the pre-developed glass substrate is subjected to development processing to obtain a glass cover plate.
  • An embodiment of the present application also provides a glass cover plate applied to an electronic device.
  • the glass cover plate includes a body and a bent side provided on the outer edge of the body.
  • the body and the bent side The bending angle is at least 60° and not more than 110°, and the inner surface edge of the bent side has a developing part.
  • An embodiment of the present application also provides a mobile terminal, the mobile terminal includes a glass cover, the glass cover includes a body and a bent side provided on the outer edge of the body, the body and the bent
  • the bending angle of the folded side edge is at least 60° and not more than 110°, and the inner surface edge of the folded side edge has a developing part.
  • the method of laser exposure processing is adopted when the photosensitive material is exposed.
  • This method directly uses the laser spot to irradiate the photosensitive material to achieve the purpose of exposure. Due to the small diameter of the laser spot and excellent directivity, the frame edge of the 3D glass cover plate made by laser exposure processing can have fewer saw teeth and high straightness.
  • the technical solution of the present application guarantees high quality such as low-tooth saw and high straightness, while the bending angle of the 3D glass cover can reach 60° ⁇ 110°, and it can be bent on both sides or on four sides. Bending can achieve the purpose of reducing the jagged edges of the frame edge after coloring the 3D glass substrate with a large bending angle, improving the straightness of the edge, and improving the quality of the product.
  • this cannot be achieved by the related mask plate exposure and development process. The specific reasons are as follows: in the related technology, the mask plate exposure and development process is adopted, and the mask plate covering is a necessary technical link.
  • the mask plate is Flat, it cannot be close enough to the large surface of the 3D glass substrate with a large bending angle (60° ⁇ 110°), and the exposure gap is too large, which cannot meet the requirements of the mask exposure and development process to achieve less jaggedness and high straightness Degree of exposure gap requirements; that is, under the condition of a large bending angle of the 3D glass substrate, if the mask exposure and development process is used, the exposure gap will be too large, resulting in a decrease in light accuracy and a decrease in exposure accuracy, resulting in 3D
  • the edge of the frame edge of the glass cover is increased by sawtooth and the straightness is decreased.
  • the technical solution of the present application due to the small diameter of the laser spot and excellent directivity, the exposure accuracy can be effectively improved, which overcomes the fact that the mask can only be exposed under the condition of low exposure gap and cannot be applied to large bending angles.
  • the defects of the 3D glass substrate realize the coloring of the 3D glass substrate with a large bending angle, which solves the pain points in the industry, and lays the foundation for the design of a larger bending angle for the 3D glass cover to facilitate mobile terminals Get a higher screen-to-body ratio.
  • FIG. 1 is a schematic flowchart of an exemplary embodiment of a method for manufacturing a glass cover plate according to the present application
  • FIG. 2 is a schematic flowchart of another exemplary embodiment of a method for manufacturing a glass cover plate according to the present application.
  • FIG. 1 is a schematic flowchart of an exemplary embodiment of a method for manufacturing a glass cover plate of the present application.
  • the manufacturing method of the glass cover plate includes the following steps:
  • S10 preparing a glass substrate, that is, performing pre-spraying treatment on the glass substrate, the glass substrate including a body and a bent side edge provided on the outer edge of the body;
  • the cleaning temperature can be set to 50°C ⁇ 2°C, the cleaning time is 9min ⁇ 1min, and the working current of the ultrasonic generator is set to 1.6A ⁇ 0.2A to reduce the glass substrate while achieving efficient cleaning.
  • the cleaning agent used in the ultrasonic cleaning line is an alkaline cleaning agent, which can better remove impurities such as oil on the surface of the glass substrate; and the ultrasonic cleaning line is an automatic cleaning line with slow pull dehydration function , Can further avoid the formation of water marks when the surface of the glass substrate is dehydrated. In this way, a glass substrate with a clean surface can be obtained, thereby facilitating the adhesion of the photosensitive material during the spraying process, so as to reduce the probability of surface defects during the formation of the photosensitive material layer and improve the yield rate. Moreover, such a treatment process makes the surface of the glass substrate not easy to be scratched, and also provides a good guarantee for outputting high-quality products.
  • the toughened 3D glass substrate with a large bending angle in this step includes a main body and a bending side provided on the outer edge of the main body, and the bending angle between the main body and the bending side is at least 60° and Not more than 110°.
