WO2020149342A1 - 方向性電磁鋼板 - Google Patents
方向性電磁鋼板 Download PDFInfo
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- WO2020149342A1 WO2020149342A1 PCT/JP2020/001183 JP2020001183W WO2020149342A1 WO 2020149342 A1 WO2020149342 A1 WO 2020149342A1 JP 2020001183 W JP2020001183 W JP 2020001183W WO 2020149342 A1 WO2020149342 A1 WO 2020149342A1
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Definitions
- the present invention relates to a grain-oriented electrical steel sheet used as an iron core material of a transformer, and more particularly to a grain-oriented electrical steel sheet with a tension insulating coating having excellent adhesion of the tension insulating coating.
- the present application claims priority based on Japanese Patent Application No. 2019-005475 filed in Japan on January 16, 2019, the contents of which are incorporated herein by reference.
- Oriented electrical steel sheets are mainly used for transformers. Since the transformer is continuously energized for a long period of time from installation to disposal and energy loss continues to occur, the energy loss when magnetized by alternating current, that is, iron loss, is a major factor that determines the performance of the transformer. It will be an index.
- the forsterite-based coating having excellent coating adhesion which is generated by the reaction between the oxide on the surface of the steel sheet and the annealing separating agent in the finish annealing step of the electromagnetic steel sheet, is a coating capable of imparting tension to the steel sheet.
- Patent Document 1 in which a coating liquid containing colloidal silica and phosphate as a main component is baked on the surface of a steel sheet to form an insulating film has a large effect of applying tension, and thus reduces iron loss.
- This is an effective method. Therefore, a general method for producing a grain-oriented electrical steel sheet is to leave the forsterite coating formed in the finish annealing step and to apply an insulating coating containing phosphate mainly on the forsterite coating.
- the forsterite coating hinders the movement of the domain wall and adversely affects iron loss.
- the magnetic domain changes as the domain wall moves under an alternating magnetic field.
- the smooth and quick movement of the domain wall is effective in reducing iron loss, but the forsterite coating has an uneven structure at the steel plate/coating interface, and this uneven structure prevents the movement of the domain wall. Therefore, iron loss is adversely affected.
- Patent Documents 2 to 5 the atmosphere dew point of decarburization annealing is controlled, and alumina is used as an annealing separator to smooth the surface of a base steel sheet without forming a forsterite coating film by finish annealing.
- the technology is disclosed.
- Patent Document 6 discloses a method of forming a tension insulating film after forming an amorphous oxide film on the surface of a base steel sheet.
- Patent Documents 7 to 11 disclose techniques for controlling the structure of an amorphous oxide film for the purpose of forming a tension insulating film having higher adhesiveness.
- the surface of the grain-oriented electrical steel sheet obtained by smoothing the surface of the base steel sheet is subjected to a pretreatment for introducing fine irregularities, and then an external oxidation type oxide is formed to form an external oxide film.
- This is a method of ensuring the adhesion between the tensile insulating coating and the base steel sheet by having a structure having a granular outer oxide mainly composed of silica in a form penetrating the film thickness.
- the method described in Patent Document 8 has a heating rate of 10° C. in a heating range of 200° C. or more and 1150° C. or less. /Sec or more and 500°C/sec or less, and by controlling the cross-sectional area ratio of the metal oxide such as iron, aluminum, titanium, manganese, and chromium in the external oxide film to 50% or less, the tension insulating coating and the mother film are formed. This is a method of ensuring adhesion with the material steel plate.
- an outer oxidation type oxide film is formed on a grain-oriented electrical steel sheet having a base material steel sheet surface smoothed, and a steel sheet with an outer oxidation type oxide film and a tension insulation coating are formed in a subsequent tension insulation coating forming step.
- heat treatment for forming an external oxidation type oxide film on a grain-oriented electrical steel sheet having a base material steel sheet surface smoothed is performed at a temperature of 1000° C. or higher, and the external oxidation type oxide film is formed at a temperature of 200° C.
- the cooling rate in the temperature range up to 100° C./sec or less and setting the cavities in the external oxidation type oxide film to 30% or less in terms of cross-sectional area ratio the adhesion between the tension insulating coating and the base steel sheet is improved. It is a way to secure.
- Patent Document 11 has a heat treatment temperature of 600° C. or higher and 1150° C. or lower and an atmospheric dew point of ⁇ 20° C. or higher in a heat treatment step of forming an external oxidation type oxide film on a grain-oriented electrical steel sheet having a base material steel sheet surface smoothed.
- Metallic iron having a cross-sectional area ratio of 5% or more and 30% or less in the external oxidation type oxide film, which is annealed under the condition of 0°C or less and the dew point of the cooling atmosphere at that time is 5°C or more and 60°C or less.
- the expected iron loss reduction effect may not be sufficiently exhibited.
- the present invention has been made in view of the current state of the art, and removes the forsterite-based coating, or intentionally prevents the generation of forsterite to eliminate the forsterite-based coating on the surface of the base steel sheet.
- the objective is to improve the adhesion between the tension insulating coating and the base material steel sheet, and to significantly reduce iron loss.
- the purpose is to provide.
- the present inventors diligently studied a method for solving the above problems.
- the glossiness (Gs20) at an incident angle of 20 degrees measured according to JIS Z 8741 should be 2.0 or more and 70.0 or less in both the parallel rolling direction and the vertical rolling direction. As a result, it was found that sufficient adhesion of the tension insulating coating was obtained and iron loss was significantly reduced.
- a grain-oriented electrical steel sheet is formed of a base material steel sheet, an amorphous oxide coating formed on the base material steel sheet, and the amorphous oxide coating. And a tension insulating coating, wherein the base material steel sheet has a chemical composition in mass% of C: 0.085% or less, Si: 0.80 to 7.00%, Mn: 1.50% or less, Acid-soluble Al: 0.065% or less, S: 0.013% or less, Cu: 0 to 0.80%, N: 0 to 0.012%, P: 0 to 0.50%, Ni: 0 to 1 0.000%, Sn:0 to 0.30%, Sb:0 to 0.30%, the balance consisting of Fe and impurities, and the surface gloss Gs20(A) in the direction parallel to the rolling direction is 2 The surface glossiness Gs20(B) in the direction perpendicular to the rolling direction is 2.0 to 70.0.
