WO2019230764A1 - Procédé antifongique pour fruits et composition antifongique pour fruits - Google Patents

Procédé antifongique pour fruits et composition antifongique pour fruits Download PDF

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Publication number
WO2019230764A1
WO2019230764A1 PCT/JP2019/021228 JP2019021228W WO2019230764A1 WO 2019230764 A1 WO2019230764 A1 WO 2019230764A1 JP 2019021228 W JP2019021228 W JP 2019021228W WO 2019230764 A1 WO2019230764 A1 WO 2019230764A1
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Prior art keywords
water
fruits
fruit
antifungal
nanobubble
Prior art date
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PCT/JP2019/021228
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English (en)
Japanese (ja)
Inventor
祐一 奥山
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株式会社アクアソリューション
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Priority to JP2020522234A priority Critical patent/JPWO2019230764A1/ja
Publication of WO2019230764A1 publication Critical patent/WO2019230764A1/fr

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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/34—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23B—PRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
    • A23B9/00—Preservation of edible seeds, e.g. cereals
    • A23B9/16—Preserving with chemicals
    • A23B9/18—Preserving with chemicals in the form of gases, e.g. fumigation; Compositions or apparatus therefor
    • A23B9/20—Preserving with chemicals in the form of gases, e.g. fumigation; Compositions or apparatus therefor in a controlled atmosphere, e.g. partial vacuum, comprising only CO2, N2, O2 or H2O
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23B—PRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
    • A23B9/00—Preservation of edible seeds, e.g. cereals
    • A23B9/16—Preserving with chemicals
    • A23B9/18—Preserving with chemicals in the form of gases, e.g. fumigation; Compositions or apparatus therefor
    • A23B9/22—Preserving with chemicals in the form of gases, e.g. fumigation; Compositions or apparatus therefor in a controlled atmosphere comprising other gases in addition to CO2, N2, O2 or H2O
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23B—PRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
    • A23B9/00—Preservation of edible seeds, e.g. cereals
    • A23B9/16—Preserving with chemicals
    • A23B9/24—Preserving with chemicals in the form of liquids or solids
    • A23B9/26—Organic compounds; Microorganisms; Enzymes