  • the glass substrate obtained in the previous step is assembled into an aluminum alloy spraying tool, and the inner surface of the glass substrate is sprayed with photosensitive material, and then the glass substrate with the photosensitive material layer is pre-baked.
  • the drying temperature can be set to 100° ⁇ 2°C, and the drying time is 300s ⁇ 30s. In this way, the dryness of the photosensitive material layer surface of the pre-exposed glass substrate can be guaranteed, which is beneficial to subsequent laser exposure processing, and it can also effectively avoid the occurrence of defects such as sand holes, particles, orange peel and the like on the surface of the photosensitive material layer, and improve product quality.
  • the photosensitive material can be either a photosensitive ink or a photosensitive photoresist, and the color of the photosensitive photoresist can be any of black, white, green, and red.
  • the water drop angle on the surface of the glass substrate does not exceed 20°. In this way, the adhesion level of the surface of the glass substrate can be effectively improved, thereby providing excellent prerequisites for the subsequent spraying treatment process of the photosensitive material, improving the adhesion stability of the photosensitive material layer, and thereby improving the product quality.
  • the sprayed film thickness of the spraying treatment is at least 1.6 ⁇ m and not more than 2.0 ⁇ m. Controlling the sprayed film thickness within the range of 1.6 ⁇ m ⁇ 2.0 ⁇ m can effectively improve the adhesion stability of the photosensitive material layer, avoiding its wanton flow, thereby effectively ensuring the uniformity of the thickness of the photosensitive material layer, and avoiding localization of the photosensitive material layer Reunion, light leakage, etc., provide good prerequisites for subsequent processes and improve product yield.
  • the pre-exposed glass substrate obtained in the previous step is sent to the laser direct writing exposure machine and placed on the exposure plane, and then the inner surface of the bent side of the pre-exposed glass substrate is aligned according to the preset frame pattern.
  • the photosensitive material layer at the edge is exposed to light.
  • a charge-coupled device (CCD) optical system can be used to perform edge-grabbing and positioning compensation on the pre-exposed glass substrate, and exposure can be performed after the position compensation is passed. In this way, the exposure can be further improved. Accuracy, improve product quality.
  • CCD charge-coupled device
  • the exposure energy of the laser exposure treatment is at least 78 MJ and not more than 82 MJ. In this way, sufficient exposure of the photosensitive material layer can be achieved, thereby facilitating the development process to obtain a frame with high straightness and less jaggedness.
  • the exposure height of the laser exposure process is at least 1.4 mm and not more than 1.6 mm.
  • the exposure height of the laser exposure process is controlled within the range of 1.4mm ⁇ 1.6mm, which not only can effectively guarantee the directionality of the laser spot and the good accuracy of the laser exposure process, but also can spray the film according to the bending angle of the 3D glass substrate Thickness and other actual conditions are flexible and reasonable to choose the specific exposure height, so that the straightness and jaggedness of the border edge of the product can be maintained at a high level.
  • Both the foreground depth and the back depth of field of the exposure depth of field of the laser exposure processing do not exceed 300 ⁇ m. In this way, even when the sprayed film thickness fluctuates within a relatively large range due to tolerances, the photosensitive material layer can still be well exposed to avoid adverse reactions such as undeveloped and over-developed photosensitive material layers during subsequent development processing, thereby ensuring the production
  • the edge of the frame of the product is high in straightness and less jagged, which effectively guarantees the quality of the product.
  • the exposure accuracy of the laser exposure processing does not exceed 20 ⁇ m. In this way, the jagged edges of the frame edge of the developed product can be effectively controlled, and its straightness can be improved.
  • the pre-developed glass substrate obtained in the previous step is put into a flat-plate developing and washing line in a single piece for development processing.
  • the developing temperature can be set to 27°C ⁇ 2°C
  • the developing speed is 5M/min ⁇ 0.2M/min
  • the developing pressure is 1Kg/cm2 ⁇ 0.05Kg/cm2.
  • the glass cover plate obtained in the previous step is put into a dust-free oven for curing treatment.
  • the curing temperature can be set to 220°C ⁇ 2°C, and the curing time is 30min ⁇ 0.5min, so that the frame of the glass cover can be completely cured and the reliability of the product can be improved.
  • the method of laser exposure processing is adopted when the photosensitive material is exposed.