- the base steel sheet may contain Cu: 0.01 to 0.80% by mass% as the chemical composition.
- the base steel sheet has a chemical composition of N: 0.001 to 0.012% and P: 0. 010 to 0.50%, Ni: 0.010 to 1.00%, Sn: 0.010 to 0.30%, and Sb: 0.010 to 0.30%, containing one or more kinds. You may.
- the grain-oriented electrical steel sheet with a tension insulating coating of the present invention includes a base material steel sheet, an amorphous oxide coating formed on the base material steel sheet, and an amorphous material.
- a tension insulating coating formed on the oxide coating, and the base steel sheet has a chemical composition of C: 0.085% or less by mass%, Si: 0.80 to 7.00%, Mn: 1.50% or less, acid-soluble Al: 0.065% or less, S: 0.013% or less, Cu: 0 to 0.80%, N: 0 to 0.012%, P: 0 to 0.
- the glossiness Gs20(A) is 2.0 to 70.0
- the surface glossiness Gs20(B) in the direction perpendicular to the rolling direction is 2.0 to 70.0.
- the numerical range represented by “to” means the range including the numerical values before and after “to” as the lower limit value and the upper limit value.
- the term “process” is used not only as an independent process, but also in the case where the intended purpose of the process is achieved even when it cannot be clearly distinguished from other processes. included. Further, it is obvious that each element of the following embodiments can be combined with each other.
- the grain-oriented electrical steel sheet obtained by removing the forsterite-based coating or intentionally preventing the generation of forsterite and producing a forsterite-based coating-free steel sheet surface coated with a tension insulating coating.
- the interface between the steel sheet surface and the tension insulating coating is required. It was thought that it is important to make the morphology of the amorphous oxide formed on the surface of the amorphous oxide that contributes to the adhesion layer uniform and flat, and to form the tension insulating film uniformly and flat on the amorphous oxide film. ..
- the present inventors examined a method for evaluating the uniformity and flatness of the amorphous oxide coating and the tension insulating coating, and determined the glossiness of the grain-oriented electrical steel sheet surface (that is, the surface of the tension insulating coating). It was found that if used, the uniformity and flatness of the amorphous oxide film and the tension insulating film can be evaluated.
- the present inventors conducted the following experiment to investigate the relationship between the core loss of the grain-oriented electrical steel sheet with a tension insulating coating and the glossiness of the grain-oriented electrical steel sheet surface.
- a decarburized annealed plate having a plate thickness of 0.23 mm is coated with an annealing separator mainly composed of alumina, subjected to finish annealing, and secondarily recrystallized so that a forsterite coating is not formed.
- a grain-oriented electrical steel sheet was prepared. This steel sheet is subjected to heat treatment in an atmosphere of nitrogen 25%, hydrogen 75%, dew point -30°C to 5°C for a soaking time of 10 seconds to form an amorphous oxide film mainly composed of silica on the surface of the steel sheet. did.
- a coating liquid containing phosphate, chromic acid, and colloidal silica as a main component was applied to this steel plate by a grooved coating roll having a groove width of 1.27 mm and a groove depth of 0.90 mm, and the mixture was mixed with nitrogen and hydrogen in a mixed atmosphere.
- a tension insulating coating was formed by heat treatment under the conditions of an oxygen partial pressure (P H2O 2 /P H2 ) of 0.01 to 0.45 at a temperature of 850° C. and a soaking time of 30 seconds.
- the glossiness of the surface of this grain-oriented electrical steel sheet with a tension insulating coating was measured by a method defined in JIS Z 8741 (a black glass standard plate (refractive index 1.567) at an incident angle of 20°, a value (Gs20) of 100).
- Gs20 measured in the direction parallel to the rolling direction may be referred to as Gs20(A)
- Gs20 measured in the direction perpendicular to the rolling direction may be referred to as Gs20(B).
- FIG. 1 shows the relationship between the gloss in the rolling parallel direction (direction parallel to the rolling direction) (Gs20(A)) and the iron loss
- FIG. 2 shows the gloss in the rolling vertical direction (direction perpendicular to the rolling direction) (Gs20(A)).
- B)) and iron loss is shown. From FIG. 1 and FIG. 2, the conditions under which good iron loss of the grain-oriented electrical steel sheet with a tension insulating coating can be ensured are expressed as follows.
- the glossiness (Gs20(A) and Gs20(B)) measured from the surface of the tensile insulating coating in this grain-oriented electrical steel sheet is specified to be 2 or more. It is preferably 15 or more.
- the grain-oriented electrical steel sheet according to the present embodiment includes a base steel sheet. First, the composition of the base steel sheet will be described. Hereinafter,% related to the component composition is “mass %”.
- C is an element effective in controlling the primary recrystallization structure, but is an element that increases iron loss by magnetic aging. Therefore, it is necessary to reduce the C content to less than 0.010% by decarburizing annealing before finish annealing. If the C content exceeds 0.085%, it takes a long time for decarburization annealing and the productivity decreases, so the C content is set to 0.085% or less. It is preferably 0.070% or less, more preferably 0.050% or less. The lower limit is not particularly limited, but is preferably 0.050% or more from the viewpoint of stably controlling the primary recrystallization structure.
- Si 0.80 to 7.00% Si is an element that increases the electric resistance of the steel sheet and reduces the iron loss. If the Si content is less than 0.80%, the effect of containing Si cannot be sufficiently obtained. Further, a phase transformation occurs during the secondary recrystallization annealing, the secondary recrystallization cannot be controlled accurately, the crystal orientation is impaired, and the magnetic properties deteriorate. Therefore, the Si content is 0.80% or more. It is preferably 2.50% or more, more preferably 3.00% or more.
- the Si content is 7.00% or less. It is preferably 4.00% or less, more preferably 3.75% or less.
- Mn 1.50% or less If the Mn content exceeds 1.50%, phase transformation occurs during secondary recrystallization annealing, and good magnetic flux density cannot be obtained. Therefore, the Mn content is set to 1.50% or less. It is preferably 1.20% or less, more preferably 0.90% or less.