Definitions

  • the present invention relates to a fruit mold prevention method and a fruit mold prevention composition.
  • an antifungal agent is often applied to fruits before harvesting or after harvesting.
  • Patent Document 1 states that “a spoilage for fruits and vegetables characterized by containing capilin and polyphenol”. Prevention composition "and its utilization method are described (see” Claim 1 "of Patent Document 1 and” Example “in the specification). According to the anti-corruption composition for fruits and vegetables described in Patent Document 1 described above, the occurrence and growth of mold can be suppressed, and the decay of fruits and vegetables can be suppressed, and as a result, the decline in the commercial value of fruits and vegetables can be prevented. Is possible.
  • the present invention provides a fruit mold prevention method and a fruit mold prevention composition that can improve the mold prevention effect on fruits without increasing the amount of use of the fungicide and changing the composition. This is the issue.
  • the present inventor applied the antifungal agent and nanobubble water to the fruit without increasing the amount of the antifungal agent used or changing the composition.
  • the present inventors have found that the antifungal effect is improved and completed the present invention. That is, the present inventor has found that the above problem can be achieved by the following configuration.
  • a method for preventing fungi of fruits which comprises applying a fungicidal agent and nanobubble water to a plant body from which fruits grow.
  • fungus prevention method for fruits and a fungicidal composition for fruits that can improve the fungicidal effect on fruits without increasing the amount of use of the fungicides or changing the composition. Can do.
  • FIG. 1 It is a schematic diagram which shows an example of a nano bubble production
  • a numerical range expressed using “to” means a range including numerical values described before and after “to” as a lower limit value and an upper limit value.
  • the antifungal method for fruits according to the present invention is an antifungal method for fruits by applying an antifungal agent and nanobubble water to the plant body from which the fruit grows.
  • the “plant body from which the fruit grows” refers to a tree (fruit tree) and a grass from which the fruit grows.
  • the fruit may be an edible fruit or an ornamental fruit.
  • the molds whose generation and growth are suppressed by the present invention are molds generated in fruits, specifically, for example, citrus blue mold fungus (Penicillium italicum), citrus green mold bacterium (Penicillium digitium), and Molds caused by apple blue mold (Penicillium expansum) and the like; molds caused by gray mold disease (Botrytis cinerea) and the like.
  • the “antifungal agent” is an agent for preventing or removing at least one of generation and growth of mold, and is also called an antifungal agent (antifungal agent), which is diluted or dissolved. Applied in a wet state (ie liquid).
  • the fungicide may be one that develops a medicinal effect by being attached to at least a part of the leaves, stems and fruits of the plant body, or the plant body after being sown in a medium such as soil. It may exhibit medicinal effects by absorption through the roots.
  • fungicide examples include, for example, thiophanate methyl, iminotacdine acetate, benomyl, TOPJIN M wettable powder, BEFTOPJIN flowable, BEFRAN liquid 25, and benzimidazole effective against blue mold.
  • Benrate wettable powder etc .; Effective against gray mold fungus, Topgin M wettable powder, Benrate wettable powder, Sumirex wettable powder, Robral wettable powder, Getter wettable powder, Sumiblend wettable powder, Polyoxin AL emulsion, Polyberine wettable powder , Diamerit DF, Berkut wettable powder, Titan flowable 20, Flupica flowable, Scarla flowable, Amister 20 flowable, Strobe dry drytable, Password granule wettable powder, Just meat granule wettable powder, Dimadine, Triazine wettable powder 50 , Botokiller wettable powder, Ecoshot, Botopica wettable powder, Qantas dry flowable, and Daconyl 1000 which is an organic chlorine-based agent.
  • Topgin M wettable powder Benrate wettable powder, Sumirex wettable powder, Robral wettable powder, Getter wettable powder, Sumiblend wettable powder, Polyoxin AL
  • the fungicide is mainly used for the purpose of suppressing the occurrence and growth of mold in the harvested fruit, but during the growth before harvesting (especially during the period from fruiting time to harvesting) It may be used for the purpose of suppressing the occurrence and growth of mold.
  • the “nano bubble water” used in the method for preventing mold of fruits of the present invention is water containing bubbles having a diameter of less than 1 ⁇ m, and more precisely, water in which nano bubbles are mixed.
  • water mixed with nanobubbles water used to generate nanobubble water (raw water of nanobubble water, for example, well water containing impurities), which is unavoidable due to its properties, etc.
  • water containing nanobubbles is excluded from the above-mentioned “water mixed with nanobubbles”.
  • the bubble diameter (particle diameter) contained in the nanobubble water, and the mode particle diameter and the number of bubbles described later are values obtained by measuring the Brownian movement speed of the bubbles in water using the nanoparticle tracking analysis method.
  • numerical values measured by the nanoparticle analysis system Nanosite Series are adopted.
  • the diameter (particle diameter) can be calculated from the speed of the Brownian motion of the particle, and the mode particle diameter exists.
  • the mode diameter can be confirmed from the particle size distribution of the nanoparticles.
  • the antifungal agent and nanobubble water are applied to the plant body from which the fruit grows, thereby increasing the amount of the antifungal agent used or changing the composition. Even if it does not do, the mold prevention effect with respect to a fruit improves.
  • the mode particle diameter of the bubbles contained in the nanobubble water is preferably 10 to 500 nm, more preferably 30 to 300 nm, and particularly 70. More preferably, it is ⁇ 130 nm.
  • the gas constituting the bubbles contained in the nanobubble water is not particularly limited, but a gas other than hydrogen is preferable from the viewpoint of remaining in water for a long time, and specifically, for example, air, oxygen, nitrogen, fluorine, carbon dioxide And ozone.