  • This method directly uses the laser spot to irradiate the photosensitive material to achieve the purpose of exposure. Due to the small diameter of the laser spot and excellent directivity, the frame edge of the 3D glass cover plate made by laser exposure processing can have fewer saw teeth and high straightness.
  • the technical solution of the present application guarantees high quality such as low-tooth saw and high straightness, while the bending angle of the 3D glass cover can reach 60° ⁇ 110°, and it can be bent on both sides or on four sides. Bending can achieve the purpose of reducing the jagged edges of the frame edge after coloring the 3D glass substrate with a large bending angle, improving the straightness of the edge, and improving the quality of the product.
  • this cannot be achieved by the related mask plate exposure and development process. The specific reasons are as follows: in the related technology, the mask plate exposure and development process is adopted, and the mask plate covering is a necessary technical link.
  • the mask plate is Flat, it cannot be close enough to the large surface of the 3D glass substrate with a large bending angle (60° ⁇ 110°), and the exposure gap is too large, which cannot meet the requirements of the mask exposure and development process to achieve less jaggedness and high straightness Degree of exposure gap requirements; that is, under the condition of a large bending angle of the 3D glass substrate, if the mask exposure and development process is used, the exposure gap will be too large, resulting in a decrease in light accuracy and a decrease in exposure accuracy, resulting in 3D
  • the edge of the frame edge of the glass cover is increased by sawtooth and the straightness is decreased.
  • the technical solution of the present application due to the small diameter of the laser spot and excellent directivity, the exposure accuracy can be effectively improved, which overcomes the fact that the mask can only be exposed under the condition of low exposure gap and cannot be applied to large bending angles.
  • the defects of the 3D glass substrate realize the coloring of the 3D glass substrate with a large bending angle, which solves the pain points in the industry, and lays the foundation for the design of a larger bending angle for the 3D glass cover to facilitate mobile terminals Get a higher screen-to-body ratio.
  • FIG. 2 is a schematic flowchart of another exemplary embodiment of a method for manufacturing a glass cover plate according to the present application.
  • the method further includes:
  • the inner edge of the exposure area in the next laser exposure process is shifted out by at least 0.2 mm from the inner edge of the exposure area in the previous laser exposure process. Due to the problem of exposure accuracy, the second exposure position cannot completely coincide with the first exposure, so it needs to be expanded by at least 0.2mm, so that the straightness of the window area frame is completely determined by the first exposure, which can effectively ensure the accuracy of the frame straight line.
  • the present application also proposes a glass cover plate, which is manufactured by the manufacturing method of the glass cover plate as described above, and the specific process of the glass cover plate manufacturing method is detailed in the foregoing embodiment. Since the present glass cover adopts all the technical solutions of all the foregoing embodiments, it has at least all the effects brought about by all the technical solutions of all the foregoing embodiments, which will not be repeated here.
  • the glass cover includes a main body and a bent side provided on the outer periphery of the main body, and the bending angle between the main body and the bent side is at least 60° and not more than 110°, and the bent side is at least 60° and not more than 110°.
  • the edge of the inner surface of the folded side has a developing part.
  • the bent sides include a first bent side and a second bent side that are arranged in parallel. That is, the form of a curved glass cover plate that is bent on both sides.
  • the bent side edge further includes a third bent side edge and a fourth bent side edge arranged in parallel, the first bent side edge and the second bent side edge
  • the side, the third bending side, and the fourth bending side are surrounded by the main body. That is, it is in the form of a curved glass cover plate that is bent on all sides.
  • the width of the developing part is at least 2.5 mm and not more than 5 mm;
  • the thickness of the developing portion is at least 1.6 ⁇ m and not more than 2.0 ⁇ m.
  • the developing part may be a flat closed-loop structure to form the “frame” in the foregoing content.
  • This application also proposes a mobile terminal, which includes the glass cover as described above, and the specific structure of the glass cover is detailed in the foregoing embodiment. Since the mobile terminal adopts all the technical solutions of all the foregoing embodiments, it has at least all the effects brought about by all the technical solutions of all the foregoing embodiments, which will not be repeated here.
  • mobile terminals can be, but are not limited to, mobile phones, tablets, personal digital assistants (Personal Digital Assistant, PDA), e-book readers, MP3 (moving picture experts compressed standard audio level 3, Moving Picture Experts) Group Audio Layer III) players, MP4 (Moving Picture Experts Group Audio Layer IV) players, laptops, car computers, set-top boxes, smart TVs, wearable devices, navigators, handhelds Game consoles, etc.