- Mn is an austenite formation promoting element and is an element that contributes to the reduction of iron loss by increasing the specific resistance of the steel sheet. If the Mn content is less than 0.01%, the effect of containing Mn is not sufficiently obtained, and the steel sheet becomes brittle during hot rolling. Therefore, the Mn content is preferably 0.01% or more. It is more preferably at least 0.05%, still more preferably at least 0.10%.
- Acid-soluble Al 0.065% or less
- the acid-soluble Al content is 0.065% or less. It is preferably 0.055% or less, more preferably 0.045% or less.
- the Al content may be 0%.
- acid-soluble Al is an element that combines with N to form (Al,Si)N that functions as an inhibitor. Therefore, if the acid-soluble Al is less than 0.010% in the slab used for production, a sufficient amount of (Al,Si)N is not formed, and secondary recrystallization is not stable. Therefore, the acid-soluble Al in the slab used for production is preferably 0.010% or more, and this Al may remain in the steel sheet.
- the content of acid-soluble Al in the slab is more preferably 0.002% or more, and even more preferably 0.030% or more.
- S 0.013% or less If the S content exceeds 0.013%, the precipitation dispersion of MnS becomes non-uniform, the required secondary recrystallization structure cannot be obtained, and the magnetic flux density decreases. Therefore, S is 0.013% or less. It is preferably 0.012% or less, more preferably 0.011% or less.
- S is an element that combines with Mn to form MnS that functions as an inhibitor. Therefore, the S content in the slab used for production is preferably 0.003% or more, and this S may remain in the steel sheet. The S content in the slab used for production is more preferably 0.005% or more, still more preferably 0.008% or more.
- the base material steel sheet according to the present embodiment includes (a) Cu: 0.01 to 0.80%, and/or (b) N:0, in addition to the above elements, in order to improve various characteristics, in addition to the above elements.
- Cu 0 to 0.80%
- Cu is an element that combines with S to form a precipitate that functions as an inhibitor. If the Cu content is less than 0.01%, the effect is not sufficiently exhibited, so Cu is preferably 0.01% or more. It is more preferably 0.04% or more.
- the Cu content exceeds 0.80%, the dispersion of precipitates becomes non-uniform and the iron loss reducing effect is saturated, so the Cu content is preferably 0.80% or less. It is more preferably 0.60% or less.
- N 0 to 0.0120% N is an element that combines with Al to form AlN that functions as an inhibitor.
- the N content is less than 0.001%, the formation of AlN will be insufficient, so the N content is preferably 0.001% or more. More preferably, it is 0.006% or more.
- N is also an element that forms blisters (holes) in the steel sheet during cold rolling. If the N content exceeds 0.0120%, blisters (holes) may be generated in the steel sheet during cold rolling, so the N content is preferably 0.012% or less. It is more preferably 0.009% or less.
- P 0 to 0.50%
- P is an element that increases the specific resistance of the steel sheet and contributes to the reduction of iron loss. From the viewpoint of reliably obtaining the effect of inclusion, the P content is preferably 0.010% or more. On the other hand, if P exceeds 0.50%, the rolling property deteriorates. Therefore, the P content is preferably 0.50% or less. It is more preferably 0.35% or less.
- the lower limit includes 0%, but if P is reduced to less than 0.0005%, the manufacturing cost increases significantly. Therefore, 0.0005% is the practical lower limit for practical steel sheets.
- Ni is an element that increases the specific resistance of the steel sheet, contributes to the reduction of iron loss, controls the metallographic structure of the hot rolled steel sheet, and contributes to the improvement of the magnetic properties.
- the lower limit includes 0%
- the Ni content is preferably 0.010% or more from the viewpoint of reliably obtaining the effect of including Ni.
- the Ni content is preferably 1.00% or less. It is more preferably 0.35% or less.
- Sn 0 to 0.30%
- Sb 0 to 0.30%
- Sn and Sb segregate at the grain boundaries
- Al is oxidized by the moisture released by the annealing separator during finish annealing (this oxidation causes different inhibitor strengths at the coil position and changes in magnetic properties).
- It is an element that acts to prevent.
- the lower limit includes 0%
- the content of any element is preferably 0.010% or more from the viewpoint of reliably obtaining the effect of inclusion.
- both Sn and Sb are preferably 0.30% or less. More preferably, each element is 0.25% or less.
- the balance of the base steel sheet according to the present embodiment excluding the above elements is Fe and impurities.
- Impurities are elements that are inevitably mixed in from the steel raw material and/or in the steelmaking process and do not impair the characteristics of the electrical steel sheet according to this embodiment.
- the above components may be measured by a general steel analysis method.
- the steel composition may be measured using ICP-AES (Inductively Coupled Plasma-Atomic Emission Spectrometry).
- the acid-soluble Al may be measured by ICP-AES using the filtrate obtained by thermally decomposing the sample with acid.
- C and S may be measured by a combustion-infrared absorption method, and N may be measured by an inert gas melting-thermal conductivity method.
- the grain-oriented electrical steel sheet according to the present embodiment includes an amorphous oxide coating film on the above base material steel sheet.
- the amorphous oxide film is a film made of only substantially amorphous oxide. Whether or not the coating film has an oxide can be confirmed using TEM or FT-IR.
- Amorphous here is a solid in which atoms and molecules do not form a regular spatial lattice, but have a disordered arrangement. Specifically, when X-ray diffraction is performed, only a halo is detected and a specific peak is not detected.
- an external oxidation type film is preferable rather than an internal oxidation type film.
- the internal oxidation type amorphous oxide film is a film in which a part of the amorphous oxide is recessed at the interface between the steel sheet and the amorphous oxide, and the depth and depth of the recessed portion are the same.
- the aspect ratio expressed as a ratio to the length of the bottom of the insertion part is 1.2 or more
- the external oxidation type amorphous oxide film is a film having an aspect ratio of less than 1.2.
- the grain-oriented electrical steel sheet according to the present embodiment includes a tension insulating coating on the above amorphous oxide coating.