  • a gas other than hydrogen is preferable from the viewpoint of remaining in water for a long time, and specifically, for example, air, oxygen, nitrogen, fluorine, carbon dioxide And ozone.
  • at least one gas selected from the group consisting of oxygen, nitrogen, ozone and carbon dioxide is included from the viewpoint of further improving the antifungal effect, and in particular, the bubbles remain for a longer time. Therefore, it is more preferable to include at least one of oxygen and ozone.
  • including at least one of oxygen and ozone means including at a concentration higher than the concentration of the gas in the air. The same applies to nitrogen and carbon dioxide.
  • concentration of oxygen it is preferable that it is 30 volume% or more in a bubble, and it is more preferable that it is more than 50 volume% and 100 volume% or less.
  • the ozone concentration is preferably 0.5 ppm or more, and more preferably 1 ppm or more.
  • the nanobubble water preferably has 1 ⁇ 10 8 bubbles / mL to 1 ⁇ 10 10 bubbles / mL. reasons balance of remaining becomes good, 1 ⁇ 10 more than 8 / mL, and more preferably has less bubbles than 1 ⁇ 10 10 cells / mL, 5 ⁇ 10 8 cells / mL ⁇ 5 It is more preferable to have ⁇ 10 9 bubbles / mL.
  • the nano bubble water may contain other components other than water and bubbles.
  • the other components include fertilizers and agricultural chemicals (excluding antifungal agents).
  • the kind and content of other components in the nanobubble water are not particularly limited and can be selected according to the purpose.
  • radicals are not substantially contained in the nanobubble water as the other component.
  • the case where radicals are inevitably included due to the water used for the generation of nanobubble water (for example, well water containing impurities) It is substantially free of radicals ”.
  • a case where a radical generated by some artificial manipulation is mixed does not mean that the radical is not substantially contained.
  • the method for producing the nanobubble water examples include a static mixer method, a venturi method, a cavitation method, a vapor agglomeration method, an ultrasonic method, a swirl flow method, a pressure dissolution method, and a micropore method.
  • the antifungal method for fruits according to the present invention may include a generation step of generating the nanobubble water before applying the nanobubble water. That is, the method for preventing mold of fruits according to the present invention includes, for example, a generation step of taking water from a water source such as a water storage tank, a well, or agricultural water into a nanobubble generating device to generate nanobubble water, and the generated nanobubble water and mold prevention.
  • An antifungal method having an application step of applying an agent may be used.
  • a method of taking water from the water source into the nano bubble generating device for example, a method of supplying water pumped up from the water source to the nano bubble generating device using a dredger or a pump, and between the water source and the nano bubble generating device
  • a method may be used in which the laid channel is connected to a nanobubble generator and water is directly sent from the channel to the nanobubble generator.
  • a generation method using an apparatus that does not intentionally generate radicals is preferable, and specifically, for example, [0080] to [0080] in JP-A-2018-15715. [0100] A method of generating using the nanobubble generating device described in the paragraph is mentioned. The above contents are incorporated herein.
  • Nanobubble generation devices that do not intentionally generate radicals include, for example, a liquid discharger that discharges water, a gas mixer that pressurizes and mixes gas into water discharged from the liquid discharger, and A microbubble generator for generating microbubbles in water by passing water mixed with gas inside, wherein the gas mixer includes the liquid ejector and the microbubble generator There is a fine bubble generating device that pressurizes and mixes gas into the liquid flowing toward the fine bubble generator in a pressurized state between the vessels.
  • the nanobubble generating device 10 illustrated in FIG. 1 includes a liquid discharger 30, a gas mixing device 40, and a nanobubble generating nozzle 50 therein.
  • the liquid discharger 30 is configured by a pump, and takes in and discharges nanobubble water raw water (for example, well water).
  • the gas mixing device 40 includes a container 41 in which compressed gas is sealed and a substantially cylindrical gas mixing device main body 42. While flowing water discharged from the liquid discharge device 30 into the gas mixing device main body 42, The compressed gas in the container 41 is introduced into the gas mixing machine main body 42. As a result, gas-containing water is generated in the gas-mixing machine main body 42.
  • the nanobubble generating nozzle 50 generates nanobubbles in the gas-mixed water according to the principle of pressure dissolution by passing the gas-mixed water through the nozzle, and the structure thereof is described in JP-A-2018-15715.
  • the same structure as the nanobubble generating nozzle made can be adopted.
  • the nanobubble water generated in the nanobubble generating nozzle 50 is ejected from the tip of the nanobubble generating nozzle 50, then flows out from the nanobubble generating device 10, and is sent toward a predetermined usage destination through a flow path (not shown).
  • the gas mixing device 40 is compressed into water (raw water) flowing toward the nanobubble generating nozzle 50 in a pressurized state between the liquid discharger 30 and the nanobubble generating nozzle 50. Mix gas.
  • the gas since the gas is mixed in the water in a pressurized (compressed) state, the gas can be mixed against the pressure of the water at the gas mixing location. For this reason, it becomes possible to mix gas into water appropriately, without generating a negative pressure especially in a gas mixing location.
  • a flow path of water supplied from a water source such as a well or water supply is connected to the suction side of the liquid discharger 30 and flows into the liquid discharger 30 from the upstream side of the liquid discharger 30 in the flow path.
  • the water pressure (that is, the water pressure on the suction side) may be positive. In this case, the above configuration becomes more meaningful.