  • PDA Personal Digital Assistant
  • MP3 moving picture experts compressed standard audio level 3, Moving Picture Experts) Group Audio Layer III
  • MP4 Motion Picture Experts Group Audio Layer IV

Abstract

一种玻璃盖板的制作方法、由玻璃盖板的制作方法制作得到的玻璃盖板及应用玻璃盖板的移动终端。玻璃盖板的制作方法包括以下步骤:准备玻璃基板,玻璃基板包括本体和设于本体外缘的弯折侧边;对玻璃基板的内表面进行感光材料的喷涂处理和预烘干处理,得到预曝光玻璃基板;对预曝光玻璃基板的弯折侧边的内表面边缘进行激光曝光处理,得到预显影玻璃基板;对预显影玻璃基板进行显影处理,得到玻璃盖板。

Description

玻璃盖板的制作方法、玻璃盖板及移动终端
本申请要求于2019年9月12日提交中国专利局、申请号为201910869798.6、发明名称为“玻璃盖板的制作方法、玻璃盖板及移动终端”的中国专利申请的优先权,其全部内容通过引用结合在本申请中。
技术领域
本申请涉及电子产品技术领域,特别涉及一种玻璃盖板的制作方法、由该玻璃盖板的制作方法制作得到的玻璃盖板及应用该玻璃盖板的移动终端。
背景技术
随着柔性显示面板在移动终端上的应用,移动终端的屏幕所使用的玻璃基板也从2D、2.5D逐步过渡到3D,近年来更是向大折弯角度的3D玻璃基板发展。但是,对于大折弯角度的3D玻璃基板而言,由于折弯角度的增大,相关的掩膜版曝光显影工艺已经无法完全适应,其上色后,边框边缘的直线度明显降低、锯齿明显增强,产品质量下降严重。
技术解决方案
本申请的主要目的是提供一种玻璃盖板的制作方法、由该玻璃盖板的制作方法制作得到的玻璃盖板及应用该玻璃盖板的移动终端,旨在减弱大折弯角度的3D玻璃基板上色后边框边缘的锯齿,提高边缘直线度,从而提升产品质量。
本申请的一实施例提出一种玻璃盖板的制作方法,包括以下步骤:
准备玻璃基板,所述玻璃基板包括本体和设于所述本体外缘的弯折侧边;
对所述玻璃基板的内表面进行感光材料的喷涂处理和预烘干处理,得到预曝光玻璃基板;
对所述预曝光玻璃基板的弯折侧边的内表面边缘进行激光曝光处理,得到预显影玻璃基板;
对所述预显影玻璃基板进行显影处理,得到玻璃盖板。
本申请的一实施例还提出一种玻璃盖板,应用于电子设备,所述玻璃盖板包括本体和设于所述本体外缘的弯折侧边,所述本体与所述弯折侧边的折弯角度至少是60°且不超过110°,所述弯折侧边的内表面边缘具有显影部。
本申请的一实施例还提出一种移动终端,所述移动终端包括玻璃盖板,所述玻璃盖板包括本体和设于所述本体外缘的弯折侧边,所述本体与所述弯折侧边的折弯角度至少是60°且不超过110°,所述弯折侧边的内表面边缘具有显影部。
本申请的技术方案,在对感光材料进行曝光处理时采用的是激光曝光处理的方式,该方式直接利用激光光斑对感光材料进行照射,以达到曝光的目的。由于激光光斑的直径小、方向性优异,可使得由激光曝光处理做出的3D玻璃盖板的边框边缘齿锯少、直线度高。
并且,本申请的技术方案,在保障少齿锯、高直线度等高品质的同时,3D玻璃盖板的折弯角度还可达到60°~110°,而且既可以是两边弯曲也可以是四边弯曲,即可实现减弱大折弯角度的3D玻璃基板上色后边框边缘的锯齿、提高边缘直线度、提升产品质量的目的。而这却是相关掩膜版曝光显影工艺无法实现的,具体理由如下:相关技术中由于采用的是掩膜版曝光显影工艺,掩膜版遮盖是必要的技术环节,但是,由于掩膜版为平板状,其与大折弯角度(60°~110°)的3D玻璃基板的大面是无法足够贴近的,曝光间隙过大,从而无法满足掩膜版曝光显影工艺能实现少锯齿、高直线度的曝光间隙要求;即,在大折弯角度的3D玻璃基板条件下,若要采用掩膜版曝光显影工艺,则会由于曝光间隙过大,导致光线精度下降、曝光精度下降,从而导致3D玻璃盖板的边框边缘锯齿增强、直线度下降。而本申请的技术方案,由于激光光斑的直径小、方向性优异,曝光精度得以有效提高,从而克服了掩膜版只能在低曝光间隙情况下曝光、无法较好的应用于大折弯角度的3D玻璃基板的缺陷,实现了对大折弯角度的3D玻璃基板的上色,解决了行业内的痛点,为3D玻璃盖板设计出更大的折弯角度奠定了基础,以便于移动终端获得更高的屏占比。