- the tension insulating coating is a glassy insulating coating formed by applying a solution mainly containing phosphate and colloidal silica (SiO 2 ) and baking the solution. With this tension insulating coating, a high surface tension can be applied to the base steel sheet.
- a slab having the required components which is melted and cast by a normal method, is used.
- the component composition of the slab according to this embodiment (the slab of the present invention) will be described.
- C is an element that significantly deteriorates iron loss characteristics due to magnetic aging. If it exceeds 0.085%, C remains even after decarburization annealing and deteriorates the iron loss characteristics, so C is set to 0.085% or less. The smaller the content of C is, the more preferable it is for the iron loss characteristics. However, since the detection limit is about 0.0001%, 0.0001% is the practical lower limit. From the viewpoint of improving iron loss characteristics, C is preferably 0.010% or less, and more preferably 0.005% or less.
- Si 0.80 to 7.00% Si is an element that contributes to the improvement of magnetic properties. If it is less than 0.80%, the steel undergoes phase transformation during secondary recrystallization annealing, secondary recrystallization cannot be controlled, and good magnetic flux density and iron loss characteristics cannot be obtained. 80% or more. It is preferably 2.50% or more, more preferably 3.00% or more.
- Si is set to 7.00% or less. It is preferably 4.00% or less, more preferably 3.75% or less.
- Mn 0.01 to 1.50%
- Mn is an austenite forming element. If it is less than 0.01%, the effect of addition is not sufficiently obtained, and the steel sheet becomes brittle during hot rolling, so Mn is made 0.01% or more. It is preferably 0.05% or more, more preferably 0.10% or more.
- Mn is made 1.50% or less. It is preferably 0.70% or less, more preferably 0.50% or less.
- Al 0.0008 to 0.065% Al is an element that forms AlN that functions as an inhibitor and contributes to the improvement of magnetic properties.
- Al is made 0.0008% or more. It is preferably 0.015% or more, more preferably 0.020% or more.
- Al is 0.065%. % Or less. It is preferably 0.060% or less, more preferably 0.055% or less.
- S 0.0001 to 0.013%
- S is an element that forms fine sulfides and inhibits iron loss characteristics. A smaller amount of S is more preferable, but the detection limit is about 0.0001%, so S is made 0.0001% or more. It is preferably 0.003% or more, more preferably 0.005% or more.
- S is made 0.013% or less. It is preferably 0.010% or less, more preferably 0.005% or less.
- the slab of the present invention may contain Cu in an amount of 0.01 to 0.80% in order to improve magnetic properties.
- the lower limit of Cu is 0%.
- Cu 0.01 to 0.80% Cu is an element that combines with S to form a precipitate that functions as an inhibitor. If it is less than 0.01%, the effect of addition is not sufficiently obtained, so Cu is set to 0.01% or more. It is preferably 0.04% or more, more preferably 0.08% or more.
- Cu is made 0.80% or less. It is preferably 0.60% or less, more preferably 0.50% or less.
- the balance other than the above elements is Fe and impurities, but N: 0.004 to 0.0120%, P: 0.02 to 0. 50% or less, Ni: 0.02 to 1.00% or less, Sn: 0.02 to 0.30% or less, Sb: 0.02 to 0.30% or less, and one or more kinds are contained. Good. However, since they do not have to be contained, the lower limits of these elements are 0%.
- N 0.004 to 0.0120%
- N is an element that forms AlN that functions as an inhibitor, but is also an element that forms blisters (holes) in the steel sheet during cold rolling. If it is less than 0.004%, the formation of AlN is insufficient, so N is made 0.004% or more. It is preferably 0.006% or more, more preferably 0.007% or more.
- N is set to 0.0120% or less. It is preferably 0.010% or less, more preferably 0.009% or less.
- P 0.50% or less
- P is an element that increases the specific resistance of the steel sheet and contributes to the reduction of iron loss. If it exceeds 0.50%, the rolling property deteriorates, so P is made 0.50% or less. It is preferably 0.35% or less.
- the lower limit includes 0%, but 0.02% or more is preferable from the viewpoint of reliably obtaining the effect of addition.
- Ni 1.00% or less
- Ni is an element that increases the specific resistance of the steel sheet and contributes to the reduction of iron loss, controls the metal structure of the hot-rolled steel sheet, and contributes to the improvement of magnetic properties. If it exceeds 1.00%, the secondary recrystallization proceeds unstablely, so Ni is made 1.00% or less. It is preferably 0.25% or less.
- the lower limit includes 0%, but 0.02% or more is preferable from the viewpoint of reliably obtaining the effect of addition.
- Sn 0.30% or less
- Sb 0.30% or less
- Sn and Sb segregate at the grain boundaries
- Al is oxidized by the moisture released by the annealing separator during the finish annealing (this oxidation causes the coil position to change).
- the inhibitor strength is different, and the magnetic characteristics fluctuate).
- each element is 0.25% or less.
- the lower limit includes 0%, 0.02% or more is preferable for each element from the viewpoint of reliably obtaining the effect of addition.
- the slab having the above-described composition is subjected to normal hot rolling and wound as a hot rolled coil (hot rolling step).
- hot rolling step the hot-rolled coil is rewound, hot-rolled sheet annealing is performed (hot-rolled sheet annealing step), and then cold rolling is performed once, or cold rolling is performed a plurality of times with intermediate annealing interposed therebetween,
- the base steel sheet having the final thickness is used (cold rolling step), and decarburization annealing is performed.
- the decarburization annealing is performed by heating in wet hydrogen to reduce C in the base material steel sheet to a region where the deterioration of magnetic properties due to magnetic aging does not occur in the base material steel sheet in the product, and primary recrystallization is performed, Prepare for secondary recrystallization (decarburization annealing step).
- the decarburization annealing step further, before or during the holding, any one of the above, or at two or more stages, annealed in an atmosphere containing ammonia to nitride the cold-rolled steel sheet, nitriding. Processing may be performed.
- the decarburization annealing step preferably includes a nitriding treatment.
- inhibitors such as AlN and (Al,Si)N are generated before the secondary recrystallization in the finish annealing step, so that the secondary recrystallization can be stably performed. Can be expressed.