  • the water (raw water) used for the production of the nanobubble water is not particularly limited.
  • surface water such as rain water, tap water, well water, river water, agricultural water, pure water, ultrapure water, and Distilled water or the like can be used.
  • Such water may have been subjected to other treatments before being used for generation of nanobubble water.
  • other treatments include pH adjustment, precipitation, filtration, and sterilization (sterilization).
  • the agricultural water after at least one of precipitation and filtration may be used.
  • the application mode of the antifungal agent and the nanobubble water is not particularly limited because it varies depending on the cultivation method of the plant body.
  • an application mode during the growth of the plant body for example, spraying in soil cultivation , Mixed in a culture solution used for hydroponics (hydroponics, spray plowing, or solid medium plowing), watering (irrigation) in hydroponic soil cultivation (simultaneous fertilization cultivation), and the like.
  • spraying in soil cultivation the above-mentioned antifungal agent and the above nanobubble water may be directly attached to a plant body, or may be seeded on a medium such as soil and absorbed from the medium to the plant body.
  • an aspect of spraying the antifungal agent and the nanobubble water on the plant body an aspect of spraying the antifungal agent diluted with the nanobubble water, and an antifungal agent and the plant body, The aspect which sprays the said nano bubble water separately at a respectively different timing is mentioned.
  • the spraying method is not particularly limited, and is a method of spraying and spraying with a spray or the like, a method of spraying or dropping from the top of a plant, or a pressure from a nozzle of a sprinkler. Any method such as a method of spraying and spraying and spraying may be used.
  • the timing of applying the antifungal agent and the nanobubble water is not particularly limited because it differs depending on the type of antifungal agent and the type of fruit, but for example, one period from sowing to harvesting It is preferably applied in part or in whole, more preferably 1 to several months before harvesting.
  • a lot of rain falls after application of a fungicide it is good to reapply the said fungicide and the said nano bubble water after the day when rain stopped.
  • the plant body to which the fungicide and the nanobubble water are applied is not particularly limited as long as the plant body is capable of generating mold, and for example, a fruit capable of generating blue mold is produced.
  • the plant body and the plant body where the fruit which can develop gray mold disease grows are mentioned.
  • citrus plants for example, mandarin oranges, kumquats, karatatachi, daidai, pomelo, lemon, lime, yuzu, orange, and grapefruit
  • vine plants for example, grapes
  • rose family plants Eg, apples, pears, pears, cherries, peaches, ume, plums, and loquats
  • oysters eg, oysters
  • scallops eg, bananas
  • camphors eg, cypresses
  • avocados etc.
  • pineapples eg, pineapples
  • papayas eg, papayas
  • urushis eg, mangoes
  • matabidae eg, kiwifruits
  • mulberrys Fruit trees (eg figs);
  • Cucurbitaceae plants for example, cucumbers, melons, watermelons, and cucumbers
  • solanaceous plants for example, eggplants, tomatoes (including cherry tomatoes), and peppers
  • roses for example,
  • plants comprising fruits that are matured by being stored in a warehouse after harvesting (for example, fruit trees of citrus plants, oysters, pears, kiwi fruits, bananas, papayas, mangoes, peaches, etc.)
  • fruits are usually stored in a dense state in a warehouse, when mold occurs in some individuals, the mold tends to propagate to other individuals. If it is such a situation, the fungi prevention method of the fruit of this invention which can improve the fungi prevention effect of a fruit will become more meaningful.
  • a citrus family plant is more preferable among the plant bodies in which the fruit which matures by being stored in a warehouse after a harvest arises, and a mandarin orange is still more preferable.
  • composition for mold prevention of fruits The fruit fungus composition of the present invention (hereinafter also simply referred to as “the composition of the present invention”) is a composition containing nanobubble water and a fungicide.
  • the nanobubble water and the antifungal agent are respectively the same as the nanobubble water and the antifungal agent described in the fruit antifungal method of the present invention described above.
  • the composition of this invention may contain the other component demonstrated with the antifungal method of the fruit of this invention mentioned above.
  • the “base material” means a component contained in excess of 50% by mass with respect to the total mass of the liquid content (components other than the solid content) contained in the composition, and 70% by mass of the liquid content. It is preferably contained in an amount of 90% by mass or more, more preferably 99% by mass or more.
  • the content of the fungicide is not particularly limited, but is preferably 0.00001 to 10 parts by mass with respect to 100 parts by mass of the nanobubble water, and 0.00005 to 5 More preferably, it is part by mass.
  • Test area I Antifungal agents (drug name: Topgin M and Omitite wettable powder) were diluted 2000 times with nanobubble water and sprayed on the mandarin fruit before harvest (November 2017).
  • Test area II Antifungal agents (drug name: Topgin M and Omitite wettable powder) were diluted 2000 times with normal tap water and sprayed on the mandarin fruit before harvest (November 2017). In each test area, seven mandarin orange trees were planted. In addition, about the application
  • Nanobubble water generates bubbles (nanobubbles) in water using a nanobubble generator (Kakuichi Seisakusho Aqua Solution Division (currently Aqua Solution Co., Ltd., 100 V, 10 L / min type) under pressure and dissolution. It was generated by letting.
  • the water (raw water) used for producing the nanobubble water was tap water, and the type of gas constituting the bubbles was oxygen (industrial oxygen, concentration: 99.5% by volume).
  • the conditions for generating nanobubbles using the nanobubble generating apparatus described above were as follows. Number of bubbles per mL of water: 5 ⁇ 10 8 / mL Bubble size (mode particle diameter): 100 nm