附图说明
为了更清楚地说明本申请实施例或现有技术中的技术方案,下面将对实施例或现有技术描述中所需要使用的附图作简单地介绍,显而易见地,下面描述中的附图仅仅是本申请的一些实施例,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图变换得到其他附图。
图1为本申请玻璃盖板的制作方法一示例性实施例的流程示意图;
图2为本申请玻璃盖板的制作方法另一示例性实施例的流程示意图。
本申请目的的实现、功能特点及优点将结合实施例,参照附图做进一步说明。
本发明的实施方式
下面将结合本申请实施例中的附图,对本申请实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本申请的一部分实施例,而不是全部的实施例。基于本申请中的实施例,本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其他实施例,都属于本申请保护的范围。
请参阅图1,图1为本申请玻璃盖板的制作方法一示例性实施例的流程示意图。该实施例中,玻璃盖板的制作方法包括以下步骤:
S10,准备玻璃基板,即对玻璃基板进行喷涂前处理,所述玻璃基板包括本体和设于所述本体外缘的弯折侧边;
具体地,将钢化后的大折弯角度的3D玻璃基板插入清洗篮中,并将其与清洗篮一同送入超声波清洗线中进行清洗处理和烘干处理,清洗处理和烘干处理的具体流程如下:1、超声波粗洗;→2、超声波精洗;→3、喷淋漂洗;→4、超声波漂洗;→5、超声波漂洗;→6、超声波漂洗;→7、超声波漂洗;→8、慢拉脱水;→9、热风烘干。可以理解的,步骤1至步骤7为清洗处理,步骤8至步骤9为烘干处理。清洗处理时,可设定清洗温度为50℃±2℃、清洗时间为9min±1min,并设定超声波发生器的工作电流为1.6A±0.2A,以在实现高效清洗的同时,降低玻璃基板表面灰尘、油污等杂质的附着水平;之后,烘干处理时,可设定烘干温度为100℃±2℃,以在实现高效烘干的同时,减少玻璃基板表面形成的水痕。此外,需要说明的是,超声波清洗线中所使用的清洗剂为碱性清洗剂,可以更好地去除玻璃基板表面的油污等杂质;并且,超声波清洗线是带慢拉脱水功能的自动清洗线,可进一步避免玻璃基板表面脱水时形成水痕。这样,便可得到表面洁净的玻璃基板,从而有利于喷涂处理时感光材料的附着,以降低感光材料层形成时表面缺陷产生的几率,提高良品率。并且,这样的处理过程,玻璃基板的表面不易划伤,也为输出高质量产品提供了良好的保障。
另外,该步骤中的钢化后的大折弯角度的3D玻璃基板包括本体和设于本体外缘的弯折侧边,所述本体与所述弯折侧边的折弯角度至少是60°且不超过110°。
S20,对所述玻璃基板的内表面进行感光材料的喷涂处理和预烘干处理,得到预曝光玻璃基板;
具体地,将前一步骤中得到的玻璃基板装配至铝合金喷涂工装中,并对玻璃基板的内表面进行感光材料的喷涂处理,之后,对附着有感光材料层的玻璃基板进行预烘干处理,以使感光材料层凝固。其中,烘干处理时,可设定烘干温度为100°±2℃,烘干时间300s±30s。这样,既可保障预曝光玻璃基板的感光材料层表面的干燥度,有利于后续激光曝光处理,而且还可有效避免感光材料层表面砂眼、颗粒、橘皮等不良的出现,提升产品质量。需要说明的是,感光材料既可选择感光油墨,也可选择感光光阻,并且,感光光阻的颜色可为黑色、白色、绿色、红色中任意一种。