- the conditions of the nitriding treatment are not particularly limited, but it is preferable to perform the nitriding treatment so that the nitrogen content is increased by 0.003% or more, preferably 0.005% or more, more preferably 0.007% or more. Since the effect is saturated when the nitrogen (N) content is 0.030% or more, the nitriding treatment may be performed so as to be 0.030% or less.
- the conditions of the nitriding treatment are not particularly limited, and known conditions may be used. For example, when the nitriding treatment is performed after keeping the oxidation degree (PH 2 O/PH 2 ) at 0.01 to 0.15 and 750 to 900° C. for 10 to 600 seconds, the cold rolled steel sheet is cooled to room temperature.
- the temperature is maintained in an atmosphere containing ammonia during the temperature lowering process. It is preferable to set the degree of oxidation (PH 2 O/PH 2 ) in the range of 0.0001 to 0.01 in the process of lowering the temperature.
- PH 2 O/PH 2 degree of oxidation
- ammonia gas is added to the atmosphere gas having this oxidation degree. Just install it.
- the base steel sheet is subjected to finish annealing at a temperature of 1100° C. or higher.
- the finish annealing is performed in the form of a coil in which a base material steel plate is wound, but an annealing separator containing Al 2 O 3 as a main component for the purpose of preventing seizure of the base material steel plate and forming a primary coating on the surface of the base material steel plate. Is applied (finish annealing step).
- excess annealing separator is removed from the base steel sheet by washing with water, and then the base steel sheet is annealed in a mixed atmosphere of hydrogen and nitrogen in which oxygen partial pressure ( PH2O / PH2 ) is adjusted.
- oxygen partial pressure PH2O / PH2
- the glossiness affects iron loss, it is also important to control the oxygen partial pressure (P H2O 2 /P H2 ) in the annealing atmosphere for forming the amorphous oxide film. Therefore, the amorphous oxide oxygen partial pressure of the annealing atmosphere during film formation (P H2O / P H2) and parallel to the rolling direction of the gloss from the surface of the steel sheet after coating the tension insulating film (Gs20 (A)) I investigated the relationship.
- the oxygen partial pressure (P H2O /P H2 ) in the annealing atmosphere for forming the amorphous oxide film having the gloss (Gs20(A)) in the rolling parallel direction of 2.0 or more is 0.01 or less.
- the oxygen partial pressure (P H2O /P H2 ) of the annealing atmosphere capable of forming an amorphous oxide film having a gloss in the rolling parallel direction (Gs20(A)) of 15 or more is 0.005 or less
- the oxygen partial pressure (P H2O /P H2 ) of the annealing atmosphere capable of forming an amorphous oxide film having a gloss (Gs20(A)) in the rolling parallel direction of 50 or more is 0.001 or less. ..
- the annealing temperature is preferably 600 to 1150°C, more preferably 700 to 900°C. Further, by adjusting the oxygen partial pressure in the above-described intermediate annealing and finish annealing, the annealing after finish annealing may be omitted and the glossiness may be set to a desired range.
- the oxygen partial pressure (PH 2 O 3 /PH 2) during annealing cooling is controlled. ) Is preferably 0.005 or less.
- the groove width of the coating roll used when applying the coating liquid for the tension insulating film is 0.5 to 2.6 mm.
- the coating liquid can be applied uniformly, and as a result, the tension insulating coating is uniformly formed.
- the preferable range of the groove width is 1.0 to 2.0 mm.
- the depth of the groove of the coating roll is 0.2 to 1.0 mm.
- the coating liquid can be applied uniformly, as a result of the groove pitch, and as a result, the tension insulating coating can be formed uniformly. it can.
- the preferable range of the groove depth is 0.3 to 0.8 mm.
- the oxygen partial pressure (P H2O /P H2 ) in the baking step is preferably 0.008 or more and 0.200 or less.
- the condition in the example is one condition example adopted for confirming the feasibility and effect of the present invention, and the present invention is based on this one condition example. It is not limited.
- the present invention can adopt various conditions as long as the object of the present invention is achieved without departing from the gist of the present invention.
- Example 1 A silicon steel slab having the composition shown in Table 1 (the balance being Fe and impurities) was heated to 1100° C. and subjected to hot rolling to obtain a hot rolled steel sheet having a plate thickness of 2.6 mm, and the hot rolled steel sheet was annealed at 1100° C. After that, cold rolling was performed once to obtain a cold rolled steel sheet having a final thickness of 0.23 mm, and the cold rolled steel sheet was subjected to decarburization annealing and nitriding annealing.
- a cold-rolled steel sheet subjected to decarburization annealing and nitriding annealing was applied with a water slurry of an annealing separator mainly composed of alumina, and then subjected to finish annealing at 1200° C. for 20 hours, and a forsterite-based coating was applied to the steel sheet surface.
- a grain-oriented electrical steel sheet having no specular gloss and having completed secondary recrystallization was obtained.
- This grain-oriented electrical steel sheet was subjected to a soaking treatment at 800° C. for 30 seconds in an atmosphere composed of 25% nitrogen and 75% hydrogen and having an oxygen partial pressure (P H2O /P H2 ) of 0.0005 to 0.01. Then, a heat treatment for cooling to room temperature is performed in an atmosphere of nitrogen 25% and hydrogen 75% and an oxygen partial pressure (P H2O /P H2 ) of 0.0005 to 0.01, and the steel sheet surface is amorphous. An oxide film was formed. This was taken as an invention example. As a comparative example, an experiment in which the oxygen partial pressure is outside this range was also conducted. Table 3-3 shows the oxygen partial pressure conditions in each experimental example of Table 3-1 and Table 3-2.
- the grain-oriented electrical steel sheet on which this amorphous oxide film is formed is coated with a coating liquid for forming a tension insulating film consisting of aluminum phosphate and colloidal silica with a groove width of 1.27 mm and a groove depth of 0.63 mm.
- a coating liquid for forming a tension insulating film consisting of aluminum phosphate and colloidal silica with a groove width of 1.27 mm and a groove depth of 0.63 mm.
- Table 2 shows the composition of the base steel sheet (the balance being Fe and impurities).