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Zoology (AREA)
  • Wood Science & Technology (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Environmental Sciences (AREA)
  • Food Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Dentistry (AREA)
  • Polymers & Plastics (AREA)
  • Microbiology (AREA)
  • Toxicology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Storage Of Fruits Or Vegetables (AREA)
  • Cultivation Of Plants (AREA)

Abstract

La présente invention aborde le problème consistant à fournir un procédé antifongique pour fruits et une composition antifongique pour fruits qui sont capables d'améliorer l'effet antifongique sur des fruits y compris sans augmenter la quantité d'agent antifongique utilisée ou changer la composition. Ce procédé antifongique pour fruits consiste à appliquer un agent antifongique et des nanobulles d'eau sur des plantes qui produisent des fruits.
PCT/JP2019/021228 2018-05-30 2019-05-29 Procédé antifongique pour fruits et composition antifongique pour fruits WO2019230764A1 (fr)

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JP2020522234A JPWO2019230764A1 (ja) 2018-05-30 2019-05-29 果実の防カビ方法、及び果実の防カビ用組成物

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JP2018103178 2018-05-30
JP2018-103178 2018-05-30

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0624916A (ja) * 1992-07-06 1994-02-01 Dainippon Ink & Chem Inc カンキツ貯蔵病害防除剤
JP2006213665A (ja) * 2005-02-04 2006-08-17 Mitsui Chemicals Inc 植物病害防除組成物及びその防除方法
JP2016053004A (ja) * 2014-09-03 2016-04-14 サンスター株式会社 希釈農薬の調整方法及び希釈農薬

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4660516B2 (ja) * 2007-08-30 2011-03-30 シャープ株式会社 抗菌水生成装置
CA2767993C (fr) * 2009-08-06 2018-06-26 Sunstar Giken Kabushiki Kaisha Composition et son procede de fabrication
JPWO2018003087A1 (ja) * 2016-06-30 2019-04-18 マルハニチロ株式会社 塩素系殺菌剤と微細気泡を組み合わせた殺菌剤、及び殺菌方法
JP2018075240A (ja) * 2016-11-10 2018-05-17 国立大学法人 東京大学 微生物の殺菌・静菌および昆虫や病害虫の防除を行う数気圧の加圧により大気に開放された水中に発生させるｃｏ２マイクロ・ナノバブル水

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0624916A (ja) * 1992-07-06 1994-02-01 Dainippon Ink & Chem Inc カンキツ貯蔵病害防除剤
JP2006213665A (ja) * 2005-02-04 2006-08-17 Mitsui Chemicals Inc 植物病害防除組成物及びその防除方法
JP2016053004A (ja) * 2014-09-03 2016-04-14 サンスター株式会社 希釈農薬の調整方法及び希釈農薬

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TW202002796A (zh) 2020-01-16

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