需要说明的是,所述玻璃基板的表面水滴角不超过20°。如此,可有效提高玻璃基板表面的附着力水平,从而为后续感光材料的喷涂处理工艺过程提供优异的先决条件,提升感光材料层的附着稳定性,进而使得产品质量得以提升。
并且,所述喷涂处理的喷涂膜厚至少是1.6μm且不超过2.0μm。将喷涂膜厚控制1.6μm~2.0μm的范围内,可有效提升感光材料层的附着稳定性,避免其发生肆意流淌的情况,从而有效确保感光材料层的厚度均匀一致,避免感光材料层出现局部团聚、漏光等情况,进而为后续工序提供良好的先决条件,提升产品良品率。
S30,对所述预曝光玻璃基板的弯折侧边的内表面边缘进行激光曝光处理,得到预显影玻璃基板;
具体地,将前一步骤中得到的预曝光玻璃基板送入激光直写曝光机中,并置于曝光平面上,之后按照预设的边框图案对预曝光玻璃基板的弯折侧边的内表面边缘的感光材料层进行曝光处理。需要说明的是,激光曝光处理前可利用电荷耦合元件(Charge-coupled Device,CCD)光学系统对预曝光玻璃基板进行抓边定位补偿,待位置补偿通过后方可进行曝光,如此,可进一步提升曝光精度,提升产品质量。
需要说明的是,所述激光曝光处理的曝光能量至少是78MJ且不超过82MJ。如此,可实现对感光材料层的充分曝光,从而有利于显影处理而得到直线度高、锯齿少的边框。
所述激光曝光处理的曝光高度至少是1.4mm且不超过1.6mm。将激光曝光处理的曝光高度控制在1.4mm~1.6mm的范围内,不仅可有效保障激光光斑的方向性,保障激光曝光处理的良好精度,而且还可根据3D玻璃基板的折弯角度、喷涂膜厚等实际情况灵活、合理地选择具体的曝光高度,从而使得做出的产品的边框边缘的直线度、锯齿情况等参数维持在较高水平。
所述激光曝光处理的曝光景深的前景深和后景深均不超过300μm。这样,即便喷涂膜厚因公差影响在较大范围内波动时,感光材料层依然能够得到良好的曝光,避免感光材料层在后续显影处理时出现显影不掉、过显等不良反应,从而保障做出的产品的边框边缘直线度高,锯齿少,有效保障产品的质量。
所述激光曝光处理的曝光精度不超过20μm。如此,可有效控制显影后产品的边框边缘的锯齿,提升其直线度。
S40,对所述预显影玻璃基板进行显影处理,得到玻璃盖板;
具体地,将前一步骤中得到的预显影玻璃基板以单片的形式放入平板式显影清洗线中进行显影处理。此时,可设定显影温度为27℃±2℃,显影速度为5M/min±0.2M/min,显影压力1Kg/cm2±0.05Kg/cm2。如此,可确保感光材料层网格尺寸良好,无显影不掉、过显等不良,并且可保障显影后形成的边框无砂眼、颗粒、橘皮、锯齿等不良,保障显影后形成的边框边缘直线度高,从而有利于提升玻璃盖板质量。需要说明的是,显影后的产品利用纯水清洗并利用风刀吹干,以保证产品品质。
S50,对玻璃盖板进行显影后处理。
具体地,将前一步骤中得到的玻璃盖板放入无尘烤箱中进行固烤处理。此时,可设定固烤温度为220℃±2℃,固烤时间为30min±0.5min,以使玻璃盖板的边框完全固化,提升产品的可靠性。
本申请的技术方案,在对感光材料进行曝光处理时采用的是激光曝光处理的方式,该方式直接利用激光光斑对感光材料进行照射,以达到曝光的目的。由于激光光斑的直径小、方向性优异,可使得由激光曝光处理做出的3D玻璃盖板的边框边缘齿锯少、直线度高。