- the numerical values with " ⁇ " added in the table of the present example were measured with the content being controlled, and the production was performed, but the measured value having sufficient reliability as the content is It means that it was not obtained (the measurement result is below the detection limit).
- the iron loss (W17/50) of a sample taken from the produced grain-oriented electrical steel sheet with a tension insulating coating was evaluated.
- the iron loss of 0.90 W/kg or less was evaluated as Good, the iron loss of 0.90 or more and less than 1.00 W/kg was evaluated as OK, and the iron loss of 1.00 W/kg or more was evaluated as NG.
- the test piece taken from the produced grain-oriented electrical steel sheet with a tension insulating coating was wound around a cylinder having a diameter of 20 mm (bending 180°), and the coating adhesion of the tension insulating coating was evaluated by the area ratio of the coating remaining when it was bent back. ..
- the coating adhesion of the tension insulating film the presence or absence of peeling of the tension insulating film was judged visually. Without peeling from the steel sheet, the coating residual area ratio was 90% or more as GOOD, 80% or more and less than 90% as OK, and less than 80% as NG.
- the surface gloss of the grain-oriented electrical steel sheet with a tension insulating coating is measured using a BYK-Gardner Micro Trigloss Glossmeter (4446) and specified in JIS Z 8741 (black glass standard plate at an incident angle of 20°).
- the glossiness in the rolling parallel direction (Gs20(A)) and the glossiness in the rolling vertical direction (Gs20(B)) were measured by (method of defining the measured value of the refractive index of 1.567 as 100).
- Tables 3-1 and 3-2 show the evaluation results of glossiness, iron loss and adhesion.
- Gs20(A), which is the gloss in the direction parallel to the rolling direction, and Gs20(B), which is the gloss in the direction perpendicular to the rolling direction, are both 2.0 to 70.0. When it is, it is understood that good iron loss and coating adhesion are obtained.
- Example 2 A silicon steel slab having the composition shown in Table 1 was heated to 1100° C. and hot-rolled to obtain a hot-rolled steel sheet having a plate thickness of 2.6 mm. The hot-rolled steel sheet was annealed at 1100° C., and then once. Was cold-rolled to give a cold-rolled steel sheet having a final thickness of 0.23 mm, and the cold-rolled steel sheet was subjected to decarburization annealing and nitriding annealing.
- a cold-rolled steel sheet subjected to decarburization annealing and nitriding annealing was applied with a water slurry of an annealing separator mainly composed of alumina, and then subjected to finish annealing at 1200° C. for 20 hours, and a forsterite-based coating was applied to the steel sheet surface.
- a grain-oriented electrical steel sheet having no specular gloss and having completed secondary recrystallization was obtained.
- This grain-oriented electrical steel sheet was subjected to a soaking treatment at 800° C. for 30 seconds in an atmosphere composed of 25% nitrogen and 75% hydrogen and having an oxygen partial pressure (P H2O /P H2 ) of 0.0005 to 0.01. Then, a heat treatment for cooling to room temperature is performed in an atmosphere composed of 25% nitrogen and 75% hydrogen and having an oxygen partial pressure (P H2O 2 /P H2 ) shown in Table 4, and the steel sheet surface is amorphous. An oxide film was formed.