并且,本申请的技术方案,在保障少齿锯、高直线度等高品质的同时,3D玻璃盖板的折弯角度还可达到60°~110°,而且既可以是两边弯曲也可以是四边弯曲,即可实现减弱大折弯角度的3D玻璃基板上色后边框边缘的锯齿、提高边缘直线度、提升产品质量的目的。而这却是相关掩膜版曝光显影工艺无法实现的,具体理由如下:相关技术中由于采用的是掩膜版曝光显影工艺,掩膜版遮盖是必要的技术环节,但是,由于掩膜版为平板状,其与大折弯角度(60°~110°)的3D玻璃基板的大面是无法足够贴近的,曝光间隙过大,从而无法满足掩膜版曝光显影工艺能实现少锯齿、高直线度的曝光间隙要求;即,在大折弯角度的3D玻璃基板条件下,若要采用掩膜版曝光显影工艺,则会由于曝光间隙过大,导致光线精度下降、曝光精度下降,从而导致3D玻璃盖板的边框边缘锯齿增强、直线度下降。而本申请的技术方案,由于激光光斑的直径小、方向性优异,曝光精度得以有效提高,从而克服了掩膜版只能在低曝光间隙情况下曝光、无法较好的应用于大折弯角度的3D玻璃基板的缺陷,实现了对大折弯角度的3D玻璃基板的上色,解决了行业内的痛点,为3D玻璃盖板设计出更大的折弯角度奠定了基础,以便于移动终端获得更高的屏占比。
请参阅图2,图2为本申请玻璃盖板的制作方法另一示例性实施例的流程示意图。该实施例中,所述“对所述预显影玻璃基板进行显影处理,得到玻璃盖板”的步骤之后,还包括:
S40a,对所述玻璃盖板的内表面进行感光材料的喷涂处理和预烘干处理,得到预曝光玻璃盖板;
S40b,对所述预曝光玻璃盖板的弯折侧边的内表面边缘进行激光曝光处理,得到预显影玻璃盖板;
S40c,对所述预显影玻璃盖板进行显影处理,得到二次上色的玻璃盖板。
喷涂处理、预烘干处理、激光曝光处理、显影处理等的具体工艺过程及参数设定可参看前述实施例做相似处理,在此不再一一赘述。
本实施例中,在对玻璃盖板进行显影后处理之后,又进行了一次“喷涂处理→预烘干处理→激光曝光处理→显影处理”的工艺流程,这样,可进一步避免只进行一次喷涂处理时感光材料层表面出现砂眼、漏光、光密度(Optical Density,OD)值不达标(低于5)等不良,从而进一步提升产品质量和良品率。
进一步地,在后一次激光曝光处理的曝光区域的内侧边缘比在前一次激光曝光处理的曝光区域的内侧边缘外移至少0.2mm。由于曝光精度的问题,第二次曝光位置不可能和第一次完全重合,所以需要外扩至少0.2mm,这样视窗区边框直线度完全由第一次曝光决定,能够有效保证边框直线的精度。
本申请还提出一种玻璃盖板,该玻璃盖板由如前所述的玻璃盖板的制作方法制作得到,该玻璃盖板的制作方法的具体流程详见前述实施例。由于本玻璃盖板采用了前述所有实施例的全部技术方案,因此至少具有前述所有实施例的全部技术方案所带来的所有效果,在此不再一一赘述。其中,所述玻璃盖板包括本体和设于所述本体外缘的弯折侧边,所述本体与所述弯折侧边的折弯角度至少是60°且不超过110°,所述弯折侧边的内表面边缘具有显影部。
在本申请玻璃盖板一实施例中,所述弯折侧边包括平行设置的第一弯折侧边和第二弯折侧边。即,两面弯折的曲面玻璃盖板的形式。
在本申请玻璃盖板一实施例中,所述弯折侧边还包括平行设置的第三弯折侧边与第四弯折侧边,所述第一弯折侧边、所述二弯折侧边、所述第三弯折侧边、所述第四弯折侧边围设于所述本体。即,四面弯折的曲面玻璃盖板的形式。
在本申请玻璃盖板一实施例中,所述显影部宽度至少是2.5mm且不超过5mm;
在本申请玻璃盖板一实施例中,所述显影部厚度至少是1.6μm且不超过2.0μm。
需要说明的是,显影部具体可呈扁平的闭环结构,以构成前述内容中的“边框”。
本申请还提出一种移动终端,该移动终端包括如前所述的玻璃盖板,该玻璃盖板的具体结构详见前述实施例。由于本移动终端采用了前述所有实施例的全部技术方案,因此至少具有前述所有实施例的全部技术方案所带来的所有效果,在此不再一一赘述。
可以理解的,移动终端可以是但并不限于手机、平板电脑、个人数字助理(Personal Digital Assistant,PDA)、电子书阅读器、MP3(动态影像专家压缩标准音频层面3,Moving Picture Experts Group Audio Layer III)播放器、MP4(动态影像专家压缩标准音频层面4,Moving Picture Experts Group Audio Layer IV)播放器、笔记本电脑、车载电脑、机顶盒、智能电视机、可穿戴设备、导航仪、掌上游戏机等。
以上所述仅为本申请的可选实施例,并非因此限制本申请的专利范围,凡是在本申请的发明构思下,利用本申请说明书及附图内容所作的等效变换,或直接/间接运用在其他相关的技术领域均包括在本申请的专利保护范围内。

Claims (16)

  1. 一种玻璃盖板的制作方法,其中,包括以下步骤:
    准备玻璃基板,所述玻璃基板包括本体和设于所述本体外缘的弯折侧边;
    对所述玻璃基板的内表面进行感光材料的喷涂处理和预烘干处理,得到预曝光玻璃基板;
    对所述预曝光玻璃基板的弯折侧边的内表面边缘进行激光曝光处理,得到预显影玻璃基板;以及
    对所述预显影玻璃基板进行显影处理,得到玻璃盖板。
  2. 如权利要求1所述的制作方法,其中,所述玻璃基板的表面水滴角不超过20°。
  3. 如权利要求1所述的制作方法,其中,所述喷涂处理的喷涂膜厚至少是1.6μm且不超过2.0μm。
  4. 如权利要求1所述的制作方法,其中,所述激光曝光处理的曝光能量至少是78MJ且不超过82MJ。
  5. 如权利要求1所述的制作方法,其中,所述激光曝光处理的曝光高度至少是1.4mm且不超过1.6mm。
  6. 如权利要求1所述的制作方法,其中,所述激光曝光处理的曝光景深的前景深和后景深均不超过300μm。
  7. 如权利要求1所述的制作方法,其中,所述激光曝光处理的曝光精度不超过20μm。
  8. 如权利要求1至7中任一项所述的制作方法,其中,在所述“对所述预曝光玻璃基板的弯折侧边的内表面边缘进行激光曝光处理,得到预显影玻璃基板”的步骤之前,还包括:
    对所述预曝光玻璃基板进行抓边定位补偿。
  9. 如权利要求1至7中任一项所述的制作方法,其中,在所述“对所述预显影玻璃基板进行显影处理,得到玻璃盖板”的步骤之后,还包括:
    对玻璃盖板进行显影后处理:将玻璃盖板放入无尘烤箱中进行固烤处理。
  10. 如权利要求1至7中任一项所述的制作方法,其中,所述“对所述预显影玻璃基板进行显影处理,得到玻璃盖板”的步骤之后,还包括:
    对所述玻璃盖板的内表面进行感光材料的喷涂处理和预烘干处理,得到预曝光玻璃盖板;
    对所述预曝光玻璃盖板的弯折侧边的内表面边缘进行激光曝光处理,得到预显影玻璃盖板;以及
    对所述预显影玻璃盖板进行显影处理,得到二次上色的玻璃盖板。
  11. 如权利要求10所述的制作方法,其中,在后一次激光曝光处理的曝光区域的内侧边缘比在前一次激光曝光处理的曝光区域的内侧边缘外移至少0.2mm。
  12. 一种玻璃盖板,应用于电子设备,其中,所述玻璃盖板包括本体和设于所述本体外缘的弯折侧边,所述本体与所述弯折侧边的折弯角度至少是60°且不超过110°,所述弯折侧边的内表面边缘具有显影部。
  13. 如权利要求12所述的玻璃盖板,其中,所述弯折侧边包括平行设置的第一弯折侧边和第二弯折侧边。
  14. 如权利要求13所述的玻璃盖板,其中,所述弯折侧边还包括平行设置的第三弯折侧边与第四弯折侧边,所述第一弯折侧边、所述二弯折侧边、所述第三弯折侧边、所述第四弯折侧边围设于所述本体。
  15. 如权利要求12至14中任一项所述的玻璃盖板,其中,所述显影部宽度至少是2.5mm且不超过5mm;
    且/或,所述显影部厚度至少是1.6μm且不超过2.0μm。
  16. 一种移动终端,其中,包括如权利要求12至15中任一项所述的玻璃盖板。
PCT/CN2020/112874 2019-09-12 2020-09-01 玻璃盖板的制作方法、玻璃盖板及移动终端 WO2021047424A1 (zh)

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