- the grain-oriented electrical steel sheet on which this amorphous oxide film was formed was coated with a coating liquid for forming a tension insulating film consisting of aluminum phosphate and colloidal silica using a grooved coating roll having the groove pitch and groove depth shown in Table 4. Then, it was baked at 850° C. for 30 seconds to produce a grain-oriented electrical steel sheet with a tension insulating coating.
- Table 5 shows the component composition of the base steel sheet, the glossiness in the rolling parallel direction and the rolling vertical direction, the iron loss and the adhesion.
- the present invention it is possible to provide a grain-oriented electrical steel sheet with a tensile insulating coating having good iron loss. Therefore, the present invention is highly applicable in the electromagnetic steel sheet manufacturing industry and the electromagnetic steel sheet utilizing industry.
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Abstract
Description
本願は、2019年1月16日に日本に出願された特願2019-005475号に基づき優先権を主張し、その内容をここに援用する。
本発明は、従来技術の現状に鑑みてなされたものであり、フォルステライト系被膜を除去するか、又は、フォルステライトの生成を意図的に防止して母材鋼板表面にフォルステライト系被膜がない方向性電磁鋼板の表面に張力絶縁被膜を被覆する際、張力絶縁被膜と母材鋼板との密着性を高め、鉄損を大幅に低減させることを課題とし、該課題を解決できる方向性電磁鋼板を提供することを目的とする。
(2)上記(1)に記載の方向性電磁鋼板は、前記母材鋼板が、前記化学組成として、質量%で、Cu:0.01~0.80%を含有してもよい。
(3)上記(1)又は(2)に記載の方向性電磁鋼板は、前記母材鋼板が、前記化学組成として、質量%で、N:0.001~0.012%、P:0.010~0.50%、Ni:0.010~1.00%、Sn:0.010~0.30%、及び、Sb:0.010~0.30%の1種又は2種以上を含有してもよい。
なお、圧延方向と平行な方向で測定したGs20をGs20(A)、圧延方向と垂直な方向で測定したGs20をGs20(B)と呼称する場合がある。
本実施形態に係る方向性電磁鋼板は、母材鋼板を備える。まず、母材鋼板の成分組成について説明する。以下、成分組成に係る%は「質量%」である。
C:0.085%以下
Cは、一次再結晶組織の制御に有効な元素であるが、磁気時効で鉄損を大きくする元素である。そのため、仕上げ焼鈍前に脱炭焼鈍で、C含有量を0.010%未満にまで低減する必要がある。
C含有量が0.085%を超えると、脱炭焼鈍に長時間を要し、生産性が低下するので、C含有量は0.085%以下とする。好ましくは0.070%以下、より好ましくは0.050%以下である。
下限は特に限定しないが、一次再結晶組織を安定的に制御する点で、0.050%以上が好ましい。
Siは、鋼板の電気抵抗を高くして、鉄損を小さくする元素である。Si含有量が0.80%未満であると、含有させる効果が十分に得られない。また、二次再結晶焼鈍時に相変態が生じて、二次再結晶を適確に制御できず、結晶方位が損なわれて、磁気特性が低下する。そのため、Si含有量は0.80%以上とする。好ましくは2.50%以上、より好ましくは3.00%以上である。
Mn含有量が1.50%を超えると、二次再結晶焼鈍時に相変態し、良好な磁束密度が得られない。そのため、Mn含有量は1.50%以下とする。好ましくは1.20%以下、より好ましくは0.90%以下である。
Alが0.065%を超えると、粗大な(Al、Si)Nが析出したり、(Al、Si)Nの析出が不均一になったりする。その結果、所要の二次再結晶組織が得られず、磁束密度が低下する。そのため、酸可溶性Al含有量は0.065%以下とする。好ましくは0.055%以下、より好ましくは0.045%以下である。Al含有量は0%でもよい。
一方、酸可溶性Alは、Nと結合し、インヒビターとして機能する(Al、Si)Nを形成する元素である。そのため、製造に用いるスラブにおいて、酸可溶性Alが0.010%未満であると、十分な量の(Al、Si)Nが形成されず、二次再結晶が安定しない。そのため、製造に用いるスラブにおける酸可溶性Alは0.010%以上とすることが好ましく、このAlが鋼板に残存してもよい。スラブ中の酸可溶性Alの含有量は、より好ましくは0.002%以上、より好ましくは0.030%以上である。
S含有量が0.013%を超えると、MnSの析出分散が不均一になり、所要の二次再結晶組織が得られず、磁束密度が低下する。そのため、Sは0.013%以下とする。好ましくは0.012%以下、より好ましくは0.011%以下である。
一方、Sは、Mnと結合して、インヒビターとして機能するMnSを形成する元素である。そのため、製造に用いるスラブにおいて、S含有量を0.003%以上とすることが好ましく、このSが鋼板に残存してもよい。製造に用いるスラブにおいてS含有量は、より好ましくは0.005%以上、さらに好ましくは0.008%以上である。
Cu:0~0.80%
Cuは、Sと結合し、インヒビターとして機能する析出物を形成する元素である。Cu含有量が0.01%未満であると、効果が十分に発現しないので、Cuは0.01%以上が好ましい。より好ましくは0.04%以上である。
N:0~0.0120%
Nは、Alと結合して、インヒビターとしての機能するAlNを形成する元素である。
Pは、鋼板の比抵抗を高め、鉄損の低減に寄与する元素である。含有させる効果を確実に得る点では、P含有量は0.010%以上が好ましい。
一方、Pが0.50%を超えると、圧延性が低下する。そのため、P含有量は0.50%以下が好ましい。より好ましくは0.35%以下である。下限は0%を含むが、Pを0.0005%未満に低減すると、製造コストが大幅に上昇するので、実用鋼板上、0.0005%が実質的な下限である。
Niは、鋼板の比抵抗を高めて、鉄損の低減に寄与するとともに、熱延鋼板の金属組織を制御し、磁気特性の向上に寄与する元素である。下限は0%を含むが、含有させる効果を確実に得る点で、Ni含有量は0.010%以上が好ましい。
一方、Ni含有量が1.00%を超えると、二次再結晶が不安定に進行し、磁気特性が低下する。そのため、Ni含有量は1.00%以下が好ましい。より好ましくは0.35%以下である。
Sb:0~0.30%
Sn及びSbは、結晶粒界に偏析し、仕上げ焼鈍時、焼鈍分離剤が放出する水分でAlが酸化される(この酸化で、コイル位置でインヒビター強度が異なり、磁気特性が変動する)のを防止する作用をなす元素である。下限は0%を含むが、含有させる効果を確実に得る点で、いずれの元素の含有量も0.010%以上が好ましい。
一方、いずれの元素もその含有量が0.30%を超えると、二次再結晶が不安定となり、磁気特性が劣化する。そのため、Sn及びSbのいずれも0.30%以下が好ましい。より好ましくは、いずれの元素も0.25%以下である。
本実施形態に係る方向性電磁鋼板は、上述の母材鋼板上に非晶質酸化物被膜を備える。非晶質酸化物被膜とは、実質的に非晶質な酸化物のみからなる被膜である。被膜が酸化物を有するかどうかは、TEMやFT-IRを用いて確認できる。
外部酸化型ではなく、内部酸化型の非晶質酸化物被膜を形成すると、上記陥入部を起点として張力絶縁被膜が剥離する場合がある。
本実施形態に係る方向性電磁鋼板は、上述の非晶質酸化物被膜上に張力絶縁被膜を備える。張力絶縁被膜は、燐酸塩とコロイド状シリカ(SiO2)を主体とする溶液を塗布して焼付けて形成されるガラス質の絶縁被膜である。
この張力絶縁被膜により、母材鋼板に高い面張力を付与することができる。
次に、本実施形態に係る方向性電磁鋼板の製造方法について説明する。
C:0.085%以下
Cは、磁気時効によって鉄損特性を著しく劣化させる元素である。0.085%を超えると、脱炭焼鈍後も、Cが残留し、鉄損特性を劣化させるので、Cは0.085%以下とする。Cは、少ないほど鉄損特性にとって好ましいが、検出限界が0.0001%程度であるので、0.0001%が実質的な下限である。鉄損特性改善の観点から、Cは0.010%以下が好ましく、より好ましくは0.005%以下である。
Siは、磁気特性の向上に寄与する元素である。0.80%未満では、二次再結晶焼鈍時に鋼が相変態して、二次再結晶を制御することができず、良好な磁束密度と鉄損特性が得られないので、Siは0.80%以上とする。好ましくは2.50%以上、より好ましくは3.00%以上である。
Mnは、オーステナイト形成元素である。0.01%未満では、添加効果が十分に得られず、また、熱間圧延時に鋼板が脆化するので、Mnは0.01%以上とする。好ましくは0.05%以上、より好ましくは0.10%以上である。
Alは、インヒビターとして機能するAlNを形成し、磁気特性の向上に寄与する元素である。
Sは、微細な硫化物を形成し、鉄損特性を阻害する元素である。Sは、少ないほど好ましいが、検出限界が0.0001%程度であるので、Sは0.0001%以上とする。好ましくは0.003%以上、より好ましくは0.005%以上である。
Cuは、Sと結合し、インヒビターとして機能する析出物を形成する元素である。0.01%未満では、添加効果が十分に得られないので、Cuは0.01%以上とする。好ましくは0.04%以上、より好ましくは0.08%以上である。
Nは、インヒビターとして機能するAlNを形成する元素であるが、一方で、冷間圧延時、鋼板中にブリスター(空孔)を形成する元素でもある。0.004%未満では、AlNの形成が不十分となるので、Nは0.004%以上とする。好ましくは0.006%以上、より好ましくは0.007%以上である。
Pは、鋼板の比抵抗を高めて、鉄損の低減に寄与する元素である。0.50%を超えると、圧延性が低下するので、Pは0.50%以下とする。好ましくは0.35%以下である。下限は0%を含むが、添加効果を確実に得る点で、0.02%以上が好ましい。
Niは、鋼板の比抵抗を高めて、鉄損の低減に寄与するとともに、熱延鋼板の金属組織を制御し、磁気特性の向上に寄与する元素である。1.00%を超えると、二次再結晶が不安定に進行するので、Niは1.00%以下とする。好ましくは0.25%以下である。下限は0%を含むが、添加効果を確実に得る点で、0.02%以上が好ましい。
Sb:0.30%以下
Sn及びSbは、結晶粒界に偏析し、仕上げ焼鈍時、焼鈍分離剤が放出する水分でAlが酸化される(この酸化で、コイル位置でインヒビター強度が異なり、磁気特性が変動する)のを防止する作用をなす元素である。いずれの元素も0.30%を超えると、脱炭焼鈍時に酸化層が形成され難く、グラス被膜の形成が不十分となるので、Sn及びSbのいずれも0.30%以下とする。好ましくは、いずれの元素も0.25%以下である。下限は0%を含むが、添加効果を確実に得る点で、いずれの元素も0.02%以上が好ましい。
なお、結果は示さないが、圧延垂直方向の光沢度(Gs20(B))もGs20(A)と同様の結果を示した。
コーティングロールの溝幅やコーティングロールの溝の深さを制御することで、所望の光沢度の調整が容易になる。なお、張力絶縁被膜を形成することで、方向性電磁鋼板としての光沢度が若干低下する。また、鋼板の長手方向(圧延方向)とコーティングロールの溝の延在方向とが平行となる塗布方法が一般的である。
表1に示す成分組成(残部はFe及び不純物)の珪素鋼スラブを1100℃に加熱して熱間圧延に供し、板厚2.6mmの熱延鋼板とし、該熱延鋼板に1100℃で焼鈍を施し、その後、一回の冷間圧延を施して、最終板厚0.23mmの冷延鋼板とし、該冷延鋼板に、脱炭焼鈍と窒化焼鈍を施した。
母材鋼板の成分組成(残部はFe及び不純物)を表2に示す。なお、本実施例の表で「≦」を付記した数値は、含有量を意識した制御及び製造を実施して含有量の測定を実施したが、含有量として十分な信頼性を有する測定値が得られなかったこと(測定結果が検出限界以下であること)を示す。
表1に示す成分組成の珪素鋼スラブを1100℃に加熱して熱間圧延に供し、板厚2.6mmの熱延鋼板とし、該熱延鋼板に1100℃で焼鈍を施し、その後、一回の冷間圧延を施して、最終板厚0.23mmの冷延鋼板とし、該冷延鋼板に、脱炭焼鈍と窒化焼鈍を施した。
次いで、脱炭焼鈍と窒化焼鈍を施した冷延鋼板に、アルミナを主体とする焼鈍分離剤の水スラリーを塗布して、1200℃、20時間の仕上げ焼鈍を施し、鋼板表面にフォルステライト系被膜がなく、鏡面光沢を有する、二次再結晶が完了した方向性電磁鋼板を得た。
Claims (3)
- 母材鋼板と;
前記母材鋼板上に形成された非晶質酸化物被膜と;
前記非晶質酸化物被膜上に形成された張力絶縁被膜と;
を有し、
前記母材鋼板が、化学組成として、質量%で、
C:0.085%以下、
Si:0.80~7.00%、
Mn:1.50%以下、
酸可溶性Al:0.065%以下、
S:0.013%以下、
Cu:0~0.80%、
N:0~0.012%、
P:0~0.50%、
Ni:0~1.00%、
Sn:0~0.30%、
Sb:0~0.30%、
を含有し、
残部がFe及び不純物からなり、
圧延方向に平行な方向の表面光沢度Gs20(A)が2.0~70.0であり、かつ、前記圧延方向に垂直な方向の表面光沢度Gs20(B)が2.0~70.0である
ことを特徴とする方向性電磁鋼板。 - 前記母材鋼板が、前記化学組成として、質量%で、Cu:0.01~0.80%を含有することを特徴とする請求項1に記載の方向性電磁鋼板。
- 前記母材鋼板が、前記化学組成として、質量%で、N:0.001~0.012%、P:0.010~0.50%、Ni:0.010~1.00%、Sn:0.010~0.30%、及び、Sb:0.010~0.30%の1種又は2種以上を含有することを特徴とする請求項1又は2に記載の方向性電磁鋼板。
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- 2020-01-16 WO PCT/JP2020/001183 patent/WO2020149342A1/ja unknown
- 2020-01-16 JP JP2020566460A patent/JP7151791B2/ja active Active
- 2020-01-16 EP EP20741646.2A patent/EP3913099A4/en active Pending
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RU2771036C1 (ru) | 2022-04-25 |
JP7151791B2 (ja) | 2022-10-12 |
CN113286911A (zh) | 2021-08-20 |
EP3913099A1 (en) | 2021-11-24 |
KR20210111287A (ko) | 2021-09-10 |
JPWO2020149342A1 (ja) | 2021-11-25 |
EP3913099A4 (en) | 2022-09-28 |
KR102582981B1 (ko) | 2023-09-26 |
US20220119906A1 (en) | 2022-04-21 |
BR112021013725A2 (pt) | 2021-09-21 |
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